CN105145615A - Imidaclothiz-and-chlorfluazuron-containing pest killing composition and application thereof - Google Patents
Imidaclothiz-and-chlorfluazuron-containing pest killing composition and application thereof Download PDFInfo
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- CN105145615A CN105145615A CN201510638000.9A CN201510638000A CN105145615A CN 105145615 A CN105145615 A CN 105145615A CN 201510638000 A CN201510638000 A CN 201510638000A CN 105145615 A CN105145615 A CN 105145615A
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Abstract
The invention relates to an imidaclothiz-and-chlorfluazuron-containing pest killing composition and an application thereof. The composition contains imidaclothiz and chlorfluazuron, wherein the weight ratio of the imidaclothiz to the chlorfluazuron is 1-30 to 1-30. The composition can be applied to controlling agricultural pests of commercial crops, cereals and the like. The composition is wide in application range, good in effect, low in cost and residue and safe for people, livestock, the environment and the like.
Description
Technical field
The present invention relates to a kind of Pesticidal combination and application, particularly relate to a kind of Pesticidal combination and the application thereof that contain imidaclothiz and chlorfluazuron, be mainly used in the control of crop pest.
Background technology
Imidaclothiz (imidaclothiz, No. CAS is 105843-36-5) for being a kind of anabasine systemic insecticide, have tag, stomach toxicity and systemic action, there is wide spectrum, efficient, low toxicity, low-residual, insect not easily develop immunity to drugs, drug effect is by temperature limiting, feature to people and animals, agricultural and natural enemies security.The mechanism of action of imidaclothiz, mainly acts on nicotinic acetylcholine esterase acceptor, is mainly used in preventing and treating sucking pest, as aphid, leafhopper, plant hopper, thrips, aleyrodid and resistant strain thereof, also effective to coleoptera, diptera and lepidoptera pest.
Chlorfluazuron (chlorfluazuron, CAS 71422-67-8) is a kind of insect growth regulator, IGR class low toxic pesticide, based on stomach poison function, has action of contace poison concurrently, without interior absorption.Its insecticidal mechanism mainly suppresses chitin synthesis, hinders insect normally to cast off a skin, and make the hatching of ovum, larval molting and pupa development deformity, adult eclosion is obstructed, and finally causes insect dead.This medicine drug effect is high, but speed of action is comparatively slow, can not be very fast dead after larva contact medicament, but feeding activity obviously weakens, and generally within 3 ~ 5 days after medicine, just can reach preventive effect peak.High to insect insecticidal activities such as multiple lepidoptera pest and orthoptera, coleoptera, Hymenoptera, dipteras, but to aphid, plant hopper weak effect.Be applicable to the comprehensive regulation insecticides such as organic phosphates, pyrethroid, carbamate having been produced to the insect of resistance.
Can be there is many generations in 1 year in most pest, if a certain agricultural chemicals single variety of Long-Time Service, be easy to produce resistance.Science.Reasonably carry out two or more Pesticidal composition, just can solve resistance problem preferably.Also there is no at present imidaclothiz and the composite relevant report of chlorfluazuron at home and abroad.The present invention finds, should have synergistic function, and also can expand insecticidal spectrum after both mixtures.
Summary of the invention
An object of the present invention is to overcome above-mentioned deficiency, provide a kind of applied widely, effective, cost is low, the lasting period is long and have the Pesticidal combination containing imidaclothiz and chlorfluazuron of synergistic effect.
Two of object of the present invention is to provide a kind of Pesticidal combination containing imidaclothiz and chlorfluazuron for preventing and treating the application of various agricultural insect pest.
The object of the present invention is achieved like this:
Contain a Pesticidal combination for imidaclothiz and chlorfluazuron, the active component contained by described composition is imidaclothiz and chlorfluazuron, and the weight ratio of described imidaclothiz and chlorfluazuron is 1-30:1-30.
The preferred weight ratio of described imidaclothiz and chlorfluazuron is 2-20:3-20;
More preferably, the weight ratio of the two is 1-9:1-15;
Most preferred, the weight ratio of the two is 1:1.
