JPS62158152A - Composition for protective coating - Google Patents
Composition for protective coatingInfo
- Publication number
- JPS62158152A JPS62158152A JP29748285A JP29748285A JPS62158152A JP S62158152 A JPS62158152 A JP S62158152A JP 29748285 A JP29748285 A JP 29748285A JP 29748285 A JP29748285 A JP 29748285A JP S62158152 A JPS62158152 A JP S62158152A
- Authority
- JP
- Japan
- Prior art keywords
- parts
- vinyl acetate
- cement
- composition
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Paints Or Removers (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Abstract] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、主として土木建築構造物、海洋構築物および
これらの建設用材料、設備の麹層保護被覆用組成物に関
する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention mainly relates to a composition for protecting the koji layer of civil engineering architectural structures, marine structures, materials for construction thereof, and equipment.
本発明の施工対象素地となるセメントコンクリ地下水、
汚水、工場排水、温水、各種薬品、直射日光、熱、衝撃
、摩耗などによる侵食、劣化、破壊の作用を強く受ける
ため、防食性能、物理強度、耐久性のすぐれた被覆材で
保護する必要がある。Cement concrete groundwater, which is the base material for construction of the present invention,
Because they are subject to strong erosion, deterioration, and destruction due to sewage, industrial wastewater, hot water, various chemicals, direct sunlight, heat, impact, and abrasion, they must be protected with coating materials that have excellent corrosion resistance, physical strength, and durability. be.
従来この目的に使用されている被覆材は有機質防食塗料
およびポリマーセメントモルタルなどである。Coating materials conventionally used for this purpose include organic anticorrosive paints and polymer cement mortars.
しかし、有機質防食塗料は防食能力を有する反面、塗装
膜厚が薄いだめ耐前撃性や耐摩耗性などの物理的性能、
ならびに長期的な耐候性に劣シ、て、何れも満足すべき
被覆材とは云えない。However, although organic anticorrosion paints have anticorrosion ability, they have poor physical performance such as front impact resistance and abrasion resistance due to the thin coating film thickness.
In addition, they have poor long-term weather resistance, and cannot be said to be satisfactory covering materials.
本発明の目的は、上記の各用途に適用されて高度の防食
性能を発揮し、且外力に耐える物理的性能とすぐれだ１
酎入力を有する新規なる礪Ｘ保護被覆用組成物を提供す
るものである。It is an object of the present invention to be applied to each of the above-mentioned applications, to exhibit a high degree of anti-corrosion performance, and to have excellent physical performance to withstand external forces.
The object of the present invention is to provide a novel composition for protective coating of 礪X, which has an anti-inflammatory effect.
本発明目的の被覆材は、基本的に下記の諸条件を満すも
のであることが必要である。即ち、（１）すぐれた防食
性能を有すること、（２）高度の耐久力を有すること、
（３）セメントコンクリート、鉄、有機材に密着性がす
ぐれること、（４１耐衝撃性、耐摩耗性、可焼性などの
物理的性能にすぐれること、（５）１回の施工で数頭厚
恩上の厚塗シができること、などがあげられる。The coating material for the purpose of the present invention basically needs to satisfy the following conditions. That is, (1) it has excellent anti-corrosion performance, (2) it has a high degree of durability,
(3) Excellent adhesion to cement concrete, iron, and organic materials; (41) Excellent physical performance such as impact resistance, abrasion resistance, and combustibility; (5) Several Examples include being able to apply thick coats on top of the head.
このような被覆材を開発するにあたり本発明者は、（１
）有機質保護塗料のもつ防食性、密着性、可セメント材
の有する曲げ強度、耐衝撃性、耐摩耗性など上記各材料
のもつ特性を同一被覆材に具備せしめることに成功し、
本発明を完成するに到った。In developing such a coating material, the present inventor
) We succeeded in providing the same coating material with the characteristics of each of the above materials, such as the corrosion resistance and adhesion of organic protective paints, and the bending strength, impact resistance, and abrasion resistance of cementable materials.
The present invention has now been completed.
