CN105028443A - Insecticidal composition containing diflubenzuron and cyantraniliprole and application thereof - Google Patents
Insecticidal composition containing diflubenzuron and cyantraniliprole and application thereof Download PDFInfo
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- CN105028443A CN105028443A CN201510521281.XA CN201510521281A CN105028443A CN 105028443 A CN105028443 A CN 105028443A CN 201510521281 A CN201510521281 A CN 201510521281A CN 105028443 A CN105028443 A CN 105028443A
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- diflubenzuron
- insect amide
- cyanogen insect
- bromine cyanogen
- pesticidal combination
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- 239000005893 Diflubenzuron Substances 0.000 title claims abstract description 70
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- 239000000203 mixture Substances 0.000 title claims abstract description 46
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- 239000005889 Cyantraniliprole Substances 0.000 title abstract description 5
- QQQYTWIFVNKMRW-UHFFFAOYSA-N diflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC=C(Cl)C=C1 QQQYTWIFVNKMRW-UHFFFAOYSA-N 0.000 title abstract description 5
- 230000000749 insecticidal effect Effects 0.000 title abstract description 4
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- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 5
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- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 5
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- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 3
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- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
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- 150000007942 carboxylates Chemical class 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
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- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
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- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
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- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 102000042094 ryanodine receptor (TC 1.A.3.1) family Human genes 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an insecticidal composition containing diflubenzuron and cyantraniliprole and application thereof. The composition contains diflubenzuron and cyantraniliprole, wherein the weight ratio of diflubenzuron to cyantraniliprole is 40: 1-1: 35. the composition can be applied to the prevention and control of crop pests. The composition has wide application range, good effect, low cost, low residue, and safety to human, livestock, and environment.
Description
Technical field
The present invention relates to a kind of Pesticidal combination and purposes, particularly relate to a kind of Pesticidal combination containing diflubenzuron and bromine cyanogen insect amide and uses thereof, be mainly used in the control of crop pests.
Technical background
Diflubenzuron (Diflubenzuron, CAS 35367-38-5) is a kind of systemic insecticide of wide spectrum.Directly can be absorbed by plant root, enter in plant corpus, mobile very rapid.Move in root system and only within 3 hours, just move to stem, within 24 hours, move to plant whole body.This product mechanism of action is unique, efficient, low toxicity, nuisanceless, can suppress the mycelial normal growth of disease fungus or direct killing pathogenic bacteria, again can Promoting plant growth.
Bromine cyanogen insect amide (Cyantraniliprole, CAS 736994-63-1) be second generation ryanodine receptor inhibitor insecticides, formed by the various polar groups changed on phenyl ring, have more efficient, applicable crops is more extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.Can effectively prevent and treat the primary pests such as aleyrodid, aphid, thrips, wood louse, Liriomyza, beetle and lepidopterous larvae.
Facts have proved that the Long-Time Service of chemical pesticide single dose very easily occurs resistance problem, cause consumption to continue to increase, risk increases, and is unfavorable for Environment Ecological Safe.Seeking scientific and rational agriculture chemical compounding, is address this problem good way.Also there is no the relevant report of diflubenzuron and high-efficient lambda-cyhalothrin compound at present at home and abroad.
Summary of the invention
An object of the present invention is to overcome above-mentioned deficiency, provide a kind of applied widely, effective, consumption is low, cost is low, the lasting period is long, residual little and there is the Pesticidal combination containing diflubenzuron and bromine cyanogen insect amide of synergistic effect.
Two of object of the present invention is to provide a kind of purposes of Pesticidal combination for control economic disease of pests evil containing diflubenzuron and bromine cyanogen insect amide.
The object of the present invention is achieved like this:
Contain a Pesticidal combination for diflubenzuron and bromine cyanogen insect amide, the active component contained by described composition is diflubenzuron and bromine cyanogen insect amide, and the weight ratio of described diflubenzuron and bromine cyanogen insect amide is 40:1 ~ 1:35.
The preferred weight ratio of described diflubenzuron and bromine cyanogen insect amide is 30:5 ~ 3:20.
More preferably, the weight ratio of the two is 9:1 ~ 1:6;
Most preferred, the weight ratio of the two is 6:1.
Described combination dosage form is any one formulation that agricultural chemicals allows.Such as wetting powder, water dispersible granules, suspending agent, aqueous emulsion, missible oil or seed coat agent etc.
Described diflubenzuron and the percentage by weight of bromine cyanogen insect amide in above-mentioned formulation are 5 ~ 75%.
