CN105273361B - A kind of filler response type epoxy composite material and preparation method and application - Google Patents
A kind of filler response type epoxy composite material and preparation method and application Download PDFInfo
- Publication number
- CN105273361B CN105273361B CN201510736801.9A CN201510736801A CN105273361B CN 105273361 B CN105273361 B CN 105273361B CN 201510736801 A CN201510736801 A CN 201510736801A CN 105273361 B CN105273361 B CN 105273361B
- Authority
- CN
- China
- Prior art keywords
- parts
- component
- curing agent
- weight
- type epoxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Epoxy Resins (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention belongs to the technical field of water shutoff material, a kind of filler response type epoxy composite material and preparation method and application is disclosed.The composite is made up of first component and second component；The first component is made up of the following component counted by weight：Epoxy resin 10~70, activated form reactive solvents 5~40, enhanced reactive solvents 0~30, reactive filler 10~65, Interface enhancer 0~5, interfacial agent 0~5；The second component is made up of the following component counted by weight：Function curing agent 5~85, solidifies adjusting control agent 0~40, difunctional curing agent 5~85, curing accelerator 0~30.Described composite can realize the effect of quick water blockoff, it is to avoid epoxy material slow curing in water, the shortcoming of hardly possible solidification；Compound Material Engineering intensity is high, excellent in durability and low temperature resistant；And curing rate is fast, mechanical strength is high, low engineering cost.
Description
Technical field
The invention belongs to the technical field of water shutoff material, it is related to a kind of epoxy composite material, more particularly to a kind of filler is anti-
Answer type epoxy composite material and preparation method and application.
Background technology
The quality of grouting for water blocking description of materials and performance, is directly connected to the quality and cost of stopping up water work.Inorganic is noted
Water shutoff material is starched because its construction costs is relatively low, and is widely used among many simple engineerings, but compared to macromolecule
Grouting for water blocking material, although inorganic grouting for water blocking material can temporarily block big water burst construction problem, but it starches material particle
Fine cracks can not be injected greatly, poor with concrete interface amalgamation, it is impossible to effectively cohesive new-old concrete, Presence of an interface problem,
And the problem of thoroughly can not solving percolating water.Therefore inorganic grouting for water blocking material water plugging effect is difficult to high score subclass slip casting
Water shutoff material is compared.
In the practice of existing stopping up water work, third is solidifying, polyurethane, acrylates are used as organic polymer grouting for water blocking material
It is widely used in obvious advantage in water blockoff seepage control project.But the above-mentioned three kinds of macromolecules grouting for water blocking material of overview
Material, they respectively have its advantage and disadvantage.Although third is solidifying with high osmosis, concretion body strength is high, the advantages of plugging effect is good,
It is prohibitted the use of as the moderately toxic close neurotoxic substance of one kind by developed countries such as America and Europes.Polyurethane grouting for water blocking material
Water blockoff processing leakage-proof effect at initial stage substantially, but in wet surface and has poor to the adhesive property of concrete surface under conditions of water, consolidates
Body easily shrinks, but easily occurs Seepage, poor durability again in the short time.Acrylates grouting for water blocking material has solid
The change time can adjust, the advantages of durability is preferable, but the solid sand body mechanical strength of acrylate material is low, it is difficult to meet engineering need
Ask.
Epoxy resin is due to having the advantages that excellent in mechanical performance, bonding force are strong, cure shrinkage is small, fine corrosion resistance
And be widely applied in the fields such as coating, adhesive, chemical grouting.Epoxide resin material excellent in mechanical performance, can
The mechanical property requirements such as the compression strength of many water blockoff seepage control projects are met easily, and its cure shrinkage is small in addition, it is viscous with concrete
Knotting strength is high, and fine corrosion resistance can fully extend the persistence of water plugging effect.Patent publication No. CN1687190A《Ring
Oxygen/Polyurethane Interpenetrating Polymer Networks subaqueous patching material and preparation method and application》In disclose a kind of epoxy/polyurethane answer
Water shutoff material is closed, it can overcome the shortcoming of polyurethane material, substantially increase the mechanical strength and water blockoff persistence of material.So
And epoxy resin is difficult to solidify under water, starches material high cost shortcoming and often hinder epoxy material in macromolecule grouting for water blocking material
The development in material field.
