CN105145614A - Imidaclothiz-and-diflubenzuron-containing pest killing composition and application thereof - Google Patents
Imidaclothiz-and-diflubenzuron-containing pest killing composition and application thereof Download PDFInfo
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Abstract
The invention relates to an imidaclothiz-and-diflubenzuron-containing pest killing composition and an application thereof. The composition contains imidaclothiz and diflubenzuron, wherein the weight ratio of the imidaclothiz to the diflubenzuron is 1-25 to 1-25. The composition can be applied to controlling agricultural pests of commercial crops, melons, fruits or vegetables and the like. The composition is wide in application range, good in effect, low in cost and residue and safe for people, livestock, the environment and the like.
Description
Technical field
The present invention relates to a kind of Pesticidal combination and application, particularly relate to a kind of Pesticidal combination and the application thereof that contain imidaclothiz and diflubenzuron, be mainly used in the control of agricultural insect pest.
Background technology
Imidaclothiz (imidaclothiz, No. CAS is 105843-36-5) for being a kind of anabasine systemic insecticide, have tag, stomach toxicity and systemic action, there is wide spectrum, efficient, low toxicity, low-residual, insect not easily develop immunity to drugs, drug effect is by temperature limiting, feature to people and animals, agricultural and natural enemies security.The mechanism of action of imidaclothiz, mainly acts on nicotinic acetylcholine esterase acceptor, is mainly used in preventing and treating sucking pest, as aphid, leafhopper, plant hopper, thrips, aleyrodid and resistant strain thereof, also effective to coleoptera, diptera and lepidoptera pest.
Diflubenzuron (Diflubenzuron, CAS 35367-38-5) for belonging to benzoyl insecticides, by suppressing the synthesis of chitin synthetase of insect, thus suppress larva, ovum, the chitinous synthesis of pupa epidermis, insect can not normally be casted off a skin polypide deformity and dead.Diflubenzuron has stomach toxicity and action of contace poison, causes accumulation property poisoning after pests, and owing to lacking chitin, larva can not form new epidermis, difficulty of casting off a skin, and pupates to be obstructed; Adult is difficult to sprout wings, lay eggs; Ovum can not normal development, hatching larva epidermis lack hardness and dead, thus affect the insect whole generation.Special efficacy is had to lepidoptera pest.Use safety, have no adverse effects, but drug effect is slow to fish, honeybee and natural enemy.
Can be there is many generations in 1 year in most pest, if a certain agricultural chemicals single variety of Long-Time Service, be easy to produce resistance.Science.Reasonably carry out two or more Pesticidal composition, just can solve resistance problem preferably.Also there is no imidaclothiz and urea compounded relevant report at home and abroad at present.The present invention finds, should have synergistic function, and also can expand insecticidal spectrum after both mixtures.
Summary of the invention
An object of the present invention is to overcome above-mentioned deficiency, provides that a kind of good disinsection effect, cost are low, insecticidal spectrum is wide and has the Pesticidal combination containing imidaclothiz and diflubenzuron of synergistic effect.
Two of object of the present invention is to provide a kind of application containing the Pesticidal combination control agricultural insect pest of imidaclothiz and diflubenzuron.
The object of the present invention is achieved like this:
Contain a Pesticidal combination for imidaclothiz and diflubenzuron, the active component contained by described composition is imidaclothiz and diflubenzuron, and the weight ratio of described imidaclothiz and diflubenzuron is 1-25:1-25.
The preferred weight ratio of described imidaclothiz and diflubenzuron is 2-15:3-15;
More preferably, the weight ratio of the two is 1-10:1-9;
Most preferred, the weight ratio of the two is 1:1.
Described combination dosage form is any one formulation that agricultural chemicals allows.Such as wetting powder, water dispersible granules, suspending agent, aqueous emulsion, missible oil or seed coat agent etc.
