CN105273361A - Filler reaction type epoxy composite material as well as preparation method and application thereof - Google Patents
Filler reaction type epoxy composite material as well as preparation method and application thereof Download PDFInfo
- Publication number
- CN105273361A CN105273361A CN201510736801.9A CN201510736801A CN105273361A CN 105273361 A CN105273361 A CN 105273361A CN 201510736801 A CN201510736801 A CN 201510736801A CN 105273361 A CN105273361 A CN 105273361A
- Authority
- CN
- China
- Prior art keywords
- parts
- composite material
- agent
- type epoxy
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Epoxy Resins (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention belongs to the technical field of a water blocking material and discloses a filler reaction type epoxy composite material as well as a preparation method and application thereof. The composite material is prepared from a component A and a component B, wherein the component A is prepared from the following components in parts by weight: 10 to 70 parts of epoxy resin, 5 to 40 parts of an activating type reactive solvent, 0 to 30 parts of an enhanced type reactive solvent, 10 to 65 parts of reactive fillers, 0 to 5 parts of an interface enhancing agent and 0 to 5 parts of an interface activating agent; the component B is prepared from the following components in parts by weight: 5 to 85 parts of a function curing agent, 0 to 40 parts of a curing regulating agent, 5 to 85 parts of a double-function curing agent and 0 to 30 parts of a curing accelerant. With the adoption of the composite material, the effect of rapidly blocking water can be realized, and the disadvantages that the curing speed of the epoxy material in water is slow and the epoxy material is difficult to cure are avoided; the composite material has high mechanical strength, good durability and low-temperature resistance; the filler reaction type epoxy composite material has rapid curing speed, high mechanical strength and low construction cost.
Description
Technical field
The invention belongs to the technical field of water shutoff material, relate to a kind of epoxy composite material, particularly a kind of filler response type epoxy composite material and preparation method thereof and application.
Background technology
The quality of grouting for water-blocking description of materials and performance, is directly connected to quality and the cost of stopping up water work.Mineral-type grouting for water-blocking material due to its construction costs lower, and be widely used among many simple engineerings, but compare polymer grouting for water-blocking material, although inorganic grouting for water-blocking material can the large water burst construction problem of temporarily shutoff, but its slurry material particle can not inject fine cracks greatly, poor with concrete interface amalgamation, effective adhesive new-old concrete can not be had, Presence of an interface problem, and cannot thoroughly solve seepage water problem.Therefore mineral-type grouting for water-blocking material water plugging effect is difficult to compare with high score subclass grouting for water-blocking material.
In the practice of existing stopping up water work, third solidifying, urethane, acrylate have obvious advantage as organic polymer grouting for water-blocking material and are widely used in water blockoff seepage control project.But the above-mentioned three kinds of polymer grouting for water-blocking materials of overview, they all respectively have its relative merits.Although third solidifying has hypertonicity, the advantages such as concretion body strength is high, and plugging effect is good, it is prohibitted the use by developed countries such as America and Europes as the moderately toxic close neurotoxic substance of one.Urethane grouting for water-blocking material water blockoff process initial stage leakage-proof effect is obvious, but at wet surface and poor to the adhesive property of concrete surface under having the condition of water, induration easily shrinks, but easily occurs Seepage again in the short period of time, poor durability.It is adjustable that Acrylates grouting for water-blocking material has set time, the advantages such as weather resistance is better, but the solid sand body mechanical strength of acrylate material is low, is difficult to meet engineering demand.
Epoxy resin owing to having excellent in mechanical performance, the advantage such as bonding force is strong, cure shrinkage is little, fine corrosion resistance and being widely applied in the fields such as coating, sizing agent, chemical grouting.Epoxide resin material excellent in mechanical performance, can meet the mechanical property requirements such as the ultimate compression strength of many water blockoff seepage control projects easily, its cure shrinkage is little in addition, high with Concrete Bond Strength, fine corrosion resistance, fully can extend the persistence of water plugging effect.A kind of epoxy/polyurethane compound water shutoff material is disclosed in patent publication No. CN1687190A " mesh subaqueous patching material of interpenetrating polymer of epoxy/polyurethane and preparation method and application ", it can overcome the shortcoming of polyurethane material, substantially increases mechanical strength and the water blockoff persistence of material.But epoxy resin is difficult to solidify under water, starches material high cost shortcoming and often hinder epoxy material in the development of polymer grouting for water-blocking Material Field.