The content of the invention
For prior art epoxy resin under water or moisture substrate is difficult to problem of solidification, it is an object of the invention to carry
For a kind of filler response type epoxy composite material.The present invention using reactive filler and epoxy resin prepare a kind of high intensity,
The water shutoff material of good endurance.Reactive filler chance water being capable of rapid curing, one inorganic water blockoff of structure in the composite
Skeleton, realizes temporary transient water blockoff；Epoxy resin can progressively solidify, so as to realize high intensity, the long-term water plugging effect of high-durability.
The present invention not only solves antiseepage, leak stopping, reinforcing construction problem, and the reactive filler relatively low by adding construction costs, drop
The low construction costs of material, so as to meet the demand of more construction works.
Another object of the present invention is to provide the preparation method of above-mentioned filler response type epoxy composite material.
Another object of the present invention is that above-mentioned filler response type epoxy composite material is applied to bridge, harbour, dam, tunnel
In the waterproof, seepage controls of the infrastructure such as road, foundation construction, reinforcement and strengthening engineering.
The purpose of the present invention is achieved through the following technical solutions：
A kind of filler response type epoxy composite material, is made up of first component and second component.
The first component is made up of the following component counted by weight：
The second component is made up of the following component counted by weight：
Wherein, the weight ratio of first, second component is (100:3)~(100:70).
Described epoxy resin is bisphenol A type epoxy resin or bisphenol f type epoxy resin.Wherein, bisphenol A type epoxy resin
For more than one in E-51 or E-44, bisphenol f type epoxy resin is one or more of F-51 or F-44.
Described activated form reactive solvents are ketone compounds, preferably isophorone, cyclohexanone, methyl-isobutyl
One or more of ketone, ketene dimer, acetone, butanone, DAA or melilotal.
Described enhanced reactive solvents are one or more of aldehyde compound and glycidol ethers compound.Institute
It is one or more of benzaldehyde, glutaraldehyde, furfural, paraformaldehyde to state aldehyde compound；Described glycidol ethers chemical combination
Thing is benzyl glycidyl ether, butyl glycidyl ether, allyl glycidyl ether, 12-14 alkyl glycidyl ethers, new penta 2
One or more of alcohol diglycidyl ether, ethylene glycol diglycidylether or glycerin triglycidyl ether.
Described reactive filler is magnesia, calcium oxide, aluminum oxide, calcium hydroxide, magnesium chloride, calcium sulfate, sulphur aluminic acid
In salt, calcined kaolin, Portland cement, Portland pozzolana cement, super-early strength cement, alumina cement it is a kind of with
On.
Described Interface enhancer is silane coupler or titanate coupling agent；The silane coupler be KH550,
More than one in KH560, KH570, KH590 or KH602, the titanate coupling agent is that (production is public by CT-56, CT-114, CT-2
One or more of take charge of and enter chemical industry for profit).
Described interfacial agent is one or more of cationic emulsifier or nonionic emulsifier；The cationic galactomannan
Agent is one or more of alkyl trimethyl quaternary ammonium bromides or alkyldimethylbenzylammonium quaternary ammonium bromides；The nonionic Emulsion
Agent is one or more of AEO or APES.
Described function curing agent is ethylenediamine, diethylenetriamine, triethylene tetramine, TEPA, N, TMSDEA N diethylamine
One or more kinds of mixtures in base propylamine, 3- dibutyl amino propylamine.
Described solidification adjusting control agent is one in modified amine curing agent, aromatic amine or Versamid class curing agent
More than kind；The modified amine curing agent 591#Or 593#One or more of；Aromatic amine curing agent m-phenylene diamine (MPD), isophthalic two
One or more of methylamine or MDA；Versamid class curing agent 650#Or 651#One or more of.