Described combination dosage form is any one formulation that agricultural chemicals allows.Such as wetting powder, water dispersible granules, suspending agent, aqueous emulsion, missible oil or seed coat agent etc.
Described imidaclothiz and the percentage by weight of chlorfluazuron in above-mentioned formulation are 5 ~ 60%.
Another object of the present invention is to, a kind of application containing the Pesticidal combination of imidaclothiz and chlorfluazuron as above is provided, described Insecticidal combinations is prevented and treated agricultural insect pest for being used for, preferably, described insect pest is: beet armyworm (SpodopteraexiguaHiibner), cabbage pieris (PierisrapaeLinne), Brown Planthopper (Nilaparvatalugens), small brown rice planthopper (Laodelphaxstriatellus), white-backed planthopper (Sogatellafurcifera), thrips (Chloethripsoryzae), striped rice borer (Chilosuppressalis) peach fruit borer (CarposinaniponensisWalsingham), dichocrocis punctiferalis (Conogethespunctiferalis), black peach aphid (Myzuspersicae), Asiatic apple leafminer (LithocolletisringoniellaMats.), olethreutid (AdoxophyesoranaFishervonRoslerstamm), woolly aphid (Eriosomalanigerum), Against Conopomorpha sinensis Bradley (ConopomorphasinensisBradley), pear sucker (Psyllachinensis), pear mealworm (Aphanostigmajakusuiesie), oriental fruit moth (Grapholithamolesta (Busck)), the green cicada of tea leaflet (EmpoascapirisugaMatumura), tea geometrid (EctropisobliquehypulinaWehrli), grape clearwing moth (ParathreneregalisButler), hair siphon-worm (IlliberistenuisBatler), cowpea Americal rice leaf miner (Liriomyzasativae (Blanchard)), cotton bollworm (Helicoverpaarmigerar), wheat mythimna separata (Mythimnaseparata), aphid (Toxopteragraminum), cucumber trialeurodes vaporariorum (Trialeurodesvaporariorum), aphid (Aphisgossypii).
Be preferred for the control of paddy rice small brown rice planthopper, oriental fruit moth, beet armyworm, capsicum thrips and tea lesser leafhopper.
Except as otherwise noted, " % " in the application is all weight percentage.
Compared with prior art, the invention has the beneficial effects as follows:
(1) present composition synergistic effect of doing well in certain ratio range, the insecticidal effect of composition has had than single dose and has significantly improved, its co-toxicity coefficient is at least more than 120, reduce Pesticide use dosage and cost simultaneously, decrease residual, also mitigate the harmful effect to environment;
(2) in the present invention, the mechanism of action of two kinds of active components is different, and the application of composition can delay or overcome the resistance of pathogen, extends the service life of product;
(3) present composition is excellent to economic crops insect pest preventive effect, in addition, also can be used for the control of its crop pests.
Embodiment
In order to be that object of the present invention, technical scheme and advantage are clearly understood, the following instantiation of the present invention is described, but the present invention is not limited to these examples.
The present composition, finds through indoor bioassay test for active ingredient with imidaclothiz and chlorfluazuron, and after both are composite, the insect pest of the antagonism property of medicine has obvious synergistic function, is specifically illustrated with following biologicall test example.
Mensuration example 1 in kind: imidaclothiz and the composite toxicity test to paddy rice small brown rice planthopper of chlorfluazuron
1, subjects: paddy rice small brown rice planthopper [Classification system: Nilaparvatalugens], belongs to Homoptera Delphacidae.
2, test method: with reference to " farm-chemical indoor determination test rule NY/T1154.11-2008 ", adopts rice-stem dipping method.
3, data statistic analysis: analyze with SAS statistical software.Calculate corrected mortality (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50and co-toxicity coefficient.
4, evaluation method: with reference to " farm-chemical indoor determination test rule NY/T1154.7-2006 ", the synergistic effect of pharmacy mix is evaluated according to the co-toxicity coefficient method (CTC) of Sun & Johnson (1960), namely CTC≤80 are antagonism, 80<CTC<120 is summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The mixture combination of imidaclothiz, chlorfluazuron and the two different proportion thereof the results are shown in Table 1 to the toxicity test of paddy rice brown plant-hopper, and in table 1, " chlorine: fluorine " is writing a Chinese character in simplified form of " imidaclothiz: chlorfluazuron ".
