CN104982447A - Bactericidal composition containing pyraclostrobin and dihydroxy imides - Google Patents
Bactericidal composition containing pyraclostrobin and dihydroxy imides Download PDFInfo
- Publication number
- CN104982447A CN104982447A CN201510317675.3A CN201510317675A CN104982447A CN 104982447 A CN104982447 A CN 104982447A CN 201510317675 A CN201510317675 A CN 201510317675A CN 104982447 A CN104982447 A CN 104982447A
- Authority
- CN
- China
- Prior art keywords
- pyraclostrobin
- procymidone
- bactericidal composition
- iprodione
- dihydroxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a bactericidal composition containing pyraclostrobin and dihydroxy imides. Effective active ingredients of the bactericidal composition contain the pyraclostrobin and a dihydroxy imides compound of iprodione or procymidone, wherein the weight ratio of the procymidone to the iprodione or the procymidone ranges from 8:1 to 1:64, auxiliaries and polybutene are added to the effective active ingredients to be made into water-dispersible granules, wettable powder and the like. The bactericidal composition containing the pyraclostrobin and the dihydroxy imides is used for preventing diseases caused by germs of ascomycetes, basidiomycetes and oomycetes.
Description
The application is divisional application, original application is the patent application " bactericidal composition of a kind of pyraclostrobin-containing and dihydroxy acid imide " of Shanxi Thompson Biological Technology Co., Ltd., the application number of original application is ︰ 201110064688.6, and original application day is 2011.03.17.
Technical field
The invention belongs to technical field of pesticide, relate to the application of bactericidal composition in crop pest of a kind of pyraclostrobin-containing and dihydroxy acid imide.
Technical background
Pyraclostrobin (pyraclostrobin), molecular formula: C
20h
23n
3o
2, chemical name: methyl (N)-[[[1-(4-chlorobenzene) pyrazoles-3 base)-oxygen]-0-methoxyl group]-N-methoxymethyl carbamate.
Pyraclostrobin is the bactericide of BASF AG's latest model methoxy acrylic.The mechanism of action is mitochondrial respiratory inhibitor.Make mitochondria can not produce and provide cell eubolism institute energy requirement, finally cause cell death.It can control most of diseases such as Ascomycetes, Basidiomycetes, deuteromycetes, Oomycete.There is very strong inhibitory action to the growth of spore germination and leaf intramatrical mycelium, there is protection and therapeutic activity.Have permeability and local systemic activity, the lasting period is long, resistance of rainwater washing against.Be widely used in preventing and treating the disease on wheat, paddy rice, peanut, grape, vegetables, potato, banana, lemon, coffee, fruit tree, walnut, tea tree, tobacco and ornamental plants, lawn and other field crops.This compound not only toxicity is low, to non-target organism safety, and to user and environment all safety close friends, is classified as " Candidate Agents reducing risk " by U.S. EPA.In addition, pyraclostrobin can produce positive physiological regulatory action to crop, the generation of its energy ethene suppressing, and crop can be helped like this to have longer time deposit bio-energy to guarantee maturity; The activity of the restore nitrification enzyme of crop can be significantly improved, mean the use that can reduce Nitrogen In Soils fertilizer, thus reduce underground water mitigation further; When crop is subject to viral attack, it can accelerate the formation of resisting albumen--and identical with the synthesis of crop self salicylic acid synthetic to degeneration-resistant albumen.Pyraclostrobin is the efficient mitochondrial respiratory inhibitor after improving on kresoxim-methyl basis, is the o-methyl-phenyl-that substituted for N-rubigan pyrazolyl in kresoxim-methyl molecular structure, and the another methoxy acrylic wide-spectrum bactericide of exploitation.Its activity is higher, is at present with 3 times of series bactericidal agent.And kresoxim-methyl just has the report occurred about wheat powdery mildew resistance for 1 year afterwards in practical application, to 2000 resistant spores (2%-99%) in the north of Germany, the existing a large amount of report in the north and Britain of France.The current preventive effect to powdery mildew is existing at home declined.