Described difunctional curing agent is one or more of mannich base class curing agent or many sulfydryl curing agent；It is described graceful
Nice bases curing agent is T-31,810#、910#；Many sulfydryl curing agent are Capcure3-800, GPM-800 (Gabriel
Performance Products (U.S.)).
Described curing accelerator be triethanolamine, dimethylaniline, (dimethylaminomethyl) phenol of 2,4,6- tri- or
One or more of methyl tetrahydro phthalic anhydride.
The preparation method of the filler response type epoxy composite material is：
(1) by the epoxy resin of 10~70 parts by weight, the activated form reactive solvents of 5~40 parts by weight, 0~30 parts by weight
Enhanced reactive solvents, the reactive filler of 10~65 parts by weight, the Interface enhancer of 0~5 parts by weight, 0~5 parts by weight
Interfacial agent in normal temperature high speed stir mix, obtain first component；The speed of agitator is 500~3000r/min, described to stir
The time is mixed for 5~30min；
(2) by 5~85 parts by weight function curing agent, the solidification adjusting control agent of 0~40 parts by weight, 5~85 parts of difunctional solidifications
Agent, 0~30 part of curing accelerator stirring at normal temperature mixes to obtain second component；250~350rpm of rotating speed of the stirring, during the stirring
Between be 10~15min；
(3) it is (100 according to weight ratio by first, second component:3)~(100:70) stirring mixing, obtains filler response type ring
O compoiste material.The rotating speed of stirring is 900~1000rpm, and the time stirred is 8~12min.The filler response type epoxy
Composite answering in bridge, harbour, dam, tunnel, the waterproof, seepage control of the infrastructure of foundation construction, reinforcement and strengthening engineering
With.
The present invention possesses following outstanding advantages and effect relative to prior art：
1) present invention meets the characteristics of water reaction solidifies, in antiseepage stopping up water work, reactive filler according to reactive filler
The temporary skeleton for constructing a sealing water blockoff is reacted with water first, the effect of the quick water blockoff in engineering is effectively realized,
Avoid epoxy material slow curing in water, the shortcoming of hardly possible solidification；
2) present invention meets the characteristics of water reaction solidifies, in antiseepage stopping up water work, reactive filler according to reactive filler
Reacted with water, improve the alkalescence in material system, promote epoxy resin cure, improved material early strength, further improve material
Expect the stability of water blockoff ability；
3) present invention is high according to epoxy material mechanical strength, the characteristics of excellent in durability, is provided for antiseepage stopping up water work
A kind of persistent high intensity antiseepage water shutoff material；Simultaneously also for the reinforcement that needs reinforcement heavy construction provide one kind can a step
The simple construction material of method impervious leakage-stopping reinforcement；
4) present invention can solidify under low temperature even severe cold condition, meet the demand of part engineering winter construction；
5) present invention reduces the problem of epoxy resin water blockoff injecting paste material construction costs, epoxy material is enable to be applied to
More impervious leakage-stopping reinforcement engineerings；
6) present invention has curing rate fast, and mechanical strength is high, and low engineering cost, the features such as construction technology is simple can be used
Waterproof, seepage control, reinforcement and strengthening engineering in infrastructure such as bridge, harbour, dam, tunnel, foundation constructions.
Embodiment
Describe the present invention in detail below by specific embodiment, but the present invention is not limited only to following examples.
Embodiment 1
By 44 parts of epoxy resin E-51,5 parts of activated form reactive solvents isophorones, 10.1 parts of benzaldehydes, 10 parts of benzyls
Glycidol ether, 0.45 part of Interface enhancer KH550,0.45 part of interfacial agent alkyl trimethyl quaternary ammonium bromides, 25 parts are anti-
Answering property filler magnesia, 5 parts of reactive filler magnesium chloride normal temperature high-speed stirreds (500r/min) stir 15min, obtain first component；
By 40 parts of function curing agent N, TMSDEA N diethylamine base propylamine, 13.8 parts of solidification adjusting control agent m-phenylene diamine (MPD)s, 10 parts of solidification adjusting control agents 651#,
25.1 parts of difunctional curing agent T31#, 11.1 parts of curing accelerator methyl tetrahydro phthalic anhydrides are stirred at 300 rpm mixes 15min, obtains
Second component；By the first and second components by 100 when using:56 part by weight mixing, stirs 10min under 1000rpm, obtains filler anti-
Type epoxy composite material is answered, the number is parts by weight.Its performance test is as shown in table 1,2,3.
