CN105084814A - Self-expansion sand-free ceramic tile gap filling treatment material and preparation method thereof - Google Patents
Self-expansion sand-free ceramic tile gap filling treatment material and preparation method thereof Download PDFInfo
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- CN105084814A CN105084814A CN201510504514.5A CN201510504514A CN105084814A CN 105084814 A CN105084814 A CN 105084814A CN 201510504514 A CN201510504514 A CN 201510504514A CN 105084814 A CN105084814 A CN 105084814A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00663—Uses not provided for elsewhere in C04B2111/00 as filling material for cavities or the like
- C04B2111/00672—Pointing or jointing materials
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a self-expansion sand-free ceramic tile gap filling treatment material and a preparation method thereof, belonging to the technical field of landfill materials. The self-expansion sand-free ceramic tile gap filling treatment material comprises a component A and a component B. The component A is prepared from the following raw materials in parts by weight: 95-105 parts of epoxy resin, 10-15 parts of reactive diluent, 2-5 parts of lauryl sodium sulfate, 1-2 parts of defoaming agent, 1-2 parts of leveling agent, 0.5-1 part of dispersing agent, 5-10 parts of organic soil and 250-300 parts of functional material. The component B is prepared from the following raw material in parts by weight: 20-30 parts of epoxy curing agent. The self-expansion sand-free ceramic tile gap filling treatment material has the advantages of high compression resistance, high tensile strength, high flexibility and microexpansive volume. The experiment proves that the compression strength of the self-expansion sand-free ceramic tile gap filling treatment material can reach 40 MPa or above, the tensile strength can reach 12 MPa or above, the bonding strength for the wet substrate can reach 3 MPa or above, and the material can slightly expand after reaction, thereby resisting cracking.
Description
Technical field:
The present invention relates to a kind of for ceramic tile gap process and decoration, be specifically related to a kind of self-expanding and completely fill out process material without husky ceramic tile gap.
Background technology:
It is main ingredient that self-expanding completely fills out process material with epoxy resin without husky ceramic tile gap, the bi-component reaction-type process material with water-proof function generated after reacting with modified amine curing agent.But asphalt mixtures modified by epoxy resin lipid is crisp, volumetric shrinkage, poor flexibility in cross-linking process, limits the application of epoxy resin to a certain extent.At present, have report repeatly to the research of epoxy resin gap process material, but the fragility improving epoxy resin can only be given prominence to, volume stability after solidification, and the volumetric expansion to system, the research without husky cracking resistance etc. almost do not have.Such as, prior art CN201210127269 discloses a kind of bi-component epoxy spackling and preparation method thereof, a kind of bi-component epoxy spackling.Comprise A, B two components, its feature, wherein: component A, this component A consists of the following composition by weight percentage: aqueous epoxy resins 13.5-33.5%, quartz sand 25.5-68.5%, propylene glycol 0.5-2.5%, glitter powder 1-5%, organosilicon flow agent 1-5%, talcum powder 1-31%; B component, this B component consists of the following composition by weight percentage: aqueous epoxy curing agent 90-95% phenol 5-10%.Component A and B component are prepared rear and are packed respectively.The weight ratio of component A and B component is 10:1-4, during use by certainty ratio be in harmonious proportion evenly bi-component epoxy spackling.A kind of bi-component epoxy spackling of the present invention has joint filling and decoration function to mosaic or ceramic tile, not only can at the material substituting cement as the joint filling between mosaic or ceramic tile etc., and, safety, efficient, have no side effect.A kind of bi-component epoxy spackling of the present invention is applicable to the joint filling such as mosaic or ceramic tile and decoration.Although this material provides a kind of ceramic tile joint filling material, can be used for ceramic tile gap filling, can not obtain one and have self-expanding, and facade contain a large amount of quartz sand, final effect, state are completely different with the present invention from design concept.
Summary of the invention:
Technical problem to be solved by this invention is, provides a kind of and has self-expanding, the self-expanding of cracking resistance completely fills out process material without husky ceramic tile gap.
The technical scheme that the present invention solves the employing of its technical problem is: a kind of self-expanding completely fills out process material without husky ceramic tile gap, comprises A, B two components, and each component is completely filled out in process material composed as follows with parts by weight in self-expanding without husky ceramic tile gap:
In the component of above table, sodium lauryl sulphate or be all present in component A or be all present in B component or arbitrary proportion portions exists in A and B; Functional filler or be all present in component A or be all present in B component or arbitrary proportion portions exists in A and B.