Iprodione (iprodione), molecular formula is C
13h
13cl
2n
3o
3, chemical name: 3-(3,5-dichlorophenyl)-N-isopropyl-2,4-dioxoimidazolidin-1-carboxylic acid amides.
Iprodione belongs to the agent of broad spectrum activity contact sterilization, and Profilin kinases controls the Intracellular signals of many cell functions, comprises carbohydrate and combines the interference effect entering fungal cell constituents.Therefore, it both can Antifungi spore germination and generation, also can suppress mycelial growth.Therapeutic action is played by root absorption.To bacterium such as Botrytis, neurospora, Sclerotinia, bulbil genus, there is good bactericidal effect.Also effective to bacterium such as Alternaria, the mould genus of compacted spore, silk core genus, Fusarium, volt leather genus.
Procymidone (procymidone), molecular formula is C
13h
11cl
2nO
2, chemical name: N-(3,5-dichlorophenyl)-1,3-dimethylcyclopropane-1,2-di carbonyl imide.
Procymidone is interior absorption fungicide, has special efficacy to Botrytis and Sclerotinia fungi, can prevent and treat fruit tree, the gray mold of vegetable crop, stalk break, and fungi benzimidazole being produced to resistance is also effective.Use that rear protected effect is good, the lasting period is long, scab developmenting spread can be stoped.Use at crop premorbid or their early stage, can promising result be obtained.
No matter be pyraclostrobin, iprodione, procymidone or other efficient germicides, be used alone for a long time, easily make disease develop immunity to drugs, cause the problem that dosage strengthens, preventive effect reduces, the lasting period shortens, be unfavorable for environment sustainable development.The active ingredient of the different mechanism of action is carried out composite, is to delay disease to develop immunity to drugs conventional method, and according to the effect in production application, judge this composite be synergistic effect or antagonism.Complex role is significantly filled a prescription, and can significantly improve preventive effect, greatly reduces the dosage of agricultural chemicals, also can expand fungicidal spectrum, improves germicidal efficiency.In the present composition, two kinds of active component mechanism of action points are different, and mutually composite have good synergistic effect within the specific limits.And composite about pyraclostrobin and iprodione or procymidone, there is not yet relevant report at home and abroad at present.
Summary of the invention
The object of the invention is to propose a kind of to there is the bactericidal composition containing pyraclostrobin that synergistic function, use cost are low, preventive effect is good.
The present invention is achieved through the following technical solutions:
A bactericidal composition for pyraclostrobin-containing and dihydroxy acid imide, it is characterized in that the weight ratio of bactericidal composition effective active composition pyraclostrobin and iprodione or procymidone is 8 ︰ 1 to 1 ︰ 64, preferred weight ratio is 2 ︰ 1 to 1 ︰ 32.
Described bactericidal composition, is characterized in that: wherein the weight ratio of pyraclostrobin and iprodione is 2 ︰ 1 to 1 ︰ 32, is preferably 1 ︰ 2 to 1 ︰ 16.
Described bactericidal composition, is characterized in that: wherein the weight ratio of pyraclostrobin and procymidone is 2 ︰ 1 to 1 ︰ 32, is preferably 1 ︰ 2 to 1 ︰ 16.
In the present composition, the content of active component depends on amount of application when being used alone, and also depends on mixed ratio and the synergistic effect degree of a kind of compound and another kind of compound, simultaneously also relevant with targeted fungal.Weight percentage active in usual composition is 1 ~ 90% of gross weight, is preferably 10% ~ 80%.
Bactericidal composition of the present invention, can add corresponding additive and excipient on demand, is processed into acceptable formulation on any agricultural chemicals, and wherein excellent formulation of comparatively selecting is wetting powder, water dispersible granules.