Embodiment 2
By 15 parts of epoxy resin E-44s, 12.5 parts of activated form reactive solvents cyclohexanone, 3.5 parts of furfurals, 4 parts of butyl shrink
Glycerin ether, 5 parts of Interface enhancer CT-56,5 parts of interfacial agent cetyl phenol polyethenoxy ethers, 40 parts of calcium oxide, 15 parts of silicon
Acid salt cement normal temperature high-speed stirred (750r/min) stirs 5min, obtains first component；By 85 parts of function curing agent diethylenetriamines,
6.3 parts of solidification adjusting control agent MDAs, 5 parts of difunctional curing agent 810#, 3.7 parts of triethanolamines stir at 300 rpm
15min is mixed, second component is obtained；By the first and second components by 100 when using:31 part by weight mixing, is stirred under 1000rpm
10min, obtains the reactive epoxy composite material of filler, and the number is parts by weight.Its performance test is as shown in table 1,2,3.
Embodiment 3
By 25 parts of epoxy resin E-44s, 32 parts of epoxy resin F-51,14 parts of activated form reactive solvents methyl iso-butyl ketone (MIBK)s,
2 parts of glutaraldehydes, 6 parts of allyl glycidyl ethers, 0.5 part of Interface enhancer KH570,0.5 part of interfacial agent fatty alcohol polyoxy
Vinethene AEO-9,6 parts of reactive filler aluminum oxide, 6 parts of reactive filler magnesium chlorides, 8 parts of reactive filler pozzolan cements are normal
Warm high-speed stirred (830r/min) stirs 30min, obtains first component；By 21.5 parts of function curing agent 3- dibutyl amino propylamine,
22.9 parts of solidification adjusting control agents 591#, 40 parts of difunctional curing agent 910#, 15.6 parts of (dimethylaminos of curing accelerator 2,4,6- tri-
Methyl) phenol stir at 300 rpm mixing 15min, obtain second component；By the first and second components by 100 when using:10 part by weight
Mixing, 10min is stirred under 1000rpm, obtains the epoxy composite material of filler response type, and the number is parts by weight.Its property
It can test as shown in table 1,2,3.
Embodiment 4
By 70 parts of epoxy resin F-44,4 parts of activated form reactive solvents ketene dimers, 3.8 parts of activated form reactive solvents
Acetone, 8 parts of furfurals, 3 parts of 12-14 alkyl glycidyl ethers, 0.7 part of Interface enhancer KH602,0.5 part of interfacial agent alkyl
Dimethyl benzyl quaternary ammonium bromides (octadecyl dimethyl benzyl oronain), 8 parts of reactive filler calcium hydroxides, 2 parts of reactivity
Filler calcium sulfate normal temperature high-speed stirred (650r/min) stirs 10min, obtains first component；By 5 parts of function curing agent ethylene diamines, 6
Part solidification adjusting control agent 593#, 50 parts of difunctional curing agent T-31,35 parts of difunctional curing agent Capcure3-800,4 parts of solidification rush
Enter agent triphenylphosphine and stir mixing 15min at 300 rpm, obtain second component；By the first and second components by 100 when using:7 weight ratio
Example mixing, 10min is stirred under 1000rpm, obtains the epoxy composite material of filler response type, and the number is parts by weight.Its
Performance test is as shown in table 1,2,3.
