CN105113015A - Low-reflectivity monocrystalline silicon piece texture surface making liquid and preparation method thereof - Google Patents
Low-reflectivity monocrystalline silicon piece texture surface making liquid and preparation method thereof Download PDFInfo
- Publication number
- CN105113015A CN105113015A CN201510515172.7A CN201510515172A CN105113015A CN 105113015 A CN105113015 A CN 105113015A CN 201510515172 A CN201510515172 A CN 201510515172A CN 105113015 A CN105113015 A CN 105113015A
- Authority
- CN
- China
- Prior art keywords
- monocrystalline silicon
- reflectivity
- water
- component
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses low-reflectivity monocrystalline silicon piece texture surface making liquid. The low-reflectivity monocrystalline silicon piece texture surface making liquid is characterized by being prepared from, by weight, 0.5-1 part of sodium hydroxide, 3-5 parts of auxiliaries, 2-4 parts of ethoxy urea, 0.1-0.2 part of xanthan gum, 0.5-1 part of sodium lauroyl sarcosine, 0.1-0.2 part of decyl glucoside, 0.1-0.2 part of isopropyl myristate, 0.01-0.02 part of N-beta-hydroxyethyl ethylenediamine triacetate and 80-100 parts of water. According to the texture surface making liquid, the consistency and repeatability of a texture surface making process are effectively improved, the density of a fabric surface is increased, the dense fabric surface is formed, the surface reflectivity of silicon pieces is reduced, the photoelectric conversion efficiency is improved, and therefore the efficiency of a solar cell is improved, and product quality is improved. No IPA is included, environmental protection and human health are facilitated, and safety and environment friendliness are achieved.
Description
Technical field
The present invention relates to silicon wafer wool making technology, be specifically related to a kind of antiradar reflectivity wool making solution for monocrystalline silicon pieces and preparation method thereof.
Background technology
Along with energy dilemma is on the rise, sun power has become following most potential substitute energy, and solar cell industry development rapidly.Restrict one of difficult problem of its development is exactly how to improve solar cell photoelectric transformation efficiency, reduce costs.Wherein leather producing process is the important step improving photoelectric transformation efficiency.
Making herbs into wool is also known as " surface-texturing ", and effective suede structure makes incident light in silicon chip surface multiple reflections and refraction, adds the absorption of light, reduces reflectivity, contributes to the performance improving battery.Solar battery sheet reflectivity is low, and the battery conversion efficiency of solar battery sheet is high, just effectively can reduce its cost of electricity-generating silicon single crystal leather producing process and the most often use chemical corrosion method, generally uses NaOH/ Virahol (IPA) system.IPA has suitable toxicity, has harm to human body, and IPA is easy to volatilization in making herbs into wool process simultaneously, produces detrimentally affect to environment.
Summary of the invention
The object of this invention is to provide a kind of antiradar reflectivity wool making solution for monocrystalline silicon pieces.
The present invention is achieved by the following technical solutions:
A kind of antiradar reflectivity wool making solution for monocrystalline silicon pieces, it is obtained by the raw material of following weight parts:
Sodium hydroxide 0.5-1, auxiliary agent 3-5, hydroxyethyl urea 2-4, xanthan gum 0.1-0.2, sodium lauroyl sareosine 0.5-1, decyl glucoside 0.1-0.2, Isopropyl myristate 0.1-0.2, N-beta-hydroxy ethyl-3-acetic acid ethylenediamine 0.01-0.02, water 80-100;
Wherein auxiliary agent is made up of the raw material of following weight part: Chinese honey locust 10-15, nano titanium oxide 0.1-0.15, ammonium persulphate 0.1-0.2, vinyl-acetic ester 1-1.5, sodium bicarbonate 0.2-0.4, Dodecyl Polyglucosides 1-2, water 100-150; The preparation method of auxiliary agent is by spaonin powder comminution powder, the spaonin powder obtained and sodium bicarbonate, Dodecyl Polyglucosides are added to the water jointly 70-80 DEG C, 200-400r/min stirs 4-6h, cooled and filtered, vinyl-acetic ester and nano titanium oxide is added and ultrasonic disperse 5-10min in filtrate, then ammonium persulfate solution 70-80 DEG C that adds 2-5% is stirred 1-2h, cooled and filtered, to obtain final product.