Described imidaclothiz and the percentage by weight of diflubenzuron in above-mentioned formulation are 2 ~ 50%.
Another object of the present invention is to, a kind of application containing the Pesticidal combination of imidaclothiz and diflubenzuron as above is provided, described Insecticidal combinations is prevented and treated agricultural insect pest for being used for, preferably, described insect pest is: beet armyworm (SpodopteraexiguaHiibner), cabbage pieris (PierisrapaeLinne), Brown Planthopper (Nilaparvatalugens), small brown rice planthopper (Laodelphaxstriatellus), white-backed planthopper (Sogatellafurcifera), thrips (Chloethripsoryzae), striped rice borer (Chilosuppressalis) peach fruit borer (CarposinaniponensisWalsingham), dichocrocis punctiferalis (Conogethespunctiferalis), black peach aphid (Myzuspersicae), Asiatic apple leafminer (LithocolletisringoniellaMats.), olethreutid (AdoxophyesoranaFishervonRoslerstamm), woolly aphid (Eriosomalanigerum), Against Conopomorpha sinensis Bradley (ConopomorphasinensisBradley), pear sucker (Psyllachinensis), pear mealworm (Aphanostigmajakusuiesie), oriental fruit moth (Grapholithamolesta (Busck)), the green cicada of tea leaflet (EmpoascapirisugaMatumura), tea geometrid (EctropisobliquehypulinaWehrli), grape clearwing moth (ParathreneregalisButler), hair siphon-worm (IlliberistenuisBatler), cowpea Americal rice leaf miner (Liriomyzasativae (Blanchard)), cotton bollworm (Helicoverpaarmigerar), wheat mythimna separata (Mythimnaseparata), aphid (Toxopteragraminum), cucumber trialeurodes vaporariorum (Trialeurodesvaporariorum), aphid (Aphisgossypii).
Be preferred for the control of Brown Planthopper, wheat aphid, wooly aphis, tea lesser leafhopper and pear sucker.
Except as otherwise noted, " % " in the application is all weight percentage.
Compared with prior art, the invention has the beneficial effects as follows:
(1) the Pesticidal combination provided by the invention synergistic effect of doing well in certain ratio range, the insecticidal effect of composition has had than single dose and has significantly improved, its co-toxicity coefficient is at least more than 120, reduce Pesticide use dosage and cost simultaneously, decrease residual, also mitigate the harmful effect to environment;
(2) in the present invention, the mechanism of action of two kinds of active components is different, and the application of composition can delay or overcome resistance development, extends the service life of product;
(3) present composition can expand insecticidal spectrum, expands the scope of application.
(4) in the present invention, the active component of composition is all low-toxin farm chemicals, and along with the enforcement of China's forbidding severe toxicity, high-toxic pesticide measure, the present composition will become one of product that alternative high-toxic pesticide is the most suitable.
Embodiment
In order to be that object of the present invention, technical scheme and advantage are clearly understood, the following instantiation of the present invention is described, but the present invention is not limited to these examples.
Pesticidal combination of the present invention for active ingredient, finds both composite after to various pests have obvious synergistic function, specifically with following biologicall test example be illustrated through indoor bioassay test with imidaclothiz and diflubenzuron.
Biologicall test example 1: imidaclothiz and the urea compounded toxicity test to Brown Planthopper
1, subjects: Brown Planthopper [Classification system Nilaparvatalugens], belongs to Homoptera Delphacidae.
2, test method: with reference to " farm-chemical indoor determination test rule NY/T1154.11-2008 ", adopts rice-stem dipping method.
3, data statistic analysis: analyze with SAS statistical software.Calculate corrected mortality (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50and co-toxicity coefficient.