Embodiment 5
By 25.2 parts of epoxy resin E-51,20 parts of activated form reactive solvents butanone, 20.2 parts of benzaldehydes, 9.8 parts new penta
Hexanediol diglycidyl ether, 1.8 parts of Interface enhancer CT-2 (profit enters chemical industry), 2 parts of interfacial agent AEOs
AEO-7,10 parts of reactive filler aluminium sulfates, 10 parts of reactive filler calcined kaolin normal temperature high-speed stirreds (3000r/min)
30min, obtains first component；By 45 parts of function curing agent TEPAs, 8 parts of solidification adjusting control agents 650#, 8 parts of difunctional curing agent
810#, 9 parts of difunctional curing agent Capcure3-800,30 parts of curing accelerator triethanolamines stir mixing at 300 rpm
15min, obtains second component；By the first and second components by weight 100 when using:3 ratio mixing, 10min is stirred under 1000rpm,
The epoxy composite material of filler response type is obtained, the number is parts by weight.Its performance test is as shown in table 1,2,3.
Embodiment 6
By 15 parts of epoxy resin E-44s, 40 parts of activated form reactive solvents melilotal, 15 parts of paraformaldehydes, 5 parts
Butyl glycidyl ether, 1 part of Interface enhancer CT-114,2 parts of interfacial agent AEO AEO-3,12 parts of fire
Mountain grey matter portland cement, 10 parts of super-early strength cement normal temperature high-speed stirreds (1500r/min) stir 20min, obtain first component；Will
15.3 parts of function curing agent triethylene tetramines, 40 parts of solidification adjusting control agent m-phenylene diamine (MPD)s, 11 parts of difunctional curing agent T-31,28.7 parts
Difunctional curing agent GPM-800,5 parts of curing accelerator dimethylanilines stir mixing 15min at 300 rpm, obtain second component；
By the first and second components by weight 100 when using:70 ratio mixing, stirs 10min under 1000rpm, obtains filler response type
Epoxy composite material, the number be parts by weight.Its performance test is as shown in table 1,2,3.
Embodiment 7
By 31 parts of epoxy resin E-51,25.8 parts of activated form reactive solvents DAAs, 1 part of glutaraldehyde, 1 part of glycerine
Triglycidyl ether, 0.6 part of Interface enhancer KH590,0.6 part of interfacial agent (octadecyl dimethyl benzyl oronain), 25
Part reactive filler alumina cement, 15 parts of reactive filler portland cement normal temperature high-speed stirreds (2200r/min) stirrings
10min, obtains first component；By 5 parts of function curing agent diethylenetriamines, 25 parts of solidification adjusting control agent m-xylene diamines, 36.5 parts double
Function curing agent 910#, 21 parts of difunctional curing agent Capcure3-800,12.5 parts of curing accelerator triethanolamines are in 300rpm
Lower stirring mixing 15min, obtains second component；By the first and second components by weight 100 when using:29 ratio mixing, under 1000rpm
10min is stirred, the epoxy composite material of filler response type is obtained, the number is parts by weight.Its performance test such as institute of table 1,2,3
Show.
Embodiment 8
By 10 parts of epoxy resin E-44s, 19.7 parts of activated form reactive solvents DAAs, 2.5 parts of furfurals, 1 part of ethylene glycol
Diglycidyl ether, 1.5 parts of Interface enhancer KH560,0.3 part of interfacial agent cetyl trimethylammonium bromide, 30 parts are anti-
Answering property filler calcium oxide, 35 parts of reactive filler superfine cement normal temperature high-speed stirreds (2500r/min) stir 5min, obtain first group
Point；By 10 parts of function curing agent ethylene diamines, 40 parts of solidification adjusting control agents 593#, 44 parts of difunctional curing agent 910#, 1 part of solidification promotion
Agent methyl tetrahydro phthalic anhydride stirs mixing 15min at 300 rpm, obtains second component；By the first and second components by 100 when using:30 weight
Ratio is mixed, and 10min is stirred under 1000rpm, obtains the epoxy composite material of filler response type, and the number is parts by weight.
Its performance test is as shown in table 1,2,3.