Summary of the invention
For prior art epoxy resin under water or moisture substrate be difficult to problem of solidification, the object of the present invention is to provide a kind of filler response type epoxy composite material.The present invention adopts reactive filler and epoxy resin to prepare the water shutoff material of a kind of high strength, good endurance.In described matrix material reactive filler meet water can fast setting, build an inorganic water blockoff skeleton, realize temporary transient water blockoff; Epoxy resin can progressively solidify, thus realizes the long-term water plugging effect of high strength, high-durability.The present invention not only solves antiseepage, leak stopping, reinforcing construction problem, and by adding the lower reactive filler of construction costs, reduces the construction costs of material, thus can meet the demand of more construction works.
Another object of the present invention is to the preparation method that above-mentioned filler response type epoxy composite material is provided.
Another object of the present invention is that above-mentioned filler response type epoxy composite material is applied in the waterproof, seepage control of the Infrastructure such as bridge, harbour, dam, tunnel, foundation construction, reinforcement and strengthening engineering.
Object of the present invention is achieved through the following technical solutions:
A kind of filler response type epoxy composite material, is made up of first component and second component.
Described first component is made up of the following component counted by weight:
Described second component is made up of the following component counted by weight:
Wherein, the weight ratio of first, second component is (100:3) ~ (100:70).
Described epoxy resin is bisphenol A type epoxy resin or bisphenol f type epoxy resin.Wherein, bisphenol A type epoxy resin be in E-51 or E-44 more than one, bisphenol f type epoxy resin is more than one in F-51 or F-44.
Described activated form reactive solvents is ketone compounds, is preferably more than one in isophorone, pimelinketone, methyl iso-butyl ketone (MIBK), ketene dimer, acetone, butanone, diacetone alcohol or p-methyl aceto phenone.
Described enhancement type reactive solvents is more than one in aldehyde compound and Racemic glycidol ether compound.Described aldehyde compound is more than one in phenyl aldehyde, glutaraldehyde, furfural, paraformaldehyde; Described Racemic glycidol ether compound is more than one in benzyl glycidyl ether, butylglycidyl ether, glycidyl allyl ether, 12-14 alkyl glycidyl ether, neopentylglycol diglycidyl ether, ethylene glycol diglycidylether or glycerin triglycidyl ether.
Described reactive filler is more than one in magnesium oxide, calcium oxide, aluminum oxide, calcium hydroxide, magnesium chloride, calcium sulfate, sulplo-aluminate, calcined kaolin, ordinary Portland cement, Portland pozzolana cement, super-early strength cement, high-alumina cement.
Described Interface enhancer is silane coupling agent or titanate coupling agent; Described silane coupling agent be in KH550, KH560, KH570, KH590 or KH602 more than one, described titanate coupling agent is more than one in CT-56, CT-114, CT-2 (production company is sharp evolution work).
Described interfacial agent is more than one in cationic emulsifier or nonionic emulsifying agent; Described cationic emulsifier is more than one in alkyl trimethyl quaternary ammonium bromides or alkyldimethylbenzylammonium quaternary ammonium bromides; Described nonionic emulsifying agent is more than one in fatty alcohol-polyoxyethylene ether or alkylphenol polyoxyethylene.
Described function solidifying agent is quadrol, diethylenetriamine, triethylene tetramine, tetraethylene pentamine, N, one or more the mixture in N dimethylamine base propylamine, 3-dibutyl amino propylamine.
Described solidification adjusting control agent is more than one in modified amine curing agent, aromatic amine or Versamid class solidifying agent; Described modified amine curing agent 591
#or 593
#in more than one; More than one in aromatic amine curing agent mphenylenediamine, m-xylene diamine or diaminodiphenylmethane; Versamid class solidifying agent 650
#or 651
#in more than one.
Described difunctional solidifying agent is more than one in mannich base class solidifying agent or many sulfydryls solidifying agent; Described mannich base class solidifying agent is T-31,810
#, 910
#; Described many sulfydryls solidifying agent is Capcure3-800, GPM-800 (GabrielPerformanceProducts (U.S.)).
Described curing catalyst is more than one in trolamine, xylidine, 2,4,6-tri-(dimethylaminomethyl) phenol or methyl tetrahydro phthalic anhydride.
