CN105118686A - 石墨烯/聚苯胺/二氧化锰三元复合电极材料的制备方法 - Google Patents
石墨烯/聚苯胺/二氧化锰三元复合电极材料的制备方法 Download PDFInfo
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- CN105118686A CN105118686A CN201510533489.3A CN201510533489A CN105118686A CN 105118686 A CN105118686 A CN 105118686A CN 201510533489 A CN201510533489 A CN 201510533489A CN 105118686 A CN105118686 A CN 105118686A
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- electrode material
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- polyaniline
- ternary composite
- manganese dioxide
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- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 239000007772 electrode material Substances 0.000 title claims abstract description 31
- 239000011206 ternary composite Substances 0.000 title claims abstract description 23
- 229920000767 polyaniline Polymers 0.000 title claims abstract description 19
- 229910002804 graphite Inorganic materials 0.000 title claims abstract description 13
- 239000010439 graphite Substances 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- -1 Graphite alkene Chemical class 0.000 title abstract 3
- 239000012286 potassium permanganate Substances 0.000 claims abstract description 18
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000178 monomer Substances 0.000 claims abstract description 8
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 35
- 239000000243 solution Substances 0.000 claims description 26
- 229910021389 graphene Inorganic materials 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000008367 deionised water Substances 0.000 claims description 15
- 229910021641 deionized water Inorganic materials 0.000 claims description 15
- 239000000706 filtrate Substances 0.000 claims description 15
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- 239000013067 intermediate product Substances 0.000 claims description 10
- 239000011259 mixed solution Substances 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 238000002242 deionisation method Methods 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 abstract description 4
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 abstract description 3
- 239000003638 chemical reducing agent Substances 0.000 abstract description 3
- 239000007788 liquid Substances 0.000 abstract description 3
- 239000007800 oxidant agent Substances 0.000 abstract description 3
- 230000001351 cycling effect Effects 0.000 abstract 1
- 239000002131 composite material Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000003990 capacitor Substances 0.000 description 5
- 238000002484 cyclic voltammetry Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 239000002048 multi walled nanotube Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000012695 Interfacial polymerization Methods 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000012983 electrochemical energy storage Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000002073 nanorod Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 238000007704 wet chemistry method Methods 0.000 description 1
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- Battery Electrode And Active Subsutance (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Carbon And Carbon Compounds (AREA)
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CN105118686A true CN105118686A (zh) | 2015-12-02 |
CN105118686B CN105118686B (zh) | 2017-12-12 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106024427A (zh) * | 2016-07-29 | 2016-10-12 | 上海交通大学 | 聚苯胺纳米管修饰的超薄石墨烯薄膜电极及其制备方法 |
CN106128802A (zh) * | 2016-07-04 | 2016-11-16 | 上海电力学院 | 一种用于超级电容器的电极材料的制备方法 |