Mechanical property parameters of each example of table 1 in dry environment
Mechanical property parameters of each example of table 2 in wet environment
Mechanical property parameters of each example of table 3 in low temperature (5 DEG C) wet environment
The mechanic property test method of examples detailed above is joined with rower JC/T 1041-2007《Distress in concrete asphalt mixtures modified by epoxy resin
Fat grouting material》Regulation is carried out.
Pass through the analysis of these sample results：
1) the invention provides a kind of reactive epoxy composite material of filler, the material, which meets water, to be solidified rapidly, real
The antiseepage water blockoff of existing engineering.
2) epoxy composite material mechanical strength provided by the present invention is high, be one kind can one-step method realize that impervious leakage-stopping is mended
Strong epoxy composite material.
3) present invention reduces the problem of epoxy resin water blockoff injecting paste material construction costs, epoxy composite material is enable to fit
For more impervious leakage-stopping reinforcement engineerings.
Above-described embodiment be reactive epoxy composite material of filler for providing of the present invention and preparation method thereof with it in ring
The more excellent embodiment applied in oxygen tree fat injecting paste material, but embodiments of the present invention are not limited by above-described embodiment, respectively
The bound value and interval value of raw material can realize the present invention, be all contained within protection scope of the present invention.
Claims (7)
1. a kind of filler response type epoxy composite material, it is characterised in that：It is made up of first component and second component；The first component by
The component composition counted by weight below：
The second component is made up of the following component counted by weight：
Wherein, the weight ratio of first, second component is (100:3)~(100:70)；
Described epoxy resin is bisphenol A type epoxy resin or bisphenol f type epoxy resin；
Described activated form reactive solvents are ketone compounds；
Described enhanced reactive solvents are one or more of aldehyde compound or glycidol ethers compound；
Described reactive filler is magnesia, calcium oxide, aluminum oxide, calcium hydroxide, magnesium chloride, calcium sulfate, aluminium sulfate, forged
Burn one or more of kaolin, Portland cement, Portland pozzolana cement, super-early strength cement or alumina cement；
Described Interface enhancer is silane coupler or titanate coupling agent；
Described interfacial agent is one or more of cationic emulsifier or nonionic emulsifier；The cationic emulsifier
For one or more of alkyl trimethyl quaternary ammonium bromides or alkyldimethylbenzylammonium quaternary ammonium bromides；The nonionic emulsifier
For one or more of AEO or APES；
Described function curing agent is ethylenediamine, diethylenetriamine, triethylene tetramine, TEPA, N, TMSDEA N diethylamine base third
One or more of amine, 3- dibutyl amino propylamine；
Described solidification adjusting control agent be in modified amine curing agent, aromatic amine or Versamid class curing agent it is a kind of with
On；
Described difunctional curing agent is one or more of mannich base class curing agent or many sulfydryl curing agent；
Described curing accelerator is triethanolamine, dimethylaniline, (dimethylaminomethyl) phenol of 2,4,6- tri- or methyl
One or more of THPA.
2. filler response type epoxy composite material according to claim 1, it is characterised in that：Described bisphenol type epoxy tree
Fat is more than one in E-51 or E-44, and bisphenol f type epoxy resin is one or more of F-51 or F-44；
Described activated form reaction dissolvent is isophorone, cyclohexanone, methyl iso-butyl ketone (MIBK), ketene dimer, acetone, butanone, two
One or more of pyruvic alcohol or melilotal；
The aldehyde compound is one or more of benzaldehyde, glutaraldehyde, furfural, paraformaldehyde；Described glycidol ether
Class compound be benzyl glycidyl ether, butyl glycidyl ether, allyl glycidyl ether, 12-14 alkyl glycidyl ethers,
One or more of neopentylglycol diglycidyl ether, ethylene glycol diglycidylether or glycerin triglycidyl ether；
The silane coupler is more than one in KH550, KH560, KH570, KH590 or KH602, the titanate coupling agent
For one or more of CT-114, CT-2.