Further, described epoxy resin is selected from one or more mixtures in bisphenol A epoxide resin, bisphenol F epoxy resin and novolac epoxy.
Further, described reactive thinner is selected from polypropylene glycol diglycidyl ether and/or ethylene glycol bisthioglycolate glyceryl ether.
Further, described dispersion agent is selected from byk-104s, HX-4020 or HX-4040.
Further, described defoamer is selected from one or more the mixture in silicone based defoamer.
Further, described flow agent is selected from one or more the mixture in polysiloxane-based and esters of acrylic acid flow agent.
Further, described anti-settling agent is selected from one or more the mixture in organobentonite.
Further, described sodium lauryl sulphate of selecting is one or both mixtures that technical grade, analytical pure, top grade are pure etc.
Further, described functional filler is selected from one or more the mixture in barium sulfate, mica powder, talcum powder, calcium carbonate, cement, silica powder.
Further, described epoxy hardener is selected from the mixture of one or more in aliphatic amide, polyamide-based solidifying agent.
Preferably, the preparation method of process material is completely filled out in the self-expanding of the present invention without husky ceramic tile gap, comprise the following steps:
The composition of component A is mixed, obtains component A; By B component composition mix
Close evenly, obtain B component;
Sodium lauryl sulphate or be all present in component A or be all present in B component or arbitrary proportion portions exists in A and B; Functional filler or be all present in component A or be all present in B component or arbitrary proportion portions exists in A and B.
The each component of two A, B of above-mentioned preparation, during use, by gained A, B component mixing by high-speed stirring Decentralized Pull in bubble, is then filled in ceramic tile gap.
The present invention introduces bubble by adopting the material such as sodium lauryl sulphate, solidifying agent by high speed dispersion, during use, exothermic heat of reaction produces the principle expanded, what substantially improve this epoxy material is cross-linked as the volume stability solid-state process from liquid state, more effectively can carry out filling decoration to ceramic tile gap.
The self-expanding of the present invention is completely filled out process material without husky ceramic tile gap and is had quite high ultimate compression strength, folding strength, volume stability, self-expanding.Experiment proves, the self-expanding of the present invention completely fills out expiring the degree of filling out and can reaching 100% of process material without husky ceramic tile gap, and ultimate compression strength can reach more than 40MPa, and moist substrate bonding intensity can reach more than 3MPa, folding strength can reach more than 30MPa, and system is without sand, surface compact.
Embodiment
Below in conjunction with embodiment, the invention will be further described, but the present invention is not limited to following examples.
Embodiment 1
By 95 parts of dihydroxyphenyl propane liquid-state epoxy resin E44,12 parts of polypropylene glycol diglycidyl ethers, 1 part of dispersion agent byk-104s, 1 part of silicone based defoamer BYK-A530,1 part of flow agent modified organic silicon class flow agent BYK310,5 parts of organobentonites, 250 parts of functional fillers comprise 50 parts, barium sulfate, mica powder 50 parts, talcum powder 50 parts, white cement 50 parts, coarse whiting 50 parts, 2 parts of sodium lauryl sulphate, mix and obtain component A;
By 20 parts of fatty amines solidifying agent, 3 parts of sodium lauryl sulphate, mix and obtain B component.
In use, ceramic tile gap is spread upon by after above-mentioned gained A, B component mixing also high-speed stirring dispersion.
Embodiment 2
By 95 parts of dihydroxyphenyl propane liquid-state epoxy resin E51,10 parts of polypropylene glycol diglycidyl ethers, 0.6 part of dispersion agent byk-104s, the mixture of 1 part of defoamer modified organic silicon BYK-A530 and DEFOM6500,1 part of flow agent modified organic silicon class LEVASLIP810,10 parts of organobentonites, 250 parts of functional fillers comprise 50 parts, barium sulfate, 800 order mica powder 50 parts, 400 order talcum powder 50 parts, the white cement 50 parts of class 4 2.5,325 order coarse whiting 50 parts, 2 parts of sodium lauryl sulphate, mix and obtain component A mixture;
By 22 parts of fatty amines solidifying agent, 2 sodium lauryl sulphate, mix and obtain B component;
In use, ceramic tile gap is filled in by after above-mentioned gained A, B component mixing also high-speed stirring dispersion.