Described auxiliary agent and excipient are selected from: one or more of dispersant, wetting agent, disintegrant, binding agent, filler.
Described dispersant be selected from polycarboxylate, lignosulfonates, alkylphenol-polyethenoxy phonetic formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, ester polyoxyethylene phonetic in one or more.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, soapberry powder.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, glucose, aluminium chloride.
Described binding agent is selected from: one or more in diatomite, starch, PVA, carboxymethyl (ethyl) cellulose.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
The bactericidal composition of described pyraclostrobin-containing and iprodione or procymidone for prevent and treat Ascomycetes, Basidiomycetes and Oomycete germ caused by disease, especially all have good preventive effect to downy mildew, gray mold, epidemic disease, powdery mildew, anthracnose, scab, spot defoliation, brown spot, spike rot etc.
Beneficial effect of the present invention: (1) present composition effective active composition pyraclostrobin and iprodione or procymidone belong to the bactericide of two kinds of different mechanisms of action, and both can not produce conflict at mutual mixture; (2) present composition has good synergistic effect within the specific limits, and preventive effect is higher than single dose, and dosage is little; (3) with an organic solvent dosage is few in the present invention, not easily produces poisoning, is convenient to transport and storage; (4) present composition has special efficacy to downy mildew, gray mold, epidemic disease, powdery mildew, anthracnose, scab, spot defoliation, brown spot, spike rot.
Embodiment
Below in conjunction with embodiment to further instruction of the present invention, the percentage in embodiment is all weight percentage, but the present invention is not limited thereto.
The embodiment of the present invention is the method adopting Toxicity Determination and field trial to combine.
Implementation of an application example one the implementation of Formulation Example
Embodiment 1 80% pyraclostrobin iprodione wettable powder
Pyraclostrobin 10%, iprodione 70%, lignosulfonates 5%, spaonin powder 3%, white carbon 7%, kaolin add to 100%, and mixture carries out air-flow crushing, obtained 80% pyraclostrobin iprodione wettable powder.
Embodiment 2 60% pyraclostrobin iprodione wettable powder
Pyraclostrobin 10%, iprodione 50%, alkylphenol-polyethenoxy are phonetic 5%, neopelex 3%, attapulgite add to 100%, and mixture carries out air-flow crushing, obtained 60% pyraclostrobin iprodione wettable powder.
Embodiment 3 55% pyraclostrobin iprodione wettable powder
Pyraclostrobin 5%, iprodione 50%, lignosulfonates 5%, wetting and penetrating agent F3%, kaolin add to 100%, and mixture carries out air-flow crushing, obtained 55% pyraclostrobin iprodione wettable powder.
Embodiment 4 80% pyraclostrobin iprodione water dispersible granules
Pyraclostrobin 10%, iprodione 70%, alkylphenol-polyethenoxy are phonetic 3%, lignosulfonates 3%, lauryl sodium sulfate 4%, bentonite add to 100%, the obtained 80% pyraclostrobin iprodione water dispersible granules of mixing.
Embodiment 5 60% pyraclostrobin iprodione water dispersible granules
Pyraclostrobin 20%, iprodione 40%, polycarboxylate 3%, polyoxyethylene carboxylate 3%, lauryl sodium sulfate 4%, sodium bicarbonate 3%, sodium chloride 5%, diatomite add to 100%, the obtained 60% pyraclostrobin iprodione water dispersible granules of mixing.
Embodiment 6 45% pyraclostrobin iprodione water dispersible granules
Pyraclostrobin 5%, iprodione 40%, alkylphenol-polyethenoxy are phonetic 5%, dodecyl benzene sulfonate 3%, starch 10%, bentonite add to 100%, the obtained 45% pyraclostrobin iprodione water dispersible granules of mixing.
Embodiment 7 80% pyraclostrobin procymidone wetting powder
Pyraclostrobin 10%, procymidone 70%, polycarboxylate 5%, neopelex 3%, soapberry powder 2%, starch add to 100%, and mixture carries out air-flow crushing, obtained 80% pyraclostrobin procymidone wetting powder.