即ち、本発明は、エポキシ樹脂とその硬化剤、酢酸ビニ
ル系共重合体エマルジョン、セメント、補強性充填材お
よび必要に応じて骨材粉末、着色剤、塗料添加剤、セメ
ント混和材などを包含し、樹脂固型分中の酢酸ビニル系
共重合体の量は５〜９５ｗｔ％、全組成物の固型分中の
樹脂固型分の量は２〜４０ｗｔ％、全組成物の固型分中
の補強性充填材の量は１〜３５ｗｔ％である職頌保護被
覆用組成物であって、ここに得られる保護被覆はエポキ
シ樹脂と酢酸ビニル系共重合体エマルジョンからなる樹
脂成分、セメントモルタル成分およびマイカ、ガラスフ
レークなどの補強性充填材の組合せによる相乗的効果に
よって、従来の有機質保護塗料やポリマーセメントモル
タルでは得られなかったすぐれた性能を発揮するもので
ある。That is, the present invention includes an epoxy resin, a curing agent thereof, a vinyl acetate copolymer emulsion, cement, a reinforcing filler, and, if necessary, an aggregate powder, a coloring agent, a paint additive, a cement admixture, and the like. , the amount of vinyl acetate copolymer in the resin solid content is 5 to 95 wt%, the amount of resin solid content in the solid content of the total composition is 2 to 40 wt%, the amount of the vinyl acetate copolymer in the solid content of the total composition is 2 to 40 wt%, The amount of the reinforcing filler is 1 to 35 wt%.The protective coating obtained here contains a resin component consisting of an epoxy resin and a vinyl acetate copolymer emulsion, and a cement mortar component. The synergistic effect of the combination of reinforcing fillers such as mica and glass flakes provides excellent performance that cannot be obtained with conventional organic protective paints or polymer cement mortars.
本発明の技術的要点の第１は、本被覆材を構成する樹脂
成分、セメントモルタル
強性充填材よりなる混合組成において、エポキシ樹脂と
酢酸ビニル系共重合体エマルジョンの混合物を樹脂成分
とすることにより、長期的な防食性能とすぐれた耐久力
を被覆に付与したこと、またその第２は、有機質詰１合
材である樹脂成分と無機質結合材であるセメントとを、
これらに共通の強化材であるフレーク状充填材を配する
ことＫよって複合強化材となし、高度の物理強度とすぐ
れた付着性、遮蔽性を被覆に付与したことである。The first technical point of the present invention is that in the mixed composition consisting of the resin component and cement mortar strong filler constituting this coating material, the resin component is a mixture of epoxy resin and vinyl acetate copolymer emulsion. This gives the coating long-term anti-corrosion performance and excellent durability.Secondly, the resin component, which is an organic filling material, and the cement, which is an inorganic binder, are
By disposing a flake-like filler, which is a common reinforcing material, in these materials, a composite reinforcing material is formed, and a high degree of physical strength and excellent adhesion and shielding properties are imparted to the coating.
本発明において、エポキシ樹脂としては、ビスフェノー
ルＡ−エピク四ルヒドリン型液状樹脂をＱ／Ｗ型エマル
ジョンに乳化したものが最も一般的に用いられ、その他
の各種エポキシ樹脂も使用できる。エポキシ樹脂硬化剤
としては、ポリアマイド樹脂、アミンアダクトなどの一
般硬化剤が使用できる。In the present invention, the most commonly used epoxy resin is one obtained by emulsifying a bisphenol A-epic tetrahydrin type liquid resin into a Q/W type emulsion, and various other epoxy resins can also be used. As the epoxy resin curing agent, general curing agents such as polyamide resin and amine adduct can be used.
酢酸ビニル系共亜合体エマルジョンとしては、例えばエ
チレン−酢酸ビニル系、エチレン−酢酸ビニル−アクリ
ル系、エチレン−酢酸ビニルーベオバ系、エチレン−酢
酸ビニル−塩化ビニル系、酢酸ビニルーベオパ糸などを
挙げることができる。Examples of the vinyl acetate co-polymer emulsion include ethylene-vinyl acetate, ethylene-vinyl acetate-acrylic, ethylene-vinyl acetate-vinyl chloride, ethylene-vinyl acetate-vinyl chloride, and vinyl acetate-rube opaline emulsions.
本発明でこれらの酢酸ビニル系共重合体エマルジョンを
エポキシ樹脂と併用する理由は、これらのエマルジョン
がエポキシ樹脂とその硬化剤およびセメントと良く混和
し、（１）組成物の施工作業性を著しく高め、（２）エ
ポキシ樹脂エマルジョンの安定性を良くして施工時の水
分離を速め、（３）低温における被覆形成能を改善して
冬期の施工を可能とし、（４）被覆の可撓性、付着性を
向上させ、（５）長期的な防食性とすぐれた耐久力を被
覆に付与することにある。樹脂成分としてエポキシ樹脂
とその硬化剤のみを用いた場合は、前述のような酢酸ビ
ニル系共重合体エマルジョン併用の利点が失われるだけ
でなく、被覆の硬度が高くなり、長期間の経過で可焼性
、１酎衝撃性などが低下し、ひびわれや剥離が発生しや
すくなるという欠点がちる。一方、樹脂成分として酢酸
ビニル系共重合体エマルジョンのみを用いるときは、被
覆強度が不足して耐衝撃性、耐摩耗性などの物性が低下
し、防食性も劣り本発明の目的達成は困難となる。また
エポキシ樹脂とその硬化剤、およびセメントとの混和性
の悪い他の熱可塑性樹脂エマルジョンを使用するときは
、組成物の異常増粘や流動性の低下を起し、作業性が悪
く施工を行うことができない。The reason why these vinyl acetate copolymer emulsions are used in combination with epoxy resins in the present invention is that these emulsions mix well with epoxy resins, their curing agents, and cement, and (1) significantly improve workability of the composition. , (2) improves the stability of the epoxy resin emulsion to speed up water separation during application, (3) improves coating formation ability at low temperatures to enable winter application, (4) flexibility of the coating, The objective is to improve adhesion and (5) provide the coating with long-term corrosion protection and excellent durability. If only an epoxy resin and its curing agent are used as resin components, not only will the above-mentioned advantages of using a vinyl acetate copolymer emulsion in combination be lost, but the hardness of the coating will increase and it will deteriorate over a long period of time. It has the drawbacks of reduced baking properties, low impact resistance, etc., and a tendency to crack and peel. On the other hand, when only a vinyl acetate copolymer emulsion is used as the resin component, the coating strength is insufficient, physical properties such as impact resistance and abrasion resistance are reduced, and corrosion resistance is also poor, making it difficult to achieve the objective of the present invention. Become. In addition, when using epoxy resin and its curing agent, as well as other thermoplastic resin emulsions that are poorly miscible with cement, the composition may become abnormally thickened and fluidity may decrease, resulting in poor workability and poor construction performance. I can't.
本発明において、樹脂固型分中の酢酸ビニル系共重合体
の量は５〜９５ｗｔ％の範囲にあり、その量が５％以下
であると前記したようなエポキシ樹脂単独使用の欠点が
現われ、また９５％以上では所期の物理強度と防食性能
を得ることができない。全組成物の固型分中の樹脂固型
分の量は２〜４０ｗｔ％の範囲にあり、その量が２％以
下のときは可視性、付着性、防食性などが低下し、４０
％を超えると厚塗り性が悪くなる。In the present invention, the amount of the vinyl acetate copolymer in the resin solid content is in the range of 5 to 95 wt%, and if the amount is less than 5%, the above-mentioned disadvantages of using epoxy resin alone will appear. Moreover, if it exceeds 95%, it is not possible to obtain the desired physical strength and anticorrosion performance. The amount of resin solids in the solids of the entire composition is in the range of 2 to 40 wt%, and when the amount is less than 2%, visibility, adhesion, corrosion resistance, etc. decrease, and
If it exceeds %, the thick coating property will deteriorate.
本発明で使用される補強性充填材は、マイカまたはガラ
スフレークであり、それぞれ単独であるいは混合して用
いられる。これらのフレーク状充填材の粒子の最大中は
０．１〜３箇の範囲が適しており、０．１１１ｎ以下の
細粒は補強効果が小さく、一方３１ｒａを超えるものは
組成物の流動性を低下させ、マイカにおいては厚みも大
きなものが多くへき開処理が面倒になる。全組成物の固
型分中の補強性充填材の量は１〜３５ｗｔ％の範囲であ
って、１％以下の量では補強効果を期待できず、また３
５％を超えると組成物の流動適性や分散性の面で支障が
起ってくる。The reinforcing filler used in the present invention is mica or glass flakes, each of which may be used alone or in combination. A range of 0.1 to 3 particles is suitable for these flaky filler particles, with fine particles of 0.111n or less having a small reinforcing effect, while particles exceeding 31ra may reduce the fluidity of the composition. Many mica materials have a large thickness, making the cleavage process troublesome. The amount of reinforcing filler in the solid content of the whole composition is in the range of 1 to 35 wt%, and if the amount is less than 1%, no reinforcing effect can be expected, and 3
If it exceeds 5%, problems will arise in terms of fluidity and dispersibility of the composition.
セメントとしてはポルトランドセメント、アルミナセメ
ントが適しており、その他のセメントも使用できる。Portland cement and alumina cement are suitable as cement, and other cements can also be used.
さらに、例えば珪砂、川砂、シリカ粉、ガラス粉、セラ
ミック扮、炭酸カルシウム粉などの骨材粉末、分散剤、
湿潤剤、増粘剤、消泡剤、凍解安定剤、防腐剤、防かび
剤などの塗料添加剤、減水剤、硬化促進剤、硬化遅延剤
、ＡＥ剤などのセメント混和剤が必要に応じて加えられ
る。Furthermore, aggregate powders such as silica sand, river sand, silica powder, glass powder, ceramic powder, calcium carbonate powder, dispersants,
Paint additives such as wetting agents, thickeners, antifoaming agents, freeze-thaw stabilizers, preservatives, and fungicides, and cement admixtures such as water reducers, curing accelerators, curing retarders, and AE agents, as required. can be added.
本被覆用組成物は、通常被塗物に対して直接スプレー、
コテ塗９、刷毛塗シ、ゴムレーキなどにより施されるが
、この際組成物中の水量は上記の各施工法について最も
作業のしやすい粘性となるように調節することができる
。また被塗物素地の条件により付着性や作業性を高める
目的でプライマーまたはシーラーを下塗シしてもよい。This coating composition is usually sprayed directly onto the object to be coated.
It is applied by troweling, brushing, rubber rake, etc. At this time, the amount of water in the composition can be adjusted so as to provide the most workable viscosity for each of the above-mentioned application methods. Depending on the conditions of the substrate to be coated, a primer or sealer may be applied as an undercoat to improve adhesion and workability.
以下、本発明を実施例によシ更に具体的に説明する。な
お実施例中「部」は重量部を表″わす。Hereinafter, the present invention will be explained in more detail with reference to Examples. In the examples, "parts" represent parts by weight.
実施例１
ポルトランドセメント１００部、８号珪砂５０部、エチ
レン−酢酸ビニル共重合体（Ｔｇ−１０”Ｃ）の５０％
エマルジョン３０部、エポキシ樹脂の５０％エマルジョ
ン２０部、ポリアマイド樹脂１０部、マイカ（６０メツ
シユ）２２部、ガラスフレーク（４８メツシユ）１０部
、水４０部を混練して各供試体を作った。Example 1 100 parts of Portland cement, 50 parts of No. 8 silica sand, 50% of ethylene-vinyl acetate copolymer (Tg-10''C)
Each specimen was prepared by kneading 30 parts of emulsion, 20 parts of 50% epoxy resin emulsion, 10 parts of polyamide resin, 22 parts of mica (60 mesh), 10 parts of glass flakes (48 mesh), and 40 parts of water.
実施例２
ポルトランドセメント１００部、８号珪砂５０部、エチ
レン−酢酸ビニル−アクリル酸エステル共重合体（Ｔｇ
−１５°Ｃ）の５０％エマルジョン３０部、エポキシ樹
脂の５０％エマルジョン２０部、ポリアマイド樹脂１０
部、マイカ（６０メツシユ）２２部、ガラスフレーク（
４８メツシユ）１０部、水４０部を混練して各供試体を
作った。Example 2 100 parts of Portland cement, 50 parts of No. 8 silica sand, ethylene-vinyl acetate-acrylic ester copolymer (Tg
-15°C) 30 parts of 50% emulsion of epoxy resin, 20 parts of 50% emulsion of epoxy resin, 10 parts of polyamide resin
22 parts of mica (60 mesh), glass flakes (
Each specimen was prepared by kneading 10 parts of 48 mesh) and 40 parts of water.
対照例１（従来の一般的ポリマーセメントモルタル処方
）
ポルトランドセメント１００部、６号珪砂３００部、エ
チレン−酢酸ビニル共重合体の５５％エマルジョン（Ｔ
ｇＯｏＣ）２０部、水６０部を混練して各供試体を作っ
た。Control example 1 (conventional general polymer cement mortar formulation) 100 parts of Portland cement, 300 parts of No. 6 silica sand, 55% emulsion of ethylene-vinyl acetate copolymer (T
Each specimen was prepared by kneading 20 parts of gOoC) and 60 parts of water.
対照例２
ポルトランドセメント１００部、８号珪砂５０部、エポ
キシ樹脂の５０％エマルジゴン３５部、ポリアマイド樹
脂１７部、マイカ（６０メツシユ）２２部、ガラスフレ
ーク（４８メツシユ）１０部、水４７部を混練して各供
試体を作った。Control Example 2 100 parts of Portland cement, 50 parts of No. 8 silica sand, 35 parts of 50% epoxy resin emuldigon, 17 parts of polyamide resin, 22 parts of mica (60 mesh), 10 parts of glass flakes (48 mesh), and 47 parts of water were kneaded. Each specimen was prepared using the same method.
対照例３
ポルトランドセメント１００部、８号珪砂５０部、エチ
レン−酢酸ビニル共重合体（Ｔｇ−１０°Ｃ）の５０％
エマルジョン３０部、エポキシ樹脂の５０％エマルジョ
ン２０部、ポリアマイド樹脂１０部、水２０部を混練し
て各供試体を作った。Control Example 3 100 parts of Portland cement, 50 parts of No. 8 silica sand, 50% of ethylene-vinyl acetate copolymer (Tg - 10°C)
Each specimen was prepared by kneading 30 parts of emulsion, 20 parts of 50% epoxy resin emulsion, 10 parts of polyamide resin, and 20 parts of water.
対照例４
ポルトランドセメント１００部、１８号珪砂５０部、エ
チＶンー酢酸ビニル共重合体（Ｔｇ−１０°Ｃ）の５０
％エマルジョン７０部、マイカ（６０メツシユ）２２部
、ガラスフレーク（４８メツシユ）１０部、水３０部を
混練して各供試体を作った。Control example 4 100 parts of Portland cement, 50 parts of No. 18 silica sand, 50 parts of ethyl V-vinyl acetate copolymer (Tg - 10°C)
Each specimen was prepared by kneading 70 parts of % emulsion, 22 parts of mica (60 mesh), 10 parts of glass flakes (48 mesh), and 30 parts of water.
対照例５
ポルトランドセメント１００部、８号珪砂５０部、アク
リル酸エステル重合体の５０％エマルジョン３０部、エ
ポキシ樹脂の５０％エマルジョン２０部、ポリアマイド
樹１１＆ １０部、マイカＣ６０メツシユ）２２部、ガ
ラスフレーク（４８メツシユ）１０部、水４０部を混練
したところ異常に増粘して供試体を作ることができなか
った。Control Example 5 100 parts of Portland cement, 50 parts of No. 8 silica sand, 30 parts of 50% emulsion of acrylic acid ester polymer, 20 parts of 50% emulsion of epoxy resin, 11 & 10 parts of polyamide tree, 22 parts of mica C60 mesh, glass flakes When 10 parts (48 mesh) and 40 parts of water were kneaded, the viscosity increased abnormally and a specimen could not be prepared.
実施例１〜２および対照例１〜４の結果を次表に示す。The results of Examples 1-2 and Control Examples 1-4 are shown in the following table.
以上説明したように、本発明の湾籾保護被覆用組成物は
、従来の有機質防食塗料やポリマーセメントモルタルに
比して、長期的な防食性、耐久力、被覆強度をはじめと
する諸性能にすぐれており、セメントコンクリート、セ
メントモルタル、鋼材、アスファルト、合成高分子材、
木材などの素地の保護被覆材、補修材、防錆防食被覆材
、防燃被覆材、下地調整材、舗装材、防水材として有用
である。As explained above, the bay rice protective coating composition of the present invention has better performance such as long-term corrosion resistance, durability, and coating strength than conventional organic anticorrosive paints and polymer cement mortars. Excellent for cement concrete, cement mortar, steel, asphalt, synthetic polymer materials,
It is useful as a protective coating material for materials such as wood, a repair material, a rust- and corrosion-proofing coating material, a flame-retardant coating material, a base conditioning material, a paving material, and a waterproofing material.