CN106449148A (zh) * | 2016-11-22 | 2017-02-22 | 中国地质大学(北京) | 一种管状二氧化锰/聚苯胺/石墨烯复合材料的制备方法 |
CN112768258A (zh) * | 2020-12-29 | 2021-05-07 | 同济大学 | 聚苯胺负载铝掺杂二氧化锰@碳布基柔性超级电容器电极材料及其制备方法和应用 |
CN114520321A (zh) * | 2022-02-10 | 2022-05-20 | 北京理工大学 | 一种石墨@二氧化锰/聚合物复合正极材料及其制备方法和应用 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101085866A (zh) * | 2007-06-13 | 2007-12-12 | 辽宁大学 | 聚苯胺插层锰氧化物复合材料的水热制备方法 |
CN101157800A (zh) * | 2007-09-26 | 2008-04-09 | 华东理工大学 | 自分散型导电聚苯胺/硅复合材料的制备方法 |
CN101613098A (zh) * | 2009-06-12 | 2009-12-30 | 中国科学院宁波材料技术与工程研究所 | 一种石墨烯的溶液相制备方法 |
CN101696323A (zh) * | 2009-10-30 | 2010-04-21 | 华南师范大学 | 一种用于超级电容器的聚苯胺/二氧化锰复合材料的制备方法 |
CN101830458A (zh) * | 2010-05-06 | 2010-09-15 | 西安交通大学 | 一种高纯度、高浓度石墨烯悬浮液的制备方法 |
CN102093712A (zh) * | 2010-11-13 | 2011-06-15 | 中国石油大学(华东) | 一种复合型超级电容器电极材料的制备方法 |
CN102225754A (zh) * | 2011-05-11 | 2011-10-26 | 中国科学技术大学 | 氧化石墨烯的制备方法及石墨烯的制备方法 |
CN102977602A (zh) * | 2012-12-11 | 2013-03-20 | 华东理工大学 | 一种制备二氧化锰/碳材料/导电聚合物复合材料的方法 |
-
2015
- 2015-08-27 CN CN201510533489.3A patent/CN105118686B/zh active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101085866A (zh) * | 2007-06-13 | 2007-12-12 | 辽宁大学 | 聚苯胺插层锰氧化物复合材料的水热制备方法 |
CN101157800A (zh) * | 2007-09-26 | 2008-04-09 | 华东理工大学 | 自分散型导电聚苯胺/硅复合材料的制备方法 |
CN101613098A (zh) * | 2009-06-12 | 2009-12-30 | 中国科学院宁波材料技术与工程研究所 | 一种石墨烯的溶液相制备方法 |
CN101696323A (zh) * | 2009-10-30 | 2010-04-21 | 华南师范大学 | 一种用于超级电容器的聚苯胺/二氧化锰复合材料的制备方法 |
CN101830458A (zh) * | 2010-05-06 | 2010-09-15 | 西安交通大学 | 一种高纯度、高浓度石墨烯悬浮液的制备方法 |
CN102093712A (zh) * | 2010-11-13 | 2011-06-15 | 中国石油大学(华东) | 一种复合型超级电容器电极材料的制备方法 |
CN102225754A (zh) * | 2011-05-11 | 2011-10-26 | 中国科学技术大学 | 氧化石墨烯的制备方法及石墨烯的制备方法 |
CN102977602A (zh) * | 2012-12-11 | 2013-03-20 | 华东理工大学 | 一种制备二氧化锰/碳材料/导电聚合物复合材料的方法 |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106128802A (zh) * | 2016-07-04 | 2016-11-16 | 上海电力学院 | 一种用于超级电容器的电极材料的制备方法 |
CN106128802B (zh) * | 2016-07-04 | 2018-01-26 | 上海电力学院 | 一种用于超级电容器的电极材料的制备方法 |
CN106024427A (zh) * | 2016-07-29 | 2016-10-12 | 上海交通大学 | 聚苯胺纳米管修饰的超薄石墨烯薄膜电极及其制备方法 |
CN106024427B (zh) * | 2016-07-29 | 2019-04-09 | 上海交通大学 | 聚苯胺纳米管修饰的超薄石墨烯薄膜电极及其制备方法 |
CN106449148A (zh) * | 2016-11-22 | 2017-02-22 | 中国地质大学(北京) | 一种管状二氧化锰/聚苯胺/石墨烯复合材料的制备方法 |
CN106449148B (zh) * | 2016-11-22 | 2018-01-30 | 中国地质大学(北京) | 一种管状二氧化锰/聚苯胺/石墨烯复合材料的制备方法 |
CN112768258A (zh) * | 2020-12-29 | 2021-05-07 | 同济大学 | 聚苯胺负载铝掺杂二氧化锰@碳布基柔性超级电容器电极材料及其制备方法和应用 |
CN112768258B (zh) * | 2020-12-29 | 2022-09-20 | 同济大学 | 聚苯胺负载铝掺杂二氧化锰@碳布基柔性超级电容器电极材料及其制备方法和应用 |
CN114520321A (zh) * | 2022-02-10 | 2022-05-20 | 北京理工大学 | 一种石墨@二氧化锰/聚合物复合正极材料及其制备方法和应用 |
CN114520321B (zh) * | 2022-02-10 | 2024-01-26 | 北京理工大学 | 一种石墨@二氧化锰/聚合物复合正极材料及其制备方法和应用 |
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Application publication date: 20151202 Assignee: Guilin Qi Hong Technology Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980044172 Denomination of invention: Preparation method of graphene/polyaniline/manganese dioxide ternary composite electrode material Granted publication date: 20171212 License type: Common License Record date: 20231024 |
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Application publication date: 20151202 Assignee: Sales and Operation Department of Qiyue Paper Products in Xixiangtang District, Nanning Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980044309 Denomination of invention: Preparation method of graphene/polyaniline/manganese dioxide ternary composite electrode material Granted publication date: 20171212 License type: Common License Record date: 20231027 |
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