A preparation method for antiradar reflectivity wool making solution for monocrystalline silicon pieces, comprises the following steps:
(1) sodium lauroyl sareosine, decyl glucoside are jointly added in the water of 1/3-1/2 weight, first 400-600r/min stirs 5-10min, then add Isopropyl myristate 70-80 DEG C, 400-600r/min stirs 10-20min, must component A after cooling;
(2) first sodium hydroxide is dissolved in remaining water, then adds all the other raw materials 40-60 DEG C, 200-400r/min stirs 2-4h, obtain B component;
(3) by mixed to component A and B component be incorporated in 70-80 DEG C, stir 10-15min under 1000-1500r/min condition, namely obtain antiradar reflectivity wool making solution for monocrystalline silicon pieces after filtration.
Advantage of the present invention is:
The present invention adopts the composite of the raw materials such as sodium lauroyl sareosine, the surface tension of effective hierarchy of control, the system of formation is made to have good surface property, stability and dispersive ability, there is good clean clean effect simultaneously, and in conjunction with auxiliary agent, surface modification is carried out to silicon chip, increase the nucleation site of silicon chip surface, promote the anisotropy of silicon single crystal, improve pyramidal density, by silicon chip surface film forming, control silicon chip corrosion speed in alkali lye, effectively improve consistence and the repeatability of leather producing process, improve matte density, form intensive matte, reduce the surface albedo of silicon chip, improve photoelectric transformation efficiency, thus improve solar battery efficiency, improve quality product, not containing IPA, be conducive to environment protection and HUMAN HEALTH, safety and environmental protection.
Embodiment
Non-limiting examples of the present invention is as follows:
A kind of antiradar reflectivity wool making solution for monocrystalline silicon pieces, is prepared from by the component raw material of following weight (kg):
Sodium hydroxide 0.5, auxiliary agent 3, hydroxyethyl urea 2, xanthan gum 0.1, sodium lauroyl sareosine 0.5, decyl glucoside 0.1, Isopropyl myristate 0.1, N-beta-hydroxy ethyl-3-acetic acid ethylenediamine 0.01, water 80;
Wherein, auxiliary agent is made up of the raw material of following weight (kg): Chinese honey locust 10, nano titanium oxide 0.1, ammonium persulphate 0.1, vinyl-acetic ester 1, sodium bicarbonate 0.2, Dodecyl Polyglucosides 1, water 100; The preparation method of auxiliary agent is by spaonin powder comminution powder, the spaonin powder obtained and sodium bicarbonate, Dodecyl Polyglucosides are added to the water jointly 80 DEG C, 200r/min stirs 4h, cooled and filtered, vinyl-acetic ester and nano titanium oxide is added and ultrasonic disperse 5min in filtrate, then the ammonium persulfate solution 70 DEG C adding 2% stirs 1h, cooled and filtered, to obtain final product.
The preparation method of antiradar reflectivity wool making solution for monocrystalline silicon pieces comprises the following steps:
(1) sodium lauroyl sareosine, decyl glucoside are jointly added in the water of 1/3 weight, first 400r/min stirs 5min, then add Isopropyl myristate 80 DEG C, 400r/min stirs 10min, must component A after cooling;
(2) first sodium hydroxide is dissolved in remaining water, then adds all the other raw materials 60 DEG C, 400r/min stirs 2h, obtain B component;
(3) by mixed to component A and B component be incorporated in 80 DEG C, stir 15min under 1000r/min condition, namely obtain antiradar reflectivity wool making solution for monocrystalline silicon pieces after filtration.
Monocrystalline silicon piece is put into above-mentioned obtained Woolen-making liquid, under 80 DEG C of condition of water bath heating, carry out making herbs into wool, the making herbs into wool time is 15min, and the surface albedo of monocrystalline silicon piece is 8.5%, and matte pyramid is of a size of 1.5-3 μm, and size is even.