4, evaluation method: with reference to " farm-chemical indoor determination test rule NY/T1154.7-2006 ", the synergistic effect of pharmacy mix is evaluated according to the co-toxicity coefficient method (CTC) of Sun & Johnson (1960), namely CTC≤80 are antagonism, 80<CTC<120 is summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The mixture combination of diflubenzuron, imidaclothiz and the two different proportion thereof the results are shown in Table 1 to the toxicity test of Brown Planthopper, and " removing: chlorine " in table 1 is writing a Chinese character in simplified form of " diflubenzuron: imidaclothiz ".
Table 1 diflubenzuron and imidaclothiz mixture are to the toxicity test result of Brown Planthopper
Indoor biometrics result shows: diflubenzuron and imidaclothiz carry out mixture with 1: 9,1: 6,1: 3,1: 1,3: 1,6: 1 and 9: 1 ratios, it all shows synergistic effect to Brown Planthopper, wherein the most obvious with the ratio mixed synergies of 1: 6,1: 3,1: 1,3: 1 and 6:1.Consider diflubenzuron and the control of imidaclothiz to Brown Planthopper is better composite with 1-6:1-6.
Biologicall test example 2: imidaclothiz and the urea compounded toxicity test to wheat aphid
1, subjects: wheat aphid [Classification system: Toxopteragraminum], belongs to Homoptera Aphidiadae.
2, test method: with reference to " farm-chemical indoor determination test rule NY/T1154.6-2006 ", adopts dip method.
3, data statistic analysis: analyze with SAS statistical software.Calculate insect corrected mortality (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50and co-toxicity coefficient.
4, evaluation method: with reference to " farm-chemical indoor determination test rule NY/T1154.7-2006 ", the synergistic effect of pharmacy mix is evaluated according to the co-toxicity coefficient method (CTC) of Sun & Johnson (1960), namely CTC≤80 are antagonism, 80<CTC<120 is summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The mixture combination of diflubenzuron, imidaclothiz and the two different proportion thereof the results are shown in Table 2 to the toxicity test of wheat aphid, and " removing: chlorine " in table 2 is writing a Chinese character in simplified form of " diflubenzuron: imidaclothiz ".
Table 2 diflubenzuron and imidaclothiz mixture are to the toxicity test result of wheat aphid
Indoor biometrics result shows: diflubenzuron and imidaclothiz carry out mixture with 1: 12,1: 8,1: 4,1: 1,4: 1,8: 1 and 12: 1 ratios, it shows synergistic effect to wheat aphid, wherein with 1: 8,1: 4,1:1,4:1 and 8: 1 ratio mixed synergies the most obvious.Consider diflubenzuron and the control of imidaclothiz to wheat aphid is better composite with 1-8:1-8.
Biologicall test example 3: imidaclothiz and the urea compounded toxicity test to wooly aphis
1, subjects: wooly aphis [Classification system: ConopomorphasinensisBradley], belongs to Homoptera Aphidiadae.
2, test method: with reference to " farm-chemical indoor determination test rule NY/T1154.6-2006 ", adopts dip method.
3, data statistic analysis: analyze with SAS statistical software.Calculate corrected mortality (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50and co-toxicity coefficient.
4, evaluation method: with reference to " farm-chemical indoor determination test rule NY/T1154.7-2006 ", the synergistic effect of pharmacy mix is evaluated according to the co-toxicity coefficient method (CTC) of Sun & Johnson (1960), namely CTC≤80 are antagonism, 80<CTC<120 is summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The mixture combination of diflubenzuron, imidaclothiz and the two different proportion thereof the results are shown in Table 3 to the toxicity test of wooly aphis, and " removing: chlorine " in table 3 is writing a Chinese character in simplified form of " diflubenzuron: imidaclothiz ".
Table 3 diflubenzuron and imidaclothiz mixture are to the toxicity test result of wooly aphis
Indoor biometrics result shows: diflubenzuron and imidaclothiz carry out mixture with 1: 12,1: 9,1: 6,1: 1,6: 1,9: 1 and 12: 1 ratios, it shows synergistic effect to wooly aphis, wherein with 1: 6, the ratio mixed synergies of 1:1,1:6 and 9:1 is the most obvious.Consider diflubenzuron and the control of imidaclothiz to wooly aphis is better composite with 1-9:1-6.