Further, the invention provides a kind of purposes containing the Pesticidal combination of diflubenzuron and bromine cyanogen insect amide as above, by described Insecticidal combinations for being used for control economic disease of pests evil.
Preferably, described insect pest is: cucumber flea beetle (Phyllotretastriolata (Fabricius)), trialeurodes vaporariorum (Trialeurodesvaporariorum (Westwood)), aphid (Aphis%ossypii), beet armyworm (Spodopteraexi%uaHiibner), cabbage pieris (PierisrapaeLinne), citrus fruit fly (Tetradacuscitri), leaf miner (PhyllocnistiscitrellaStainton), bud maggot (ContariniacitriBarnes), wood louse (Diaphorinacitri (Kuwayama)), peach fruit borer (CarposinaniponensisWalsin%ham), dichocrocis punctiferalis (Cono%ethespunctiferalis), black peach aphid (Myzuspersicae), Asiatic apple leafminer (Lithocolletisrin%oniellaMats.), olethreutid (AdoxophyesoranaFishervonRoslerstamm), Against Conopomorpha sinensis Bradley (ConopomorphasinensisBradley), pear sucker (Psyllachinensis), pear mealworm (Aphanosti%majakusuiesie), oriental fruit moth (%rapholithamolesta (Busck)), the green cicada of tea leaflet (Empoascapirisu%aMatumura), tea geometrid (EctropisobliquehypulinaWehrli), grape clearwing moth (Parathrenere%alisButler), hair siphon-worm (IlliberistenuisBatler), cowpea Americal rice leaf miner (Liriomyzasativae (Blanchard)), cotton bollworm (Helicoverpaarmi%erar), wheat mythimna separata (Mythimnaseparata), wheat aphid (Macrosiphumavenae (Fabricius)), Brown Planthopper (Nilaparvatalu%ens), small brown rice planthopper (Laodelphaxstriatellus), striped rice borer (Chilosuppressalis), leaf-roller (Cnaphalocrocismedinalis%uenee), paddy rice thrips (Chloethripsoryzae (Wil.)).
Be preferred for the control of beet armyworm, diaphorina citri, codling moth, tea geometrid and cucumber trialeurodes vaporariorum.
Compared with prior art, the invention has the beneficial effects as follows:
(1) present composition synergistic effect of doing well in certain ratio range, the insecticidal effect of composition has had than single dose and has significantly improved, and its co-toxicity coefficient is at least more than 120, reduces Pesticide use dosage and cost simultaneously, decrease residual, also mitigate the harmful effect to environment;
(2) in the present invention, the mechanism of action of two kinds of active components is different, and the application of composition can delay or overcome the resistance of pathogen, extends the service life of product;
(3) present composition is excellent to economic crops disease preventive effect, in addition, also can be used for the control of its corps diseases.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearly understand, the following instantiation of the present invention is described, but the present invention is not limited to these examples.
The present composition, finds through indoor bioassay test for active ingredient with diflubenzuron and bromine cyanogen insect amide, and after both are composite, antagonistic drug venereal diseases evil has obvious synergistic function, is specifically illustrated with following biologicall test example.
Mensuration example 1 in kind: diflubenzuron and the composite toxicity test to beet armyworm of bromine cyanogen insect amide
1, subjects: beet armyworm [Classification system:
spodopteraexi%uaHiibner], belong to Lepidoptera Noctuidae.
2, test method: with reference to " farm-chemical indoor determination test rule NY/T1154.6-2006 ", adopts dip method.
3, data statistic analysis: analyze with SAS statistical software.Calculate corrected mortality (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50and co-toxicity coefficient.
4, evaluation method: with reference to " farm-chemical indoor determination test rule NY/T1156.7-2006 ", the synergistic effect of pharmacy mix is evaluated according to the co-toxicity coefficient method (CTC) of the abundant method of Sun Yun (1960), namely CTC≤80 are antagonism, 80<CTC<120 is summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The mixture combination of diflubenzuron, bromine cyanogen insect amide and the two different proportion thereof the results are shown in Table 1 to the toxicity test of beet armyworm, and " removing: bromine " in table 1 is writing a Chinese character in simplified form of " diflubenzuron: bromine cyanogen insect amide ".
Table 1 diflubenzuron and bromine cyanogen insect amide mixture are to the toxicity test result of beet armyworm
Indoor biometrics result shows: diflubenzuron and bromine cyanogen insect amide with 1: 12,1: 9,1:6,1: 3,1: 1,3: 1,6: 1,9:1 and 12: 1 ratios carry out mixture, it all shows synergistic effect to beet armyworm, wherein with 1: 6,1: 3,1: 1,3:1,6:1 and 9: 1 ratio mixed synergies the most obvious.Consider diflubenzuron and the control of bromine cyanogen insect amide to beet armyworm is better composite with 1:6 ~ 9:1.