Table 1 imidaclothiz and chlorfluazuron mixture are to the toxicity test result of paddy rice small brown rice planthopper
Indoor biometrics result shows: imidaclothiz and chlorfluazuron carry out mixture with 1: 15,1: 10,1: 5,1: 1,5: 1,10: 1 and 15: 1 ratios, it all shows synergistic effect to paddy rice small brown rice planthopper, wherein with 1: 5,1: 1,5: 1, the ratio mixed synergies of 10:1 and 15: 1 is the most obvious.Consider imidaclothiz and the control of chlorfluazuron to paddy rice small brown rice planthopper is better composite with 1-15:1-5.
Mensuration example 2 in kind: imidaclothiz and the composite toxicity test to oriental fruit moth of chlorfluazuron
1, subjects: oriental fruit moth [Classification system: CarposinaniponensisWalsingham], Lepidoptera Tortricidae.
2, test method: with reference to " farm-chemical indoor determination test rule NY/T1154.6-2006 ", adopts dip method.
3, data statistic analysis: analyze with SAS statistical software.Calculate corrected mortality (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50and co-toxicity coefficient.
4, evaluation method: with reference to " farm-chemical indoor determination test rule NY/T1154.7-2006 ", the synergistic effect of pharmacy mix is evaluated according to the co-toxicity coefficient method (CTC) of Sun & Johnson (1960), namely CTC≤80 are antagonism, 80<CTC<120 is summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The mixture combination of imidaclothiz, chlorfluazuron and the two different proportion thereof the results are shown in Table 2 to the toxicity test of oriental fruit moth, and in table 2, " chlorine: fluorine " is writing a Chinese character in simplified form of " imidaclothiz: chlorfluazuron ".
Table 2 imidaclothiz and chlorfluazuron mixture are to the toxicity test result of oriental fruit moth
Indoor biometrics result shows: imidaclothiz and chlorfluazuron carry out mixture with 1: 12,1: 8,1: 4,1: 1,4: 1,8: 1 and 12: 1 ratios, it all shows synergistic effect to oriental fruit moth, wherein with 1: 4,1: 1,4:1,8:1 and 12: 1 ratio mixed synergies the most obvious.Consider imidaclothiz and the control of chlorfluazuron to oriental fruit moth is better composite with 1-12:1-4.
Mensuration example 3 in kind: imidaclothiz and the composite toxicity test to beet armyworm of chlorfluazuron
1, subjects: beet armyworm Classification system: SpodopteraexiguaHiibner], belong to Lepidoptera Noctuidae.
2, test method: with reference to " farm-chemical indoor determination test rule NY/T1154.2-2006 ", adopts the malicious blade method of folder.
3, data statistic analysis: analyze with SAS statistical software.Calculate corrected mortality (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50and co-toxicity coefficient.
4, evaluation method: with reference to " farm-chemical indoor determination test rule NY/T1154.7-2006 ", the synergistic effect of pharmacy mix is evaluated according to the co-toxicity coefficient method (CTC) of Sun & Johnson (1960), namely CTC≤80 are antagonism, 80<CTC<120 is summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The mixture combination of imidaclothiz, chlorfluazuron and the two different proportion thereof the results are shown in Table 3 to the toxicity test of beet armyworm, and in table 3, " chlorine: fluorine " is writing a Chinese character in simplified form of " imidaclothiz: chlorfluazuron ".
Table 3 imidaclothiz and chlorfluazuron mixture are to the toxicity test result of beet armyworm
Indoor biometrics result shows: imidaclothiz and chlorfluazuron carry out mixture with 1: 12,1: 9,1: 1,1: 1,3: 1,9: 1 and 12: 1 ratios, it all shows synergistic effect to beet armyworm, wherein with 1: 9,1: 3, the ratio mixed synergies of 1:1,3:1 and 9:1 is the most obvious.Consider imidaclothiz and the control of chlorfluazuron to beet armyworm is better composite with 1-9:1-9.