The preparation method of described filler response type epoxy composite material is:
(1) by the epoxy resin of 10 ~ 70 weight parts, the activated form reactive solvents of 5 ~ 40 weight parts, the enhancement type reactive solvents of 0 ~ 30 weight part, the reactive filler of 10 ~ 65 weight parts, the Interface enhancer of 0 ~ 5 weight part, the interfacial agent of 0 ~ 5 weight part is uniformly mixed in normal temperature high speed, obtains first component; Described mixing speed is 500 ~ 3000r/min, and described churning time is 5 ~ 30min;
(2) by 5 ~ 85 weight part function solidifying agent, the solidification adjusting control agent of 0 ~ 40 weight part, 5 ~ 85 parts of difunctional solidifying agent, 0 ~ 30 part of curing catalyst stirring at normal temperature is mixed to get second component; Rotating speed 250 ~ the 350rpm of described stirring, described churning time is 10 ~ 15min;
(3) be that (100:3) ~ (100:70) is uniformly mixed by first, second component according to weight ratio, obtain filler response type epoxy composite material.The rotating speed stirred is 900 ~ 1000rpm, described in time of stirring be 8 ~ 12min.The application of described filler response type epoxy composite material in the waterproof, seepage control, reinforcement and strengthening engineering of the Infrastructure of bridge, harbour, dam, tunnel, foundation construction.
The present invention possesses following outstanding advantages and effect relative to prior art:
1) the present invention meets the feature of water reaction solidification according to reactive filler, in antiseepage stopping up water work, first reactive filler reacts the temporary skeleton constructing a sealing water blockoff with water, effectively achieve the effect of the quick water blockoff in engineering, avoid epoxy material solidifies slowly in water, the shortcoming of difficult solidification;
2) the present invention meets the feature of water reaction solidification according to reactive filler, and in antiseepage stopping up water work, reactive filler and water react, improve the alkalescence in material system, promote epoxy resin cure, improve material early strength, improve the stability of material water blockoff ability further;
3) the present invention is high according to epoxy material mechanical strength, the feature of excellent in durability, for antiseepage stopping up water work provides a kind of persistent high strength antiseepage water shutoff material; Simultaneously also for the heavy construction of the reinforcement that needs reinforcement provide a kind of can the simple construction material of single stage method impervious leakage-stopping reinforcement;
4) the present invention can be solidified under low temperature even severe cold condition, meets the demand of part engineering construction in winter;
5) present invention reduces the problem of epoxy resin water blockoff injecting paste material construction costs, enable epoxy material be applicable to more impervious leakage-stopping reinforcement engineering;
6) the present invention has curing speed soon, and the features such as mechanical strength is high, and construction costs is low, and construction technology is simple, can be used for waterproof, seepage control, the reinforcement and strengthening engineering of the Infrastructure such as bridge, harbour, dam, tunnel, foundation construction.
Embodiment
Describe the present invention in detail below by specific embodiment, but the present invention is not limited only to following examples.
Embodiment 1
By 44 parts of epoxy resin E-51,5 parts of activated form reactive solvents isophorones, 10.1 part phenyl aldehyde, 10 parts of benzyl glycidyl ethers, 0.45 part of Interface enhancer KH550,0.45 part of interfacial agent alkyl trimethyl quaternary ammonium bromides, 25 parts of reactive filler magnesium oxide, 5 parts of reactive filler magnesium chloride normal temperature high-speed stirring (500r/min) stir 15min, obtain first component; By 40 parts of function solidifying agent N, N dimethylamine base propylamine, 13.8 parts of solidification adjusting control agent mphenylenediamines, 10 parts of solidification adjusting control agents 651
#, 25.1 parts of difunctional solidifying agent T31
#, 11.1 parts of curing catalyst methyl tetrahydro phthalic anhydrides are uniformly mixed 15min at 300 rpm, obtain second component; During use, the first and second components are pressed the part by weight mixing of 100:56, under 1000rpm, stir 10min, obtain filler response type epoxy composite material, described number is weight part.Its performance test is as shown in table 1,2,3.