Mensuration example 2 in kind: diflubenzuron and the composite toxicity test to diaphorina citri of bromine cyanogen insect amide
1, subjects: diaphorina citri [Classification system:
diaphorinacitri (Kuwayama)], belong to Homoptera Psyllidae.
2, test method: with reference to " farm-chemical indoor determination test rule NY/T1156.8-2007 ", adopts filter paper medicine embrane method.
3, data statistic analysis: analyze with SAS statistical software.Calculate corrected mortality (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50and co-toxicity coefficient.
4, evaluation method: with reference to " farm-chemical indoor determination test rule NY/T1156.7-2006 ", the synergistic effect of pharmacy mix is evaluated according to the co-toxicity coefficient method (CTC) of the abundant method of Sun Yun (1960), namely CTC≤80 are antagonism, 80<CTC<120 is summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The mixture combination of diflubenzuron, bromine cyanogen insect amide and the two different proportion thereof the results are shown in Table 2 to the toxicity test of diaphorina citri, and " removing: bromine " in table 2 is writing a Chinese character in simplified form of " diflubenzuron: bromine cyanogen insect amide ".
Table 2 diflubenzuron and bromine cyanogen insect amide mixture are to the toxicity test result of diaphorina citri
Indoor biometrics result shows: diflubenzuron and bromine cyanogen insect amide with 1: 12,1: 9,1:6,1: 3,1: 1,3: 1,6: 1,9:1 and 12: 1 ratios carry out mixture, it all shows synergistic effect to diaphorina citri, wherein with 1: 6,1: 3,1:1,3:1,6:1 and 9: 1 ratio mixed synergies the most obvious.Consider diflubenzuron and the control of bromine cyanogen insect amide to diaphorina citri is better composite with 1:6 ~ 9:1.
Mensuration example 3 in kind: diflubenzuron and the composite toxicity test to cucumber trialeurodes vaporariorum of bromine cyanogen insect amide
1, subjects: cucumber trialeurodes vaporariorum [Classification system:
trialeurodesvaporariorum (Westwood)], belong to Homoptera Aleyrodidae.
2, test method: with reference to " farm-chemical indoor determination test rule NY/T1154.8-2007 ", adopts filter paper medicine embrane method.
3, data statistic analysis: analyze with SAS statistical software.Calculate corrected mortality (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50and co-toxicity coefficient.
4, evaluation method: with reference to " farm-chemical indoor determination test rule NY/T1154.7-2006 ", the synergistic effect of pharmacy mix is evaluated according to the co-toxicity coefficient method (CTC) of the abundant method of Sun Yun (1960), namely CTC≤80 are antagonism, 80<CTC<120 is summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The mixture combination of diflubenzuron, bromine cyanogen insect amide and the two different proportion thereof the results are shown in Table 3 to the toxicity test of cucumber trialeurodes vaporariorum, and " removing: bromine " in table 3 is writing a Chinese character in simplified form of " diflubenzuron: bromine cyanogen insect amide ".
Table 3 diflubenzuron and bromine cyanogen insect amide mixture are to the toxicity test result of cucumber trialeurodes vaporariorum
Indoor biometrics result shows: diflubenzuron and bromine cyanogen insect amide with 1: 12,1: 9,1:6,1: 3,1: 1,3: 1,6: 1,9:1 and 12: 1 ratios carry out mixture, it shows synergistic effect to cucumber trialeurodes vaporariorum, wherein with 1: 6,1: 3, the ratio mixed synergies of 1:1,6:1 and 9:1 is the most obvious.Consider diflubenzuron and the control of bromine cyanogen insect amide to cucumber trialeurodes vaporariorum is better composite with 1:6 ~ 9:1.
Mensuration example 4 in kind: diflubenzuron and the composite toxicity test to codling moth of bromine cyanogen insect amide
1, subjects: codling moth [Classification system:
adoxophyesoranaFishervonRoslerstamm], belong to Lepidoptera Tortricidae.
2, test method: with reference to " farm-chemical indoor determination test rule NY/T1154.2-2006 ", adopts the malicious blade method of folder.
3, data statistic analysis: analyze with SAS statistical software.Calculate corrected mortality (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50and co-toxicity coefficient.
