CN1050373C - 聚癸二酰癸二胺/聚丙烯稀土塑料合金工艺 - Google Patents
聚癸二酰癸二胺/聚丙烯稀土塑料合金工艺 Download PDFInfo
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- CN1050373C CN1050373C CN95100060A CN95100060A CN1050373C CN 1050373 C CN1050373 C CN 1050373C CN 95100060 A CN95100060 A CN 95100060A CN 95100060 A CN95100060 A CN 95100060A CN 1050373 C CN1050373 C CN 1050373C
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- polypropylene
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- 239000004743 Polypropylene Substances 0.000 title claims abstract description 24
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 24
- 229910052761 rare earth metal Inorganic materials 0.000 title claims abstract description 19
- 150000002910 rare earth metals Chemical class 0.000 title claims abstract description 19
- 239000004033 plastic Substances 0.000 title claims abstract description 9
- 229920003023 plastic Polymers 0.000 title claims abstract description 9
- 239000000956 alloy Substances 0.000 title abstract description 6
- 229910045601 alloy Inorganic materials 0.000 title abstract description 6
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000004677 Nylon Substances 0.000 claims abstract description 23
- 229920001778 nylon Polymers 0.000 claims abstract description 23
- -1 polypropylene Polymers 0.000 claims abstract description 15
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000002360 preparation method Methods 0.000 claims abstract description 4
- 239000003054 catalyst Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 238000001125 extrusion Methods 0.000 claims description 2
- 238000005469 granulation Methods 0.000 claims description 2
- 230000003179 granulation Effects 0.000 claims description 2
- 238000002156 mixing Methods 0.000 abstract description 3
- 125000003368 amide group Chemical group 0.000 abstract description 2
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 125000004018 acid anhydride group Chemical group 0.000 abstract 1
- 230000000977 initiatory effect Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 150000008064 anhydrides Chemical group 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920006112 polar polymer Polymers 0.000 description 1
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- Polyamides (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
本发明属于尼龙1010/聚丙烯稀土塑料合金的制备工艺，本发明利用稀土引发下聚丙烯接枝马来酸酐的接枝物中的酸酐基团与尼龙1010酰胺基中-NH2发生化学反应，进而改善聚丙烯与尼龙1010共混相容性，制备的尼龙1010/聚丙烯稀土塑料合金抗张强度60～65MPa，弯曲模量1000～1300MPa，缺口冲击强度70～90J/M，吸水率0.5～1%，收缩率降低。
Description
本发明属于聚癸二酰癸二胺(简称尼龙1010)/聚丙烯稀土塑料合金的制备工艺。
尼龙1010是很重要的工程塑料之一，其吸水率虽比尼龙6和尼龙66都低，但吸水率也大于2％，用做某些工程构件或制件吸水率偏高，收缩率偏大，尺寸稳定性差。另外尼龙1010价格昂贵，开发应用受到限制。
尼龙1010为极性高聚物，聚丙烯为非极性，二者共混不相溶，在熔融共混时，发生严重相分离，合金力学性能差，抗张强度25～30MPa，伸长率123％～137％，Izod缺口冲击强度30～40J/M，没有应用价值。