Embodiment 2
By 15 parts of epoxy resin E-44s, 12.5 parts of activated form reactive solvents pimelinketone, 3.5 parts of furfurals, 4 parts of butylglycidyl ethers, 5 parts of Interface enhancer CT-56,5 parts of interfacial agent hexadecyl phenol polyethenoxy ethers, 40 parts of calcium oxide, 15 parts of silicate cement normal temperature high-speed stirring (750r/min) stir 5min, obtain first component; By 85 parts of function solidifying agent diethylenetriamines, 6.3 parts of solidification adjusting control agent diaminodiphenylmethane, 5 parts of difunctional solidifying agent 810
#, 3.7 parts of trolamines are uniformly mixed 15min at 300 rpm, obtain second component; During use, the first and second components are pressed the part by weight mixing of 100:31, under 1000rpm, stir 10min, obtain the epoxy composite material that filler can react, described number is weight part.Its performance test is as shown in table 1,2,3.
Embodiment 3
By 25 parts of epoxy resin E-44s, 32 parts of epoxy resin F-51,14 parts of activated form reactive solvents methyl iso-butyl ketone (MIBK), 2 parts of glutaraldehyde, 6 parts of glycidyl allyl ethers, 0.5 part of Interface enhancer KH570,0.5 part of interfacial agent fatty alcohol-polyoxyethylene ether AEO-9,6 parts of reactive filler aluminum oxide, 6 parts of reactive filler magnesium chlorides, 8 parts of reactive filler trass cement normal temperature high-speed stirring (830r/min) stir 30min, obtain first component; By 21.5 parts of function solidifying agent 3-dibutyl amino propylamine, 22.9 parts of solidification adjusting control agents 591
#, 40 parts of difunctional solidifying agent 910
#, 15.6 parts of curing catalyst 2,4,6-tri-(dimethylaminomethyl) phenol are uniformly mixed 15min at 300 rpm, obtain second component; During use, the first and second components are pressed the part by weight mixing of 100:10, under 1000rpm, stir 10min, obtain the epoxy composite material of filler response type, described number is weight part.Its performance test is as shown in table 1,2,3.
Embodiment 4
By 70 parts of epoxy resin F-44,4 parts of activated form reactive solvents ketene dimers, 3.8 parts of activated form reactive solvents acetone, 8 parts of furfurals, 3 parts of 12-14 alkyl glycidyl ethers, 0.7 part of Interface enhancer KH602,0.5 part of interfacial agent alkyldimethylbenzylammonium quaternary ammonium bromides (octadecyl dimethyl benzyl oronain), 8 parts of reactive filler calcium hydroxides, 2 parts of reactive filler calcium sulfate normal temperature high-speed stirring (650r/min) stir 10min, obtain first component; By 5 parts of function curing agent ethylene diamines, 6 parts of solidification adjusting control agents 593
#, 50 parts of difunctional solidifying agent T-31,35 parts of difunctional solidifying agent Capcure3-800,4 parts of curing catalyst triphenylphosphines are uniformly mixed 15min at 300 rpm, obtain second component; During use, the first and second components are pressed the part by weight mixing of 100:7, under 1000rpm, stir 10min, obtain the epoxy composite material of filler response type, described number is weight part.Its performance test is as shown in table 1,2,3.
Embodiment 5
By 25.2 parts of epoxy resin E-51,20 parts of activated form reactive solvents butanone, 20.2 parts of phenyl aldehydes, 9.8 parts of neopentylglycol diglycidyl ethers, 1.8 parts of Interface enhancer CT-2 (sharp evolution work), 2 parts of interfacial agent fatty alcohol-polyoxyethylene ether AEO-7,10 parts of reactive filler sulplo-aluminates, 10 parts of reactive filler calcined kaolin normal temperature high-speed stirring (3000r/min) 30min, obtain first component; By 45 parts of function solidifying agent tetraethylene pentamine, 8 parts of solidification adjusting control agents 650
#, 8 parts of difunctional solidifying agent 810
#, 9 parts of difunctional solidifying agent Capcure3-800,30 parts of curing catalyst trolamines are uniformly mixed 15min at 300 rpm, obtain second component; The ratio of the first and second components by weight 100:3 mixed during use, stir 10min, obtain the epoxy composite material of filler response type under 1000rpm, described number is weight part.Its performance test is as shown in table 1,2,3.