Mensuration example 4 in kind: imidaclothiz and the composite toxicity test to capsicum thrips of chlorfluazuron
1, subjects: capsicum thrips [Classification system: Frankliniellaoccidentalis], belongs to thrips Thripidae.
2, test method: with reference to " farm-chemical indoor determination test rule NY/T1156.14-2008 ", adopts the malicious blade method of folder.
3, data statistic analysis: analyze with SAS statistical software.Calculate corrected mortality (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50and co-toxicity coefficient.
4, evaluation method: with reference to " farm-chemical indoor determination test rule NY/T1156.7-2006 ", the synergistic effect of pharmacy mix is evaluated according to the co-toxicity coefficient method (CTC) of Sun & Johnson (1960), namely CTC≤80 are antagonism, 80<CTC<120 is summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The mixture combination of imidaclothiz, chlorfluazuron and the two different proportion thereof the results are shown in Table 4 to the toxicity test of capsicum thrips, and in table 4, " chlorine: fluorine " is writing a Chinese character in simplified form of " imidaclothiz: chlorfluazuron ".
Table 4 imidaclothiz and chlorfluazuron mixture are to the toxicity test result of capsicum thrips
Indoor biometrics result shows: imidaclothiz and chlorfluazuron carry out mixture with 1: 9,1: 6,1: 3,1: 1,3: 1,6: 1 and 9: 1 ratios, it shows synergistic effect to capsicum thrips, wherein with 1: 6,1: 3,1:1,3:1 and 6: 1 ratio mixed synergies the most obvious.Consider imidaclothiz and the control of chlorfluazuron to capsicum thrips is better composite with 1-6:1-6.
Mensuration example 5 in kind: imidaclothiz and the composite toxicity test to tea lesser leafhopper of chlorfluazuron
1, subjects: tea lesser leafhopper [Classification system: EmpoascapirisugaMatumura], belongs to Semiptera Cicadellidae.
2, test method: with reference to " farm-chemical indoor determination test rule NY/T1156.2-2006 ", adopts the malicious blade method of folder.
3, data statistic analysis: analyze with SAS statistical software.Calculate corrected mortality (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50and co-toxicity coefficient.
4, evaluation method: with reference to " farm-chemical indoor determination test rule NY/T1156.7-2006 ", the synergistic effect of pharmacy mix is evaluated according to the co-toxicity coefficient method (CTC) of Sun & Johnson (1960), namely CTC≤80 are antagonism, 80<CTC<120 is summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The mixture combination of imidaclothiz, chlorfluazuron and the two different proportion thereof the results are shown in Table 5 to the toxicity test of tea lesser leafhopper, and in table 5, " chlorine: fluorine " is writing a Chinese character in simplified form of " imidaclothiz: chlorfluazuron ".
Table 5 imidaclothiz and chlorfluazuron mixture are to the toxicity test result of tea lesser leafhopper
Indoor biometrics result shows: imidaclothiz and chlorfluazuron carry out mixture with 1: 12,1: 8,1: 4,1: 1,4: 1,8: 1 and 12: 1 ratios, it shows synergistic effect to tea lesser leafhopper, wherein with 1: 8,1: 4, the ratio mixed synergies of 1:1 and 4:1 is the most obvious.Consider imidaclothiz and the control of chlorfluazuron to tea lesser leafhopper is better composite with 1-4:1-8.
Biologicall test example 6: imidaclothiz and the composite toxicity test to oranges and tangerines ash weevil of chlorfluazuron
1, subjects: oranges and tangerines ash weevil [Classification system Sympiezomiacitre (Chao)], belongs to coleoptera Culculionidae.
2, test method: with reference to " farm-chemical indoor determination test rule NY/T1154.6-2006 ", adopts dip method.
3, data statistic analysis: analyze with SAS statistical software.Calculate corrected mortality (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50and co-toxicity coefficient.