本发明的目的是提供一种利用稀土引发下聚丙烯接枝马来酸酐的接枝物中的酸酐基团与尼龙1010酰胺基中-NH2发生化学反应，进而改善聚丙烯与尼龙1010共混相溶性，制备尼龙1010/聚丙烯稀土塑料合金的工艺。
本发明的方法是将尼龙1010按重量比95～60％与聚丙烯重量比5～40％，再加入稀土催化引发下聚丙烯接枝马来酸酐的接枝物(简称稀土接枝物)，其量为前两者总重量的5～10％，将尼龙1010，聚丙烯和稀土接枝物放入螺杆挤出机或捏合机中熔融反应，反应温度190～230℃，挤出速度2mm/分～6mm/分，挤出物经气冷造粒，制成的尼龙1010/聚丙烯稀土塑料合金，抗张强度55～65MPa，伸长率250％～320％，弯曲强度60～65MPa，弯曲模量1000～1300MPa，缺口冲击强度70～90J/M，吸水率0.5～1％，收缩率降低。
本发明提供的实施例如下：
实施例1：
取尼龙1010 95g与聚丙烯5g，再加入稀土接枝物(稀土催化引发下聚丙烯接枝马来酸酐的接枝物)5g，三者一起熔融共混，挤出速度为2mm/分，测其抗张强度为65MPa，伸长率270％，吸水率0.5％，弯曲强度64MPa，弯曲模量为1290MPa。
实施例2：
尼龙1010 90g与聚丙烯10g，再加入稀土接枝物10g，反应加工条件同实施例1，其合金性能抗张强度为58MPa，伸长率300％，吸水率0.8％，冲击强度90J/M。
实施例3：
尼龙1010 70g与聚丙烯30g，再加稀土接枝物10g，反应加工条件同实施例1，其合金抗张强度55MPa，伸长率为320％，吸水率0.5％，冲击强度80J/M，弯曲模量为1000MPa。
Claims (1)
1.一种尼龙1010/聚丙烯稀土塑料合金的制备工艺，其特征是将尼龙1010按重量比95～60％与聚丙烯重量比5～40％，再加入稀土催化引发下聚丙烯接枝马来酸酐的接枝物，其量为前两者总重量的5～10％，将尼龙1010，聚丙烯和稀土接枝物放入螺杆挤出机或捏合机中熔融反应，反应温度190～230℃，挤出速度2mm～6mm/分，挤出物经气冷造粒，制成的尼龙1010/聚丙烯稀土塑料合金，抗张强度55～65MPa，伸长率250％～320％，弯曲强度60～65MPa，弯曲模量1000～1300MPa，缺口冲击强度70～90J/M，吸水率0.5～1％，收缩率降低。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95100060A CN1050373C (zh) | 1995-01-14 | 1995-01-14 | 聚癸二酰癸二胺/聚丙烯稀土塑料合金工艺 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95100060A CN1050373C (zh) | 1995-01-14 | 1995-01-14 | 聚癸二酰癸二胺/聚丙烯稀土塑料合金工艺 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1126652A CN1126652A (zh) | 1996-07-17 |
| CN1050373C true CN1050373C (zh) | 2000-03-15 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95100060A Expired - Fee Related CN1050373C (zh) | 1995-01-14 | 1995-01-14 | 聚癸二酰癸二胺/聚丙烯稀土塑料合金工艺 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1050373C (zh) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7071259B2 (en) * | 2004-07-27 | 2006-07-04 | Equistar Chemicals, Lp | Functionalized propylene polymer compositions and composites containing same |
| CN100402596C (zh) * | 2006-04-27 | 2008-07-16 | 刘信东 | 一种沥青包装袋用聚丙烯尼龙塑料合金 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5065377A (zh) * | 1973-10-09 | 1975-06-03 | ||
| JPS6179815A (ja) * | 1984-09-27 | 1986-04-23 | Yamaha Motor Co Ltd | 自動二輪車用エンジンの排気消音装置 |
| JPS6179784A (ja) * | 1984-09-27 | 1986-04-23 | Toshiba Corp | シヤドウマスクの製造方法及びその装置 |
| CN1033821A (zh) * | 1987-11-04 | 1989-07-12 | 三井石油化学工业株式会社 | 玻璃纤维强化的热塑性树脂组合物 |
-
1995
- 1995-01-14 CN CN95100060A patent/CN1050373C/zh not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5065377A (zh) * | 1973-10-09 | 1975-06-03 | ||
| JPS6179815A (ja) * | 1984-09-27 | 1986-04-23 | Yamaha Motor Co Ltd | 自動二輪車用エンジンの排気消音装置 |
| JPS6179784A (ja) * | 1984-09-27 | 1986-04-23 | Toshiba Corp | シヤドウマスクの製造方法及びその装置 |
| CN1033821A (zh) * | 1987-11-04 | 1989-07-12 | 三井石油化学工业株式会社 | 玻璃纤维强化的热塑性树脂组合物 |
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| Publication number | Publication date |
|---|---|
| CN1126652A (zh) | 1996-07-17 |
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