Claims (2)
1. an antiradar reflectivity wool making solution for monocrystalline silicon pieces, is characterized in that, it is obtained by the raw material of following weight parts:
Sodium hydroxide 0.5-1, auxiliary agent 3-5, hydroxyethyl urea 2-4, xanthan gum 0.1-0.2, sodium lauroyl sareosine 0.5-1, decyl glucoside 0.1-0.2, Isopropyl myristate 0.1-0.2, N-beta-hydroxy ethyl-3-acetic acid ethylenediamine 0.01-0.02, water 80-100;
Described auxiliary agent is made up of the raw material of following weight part: Chinese honey locust 10-15, nano titanium oxide 0.1-0.15, ammonium persulphate 0.1-0.2, vinyl-acetic ester 1-1.5, sodium bicarbonate 0.2-0.4, Dodecyl Polyglucosides 1-2, water 100-150; The preparation method of auxiliary agent is by spaonin powder comminution powder, the spaonin powder obtained and sodium bicarbonate, Dodecyl Polyglucosides are added to the water jointly 70-80 DEG C, 200-400r/min stirs 4-6h, cooled and filtered, vinyl-acetic ester and nano titanium oxide is added and ultrasonic disperse 5-10min in filtrate, then ammonium persulfate solution 70-80 DEG C that adds 2-5% is stirred 1-2h, cooled and filtered, to obtain final product.
2. the preparation method of a kind of antiradar reflectivity wool making solution for monocrystalline silicon pieces according to claim 1, is characterized in that, comprise the following steps:
(1) sodium lauroyl sareosine, decyl glucoside are jointly added in the water of 1/3-1/2 weight, first 400-600r/min stirs 5-10min, then add Isopropyl myristate 70-80 DEG C, 400-600r/min stirs 10-20min, must component A after cooling;
(2) first sodium hydroxide is dissolved in remaining water, then adds all the other raw materials 40-60 DEG C, 200-400r/min stirs 2-4h, obtain B component;
(3) by mixed to component A and B component be incorporated in 70-80 DEG C, stir 10-15min under 1000-1500r/min condition, namely obtain antiradar reflectivity wool making solution for monocrystalline silicon pieces after filtration.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510515172.7A CN105113015A (en) | 2015-08-21 | 2015-08-21 | Low-reflectivity monocrystalline silicon piece texture surface making liquid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510515172.7A CN105113015A (en) | 2015-08-21 | 2015-08-21 | Low-reflectivity monocrystalline silicon piece texture surface making liquid and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105113015A true CN105113015A (en) | 2015-12-02 |
Family
ID=54661111
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510515172.7A Pending CN105113015A (en) | 2015-08-21 | 2015-08-21 | Low-reflectivity monocrystalline silicon piece texture surface making liquid and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105113015A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110295395A (en) * | 2019-07-16 | 2019-10-01 | 中国科学院上海硅酸盐研究所 | A kind of monocrystalline silicon flocking additive and its application for adding graphene oxide quantum dot |
| CN113981543A (en) * | 2021-11-02 | 2022-01-28 | 常州君合科技股份有限公司 | Texturing additive with liquid crystal structure and preparation method and application thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101717946A (en) * | 2009-12-30 | 2010-06-02 | 江阴市润玛电子材料有限公司 | Liquid and method for etching texture on surfaces of silicon wafers |
| CN103219427A (en) * | 2013-04-10 | 2013-07-24 | 中国科学院微电子研究所 | Method for realizing single-sided texturing of high-light-trapping nano structure |
| CN103451739A (en) * | 2013-09-04 | 2013-12-18 | 常州时创能源科技有限公司 | Monocrystalline silicon wafer texturizing additive and using method thereof |
| CN103614778A (en) * | 2013-11-25 | 2014-03-05 | 英利能源（中国）有限公司 | Alcohol-free alkaline texturing solution for mono-crystalline silicon wafer, texturing method for mono-crystalline silicon wafer, solar cell and manufacturing method for solar cell |
| CN103938276A (en) * | 2013-01-23 | 2014-07-23 | 尚德太阳能电力有限公司 | Monocrystalline silicon wafer texturing additive, texturing solution and corresponding texturing method |
| CN104576831A (en) * | 2014-12-31 | 2015-04-29 | 江苏顺风光电科技有限公司 | Monocrystalline silicon wafer alcohol-free texturing process and texturing additive |
-
2015
- 2015-08-21 CN CN201510515172.7A patent/CN105113015A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101717946A (en) * | 2009-12-30 | 2010-06-02 | 江阴市润玛电子材料有限公司 | Liquid and method for etching texture on surfaces of silicon wafers |
| CN103938276A (en) * | 2013-01-23 | 2014-07-23 | 尚德太阳能电力有限公司 | Monocrystalline silicon wafer texturing additive, texturing solution and corresponding texturing method |