3. filler response type epoxy composite material according to claim 1, it is characterised in that：The modified amine curing agent
591#Or 593#One or more of；Aromatic amine curing agent is in m-phenylene diamine (MPD), m-xylene diamine or MDA
More than one；Versamid class curing agent is 650#Or 651#One or more of；
The mannich base class curing agent is T-31,810#Or 910#；Many sulfydryl curing agent are Capcure3-800 or GPM-
800。
4. according to the preparation method of any one of claims 1 to 3 filler response type epoxy composite material, it is characterised in that：
Concretely comprise the following steps：
(1) by the epoxy resin of 10~70 parts by weight, the activated form reactive solvents of 5~40 parts by weight, the increasing of 0~30 parts by weight
Strong type reactive solvents, the reactive filler of 10~65 parts by weight, the Interface enhancer of 0~5 parts by weight, the boundary of 0~5 parts by weight
Face activator is stirred in normal temperature high speed and mixed, and obtains first component；
(2) by 5~85 parts by weight function curing agent, the solidification adjusting control agent of 0~40 parts by weight, 5~85 parts of difunctional curing agent, 0
~30 parts of curing accelerator stirring at normal temperature mix to obtain second component；
(3) it is (100 according to weight ratio by first, second component:3)~(100:70) stirring mixing, obtains filler response type epoxy and answers
Condensation material.
5. the preparation method of filler response type epoxy composite material according to claim 4, it is characterised in that：In step (1)
The speed of agitator is 500~3000rpm, and the mixing time is 5~30min；The rotating speed 250 stirred described in step (2)
~350rpm, the mixing time is 10~15min；The rotating speed of stirring is 900~1000rpm in step (3), the stirring
Time is 8~12min.
6. one kind is by any one of claims 1 to 3 filler response type epoxy composite material in bridge, harbour, dam, tunnel
Waterproof, seepage control, the application in reinforcement and strengthening engineering.
7. it is a kind of by any one of claims 1 to 3 filler response type epoxy composite material foundation construction waterproof, seepage control,
Application in reinforcement and strengthening engineering.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510736801.9A CN105273361B (en) | 2015-10-30 | 2015-10-30 | A kind of filler response type epoxy composite material and preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510736801.9A CN105273361B (en) | 2015-10-30 | 2015-10-30 | A kind of filler response type epoxy composite material and preparation method and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105273361A CN105273361A (en) | 2016-01-27 |
| CN105273361B true CN105273361B (en) | 2017-10-20 |
Family
ID=55143234
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510736801.9A Active CN105273361B (en) | 2015-10-30 | 2015-10-30 | A kind of filler response type epoxy composite material and preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105273361B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105837136B (en) * | 2016-03-22 | 2017-12-01 | 浙江海鸿工业产品设计有限公司 | A kind of piezo-electric ceramic composite material and preparation method thereof |
| CN109161166B (en) * | 2018-08-16 | 2020-12-15 | 湖北双键精细化工有限公司 | Fast-curing low-shrinkage epoxy pouring filler and preparation method thereof |
| CN109320919A (en) * | 2018-11-09 | 2019-02-12 | 陈鹏 | A kind of shock-absorbing bridge support composite material and preparation method |
| EP3947560A1 (en) * | 2019-03-25 | 2022-02-09 | 3M Innovative Properties Company | Curable compositions, articles therefrom, and methods of making and using same |
| CN110903051A (en) * | 2019-11-04 | 2020-03-24 | 广州永科新材料科技有限公司 | Environment-friendly high-durability epoxy mortar |
| CN110746811A (en) * | 2019-11-04 | 2020-02-04 | 刘宇 | Environment-friendly high-durability epoxy modified putty |
| CN110804366B (en) * | 2019-11-04 | 2022-07-05 | 刘宇 | Coating capable of being applied to damp or open water base surface |
| CN112979209B (en) * | 2021-02-04 | 2022-07-12 | 中国石油大学(华东) | Oil well cement composite shrinkage reducing agent, preparation method and application thereof |