Embodiment 6
By 15 parts of epoxy resin E-44s, 40 parts of activated form reactive solvents p-methyl aceto phenone, 15 parts of paraformaldehydes, 5 parts of butylglycidyl ethers, 1 part of Interface enhancer CT-114,2 parts of interfacial agent fatty alcohol-polyoxyethylene ether AEO-3,12 parts of Portland pozzolana cements, 10 parts of super-early strength cement normal temperature high-speed stirring (1500r/min) stir 20min, obtain first component; By 15.3 parts of function solidifying agent triethylene tetramines, 40 parts of solidification adjusting control agent mphenylenediamines, 11 parts of difunctional solidifying agent T-31,28.7 parts of difunctional solidifying agent GPM-800,5 parts of curing catalyst xylidines are uniformly mixed 15min at 300 rpm, obtain second component; The ratio of the first and second components by weight 100:70 mixed during use, stir 10min, obtain the epoxy composite material of filler response type under 1000rpm, described number is weight part.Its performance test is as shown in table 1,2,3.
Embodiment 7
By 31 parts of epoxy resin E-51,25.8 parts of activated form reactive solvents diacetone alcohols, 1 part of glutaraldehyde, 1 part of glycerin triglycidyl ether, 0.6 part of Interface enhancer KH590,0.6 part of interfacial agent (octadecyl dimethyl benzyl oronain), 25 parts of reactive filler high-alumina cements, 15 parts of reactive filler silicate cement normal temperature high-speed stirring (2200r/min) stir 10min, obtain first component; By 5 parts of function solidifying agent diethylenetriamines, 25 parts of solidification adjusting control agent m-xylene diamines, 36.5 parts of difunctional solidifying agent 910
#, 21 parts of difunctional solidifying agent Capcure3-800,12.5 parts of curing catalyst trolamines are uniformly mixed 15min at 300 rpm, obtain second component; The ratio of the first and second components by weight 100:29 mixed during use, stir 10min, obtain the epoxy composite material of filler response type under 1000rpm, described number is weight part.Its performance test is as shown in table 1,2,3.
Embodiment 8
By 10 parts of epoxy resin E-44s, 19.7 parts of activated form reactive solvents diacetone alcohols, 2.5 parts of furfurals, 1 part of ethylene glycol diglycidylether, 1.5 parts of Interface enhancer KH560,0.3 part of interfacial agent cetyl trimethylammonium bromide, 30 parts of reactive filler calcium oxide, 35 parts of reactive filler superfine cement normal temperature high-speed stirring (2500r/min) stir 5min, obtain first component; By 10 parts of function curing agent ethylene diamines, 40 parts of solidification adjusting control agents 593
#, 44 parts of difunctional solidifying agent 910
#, 1 part of curing catalyst methyl tetrahydro phthalic anhydride is uniformly mixed 15min at 300 rpm, obtains second component; During use, the first and second components are pressed the part by weight mixing of 100:30, under 1000rpm, stir 10min, obtain the epoxy composite material of filler response type, described number is weight part.Its performance test is as shown in table 1,2,3.
The mechanical property parameters of each example of table 1 in dry environment
The mechanical property parameters of each example of table 2 in wet environment
The mechanical property parameters of each example of table 3 in low temperature (5 DEG C) wet environment
The mechanic property test method of above-mentioned example is all joined and is undertaken by rower JC/T1041-2007 " distress in concrete epoxide resin grouting material " regulation.
Known by the analysis of these sample results:
1) the invention provides the epoxy composite material that a kind of filler can react, water met by this material can rapid solidification, realizes the antiseepage water blockoff of engineering.
2) epoxy composite material mechanical strength provided by the present invention is high, is a kind ofly single stage method to realize the epoxy composite material of impervious leakage-stopping reinforcement.
3) present invention reduces the problem of epoxy resin water blockoff injecting paste material construction costs, enable epoxy composite material be applicable to more impervious leakage-stopping reinforcement engineering.
Above-described embodiment is the more excellent embodiment that filler provided by the invention epoxy composite material that can react and preparation method thereof is applied in epoxy resin injecting paste material with it; but embodiments of the present invention do not limit by above-described embodiment; the bound value of each raw material and interval value all can realize the present invention, are all included within protection scope of the present invention.
Claims (10)
1. a filler response type epoxy composite material, is characterized in that: be made up of first component and second component; Described first component is made up of the following component counted by weight:
Described second component is made up of the following component counted by weight:
Wherein, the weight ratio of first, second component is (100:3) ~ (100:70).