Embodiment 3
By 95 parts of bisphenol F epoxy resin F652,10 parts of ethylene glycol diglycidylethers, 1 part of dispersion agent agent HX-4020,1 part of defoamer DEFOM6500, the esters of acrylic acid flow agent LEVASLIP839 of 1 part of fluorine richness, 3 parts of sodium lauryl sulphate, 280 parts of functional fillers comprise 80 parts of talcum powder, 100 part of 325 order silica powder, 100 part of 400 order coarse whiting, 8 parts of organobentonites, mix and obtain component A;
By 22 parts of fatty amines solidifying agent, 1 part of sodium lauryl sulphate, mixes and obtains B component;
In use, ceramic tile gap is filled in by after above-mentioned gained A, B component mixing also high-speed stirring dispersion.
Embodiment 4
By 105 parts of liquefied phenol formaldehyde epoxy resin F51,15 parts of polypropylene glycol diglycidyl ethers, 0.5 part of dispersion agent, 1 part of defoamer DEFOM6500,1 part of flow agent acrylate SKR-1153,5 parts of organobentonites, 290 parts of functional fillers comprise 90 parts of white cements, 20 parts of barium sulfate, 90 part of 325 order silica powder, 90 part of 600 order coarse whiting, 2 parts of sodium lauryl sulphate, mix and obtain component A;
By 20 parts of fatty amines curing agent mixtures, 4 parts of sodium lauryl sulphate, mix and obtain B component;
In use, ceramic tile gap is filled in by after above-mentioned gained A, B component mixing also high-speed stirring dispersion.
Embodiment 5
By the mixture of 105 parts of liquefied phenol formaldehyde epoxy resin F51 and bisphenol A epoxide resin E51, the mixture of 14 parts of polypropylene glycol diglycidyl ethers and diglycidyl ether of ethylene glycol, the mixture of 0.3 part of dispersion agent HX-4040 and BYK104s, 2 parts of silicone based defoamer DEFOM6500, 2 parts of flow agents: the mixture of acrylate flow agent SKR-1153 and BYK310, 3 parts of sodium lauryl sulphate, 5 parts of organobentonites, 160 parts of functional fillers comprise 3 parts of silica mixture, 30 parts of white cements, 30 parts of barium sulfate, 30 part of 325 order silica powder, 67 part of 600 order coarse whiting, mix and obtain component A,
By 20 parts of polyamide-based solidifying agent, 4 parts of sodium lauryl sulphate, 100 parts of functional fillers comprise 10 parts of white cements, 60 part of 325 order silica powder, 30 part of 400 order coarse whiting, and 5 parts of anti-settling agent organobentonite mixtures, mix and obtain B component;
In use, ceramic tile gap is filled in by after above-mentioned gained A, B component mixing also high-speed stirring dispersion.
The self-expanding prepared by above-described embodiment 1 ~ 5 is completely filled out process material without husky ceramic tile gap and is carried out performance test, and the performance test results is as shown in table 1 below;
The performance test results of process material is completely filled out in self-expanding prepared by table 1 embodiment 1 ~ 5 without husky ceramic tile gap
As shown in Table 1, embodiment 1 ~ 5 prepare self-expanding without husky ceramic tile gap completely fill out process material can ceramic tile analyze in microdilatancy, ultimate compression strength can reach more than 50MPa, and folding strength can reach more than 30MPa, and shrinking percentage is extremely low, does not ftracture.
Claims (6)
1. self-expanding completely fills out a process material without husky ceramic tile gap, it is characterized in that, comprises A, B two components, and each component is completely filled out in process material composed as follows with parts by weight in self-expanding without husky ceramic tile gap:
In the component of above table, sodium lauryl sulphate or be all present in component A or be all present in B component or arbitrary proportion portions exists in A and B; Functional filler or be all present in component A or be all present in B component or arbitrary proportion portions exists in A and B.
2. completely fill out process material according to a kind of self-expanding of claim 1 without husky ceramic tile gap, it is characterized in that, described epoxy resin is selected from one or more mixtures in bisphenol A epoxide resin, bisphenol F epoxy resin and novolac epoxy; Described reactive thinner is selected from polypropylene glycol diglycidyl ether and/or ethylene glycol bisthioglycolate glyceryl ether; Described dispersion agent is selected from byk-104s, HX-4020 or HX-4040; Described defoamer is selected from one or more the mixture in silicone based defoamer; Described flow agent is selected from one or more the mixture in polysiloxane-based and esters of acrylic acid flow agent; Described anti-settling agent is selected from one or more the mixture in organobentonite.
3. completely fill out process material according to a kind of self-expanding of claim 1 without husky ceramic tile gap, it is characterized in that, described functional filler is selected from one or more the mixture in barium sulfate, mica powder, talcum powder, calcium carbonate, cement, silica powder.