Biologicall test example 4: imidaclothiz and the urea compounded toxicity test to tea lesser leafhopper
1, subjects: tea lesser leafhopper [Classification system: EmpoascapirisugaMatumura], belongs to Semiptera Cicadellidae.
2, test method: with reference to " farm-chemical indoor determination test rule NY/T1154.7-2006 ", adopts dip method.
3, data statistic analysis: analyze with SAS statistical software.Calculate corrected mortality (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50and co-toxicity coefficient.
4, evaluation method: with reference to " farm-chemical indoor determination test rule NY/T1154.6-2006 ", the synergistic effect of pharmacy mix is evaluated according to the co-toxicity coefficient method (CTC) of Sun & Johnson (1960), namely CTC≤80 are antagonism, 80<CTC<120 is summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The mixture combination of diflubenzuron, imidaclothiz and the two different proportion thereof the results are shown in Table 4 to the toxicity test of tea lesser leafhopper, and " removing: chlorine " in table 4 is writing a Chinese character in simplified form of " diflubenzuron: imidaclothiz ".
Table 4 diflubenzuron and imidaclothiz mixture are to the toxicity test result of tea lesser leafhopper
Indoor biometrics result shows: diflubenzuron and imidaclothiz carry out mixture with 1: 10,1: 5,1: 3,1: 1,3: 1,5: 1 and 10: 1 ratios, it all shows synergistic effect to tea lesser leafhopper, wherein with 1: 10,1: 5,3:1,1: 1, the ratio mixed synergies of 3:1 and 5:1 is the most obvious.Consider diflubenzuron and the control of imidaclothiz to tea lesser leafhopper is better composite with 1-5:1-10.
Biologicall test example 5: imidaclothiz and the urea compounded toxicity test to pear sucker
1, subjects: pear sucker [Classification system: Psyllachinensis], Homoptera Psyllidae.
2, test method: with reference to " farm-chemical indoor determination test rule NY/T1154.8-2007 ", adopts filter paper medicine embrane method.
3, data statistic analysis: analyze with SAS statistical software.Calculate corrected mortality (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50and co-toxicity coefficient.
4, evaluation method: with reference to " farm-chemical indoor determination test rule NY/T1154.7-2006 ", the synergistic effect of pharmacy mix is evaluated according to the co-toxicity coefficient method (CTC) of Sun & Johnson (1960), namely CTC≤80 are antagonism, 80<CTC<120 is summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The mixture combination of diflubenzuron, imidaclothiz and the two different proportion thereof the results are shown in Table 5 to the toxicity test of cotton bollworm, and " removing: chlorine " in table 5 is writing a Chinese character in simplified form of " diflubenzuron: imidaclothiz ".
5 diflubenzurons and imidaclothiz mixture are to the toxicity test result of pear sucker
Indoor biometrics result shows: diflubenzuron and imidaclothiz carry out mixture with 1: 20,1: 10,1: 5,1: 1,5: 1,10: 1 and 20: 1 ratios, it shows synergistic effect to pear sucker, wherein with 1: 10,1: 5, the ratio mixed synergies of 1:1 and 5:1 is the most obvious.Consider diflubenzuron and the control of imidaclothiz to pear sucker is better composite with 1-5:1-10.
Biologicall test example 6: imidaclothiz and the urea compounded toxicity test to oranges and tangerines ash weevil
1, subjects: oranges and tangerines ash weevil [Classification system Sympiezomiacitre (Chao)], belongs to coleoptera Culculionidae.
2, test method: with reference to " farm-chemical indoor determination test rule NY/T1154.6-2006 ", adopts dip method.
3, data statistic analysis: analyze with SAS statistical software.Calculate corrected mortality (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50and co-toxicity coefficient.