4, evaluation method: with reference to " farm-chemical indoor determination test rule NY/T1156.7-2006 ", the synergistic effect of pharmacy mix is evaluated according to the co-toxicity coefficient method (CTC) of the abundant method of Sun Yun (1960), namely CTC≤80 are antagonism, 80<CTC<120 is summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The mixture combination of diflubenzuron, bromine cyanogen insect amide and the two different proportion thereof the results are shown in Table 4 to the toxicity test of codling moth, and " removing: bromine " in table 4 is writing a Chinese character in simplified form of " diflubenzuron: bromine cyanogen insect amide ".
Table 4 diflubenzuron and bromine cyanogen insect amide mixture are to the toxicity test result of codling moth
Indoor biometrics result shows: diflubenzuron and bromine cyanogen insect amide with 1: 12,1: 9,1:6,1: 3,1: 1,3: 1,6: 1,9:1 and 12: 1 ratios carry out mixture, it shows synergistic effect to codling moth, wherein with 1: 6,1: 3,1:1,3:1 and 6: 1 ratio mixed synergies the most obvious.Consider diflubenzuron and the control of bromine cyanogen insect amide to codling moth disease is better composite with 1:6 ~ 6:1.
Mensuration example 5 in kind: diflubenzuron and the composite toxicity test to tea geometrid of bromine cyanogen insect amide
1, subjects: tea geometrid [Classification system:
ectropisobliquehypulinaWehrli], belong to Lepidoptera Geometridae.
2, test method: with reference to " farm-chemical indoor determination test rule NY/T1156.14-2008 ", adopts pastille medium therapy.
3, data statistic analysis: analyze with SAS statistical software.Calculate corrected mortality (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50and co-toxicity coefficient.
4, evaluation method: with reference to " farm-chemical indoor determination test rule NY/T1156.14-2008 ", the synergistic effect of pharmacy mix is evaluated according to the co-toxicity coefficient method (CTC) of the abundant method of Sun Yun (1960), namely CTC≤80 are antagonism, 80<CTC<120 is summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The mixture combination of diflubenzuron, bromine cyanogen insect amide and the two different proportion thereof the results are shown in Table 5 to the toxicity test of tea geometrid, and " removing: bromine " in table 5 is writing a Chinese character in simplified form of " diflubenzuron: bromine cyanogen insect amide ".
Table 5 diflubenzuron and bromine cyanogen insect amide mixture are to the toxicity test result of tea geometrid
Indoor biometrics result shows: diflubenzuron and bromine cyanogen insect amide with 1: 12,1: 9,1:6,1: 3,1: 1,3: 1,6: 1,9:1 and 12: 1 ratios carry out mixture, it shows synergistic effect to tea geometrid, wherein with 1: 6,1: 3, the ratio mixed synergies of 1:1,3:1 and 6:1 is the most obvious.Consider diflubenzuron and the control of bromine cyanogen insect amide to tea geometrid is better composite with 1:6 ~ 6:1.
The present composition can with known auxiliary agent and assistant agent, prepare any one formulation in being applicable to agriculturally using by known method, wherein reasonable formulation has water dispersible granules, suspending agent, aqueous emulsion, missible oil or seed coat agent, and these known auxiliary agents, assistant agent have dispersant, diffusant, defoamer, wetting agent, disintegrant, film forming agent and filler etc.
Be described with instantiation below.
Preparation embodiment 1:
Diflubenzuron 12%, bromine cyanogen insect amide 3%, cyclohexanone 15%, soybean oil are added to 100%, is mixed to homogeneous liquid phase, the obtained present composition 15% missible oil.
Preparation embodiment 2:
Diflubenzuron 25%, bromine cyanogen insect amide 5%, polyoxyethylene nonylphenol ether 8%, lauryl sodium sulfate 6%, Magnesiumaluminumsilicate 1%, diatomite are added to 100%, obtains the present composition 30% water dispersible granules through mixing, ultra-fine grinding, granulation.
Preparation embodiment 3:
By diflubenzuron 5%, bromine cyanogen insect amide 20%, polyoxyethylene carboxylate 5%, alkylphenol polyoxyethylene 6%, xanthans 0.5%, propane diols 2%, organosilicon 0.5%, add water to 100%, mix through wet grinding, homogenizing, the obtained present composition 25% suspending agent.
Preparation embodiment 4:
Diflubenzuron 30%, bromine cyanogen insect amide 5%, sodium lignin sulfonate 8%, lauryl sodium sulfate 5%, white carbon 10%, bentonite are added to 100%, mixes and obtain the present composition 35% wetting powder through air-flow crushing.