| CN103219427A (en) * | 2013-04-10 | 2013-07-24 | 中国科学院微电子研究所 | Method for realizing single-sided texturing of high-light-trapping nano structure |
| CN103451739A (en) * | 2013-09-04 | 2013-12-18 | 常州时创能源科技有限公司 | Monocrystalline silicon wafer texturizing additive and using method thereof |
| CN103614778A (en) * | 2013-11-25 | 2014-03-05 | 英利能源（中国）有限公司 | Alcohol-free alkaline texturing solution for mono-crystalline silicon wafer, texturing method for mono-crystalline silicon wafer, solar cell and manufacturing method for solar cell |
| CN104576831A (en) * | 2014-12-31 | 2015-04-29 | 江苏顺风光电科技有限公司 | Monocrystalline silicon wafer alcohol-free texturing process and texturing additive |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110295395A (en) * | 2019-07-16 | 2019-10-01 | 中国科学院上海硅酸盐研究所 | A kind of monocrystalline silicon flocking additive and its application for adding graphene oxide quantum dot |
| CN110295395B (en) * | 2019-07-16 | 2021-04-16 | 中国科学院上海硅酸盐研究所 | Monocrystalline silicon texturing additive added with graphene oxide quantum dots and application thereof |
| CN113981543A (en) * | 2021-11-02 | 2022-01-28 | 常州君合科技股份有限公司 | Texturing additive with liquid crystal structure and preparation method and application thereof |
| CN113981543B (en) * | 2021-11-02 | 2024-04-12 | 常州君合科技股份有限公司 | Texturing additive with liquid crystal structure and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105113009A (en) | Environment-friendly monocrystalline silicon piece texturing liquid and preparation method thereof | |
| CN105113014A (en) | Monocrystalline silicon wafer texturization liquid capable of removing peculiar smells and preparation method thereof | |
| TWI532824B (en) | Single crystal silicon chip velvet additive, velveteen and its velvet method | |
| CN105113017A (en) | Coptis extract silicon slice texturing agent and preparation method thereof | |
| CN105133026A (en) | Low-damage monocrystalline silicon slice texturing solution and preparation method thereof | |
| CN106087068A (en) | A kind of amino of chitosan sulfonic acid monocrystaline silicon solar cell sheet surface texture liquid and preparation method thereof | |
| CN105133027A (en) | Small-textured-face monocrystalline silicon slice texturing solution and preparation method thereof | |
| CN105133023A (en) | Low-volatility monocrystalline silicon slice texturing solution and preparation method thereof | |
| CN105113015A (en) | Low-reflectivity monocrystalline silicon piece texture surface making liquid and preparation method thereof | |
| CN105113012A (en) | High-homogeneity monocrystalline silicon piece texture surface making liquid and preparation method thereof | |
| CN105977343A (en) | Monocrystalline silicon solar cell surface texture liquid having high stability and tannin extract and preparation method thereof | |
| CN102877130B (en) | Preparation method of bismuth ferrite BiFeO3 monocrystal micrometer sheet | |
| CN105154984A (en) | Easy-to-clean monocrystalline silicon wafer texturing solution and preparation method thereof | |
| CN105133035A (en) | Cleaning and decontaminating silicon wafer texturing agent and preparation method therefor | |
| CN101168602B (en) | Corn protein/cellulose mixed solution, and preparation method and use thereof | |
| CN105113013A (en) | Efficient and environment-friendly monocrystalline silicon piece texture surface making liquid and preparation method thereof | |
| CN105206687A (en) | Efficient and rapid monocrystalline silicon wafer texturing solution and preparation method thereof | |
| CN105113010A (en) | Environmentally-friendly monocrystalline silicon wafer texturing liquor and preparation method thereof | |
| CN105088351A (en) | Low-reflectivity silicon wafer texturing agent and preparation method thereof | |
| CN105133024A (en) | Low-residue monocrystalline silicon slice texturing solution and preparation method thereof | |
| CN102732886A (en) | Matte manufacturing solution of solar energy single crystal silicon wafers and its preparation method | |
| CN105133034A (en) | Antibacterial silicon wafer texturing agent and preparation method therefor | |
| CN105133025A (en) | High-efficiency monocrystalline silicon slice texturing solution and preparation method thereof | |
| CN106012028A (en) | Single crystalline silicon solar cell piece surface texture solution containing peach gum and preparation method thereof | |
| CN105113011A (en) | Degreasing monocrystalline silicon piece texture surface making liquid and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151202 |
|
| RJ01 | Rejection of invention patent application after publication |