4, evaluation method: with reference to " farm-chemical indoor determination test rule NY/T1154.7-2006 ", the synergistic effect of pharmacy mix is evaluated according to the co-toxicity coefficient method (CTC) of Sun & Johnson (1960), namely CTC≤80 are antagonism, 80<CTC<120 is summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The toxicity test of mixture combination to oranges and tangerines ash weevil of diflubenzuron, imidaclothiz and the two different proportion thereof the results are shown in Table 6, and " removing: chlorine " in table 6 is writing a Chinese character in simplified form of " diflubenzuron: imidaclothiz ".
Table 6 diflubenzuron and imidaclothiz mixture are to the toxicity test result of oranges and tangerines ash weevil
Indoor biometrics result shows: diflubenzuron and imidaclothiz carry out mixture with 1: 9,1: 6,1: 3,1: 1,3: 1,6: 1 and 9: 1 ratios, it shows as addition or antagonism to oranges and tangerines ash weevil, does not advise that diflubenzuron and imidaclothiz mixture are for the control to oranges and tangerines ash weevil.
The present composition can with known auxiliary agent and assistant agent, prepare any one formulation in being applicable to agriculturally using by known method, wherein reasonable formulation has missible oil, water dispersible granules, aqueous emulsion, suspending agent, wetting powder and suspension seed-coating agent, and these known auxiliary agents, assistant agent have dispersant, diffusant, defoamer, wetting agent, disintegrant, film forming agent and filler etc.
Be described with instantiation below.
Preparation embodiment 1:
Diflubenzuron 10g, imidaclothiz 10g, calcium dodecyl benzene sulfonate 8g, cyclohexanedione 10g, the agriculture oil that methylates are added to 100g, is mixed to homogeneous liquid phase, the obtained present composition 20% missible oil.
Preparation embodiment 2:
Imidaclothiz 15g, diflubenzuron 25g, sodium methylene bis-naphthalene sulfonate 5g, sodium lignin sulfonate 3g, organic silicone 1g, white carbon are added to 100g, through air-flow crushing, extruder grain, the obtained present composition 40% water dispersible granules.
Preparation embodiment 3:
By imidaclothiz 12.5g, diflubenzuron 12.5g, dodecyl sodium sulfate 5g, polyoxyethylene nonylphenol ether 4g, xanthans 0.3g, polyethylene glycol 3g, add water to 100g, mix through wet grinding, homogenizing, the obtained present composition 25% suspending agent.
Preparation embodiment 4:
Imidaclothiz 25g, diflubenzuron 25g, polyoxyethylene carboxylate 6g, sodium lignin sulfonate 3g, white carbon 5g, kaolin are added to 100g, mixes and obtain the present composition 50% wetting powder through air-flow crushing.
Preparation embodiment 5:
By imidaclothiz 10g, diflubenzuron 5g, 1-METHYLPYRROLIDONE 20g, phenethyl phenol polyethenoxy ether 10g, ethylene glycol 5g, add water to 100g, preparation oil phase, preparation aqueous phase, under high shear, to add in oil phase in oil phase aqueous phase or by aqueous phase, shear the obtained present composition 15% aqueous emulsion.
Preparation embodiment 6:
By imidaclothiz 22.5g, diflubenzuron 12.5g, lauryl sodium sulfate 5g, polyoxyethylene carboxylate 6g, xanthans 0.3g, polyethylene glycol 3g, silicone defoaming agent 0.5g, add water to 100g, mixing is through wet grinding, homogenizing, the obtained present composition 35% suspending agent.
A kind of Pesticidal combination containing imidaclothiz and diflubenzuron of the present invention is described by concrete example, those skilled in the art can use for reference content of the present invention, the links such as suitable feed change, process conditions realize other object corresponding, its relevant change does not all depart from content of the present invention, all similar replacements and change will become apparent to those skilled in the art that and be all deemed to be included within scope of the present invention.