2. filler response type epoxy composite material according to claim 1, is characterized in that: described epoxy resin is bisphenol A type epoxy resin or bisphenol f type epoxy resin;
Described activated form reactive solvents is ketone compounds;
Described enhancement type reactive solvents is more than one in aldehyde compound or Racemic glycidol ether compound;
Described reactive filler is more than one in magnesium oxide, calcium oxide, aluminum oxide, calcium hydroxide, magnesium chloride, calcium sulfate, sulplo-aluminate, calcined kaolin, ordinary Portland cement, Portland pozzolana cement, super-early strength cement or high-alumina cement;
Described Interface enhancer is silane coupling agent or titanate coupling agent.
3. filler response type epoxy composite material according to claim 2, is characterized in that: described bisphenol A type epoxy resin be in E-51 or E-44 more than one, bisphenol f type epoxy resin is more than one in F-51 or F-44;
Described activated form reaction solvent is more than one in isophorone, pimelinketone, methyl iso-butyl ketone (MIBK), ketene dimer, acetone, butanone, diacetone alcohol or p-methyl aceto phenone;
Described aldehyde compound is more than one in phenyl aldehyde, glutaraldehyde, furfural, paraformaldehyde; Described Racemic glycidol ether compound is more than one in benzyl glycidyl ether, butylglycidyl ether, glycidyl allyl ether, 12-14 alkyl glycidyl ether, neopentylglycol diglycidyl ether, ethylene glycol diglycidylether or glycerin triglycidyl ether;
Described silane coupling agent be in KH550, KH560, KH570, KH590 or KH602 more than one, described titanate coupling agent is more than one in CT-56, CT-114, CT-2.
4. filler response type epoxy composite material according to claim 1, is characterized in that: described interfacial agent is more than one in cationic emulsifier or nonionic emulsifying agent.
5. filler response type epoxy composite material according to claim 4, is characterized in that: described cationic emulsifier is more than one in alkyl trimethyl quaternary ammonium bromides or alkyldimethylbenzylammonium quaternary ammonium bromides; Described nonionic emulsifying agent is more than one in fatty alcohol-polyoxyethylene ether or alkylphenol polyoxyethylene.
6. filler response type epoxy composite material according to claim 1, it is characterized in that: described function solidifying agent is quadrol, diethylenetriamine, triethylene tetramine, tetraethylene pentamine, N, more than one in N dimethylamine base propylamine, 3-dibutyl amino propylamine;
Described solidification adjusting control agent is more than one in modified amine curing agent, aromatic amine or Versamid class solidifying agent;
Described difunctional solidifying agent is more than one in mannich base class solidifying agent or many sulfydryls solidifying agent;
Described curing catalyst is more than one in trolamine, xylidine, 2,4,6-tri-(dimethylaminomethyl) phenol or methyl tetrahydro phthalic anhydride.
7. filler response type epoxy composite material according to claim 6, is characterized in that: described modified amine curing agent 591
#or 593
#in more than one; Aromatic amine curing agent is more than one in mphenylenediamine, m-xylene diamine or diaminodiphenylmethane; Versamid class solidifying agent is 650
#or 651
#in more than one;
Described mannich base class solidifying agent is T-31,810
#or 910
#; Described many sulfydryls solidifying agent is Capcure3-800 or GPM-800.
8. the preparation method of filler response type epoxy composite material according to any one of claim 1 ~ 7, is characterized in that: concrete steps are:
(1) by the epoxy resin of 10 ~ 70 weight parts, the activated form reactive solvents of 5 ~ 40 weight parts, the enhancement type reactive solvents of 0 ~ 30 weight part, the reactive filler of 10 ~ 65 weight parts, the Interface enhancer of 0 ~ 5 weight part, the interfacial agent of 0 ~ 5 weight part is uniformly mixed in normal temperature high speed, obtains first component;
(2) by 5 ~ 85 weight part function solidifying agent, the solidification adjusting control agent of 0 ~ 40 weight part, 5 ~ 85 parts of difunctional solidifying agent, 0 ~ 30 part of curing catalyst stirring at normal temperature is mixed to get second component;
(3) be that (100:3) ~ (100:70) is uniformly mixed by first, second component according to weight ratio, obtain filler response type epoxy composite material.
9. the preparation method of filler response type epoxy composite material according to claim 8, it is characterized in that: described in step (1), mixing speed is 500 ~ 3000rpm, described churning time is 5 ~ 30min; Rotating speed 250 ~ the 350rpm stirred described in step (2), described churning time is 10 ~ 15min; The rotating speed stirred in step (3) is 900 ~ 1000rpm, described in time of stirring be 8 ~ 12min.