4, evaluation method: with reference to " farm-chemical indoor determination test rule NY/T1154.7-2006 ", the synergistic effect of pharmacy mix is evaluated according to the co-toxicity coefficient method (CTC) of Sun & Johnson (1960), namely CTC≤80 are antagonism, 80<CTC<120 is summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The toxicity test of mixture combination to oranges and tangerines ash weevil of chlorfluazuron, imidaclothiz and the two different proportion thereof the results are shown in Table 6, and in table 6, " fluorine: chlorine " is writing a Chinese character in simplified form of " chlorfluazuron: imidaclothiz ".
Table 6 chlorfluazuron and imidaclothiz mixture are to the toxicity test result of oranges and tangerines ash weevil
Indoor biometrics result shows: chlorfluazuron and imidaclothiz carry out mixture with 1: 9,1: 6,1: 3,1: 1,3: 1,6: 1 and 9: 1 ratios, it shows as addition or antagonism to oranges and tangerines ash weevil, there is no synergistic effect, do not advise that chlorfluazuron and imidaclothiz mixture are for the control to oranges and tangerines ash weevil.
The present composition can with known auxiliary agent and assistant agent, prepare any one formulation in being applicable to agriculturally using by known method, wherein reasonable formulation has water dispersible granules, suspending agent, aqueous emulsion, missible oil or seed coat agent, and these known auxiliary agents, assistant agent have dispersant, diffusant, defoamer, wetting agent, disintegrant, film forming agent and filler etc.
Be described with instantiation below.
Embodiment 1:
Imidaclothiz 7.5g, chlorfluazuron 12.5g, cyclohexanone 15g, soybean oil are added to 100g, is mixed to homogeneous liquid phase, the obtained present composition 20% missible oil.
Embodiment 2:
Imidaclothiz 10g, chlorfluazuron 15g, alkylphenol polyoxyethylene 8g, lauryl sodium sulfate 6g, Magnesiumaluminumsilicate 1g, diatomite are added to 100g, obtains the present composition 25% water dispersible granules through mixing, ultra-fine grinding, granulation.
Embodiment 3:
By imidaclothiz 15g, chlorfluazuron 15g, polyoxyethylene carboxylate 5g, polyoxyethylene nonylphenol ether 6g, CMC 0.5g, propane diols 2g, organosilicon 0.5g, add water to 100g, mixing is through wet grinding, and homogenizing, obtains the present composition 30% suspending agent.
Embodiment 4:
Imidaclothiz 30g, chlorfluazuron 20g, sodium lignin sulfonate 8g, lauryl sodium sulfate 5g, white carbon 10g, diatomite are added to 100g, mixes and obtain the present composition 50% wetting powder through air-flow crushing.
Embodiment 5:
By imidaclothiz 10g, chlorfluazuron 10g, turpentine oil 6g, polyoxyethylene nonylphenol ether 10g, alkylphenol polyoxyethylene phosphate 1g, polyvinyl alcohol 2g, xanthans 0.1g, add water to 100g, preparation oil phase, preparation aqueous phase, under high shear, to add in oil phase in oil phase aqueous phase or by aqueous phase, shear the obtained present composition 15% aqueous emulsion.
Embodiment 6:
By imidaclothiz 3g, chlorfluazuron 5g, polyoxyethylene carboxylate 6g, polyoxyethylene nonylphenol ether 5g, Magnesiumaluminumsilicate 0.5g, polyvinylpyrrolidone 2g, C
8-10fat alcohol compound 0.5g, polyvinyl alcohol 2g, basic rhodamine 0.5g, add water to 100g, mixes through wet grinding, homogenizing, the obtained present composition 8% suspension seed-coating agent.
A kind of Pesticidal combination containing imidaclothiz and chlorfluazuron of the present invention is described by concrete example, those skilled in the art can use for reference content of the present invention, the links such as suitable feed change, process conditions realize other object corresponding, its relevant change does not all depart from content of the present invention, all similar replacements and change will become apparent to those skilled in the art that and be all deemed to be included within scope of the present invention.
Claims (9)
1. contain a Pesticidal combination for imidaclothiz and chlorfluazuron, it is characterized in that, the active component contained by described composition is imidaclothiz and chlorfluazuron, and the weight ratio of described imidaclothiz and chlorfluazuron is 1-30:1-30.