Claims (9)
1. contain a Pesticidal combination for imidaclothiz and diflubenzuron, it is characterized in that, the active component contained by described composition is imidaclothiz and diflubenzuron, and the weight ratio of described imidaclothiz and diflubenzuron is 1-25:1-25.
2. Pesticidal combination according to claim 1, is characterized in that, the weight ratio of described imidaclothiz and diflubenzuron is 2-15:3-15.
3. Pesticidal combination according to claim 1, is characterized in that, the weight ratio of described imidaclothiz and diflubenzuron is 1-10:1-9.
4. Pesticidal combination according to claim 1, is characterized in that, the weight ratio of described imidaclothiz and diflubenzuron is 1:1.
5., according to the arbitrary described Pesticidal combination of Claims 1-4, it is characterized in that, described combination dosage form is wetting powder, water dispersible granules, suspending agent, aqueous emulsion, missible oil or seed coat agent.
6. Pesticidal combination according to claim 5, is characterized in that, described imidaclothiz and the percentage by weight of diflubenzuron in above-mentioned formulation are 5 ~ 50%.
7. the application of the Pesticidal combination control agricultural insect pest as described in as arbitrary in Claims 1-4.
8. application according to claim 7, described agricultural disease is beet armyworm (SpodopteraexiguaHiibner), cabbage pieris (PierisrapaeLinne), Brown Planthopper (Nilaparvatalugens), small brown rice planthopper (Laodelphaxstriatellus), white-backed planthopper (Sogatellafurcifera), thrips (Chloethripsoryzae), striped rice borer (Chilosuppressalis) peach fruit borer (CarposinaniponensisWalsingham), dichocrocis punctiferalis (Conogethespunctiferalis), black peach aphid (Myzuspersicae), Asiatic apple leafminer (LithocolletisringoniellaMats.), olethreutid (AdoxophyesoranaFishervonRoslerstamm), woolly aphid (Eriosomalanigerum), Against Conopomorpha sinensis Bradley (ConopomorphasinensisBradley), pear sucker (Psyllachinensis), pear mealworm (Aphanostigmajakusuiesie), oriental fruit moth (Grapholithamolesta (Busck)), the green cicada of tea leaflet (EmpoascapirisugaMatumura), tea geometrid (EctropisobliquehypulinaWehrli), grape clearwing moth (ParathreneregalisButler), hair siphon-worm (IlliberistenuisBatler), cowpea Americal rice leaf miner (Liriomyzasativae (Blanchard)), cotton bollworm (Helicoverpaarmigerar), wheat mythimna separata (Mythimnaseparata), aphid (Toxopteragraminum), cucumber trialeurodes vaporariorum (Trialeurodesvaporariorum) or aphid (Aphisgossypii).
9. application according to claim 8, described agricultural insect pest is Brown Planthopper, wheat aphid, wooly aphis, tea lesser leafhopper or pear sucker.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07330517A (en) * | 1994-05-30 | 1995-12-19 | Ciba Geigy Ag | Noxious living organism controller |
| CN102726438A (en) * | 2012-06-21 | 2012-10-17 | 江苏绿叶农化有限公司 | Dinotefuran-containing insecticidal composition and its application |
| CN103493840A (en) * | 2013-09-12 | 2014-01-08 | 薛列驹 | Compounded insecticide |
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2015
- 2015-09-30 CN CN201510637985.3A patent/CN105145614A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07330517A (en) * | 1994-05-30 | 1995-12-19 | Ciba Geigy Ag | Noxious living organism controller |
| CN102726438A (en) * | 2012-06-21 | 2012-10-17 | 江苏绿叶农化有限公司 | Dinotefuran-containing insecticidal composition and its application |
| CN103493840A (en) * | 2013-09-12 | 2014-01-08 | 薛列驹 | Compounded insecticide |
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Application publication date: 20151216 |