| CN115322766A (en) * | 2022-08-18 | 2022-11-11 | 北京奇想达新材料有限公司 | Bi-component low-temperature curable coated proppant and preparation method thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100478393C (en) * | 2005-04-12 | 2009-04-15 | 中国科学院广州化学研究所 | Organosilicon modified carbonyl epoxy composite material |
| CN102585441B (en) * | 2012-02-28 | 2014-06-11 | 华南理工大学 | Performance-controllable epoxy-polyketone grouting material as well as preparation method and application thereof |
| CN102977555A (en) * | 2012-11-30 | 2013-03-20 | 华南理工大学 | Light epoxy grouting material as well as preparation method and application thereof |
| CN103183927B (en) * | 2013-03-05 | 2015-06-03 | 华南理工大学 | Environment-friendly aldehyde-free epoxy injecting paste material and preparation method and application therefor |
| CN103333302B (en) * | 2013-06-25 | 2015-10-28 | 华南理工大学 | A kind of preparation method and application of reacting mild aldehyde ketone resin |
| CN103289326B (en) * | 2013-06-28 | 2015-10-07 | 山东科技大学 | For the halogen-free flame retardant epoxy resin composition of potting compound |
-
2015
- 2015-10-30 CN CN201510736801.9A patent/CN105273361B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN105273361A (en) | 2016-01-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105273361B (en) | A kind of filler response type epoxy composite material and preparation method and application | |
| CN102585441B (en) | Performance-controllable epoxy-polyketone grouting material as well as preparation method and application thereof | |
| CN103183927B (en) | Environment-friendly aldehyde-free epoxy injecting paste material and preparation method and application therefor | |
| CN102532924B (en) | Normal temperature solidified thermosetting epoxy bitumen material and preparation method thereof | |
| CN103819144A (en) | Preparation method of epoxy mortar for filling ocean oil and gas pipeline | |
| CN102070874B (en) | High-permeability and high-strength epoxy grouting material, preparation method thereof and application thereof | |
| CN107151419B (en) | A kind of high tenacity cold mixing bituminous epoxy binder and preparation method thereof | |
| CN103333302B (en) | A kind of preparation method and application of reacting mild aldehyde ketone resin | |
| CN102344647B (en) | Environmentally-friendly high-seepage epoxy grouting material and preparation method and application thereof | |
| CN105884257A (en) | High-strength rapid-hardening type epoxy resin mortar and preparation method thereof | |
| CN105419241A (en) | Transparent and environment-friendly underwater consolidated solvent-free epoxy grouting material and preparation method and application thereof | |
| CN101747882A (en) | Tectorial membrane sand solidifying system suitable for low-temperature reservoir sand prevention | |
| CN105238217B (en) | One kind penetrates into consolidation type solventless epoxy anti-corrosive coating and preparation method and application | |
| CN102977555A (en) | Light epoxy grouting material as well as preparation method and application thereof | |
| CN105948664A (en) | Asphalt pavement crack rapid repair material with low shrinkage and high bonding strength and preparation method thereof | |
| CN105176465A (en) | Epoxy grout and preparation method thereof | |
| CN107572967A (en) | A kind of cement group water-proofing material and its preparation technology | |
| CN104559067B (en) | A kind of self-emulsifying epoxy base heat conduction water-proof composite material and its preparation method and application | |
| CN106280277A (en) | A kind of preparation method and application of environmental protection low viscosity high-strength epoxy radicals grouting material | |
| CN104211356A (en) | Emulsified asphalt modified cement-based waterproof slurry as well as preparation and use method thereof | |
| CN101786831A (en) | Quick healant with low viscosity and high performance for concrete structure | |
| CN106189862B (en) | A kind of polymer modified asphalt waterproof composite material and preparation method thereof | |
| CN107629630A (en) | A kind of production method for spraying rapid-hardening colour epoxy asphalt waterproofing paint | |
| CN106280276A (en) | A kind of environmental protection low viscosity high-strength epoxy radicals chemical grouting material | |
| JPS62158152A (en) | Composition for protective coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |