CN105038174B - 一种聚碳酸酯组合物及其制备方法 - Google Patents
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- CN105038174B CN105038174B CN201510385802.3A CN201510385802A CN105038174B CN 105038174 B CN105038174 B CN 105038174B CN 201510385802 A CN201510385802 A CN 201510385802A CN 105038174 B CN105038174 B CN 105038174B
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Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 | 实施例7 | 实施例8 | 实施例9 | 实施例10 | 实施例11 | 实施例12 | 实施例13 | 实施例14 | 实施例15 | |
组分a-1 | 50 | 50 | 60.5 | 60.5 | 72.2 | 72.2 | 50 | 50 | 60 | 60 | 70 | 70 | |||
组分a-2 | 50 | 60.5 | 72.2 | ||||||||||||
组分b-1 | 40 | 32 | 32 | 20 | 20 | 31 | 22.6 | 22.95 | |||||||
组分b-2 | 40 | 40 | 32 | 20 | 26 | 33.7 | 16 | ||||||||
组分c-1 | 1 | 1 | 1 | 0.8 | 0.8 | 0.8 | 10 | 15 | 0.3 | 18 | 0.4 | 0.05 | |||
组分c-2 | 1.5 | 1.5 | 1.5 | ||||||||||||
组分d-1 | 8 | 8 | 5 | 5 | 6 | 6 | 8 | 6 | 6 | ||||||
组分d-2 | 8 | 5 | 6 | 8 | 5 | 5 | |||||||||
组分e-1 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
组分e-2 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
苯酚类物质含量(ppm) | 0.15 | 19 | 42 | 0.6 | 62 | 32 | 79 | 12 | 27 | 42 | 42 | 32 | 32 | 27 | 27 |
双酚A含量(ppm) | - | - | - | - | - | - | - | - | - | - | - | - | - | ||
受阻酚含量(ppm) | |||||||||||||||
150℃冲击性能保持率(0h) | 100% | 100% | 100% | 100% | 100% | 100% | 100% | 100% | 100% | 100% | 100% | 100% | 100% | 100% | 100% |
150℃冲击性能保持率(500h) | 61% | 72% | 84% | 63% | 71% | 85% | 64% | 74% | 87% | 71% | 62% | 70% | 61% | 72% | 64% |
增容效果 | + | ++ | +++ | + | ++ | +++ | + | ++ | +++ | ++ | + | ++ | ○ | ++ | ○ |
阻燃效果(2.0mm) | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 |
对比例1 | 对比例2 | 对比例3 | 对比例4 | 对比例5 | 对比例6 | 对比例7 | 对比例8 | 对比例9 | 对比例10 | 对比例11 | |
组分a-1 | 50 | 50 | 60 | 60 | 70 | 70 | 50 | 50 | |||
组分a-2 | 50 | 60 | 70 | ||||||||
组分b-1 | 41 | 32 | 32 | 20 | 20 | 40 | 40 | ||||
组分b-2 | 16 | 11 | 32 | 20 | |||||||
组分c-1 | 0 | 25 | 30 | 3 | 3 | 3 | 1 | 1 | |||
组分c-2 | 2 | 2 | 2 | ||||||||
组分d-1 | 8 | 8 | 5 | 5 | 6 | 6 | 8 | 8 | |||
组分d-2 | 8 | 5 | 6 | ||||||||
组分e-1 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
组分e-2 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
苯酚类物质含量(ppm) | 0.05 | 143 | 42 | 0 | 110 | 98 | 0.1 | 125 | 0 | ||
双酚A含量(ppm) | 17 | ||||||||||
受阻酚含量(ppm) | 17 | ||||||||||
150℃冲击性能保持率(0h) | 100% | 100% | 100% | 100% | 100% | 100% | 100% | 100% | 100% | 100% | 100% |
150℃冲击性能保持率(500h) | 31% | 45% | 13% | 24% | 16% | 34% | 43% | 46% | 52% | 57% | 53% |
增容效果 | ╳ | ╳ | ╳ | ╳ | ╳ | ╳ | ╳ | ╳ | ╳ | ╳ | ╳ |
阻燃效果(2.0mm) | V-2 | V-2 | V-2 | V-2 | V-2 | V-2 | V-2 | V-2 | V-2 | V-2 | V-2 |
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