Preparation embodiment 5:
By diflubenzuron 10%, bromine cyanogen insect amide 5%, turpentine oil 6%, polyoxyethylene nonylphenol ether 10%, alkylphenol polyoxyethylene phosphate 1%, polyvinyl alcohol 2%, xanthans 0.1%, add water to 100%, preparation oil phase, preparation aqueous phase, under high shear, to add in oil phase in oil phase aqueous phase or by aqueous phase, shear the obtained present composition 15% aqueous emulsion.
Preparation embodiment 6:
By diflubenzuron 7.5%, bromine cyanogen insect amide 2.5%, polyoxyethylene carboxylate 6%, polyoxyethylene nonylphenol ether 5%, Magnesiumaluminumsilicate 1%, polyvinyl alcohol 2%, organosilicon 0.5%, ethylene glycol 2%, basic rhodamine 0.5%, add water to 100%, mixing is through wet grinding, homogenizing, the obtained present composition 10% suspension seed-coating agent.
A kind of Pesticidal combination containing diflubenzuron and bromine cyanogen insect amide of the present invention is described by concrete example, those skilled in the art can use for reference content of the present invention, the links such as suitable feed change, process conditions realize other object corresponding, its relevant change does not all depart from content of the present invention, all similar replacements and change will become apparent to those skilled in the art that and be all deemed to be included within scope of the present invention.
Claims (8)
1. contain a Pesticidal combination for diflubenzuron and bromine cyanogen insect amide, it is characterized in that, the active component contained by described composition is diflubenzuron and bromine cyanogen insect amide, and the weight ratio of described diflubenzuron and bromine cyanogen insect amide is 40:1 ~ 1:35.
2. a kind of Pesticidal combination containing diflubenzuron and bromine cyanogen insect amide according to claim 1, it is characterized in that, the weight ratio of described diflubenzuron and bromine cyanogen insect amide is 30:5 ~ 3:20.
3. a kind of Pesticidal combination containing diflubenzuron and bromine cyanogen insect amide according to claim 2, it is characterized in that, the weight ratio of described diflubenzuron and bromine cyanogen insect amide is 9:1 ~ 1:6.
4. a kind of Pesticidal combination containing diflubenzuron and bromine cyanogen insect amide according to claim 3, it is characterized in that, the weight ratio of described diflubenzuron and bromine cyanogen insect amide is 6:1.
5., according to the arbitrary described a kind of Pesticidal combination containing diflubenzuron and bromine cyanogen insect amide of Claims 1-4, it is characterized in that, described composition is mixed with wetting powder, water dispersible granules, suspending agent, aqueous emulsion, missible oil or seed coat agent.
6. a kind of Pesticidal combination containing diflubenzuron and bromine cyanogen insect amide according to claim 5, it is characterized in that, active component diflubenzuron and the percentage by weight of bromine cyanogen insect amide in described formulation are 5-75%.
7. contain a purposes for the Pesticidal combination of diflubenzuron and bromine cyanogen insect amide, it is characterized in that, the Pesticidal combination containing diflubenzuron and bromine cyanogen insect amide one of claim 1-6 Suo Shu is used for control economic disease of pests evil
.
8. a kind of purposes containing the Pesticidal combination of diflubenzuron and bromine cyanogen insect amide according to claim 7, it is characterized in that, described economic crops disease comprises: cucumber flea beetle, trialeurodes vaporariorum, aphid, beet armyworm, cabbage pieris, citrus fruit fly, leaf miner, bud maggot, wood louse, peach fruit borer, dichocrocis punctiferalis, black peach aphid, Asiatic apple leafminer, olethreutid, Against Conopomorpha sinensis Bradley, pear sucker, pear mealworm, oriental fruit moth, the green cicada of tea leaflet, tea geometrid, grape clearwing moth, hair siphon-worm, cowpea Americal rice leaf miner, cotton bollworm, wheat mythimna separata, wheat aphid, Brown Planthopper, small brown rice planthopper, striped rice borer, leaf-roller or paddy rice thrips.
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| CN108013060A (en) * | 2017-11-15 | 2018-05-11 | 安阳市安林生物化工有限责任公司 | A kind of Pesticidal combination containing diflubenzuron and ring bromine insect amide |
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| CN108013060A (en) * | 2017-11-15 | 2018-05-11 | 安阳市安林生物化工有限责任公司 | A kind of Pesticidal combination containing diflubenzuron and ring bromine insect amide |
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