Claims (1)
エマルジョン、セメント、補強性充填材および必要に応
じて骨材粉末、着色剤、塗料添加剤、セメント混和材な
どを包含し、樹脂固型分中の酢酸ビニル系共重合体の量
は５〜９５ｗｔ％、全組成物の固型分中の樹脂固型分の
量は２〜４０ｗｔ％、全組成物の固型分中の補強性充填
材の量は１〜３５ｗｔ％である保護被覆用組成物。 ２ 補強性充填材がマイカおよび／またはガラスフレー
クである特許請求の範囲第１項記載の保護被覆用組成物
。[Claims] 1. Epoxy resin and its curing agent, vinyl acetate copolymer emulsion, cement, reinforcing filler, and if necessary aggregate powder, coloring agent, paint additive, cement admixture, etc. The amount of vinyl acetate copolymer in the resin solid content is 5 to 95 wt%, the amount of resin solid content in the solid content of the total composition is 2 to 40 wt%, and the solid content of the total composition is 5 to 95 wt%. A protective coating composition in which the amount of reinforcing filler is from 1 to 35 wt%. 2. The protective coating composition according to claim 1, wherein the reinforcing filler is mica and/or glass flakes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29748285A JPS62158152A (en) | 1985-12-30 | 1985-12-30 | Composition for protective coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29748285A JPS62158152A (en) | 1985-12-30 | 1985-12-30 | Composition for protective coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62158152A true JPS62158152A (en) | 1987-07-14 |
Family
ID=17847070
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP29748285A Pending JPS62158152A (en) | 1985-12-30 | 1985-12-30 | Composition for protective coating |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62158152A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06121965A (en) * | 1992-07-06 | 1994-05-06 | Kanebo Nsc Ltd | Production of coating film and film forming chemicals used therefor |
| JP2001131468A (en) * | 1999-11-09 | 2001-05-15 | Nippon Steel Chem Co Ltd | Coating composition for repair and facility-repairing method |
| JP2008127245A (en) * | 2006-11-21 | 2008-06-05 | Taiheiyo Material Kk | Substrate conditioning material |
| CN105669099A (en) * | 2015-12-31 | 2016-06-15 | 富思特新材料科技发展股份有限公司 | Aqueous epoxy coating for terraces, and preparation method thereof |
| US20160368822A1 (en) * | 2013-07-05 | 2016-12-22 | Sika Technology Ag | Multi-component composition |
| CN106277931A (en) * | 2016-07-21 | 2017-01-04 | 东华大学 | A kind of BAPP type granolith sheet material and preparation method thereof |
| CN106277930A (en) * | 2016-07-21 | 2017-01-04 | 东华大学 | A kind of 13BDAPB type granolith sheet material and preparation method thereof |
| CN106277929A (en) * | 2016-07-21 | 2017-01-04 | 东华大学 | A kind of BDATHQ type granolith sheet material and preparation method thereof |
| JP2017141320A (en) * | 2016-02-08 | 2017-08-17 | 旭化成アドバンス株式会社 | Aqueous lining material for water supply facilities |
-
1985
- 1985-12-30 JP JP29748285A patent/JPS62158152A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06121965A (en) * | 1992-07-06 | 1994-05-06 | Kanebo Nsc Ltd | Production of coating film and film forming chemicals used therefor |
| JP2001131468A (en) * | 1999-11-09 | 2001-05-15 | Nippon Steel Chem Co Ltd | Coating composition for repair and facility-repairing method |
| JP2008127245A (en) * | 2006-11-21 | 2008-06-05 | Taiheiyo Material Kk | Substrate conditioning material |
| US20160368822A1 (en) * | 2013-07-05 | 2016-12-22 | Sika Technology Ag | Multi-component composition |
| CN105669099A (en) * | 2015-12-31 | 2016-06-15 | 富思特新材料科技发展股份有限公司 | Aqueous epoxy coating for terraces, and preparation method thereof |
| JP2017141320A (en) * | 2016-02-08 | 2017-08-17 | 旭化成アドバンス株式会社 | Aqueous lining material for water supply facilities |
| CN106277931A (en) * | 2016-07-21 | 2017-01-04 | 东华大学 | A kind of BAPP type granolith sheet material and preparation method thereof |
| CN106277930A (en) * | 2016-07-21 | 2017-01-04 | 东华大学 | A kind of 13BDAPB type granolith sheet material and preparation method thereof |
| CN106277929A (en) * | 2016-07-21 | 2017-01-04 | 东华大学 | A kind of BDATHQ type granolith sheet material and preparation method thereof |
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