Embodiment 8 65% pyraclostrobin procymidone wetting powder
Pyraclostrobin 5%, procymidone 60%, lignosulfonates 5%, spaonin powder 3%, white carbon 7%, diatomite add to 100%, and mixture carries out air-flow crushing, obtained 65% pyraclostrobin procymidone wetting powder.
Embodiment 9 55% pyraclostrobin procymidone wetting powder
Pyraclostrobin 5%, procymidone 50%, alkylphenol-polyethenoxy are phonetic 5%, neopelex 3%, white carbon 8%, precipitated calcium carbonate add to 100%, and mixture carries out air-flow crushing, obtained 55% pyraclostrobin procymidone wetting powder.
Embodiment 10 80% pyraclostrobin procymidone water dispersible granules
Pyraclostrobin 15%, procymidone 65%, alkylphenol-polyethenoxy are phonetic 3%, polyoxyethylene carboxylate 3%, lauryl sodium sulfate 4%, ammonium sulfate 2%, bentonite add to 100%, the obtained 80% pyraclostrobin procymidone water dispersible granules of mixing.
Embodiment 11 50% pyraclostrobin procymidone water dispersible granules
Pyraclostrobin 40%, procymidone 10%, polycarboxylate 3%, lignosulfonates 3%, lauryl sodium sulfate 4%, sodium bicarbonate 3%, bentonite 8%, kaolin add to 100%, the obtained 50% pyraclostrobin procymidone water dispersible granules of mixing.
Embodiment 12 15% pyraclostrobin procymidone water dispersible granules
Pyraclostrobin 10%, procymidone 5%, alkylphenol-polyethenoxy are phonetic 4%, DBSA 4%, urea 10%, diatomite add to 100%, the obtained 10% pyraclostrobin procymidone water dispersible granules of mixing.
Implementation of an application example two: pyraclostrobin and iprodione (or procymidone) composite to botrytis cinerea pers Toxicity Determination
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Determine that after the effective inhibition concentration scope of each medicament, each medicament establishes 5 dosage process respectively by active constituent content through prerun, if clear water contrast.Carry out with reference to " farm-chemical indoor determination test rule bactericide ", adopt mycelial growth rate method to measure medicament to the virulence of botrytis cinerea pers.Measure colony diameter by right-angled intersection method after 72h, calculate each process net growth, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), liquor strength (μ g/mL) converts logarithm value (x) to, try to achieve virulence regression equation (y=a+bx) with method of least squares, and calculate the EC of often kind of medicament thus
50value.Calculate two medicament different ratio synergies ratio (SR) according to Wadley method, SR < 0.5 is antagonism, and 0.5≤SR≤1.5 are summation action simultaneously, and SR > 1.5 is synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively pyraclostrobin and the ratio of iprodione (or procymidone) shared by combination.
A is pyraclostrobin
B is iprodione or procymidone
Result of the test is as shown in table 1, table 2:
Toxicity test result one:
Table 1 pyraclostrobin, iprodione and the composite toxicity test analysis of results table to bacterium of downy mildew of cucumber thereof
As shown in Table 1, pyraclostrobin, iprodione are to the EC of bacterium of downy mildew of cucumber
50be respectively 0.93mg/L and 10.54mg/L.Pyraclostrobin and iprodione mixture in 8 ︰ 1 to 1 ︰ 64 scopes all shows obvious synergistic effect, and wherein when pyraclostrobin and iprodione weight ratio are in 2 ︰ 1 to 1 ︰ 16 scopes, synergistic effect is the most obvious.