2. Pesticidal combination according to claim 1, is characterized in that, the weight ratio of described imidaclothiz and chlorfluazuron is 2-20:3-20.
3. Pesticidal combination according to claim 1, is characterized in that, the weight ratio of described imidaclothiz and chlorfluazuron is 1-9:1-15.
4. Pesticidal combination according to claim 1, is characterized in that, the weight ratio of described imidaclothiz and chlorfluazuron is 1:1.
5., according to the arbitrary described Pesticidal combination of Claims 1-4, it is characterized in that, described combination dosage form is wetting powder, water dispersible granules, suspending agent, aqueous emulsion, missible oil or seed coat agent.
6. Pesticidal combination according to claim 5, is characterized in that, described imidaclothiz and the percentage by weight of chlorfluazuron in above-mentioned formulation are 5 ~ 60%.
7. the application of the Pesticidal combination control agricultural insect pest as described in as arbitrary in Claims 1-4.
8. application according to claim 7, described agricultural disease is beet armyworm (SpodopteraexiguaHiibner), cabbage pieris (PierisrapaeLinne), Brown Planthopper (Nilaparvatalugens), small brown rice planthopper (Laodelphaxstriatellus), white-backed planthopper (Sogatellafurcifera), thrips (Chloethripsoryzae), striped rice borer (Chilosuppressalis) peach fruit borer (CarposinaniponensisWalsingham), dichocrocis punctiferalis (Conogethespunctiferalis), black peach aphid (Myzuspersicae), Asiatic apple leafminer (LithocolletisringoniellaMats.), olethreutid (AdoxophyesoranaFishervonRoslerstamm), woolly aphid (Eriosomalanigerum), Against Conopomorpha sinensis Bradley (ConopomorphasinensisBradley), pear sucker (Psyllachinensis), pear mealworm (Aphanostigmajakusuiesie), oriental fruit moth (Grapholithamolesta (Busck)), the green cicada of tea leaflet (EmpoascapirisugaMatumura), tea geometrid (EctropisobliquehypulinaWehrli), grape clearwing moth (ParathreneregalisButler), hair siphon-worm (IlliberistenuisBatler), cowpea Americal rice leaf miner (Liriomyzasativae (Blanchard)), cotton bollworm (Helicoverpaarmigerar), wheat mythimna separata (Mythimnaseparata), aphid (Toxopteragraminum), cucumber trialeurodes vaporariorum (Trialeurodesvaporariorum) or aphid (Aphisgossypii).
9. application according to claim 7, described agricultural insect pest is paddy rice small brown rice planthopper, oriental fruit moth, beet armyworm, capsicum thrips or tea lesser leafhopper.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6232328B1 (en) * | 1994-05-20 | 2001-05-15 | Bayer Aktiengesellschaft | Non-systemic control of parasites |
| CN1401646A (en) * | 2001-08-08 | 2003-03-12 | 南通江山农药化工股份有限公司 | Insecticidal compound and production process thereof |
| CN103621534A (en) * | 2012-08-27 | 2014-03-12 | 南京华洲药业有限公司 | Synergistic insecticidal composition containing thiamethoxam and chlorfluazuron, and application thereof |
| CN105052966A (en) * | 2015-02-12 | 2015-11-18 | 四川利尔作物科学有限公司 | Insecticidal composition and application thereof |
-
2015
- 2015-09-30 CN CN201510638000.9A patent/CN105145615A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6232328B1 (en) * | 1994-05-20 | 2001-05-15 | Bayer Aktiengesellschaft | Non-systemic control of parasites |
| CN1401646A (en) * | 2001-08-08 | 2003-03-12 | 南通江山农药化工股份有限公司 | Insecticidal compound and production process thereof |
| CN103621534A (en) * | 2012-08-27 | 2014-03-12 | 南京华洲药业有限公司 | Synergistic insecticidal composition containing thiamethoxam and chlorfluazuron, and application thereof |
| CN105052966A (en) * | 2015-02-12 | 2015-11-18 | 四川利尔作物科学有限公司 | Insecticidal composition and application thereof |
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