4. completely fill out process material according to a kind of self-expanding of claim 1 without husky ceramic tile gap, it is characterized in that, described epoxy hardener is selected from the mixture of one or more in aliphatic amide, polyamide-based solidifying agent.
5. the method for process material is completely filled out in a kind of self-expanding preparing claim 1 without husky ceramic tile gap, it is characterized in that, mixed by the composition of component A, obtain component A; By B component composition mix, obtain B component;
Sodium lauryl sulphate or be all present in component A or be all present in B component or arbitrary proportion portions exists in A and B; Functional filler or be all present in component A or be all present in B component or arbitrary proportion portions exists in A and B.
6. use a kind of self-expanding of claim 1 completely to fill out the method for process material without husky ceramic tile gap, it is characterized in that, by gained A, B component mixing by high-speed stirring Decentralized Pull in bubble, be then filled in ceramic tile gap.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510504514.5A CN105084814B (en) | 2015-08-17 | 2015-08-17 | Processing material and preparation method are completely filled out in a kind of self-expanding without husky ceramic tile gap |
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| CN201510504514.5A CN105084814B (en) | 2015-08-17 | 2015-08-17 | Processing material and preparation method are completely filled out in a kind of self-expanding without husky ceramic tile gap |
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| CN105084814A true CN105084814A (en) | 2015-11-25 |
| CN105084814B CN105084814B (en) | 2018-03-13 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106009523A (en) * | 2016-07-05 | 2016-10-12 | 东方雨虹民用建材有限责任公司 | Joint beautifying agent for ceramic tile joint treatment and decoration |
| CN108625618A (en) * | 2018-06-21 | 2018-10-09 | 成都益鸟科技有限公司 | It is a kind of not tear brick quick service method open for the rupture infiltration of toilet warterproof layer |
| CN115353848A (en) * | 2022-09-15 | 2022-11-18 | 荆门科顺新材料有限公司 | Ceramic tile adhesive composition |
| CN115353848B (en) * | 2022-09-15 | 2024-07-02 | 荆门科顺新材料有限公司 | Ceramic tile adhesive composition |
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| CN102674751A (en) * | 2012-04-27 | 2012-09-19 | 刘伟 | Bi-component epoxy caulking agent and preparation method thereof |
| CN103553526A (en) * | 2013-10-16 | 2014-02-05 | 上海利物宝建筑科技有限公司 | Gypsum-based door and window seam filling and sealing mortar as well as preparation method and application thereof |
| CN103880331A (en) * | 2013-11-11 | 2014-06-25 | 东南大学 | Epoxy resin plaster for building jointing and preparation method thereof |
| CN104673162A (en) * | 2015-03-04 | 2015-06-03 | 万海科技股份有限公司 | Joint sealant for thermosetting composite floor as well as preparation method and application of joint sealant |
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2015
- 2015-08-17 CN CN201510504514.5A patent/CN105084814B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102674751A (en) * | 2012-04-27 | 2012-09-19 | 刘伟 | Bi-component epoxy caulking agent and preparation method thereof |
| CN103553526A (en) * | 2013-10-16 | 2014-02-05 | 上海利物宝建筑科技有限公司 | Gypsum-based door and window seam filling and sealing mortar as well as preparation method and application thereof |
| CN103880331A (en) * | 2013-11-11 | 2014-06-25 | 东南大学 | Epoxy resin plaster for building jointing and preparation method thereof |
| CN104673162A (en) * | 2015-03-04 | 2015-06-03 | 万海科技股份有限公司 | Joint sealant for thermosetting composite floor as well as preparation method and application of joint sealant |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106009523A (en) * | 2016-07-05 | 2016-10-12 | 东方雨虹民用建材有限责任公司 | Joint beautifying agent for ceramic tile joint treatment and decoration |
| CN108625618A (en) * | 2018-06-21 | 2018-10-09 | 成都益鸟科技有限公司 | It is a kind of not tear brick quick service method open for the rupture infiltration of toilet warterproof layer |
| CN108625618B (en) * | 2018-06-21 | 2024-01-26 | 成都益鸟科技有限公司 | Quick repair method for water seepage caused by rupture of waterproof layer of bathroom without disassembling bricks |
| CN115353848A (en) * | 2022-09-15 | 2022-11-18 | 荆门科顺新材料有限公司 | Ceramic tile adhesive composition |
| CN115353848B (en) * | 2022-09-15 | 2024-07-02 | 荆门科顺新材料有限公司 | Ceramic tile adhesive composition |
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| CN105084814B (en) | 2018-03-13 |
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