10. one kind by the application of filler response type epoxy composite material described in any one of claim 1 ~ 7 in the waterproof, seepage control, reinforcement and strengthening engineering of the Infrastructure of bridge, harbour, dam, tunnel, foundation construction.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510736801.9A CN105273361B (en) | 2015-10-30 | 2015-10-30 | A kind of filler response type epoxy composite material and preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510736801.9A CN105273361B (en) | 2015-10-30 | 2015-10-30 | A kind of filler response type epoxy composite material and preparation method and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105273361A true CN105273361A (en) | 2016-01-27 |
| CN105273361B CN105273361B (en) | 2017-10-20 |
Family
ID=55143234
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510736801.9A Active CN105273361B (en) | 2015-10-30 | 2015-10-30 | A kind of filler response type epoxy composite material and preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105273361B (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105837136A (en) * | 2016-03-22 | 2016-08-10 | 苏州捷德瑞精密机械有限公司 | Piezoelectric ceramic composite material and preparation method thereof |
| CN109161166A (en) * | 2018-08-16 | 2019-01-08 | 湖北双键精细化工有限公司 | A kind of rapid curing low shrinkage epoxy casting filler and preparation method thereof |
| CN109320919A (en) * | 2018-11-09 | 2019-02-12 | 陈鹏 | A kind of shock-absorbing bridge support composite material and preparation method |
| CN110746811A (en) * | 2019-11-04 | 2020-02-04 | 刘宇 | Environment-friendly high-durability epoxy modified putty |
| CN110804366A (en) * | 2019-11-04 | 2020-02-18 | 刘宇 | Coating capable of being applied to damp or open water base surface |
| CN110903051A (en) * | 2019-11-04 | 2020-03-24 | 广州永科新材料科技有限公司 | Environment-friendly high-durability epoxy mortar |
| WO2020192185A1 (en) * | 2019-03-25 | 2020-10-01 | 3M Innovative Properties Company | Curable compositions, articles therefrom, and methods of making and using same |
| CN112979209A (en) * | 2021-02-04 | 2021-06-18 | 中国石油大学(华东) | Novel composite shrinkage reducing agent for oil well cement, preparation method and application thereof |
| CN115322766A (en) * | 2022-08-18 | 2022-11-11 | 北京奇想达新材料有限公司 | Bi-component low-temperature curable coated proppant and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1847309A (en) * | 2005-04-12 | 2006-10-18 | 中国科学院广州化学研究所 | Organosilicon modified carbonyl epoxy composite material |
| CN102585441A (en) * | 2012-02-28 | 2012-07-18 | 华南理工大学 | Performance-controllable epoxy-polyketone grouting material as well as preparation method and application thereof |
| CN102977555A (en) * | 2012-11-30 | 2013-03-20 | 华南理工大学 | Light epoxy grouting material as well as preparation method and application thereof |
| CN103183927A (en) * | 2013-03-05 | 2013-07-03 | 华南理工大学 | Environment-friendly aldehyde-free epoxy injecting paste material and preparation method and application therefor |
| CN103289326A (en) * | 2013-06-28 | 2013-09-11 | 山东科技大学 | Halogen-free flame retardant epoxy resin compound for potting material |
| CN103333302A (en) * | 2013-06-25 | 2013-10-02 | 华南理工大学 | Preparation method and application of mild reaction type aldehyde ketone resin |
-
2015
- 2015-10-30 CN CN201510736801.9A patent/CN105273361B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1847309A (en) * | 2005-04-12 | 2006-10-18 | 中国科学院广州化学研究所 | Organosilicon modified carbonyl epoxy composite material |
| CN102585441A (en) * | 2012-02-28 | 2012-07-18 | 华南理工大学 | Performance-controllable epoxy-polyketone grouting material as well as preparation method and application thereof |
| CN102977555A (en) * | 2012-11-30 | 2013-03-20 | 华南理工大学 | Light epoxy grouting material as well as preparation method and application thereof |
| CN103183927A (en) * | 2013-03-05 | 2013-07-03 | 华南理工大学 | Environment-friendly aldehyde-free epoxy injecting paste material and preparation method and application therefor |
| CN103333302A (en) * | 2013-06-25 | 2013-10-02 | 华南理工大学 | Preparation method and application of mild reaction type aldehyde ketone resin |
| CN103289326A (en) * | 2013-06-28 | 2013-09-11 | 山东科技大学 | Halogen-free flame retardant epoxy resin compound for potting material |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105837136A (en) * | 2016-03-22 | 2016-08-10 | 苏州捷德瑞精密机械有限公司 | Piezoelectric ceramic composite material and preparation method thereof |