Toxicity test result two:
Table 2 pyraclostrobin, procymidone and the composite toxicity test analysis of results table to bacterium of downy mildew of cucumber thereof
As shown in Table 2, pyraclostrobin, procymidone are to the EC of bacterium of downy mildew of cucumber
50be respectively 0.94mg/L and 9.38mg/L.Pyraclostrobin and procymidone mixture in 8 ︰ 1 to 1 ︰ 64 scopes all shows obvious synergistic effect, and wherein when pyraclostrobin and procymidone weight ratio are in 2 ︰ 1 to 1 ︰ 16 scopes, synergistic effect is the most obvious.
Implementation of an application example three pyraclostrobin and iprodione (or procymidone) and the composite control graw mold of tomato test of pesticide effectiveness thereof
This experimental establishment is in Jingyuan County, Baiyin City, gansu Province, test medicine is researched and developed by Shanxi Thompson Biological Technology Co., Ltd., is provided, contrast medicament 10% pyraclostrobin wetting powder (commercial), 50% iprodione water dispersible granules (commercial), 50% procymidone wetting powder (commercial).
In the dispenser of cucumber downy mildew their early stage, dispenser in every 7 days once, is total to dispenser 2 times, investigation disease index before dispenser, and within after the 2nd dispenser 10 days, 20 days, investigate disease index respectively, and calculate Rectifying efficacies, result of the test is as follows:
Table 3 pyraclostrobin and iprodione (or procymidone) and the composite control cucumber downy mildew test of pesticide effectiveness thereof
As can be seen from Table 3, pyraclostrobin, iprodione (or procymidone) can effectively preventing cucumber downy mildews, and control efficiency is all better than contrasting medicament, and dosage is little, in test scope of medication to target crop without harm.
Embodiment applies four pyraclostrobins and iprodione (or procymidone) and the composite control alternaria leaf spot of apple test of pesticide effectiveness thereof
This experimental establishment is in Liquan County, Shaanxi Province, test medicine is researched and developed by Shanxi Thompson Biological Technology Co., Ltd., is provided, contrast medicament 10% pyraclostrobin wetting powder (commercial), 50% iprodione water dispersible granules (commercial), 50% procymidone wetting powder (commercial).
Investigation alternaria leaf spot of apple disease index before medicine, in their early stage dispenser, once, dispenser 3 times altogether, 7 days, 15 days, 30 days investigation disease indexs after third time dispenser also calculate preventive effect in dispenser in every 7 days.Experimental result is as follows:
Table 4 pyraclostrobin, iprodione (or procymidone) and the composite control alternaria leaf spot of apple test of pesticide effectiveness thereof
As can be seen from Table 4, pyraclostrobin and iprodione (or procymidone) composite after effectively can prevent and treat alternaria leaf spot of apple, control efficiency be all better than contrast medicament, the lasting period is long.In test scope of medication, target crop is had no adverse effects.
Implementation of an application example five pyraclostrobin, iprodione (or procymidone) and the composite control cucumber downy mildew test of pesticide effectiveness thereof
This experimental establishment is in Lantian County, Shaanxi Province, test medicine is researched and developed by Shanxi Thompson Biological Technology Co., Ltd., is provided, contrast medicament 10% pyraclostrobin wetting powder (commercial), 50% iprodione water dispersible granules (commercial), 50% procymidone wetting powder (commercial).
Investigation graw mold of tomato state of an illness radix, the total number of sheets, the sick number of sheets and sick leaf-size class number before medicine, in their early stage dispenser, once, dispenser 2 times altogether, investigates disease index and calculates preventive effect for after second time dispenser 10 days, 20 days respectively in dispenser in every 7 days.Experimental result is as follows:
Table 5 pyraclostrobin, iprodione (or procymidone) and the composite control graw mold of tomato test of pesticide effectiveness thereof
As can be seen from Table 5, pyraclostrobin and iprodione (or procymidone) composite after effectively can prevent and treat graw mold of tomato and occur, control efficiency is all better than contrasting medicament, has no adverse effects in this test scope of medication to target crop.
Claims (7)
1. a bactericidal composition for pyraclostrobin-containing and dihydroxy acid imide, is characterized in that the weight ratio of bactericidal composition effective active composition pyraclostrobin and procymidone is 8 ︰ 1 to 1 ︰ 64.
2. the bactericidal composition of pyraclostrobin-containing according to claim 1 and dihydroxy acid imide, is characterized in that: wherein the weight ratio of pyraclostrobin and procymidone is 2 ︰ 1 to 1 ︰ 32.
3. the bactericidal composition of pyraclostrobin-containing according to claim 2 and dihydroxy acid imide, is characterized in that: wherein the weight ratio of pyraclostrobin and procymidone is 1 ︰ 2 to 1 ︰ 16.
4. the bactericidal composition of pyraclostrobin-containing according to claim 1 and dihydroxy acid imide, is characterized in that: wherein effective active component content accounts for 1 ~ 90% of gross weight.
5. the bactericidal composition of pyraclostrobin-containing according to claim 4 and dihydroxy acid imide, is characterized in that: wherein effective active component content accounts for 10 ~ 80% of gross weight.
6. the bactericidal composition of pyraclostrobin-containing according to claim 1 and dihydroxy acid imide, is characterized in that: bactericidal composition is for preventing and treating the disease on fruit tree, vegetables and cereal crop.
7. the bactericidal composition of pyraclostrobin-containing according to claim 6 and dihydroxy acid imide, is characterized in that: bactericidal composition is used for preventing and treating downy mildew, gray mold, epidemic disease, powdery mildew, anthracnose, scab, spot defoliation, brown spot, spike rot.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110064688.6A CN102308831B (en) | 2011-03-17 | 2011-03-17 | The bactericidal composition of a kind of pyraclostrobin-containing and dicarboxyl carboximide class |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110064688.6A Division CN102308831B (en) | 2011-03-17 | 2011-03-17 | The bactericidal composition of a kind of pyraclostrobin-containing and dicarboxyl carboximide class |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104982447A true CN104982447A (en) | 2015-10-21 |
Family
ID=45422700
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510317675.3A Pending CN104982447A (en) | 2011-03-17 | 2011-03-17 | Bactericidal composition containing pyraclostrobin and dihydroxy imides |
| CN201110064688.6A Active CN102308831B (en) | 2011-03-17 | 2011-03-17 | The bactericidal composition of a kind of pyraclostrobin-containing and dicarboxyl carboximide class |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110064688.6A Active CN102308831B (en) | 2011-03-17 | 2011-03-17 | The bactericidal composition of a kind of pyraclostrobin-containing and dicarboxyl carboximide class |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN104982447A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106922729A (en) * | 2017-04-26 | 2017-07-07 | 深圳诺普信农化股份有限公司 | Bactericidal composition and its application |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102396484A (en) * | 2011-12-03 | 2012-04-04 | 陕西美邦农药有限公司 | Bactericidal combination containing iprodione and methoxyacrylic acid ester |
| CN103250717A (en) * | 2012-02-17 | 2013-08-21 | 陕西美邦农药有限公司 | Bactericidal composition containing procymidone |
| CN105360146A (en) * | 2015-12-02 | 2016-03-02 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Bactericidal composition containing pyraclostrobin and procymidone |
| CN105360152A (en) * | 2015-12-02 | 2016-03-02 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Bactericidal composition containing pyraclostrobin and hydantoin |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000076317A1 (en) * | 1999-06-14 | 2000-12-21 | Syngenta Participations Ag | Fungicidal combinations |
| CN101039578A (en) * | 2004-10-12 | 2007-09-19 | 拜尔农作物科学股份公司 | Fungicidal active ingredient combinations containing fluoxastrobin |
| CN101647456A (en) * | 2009-06-22 | 2010-02-17 | 陕西标正作物科学有限公司 | Antifungal composite with pyraclostrobin and cymoxanil |
| CN101836634A (en) * | 2010-06-02 | 2010-09-22 | 利尔化学股份有限公司 | Sterilizing pesticide composition containing azoxystrobin as well as application thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19739982A1 (en) * | 1996-12-10 | 1998-06-18 | Bayer Ag | Fungicidal active ingredient combinations |
| ATE388635T1 (en) * | 2004-11-26 | 2008-03-15 | Basf Se | USE OF MENADIONE TO ENHANCE THE EFFECTIVENESS OF AGROCHEMICALS |
-
2011
- 2011-03-17 CN CN201510317675.3A patent/CN104982447A/en active Pending
- 2011-03-17 CN CN201110064688.6A patent/CN102308831B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000076317A1 (en) * | 1999-06-14 | 2000-12-21 | Syngenta Participations Ag | Fungicidal combinations |
| CN101039578A (en) * | 2004-10-12 | 2007-09-19 | 拜尔农作物科学股份公司 | Fungicidal active ingredient combinations containing fluoxastrobin |
| CN101647456A (en) * | 2009-06-22 | 2010-02-17 | 陕西标正作物科学有限公司 | Antifungal composite with pyraclostrobin and cymoxanil |
| CN101836634A (en) * | 2010-06-02 | 2010-09-22 | 利尔化学股份有限公司 | Sterilizing pesticide composition containing azoxystrobin as well as application thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106922729A (en) * | 2017-04-26 | 2017-07-07 | 深圳诺普信农化股份有限公司 | Bactericidal composition and its application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102308831A (en) | 2012-01-11 |
| CN102308831B (en) | 2015-09-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102172241B (en) | Pesticide composition containing pyraclostrobin and triazoles | |
| CN102302025A (en) | Bactericidal composition containing pyraclostrobin and thiocarbamate | |
| CN102308831B (en) | The bactericidal composition of a kind of pyraclostrobin-containing and dicarboxyl carboximide class | |
| WO2014180020A1 (en) | Sterilization composition with synergism | |
| CN102100234B (en) | Sterilization composition containing pyraclostrobin and carbamates | |
| CN102308823B (en) | Bactericide composition containing pyraclostrobin | |
| CN104509539A (en) | Compounded bactericide containing metalaxyl and carbendazim and used for controlling main diseases of vegetables and grape | |
| CN102138563A (en) | Antibacterial composition containing polyoxin | |
| CN103828825B (en) | Pesticide composition containing pyraclostrobin and triazoles | |
| CN101755837B (en) | Fungicidal composition containing bromothalonil and prochloraz manganese | |
| CN102067852A (en) | Fungicide combination containing polyoxin and pyrimidine compound | |
| CN102007929B (en) | Thifluzamide-containing bactericidal composition | |
| CN102550600B (en) | Sterilization composition containing fluazinam and sulphur | |
| CN101999380B (en) | Difenoconazole- and propineb-containing pesticidal composition | |
| CN103385244A (en) | Bactericidal composition comprising fluxapyroxad and thiocarbamate | |
| CN102067856B (en) | Bactericidal composition containing polyoxin and oxazole compounds | |
| CN102138564A (en) | Antibacterial composition containing polyoxin | |
| CN102283225B (en) | Germicide composition containing coumoxystrobin and protective fungicide | |
| CN101999390B (en) | Antibacterial composition containing prochloraz and thiocatbamate compounds | |
| CN102742584A (en) | Bactericidal composition containing propiconazol and mancozeb | |
| CN101720767B (en) | Bactericidal composition containing dithianone and prochloraz manganese | |
| CN101946793A (en) | Bactericidal composition containing fluopyram and iprodione | |
| CN103314967B (en) | A kind of bactericidal composition containing fenhexamid | |
| CN101971839A (en) | Bactericidal composition containing cyproconazole | |
| CN104705327A (en) | Pyrazole fungicide composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20151021 |
|
| WD01 | Invention patent application deemed withdrawn after publication |