| CN109161166A (en) * | 2018-08-16 | 2019-01-08 | 湖北双键精细化工有限公司 | A kind of rapid curing low shrinkage epoxy casting filler and preparation method thereof |
| CN109320919A (en) * | 2018-11-09 | 2019-02-12 | 陈鹏 | A kind of shock-absorbing bridge support composite material and preparation method |
| WO2020192185A1 (en) * | 2019-03-25 | 2020-10-01 | 3M Innovative Properties Company | Curable compositions, articles therefrom, and methods of making and using same |
| CN110746811A (en) * | 2019-11-04 | 2020-02-04 | 刘宇 | Environment-friendly high-durability epoxy modified putty |
| CN110804366A (en) * | 2019-11-04 | 2020-02-18 | 刘宇 | Coating capable of being applied to damp or open water base surface |
| CN110903051A (en) * | 2019-11-04 | 2020-03-24 | 广州永科新材料科技有限公司 | Environment-friendly high-durability epoxy mortar |
| CN112979209A (en) * | 2021-02-04 | 2021-06-18 | 中国石油大学(华东) | Novel composite shrinkage reducing agent for oil well cement, preparation method and application thereof |
| CN115322766A (en) * | 2022-08-18 | 2022-11-11 | 北京奇想达新材料有限公司 | Bi-component low-temperature curable coated proppant and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105273361B (en) | 2017-10-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105273361A (en) | Filler reaction type epoxy composite material as well as preparation method and application thereof | |
| CN102585441B (en) | Performance-controllable epoxy-polyketone grouting material as well as preparation method and application thereof | |
| CN100457824C (en) | Green high-strength epoxy grouting material and its prepn | |
| CN103183927B (en) | Environment-friendly aldehyde-free epoxy injecting paste material and preparation method and application therefor | |
| CN104789178B (en) | Modified bisphenol-A epoxy resin inserted bar glue in complete underwater environment and preparation method | |
| CN105295644B (en) | A kind of high osmosis epoxy waterproof coating | |
| CN106700992A (en) | Underwater curing high-performance epoxy anchoring glue as well as preparation method and application of underwater curing high-performance epoxy anchoring glue | |
| CN103819144A (en) | Preparation method of epoxy mortar for filling ocean oil and gas pipeline | |
| CN103333302B (en) | A kind of preparation method and application of reacting mild aldehyde ketone resin | |
| CN102070874B (en) | High-permeability and high-strength epoxy grouting material, preparation method thereof and application thereof | |
| CN102344647B (en) | Environmentally-friendly high-seepage epoxy grouting material and preparation method and application thereof | |
| CN105884257A (en) | High-strength rapid-hardening type epoxy resin mortar and preparation method thereof | |
| CN105176002B (en) | A kind of impervious leakage-stopping environment-friendly epoxy grouting material | |
| CN102070873A (en) | Environment-friendly flexible epoxy resin grouting material | |
| CN105419241A (en) | Transparent and environment-friendly underwater consolidated solvent-free epoxy grouting material and preparation method and application thereof | |
| CN102977555A (en) | Light epoxy grouting material as well as preparation method and application thereof | |
| CN105176465A (en) | Epoxy grout and preparation method thereof | |
| CN102604327B (en) | Solvent-free epoxy resin as plugging material, and preparation method and application of the solvent-free epoxy resin | |
| CN105238217A (en) | Permeation consolidation type solvent-free epoxy anticorrosive coating, and preparation method and application thereof | |
| CN104559067B (en) | A kind of self-emulsifying epoxy base heat conduction water-proof composite material and its preparation method and application | |
| CN106280277A (en) | A kind of preparation method and application of environmental protection low viscosity high-strength epoxy radicals grouting material | |
| CN1847309A (en) | Organosilicon modified carbonyl epoxy composite material | |
| CN109593512A (en) | Bisphenol type epoxy organic siliconresin and preparation method, adhesive and preparation method | |
| CN108947457B (en) | Organic-inorganic composite photo-initiation latent soil curing agent and preparation method thereof | |
| CN107629630A (en) | A kind of production method for spraying rapid-hardening colour epoxy asphalt waterproofing paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |