CN102742584A - Bactericidal composition containing propiconazol and mancozeb - Google Patents
Bactericidal composition containing propiconazol and mancozeb Download PDFInfo
- Publication number
- CN102742584A CN102742584A CN2010101159267A CN201010115926A CN102742584A CN 102742584 A CN102742584 A CN 102742584A CN 2010101159267 A CN2010101159267 A CN 2010101159267A CN 201010115926 A CN201010115926 A CN 201010115926A CN 102742584 A CN102742584 A CN 102742584A
- Authority
- CN
- China
- Prior art keywords
- mancozeb
- propiconazole
- bactericidal composition
- days
- weight ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a bactericidal composition with synergistic interaction. The bactericidal composition contains active ingredients of propiconazol and mancozeb in a weight ratio of 1-60:1-80. The active ingredients can be added with additive and excipient to prepare into a wettable powder and water dispersible granule. The bactericidal composition is mainly for prevention and control of powdery mildew, rust disease, banded sclerotial blight and alternaria mali roberts.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of bactericidal composition that contains propiconazole and mancozeb.
Background technology
Propiconazole (propiconazol) is an azoles fungicide.Molecular formula is C
15H
17O
2N
3Cl
2, chemical name: 1-[2-(2,4 dichloro benzene base)-4-propyl group-1,3-dioxolanes-Alpha-Methyl]-1-hydrogen-1,2,4-triazole.
Propiconazole is a kind of the have protection and interior absorption triazole bactericidal agent of therapeutic action, can be absorbed by root, stem, leaf portion, and can be very fast in the plant body on conduct.It is sterol deoxidation methylation inhibitor.In the antithetical phrase due to the germ of Gammaproteobacteria, Basidiomycetes and Fungi Imperfecti disease effective, invalid to oomycetes.
Mancozeb (mancozeb) molecular formula: C
4H
6N
2S
4MnZn chemical name: the complex salt of two two thiocarbamoyl manganese of ethylene and zinc.
Mancozeb is the complex that maneb and zinc are formed, and belongs to the wider protective fungicide of fungicidal spectrum.It mainly is the oxidation that suppresses pyruvic acid in the thalline.Effective to multiple diseases such as the anthracnose on fruit tree, the vegetables, early blight, simultaneously its normal and systemic fungicide is mixed, and is used for the generation of delaying drug resistance.
No matter be propiconazole, mancozeb or other efficient germicides, long-term use separately makes disease develop immunity to drugs easily, causes the problem that dosage strengthens, preventive effect reduces, the lasting period shortens, and is unfavorable for environment sustainable development.The active ingredient of different effects mechanism is carried out composite, is to delay the disease method commonly used that develops immunity to drugs, and according to the effect in the production application, judge this composite be synergistic effect or antagonism.Complex role is more significantly filled a prescription, and can obviously improve preventive effect, reduces the dosage of agricultural chemicals greatly, also can enlarge fungicidal spectrum, improves germicidal efficiency.Propiconazole is different with the mancozeb mechanism of action, and each other composite have good synergistic effect within the specific limits.And composite about propiconazole and mancozeb do not see relevant report at present at home and abroad as yet.
Summary of the invention
The objective of the invention is to propose a kind of have synergistic function, use cost is low, preventive effect the is good bactericidal composition that contains propiconazole and mancozeb.
The present invention realizes through following technical scheme:
A kind of bactericidal composition that contains propiconazole and mancozeb, wherein propiconazole and mancozeb weight ratio are 1～40: 1～80.
The described bactericidal composition that contains propiconazole and mancozeb, wherein the weight ratio of propiconazole and mancozeb is 1～30: 5～70.
The described bactericidal composition that contains propiconazole and mancozeb, wherein the weight ratio of propiconazole and mancozeb is 1～20: 10～60.
The described bactericidal composition that contains propiconazole and mancozeb, wherein the weight ratio of propiconazole and mancozeb is 1～15: 10～60.
The described bactericidal composition effective active composition propiconazole that contains propiconazole and mancozeb, mancozeb adds conventional auxiliary agent and excipient is processed wetting powder, water dispersible granules.
Described auxiliary agent and excipient are selected from: one or more of dispersant, wetting agent, disintegrant, filler.
Described dispersant is selected from polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, in phonetic one or more of polyoxyethylene carboxylate, ester polyoxyethylene.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, the soapberry powder.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, the aluminium chloride.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Composition of the present invention is mainly used in powdery mildew, rust, banded sclerotial blight, ring spot, the spot defoliation of control vegetables and fruit tree.
Beneficial effect of the present invention: (1) present composition effective active composition propiconazole and mancozeb belong to the bactericide of two kinds of different effects mechanism, and both are mixed each other and can produce conflict; (2) present composition has good synergistic effect within the specific limits, and preventive effect is higher than single agent, and dosage is little; (3) the present invention not with an organic solvent is not difficult for producing poisoning, is convenient to transportation and storage; (4) present composition has special efficacy to powdery mildew, rust, banded sclerotial blight, ring spot.
Embodiment
The present invention is explained further that the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.
Practice example one and implement the prescription example
Embodiment 1 80% propiconazole mancozeb wettable powder
Propiconazole 40%, mancozeb 40%, lignosulfonates 5%, lauryl sodium sulfate 2%, spaonin powder 3%, bentonite 10%, mixture carries out comminution by gas stream, makes 80% propiconazole mancozeb wettable powder.
Embodiment 2 70% propiconazole mancozeb wettable powders
Propiconazole 10%, mancozeb 60%, alkylaryl APEO 4%, soapberry powder 4%, white carbon 12%, bentonite 10%, mixture carries out comminution by gas stream, makes 70% propiconazole mancozeb wettable powder.
Embodiment 3 55% propiconazole mancozeb wettable powders
Propiconazole 5%, mancozeb 50%, alkyl benzene sulfonate calcium salt 4%, sldium lauryl sulfate 4%, white carbon 17%, bentonite 20%, mixture carries out comminution by gas stream, makes 55% propiconazole mancozeb wettable powder.
Embodiment 4 42% propiconazole mancozeb wettable powders
Propiconazole 2%, mancozeb 40%, lignosulfonates 3%, wetting and penetrating agent F2%, white carbon 20%, bentonite 23%, mixture carries out comminution by gas stream, makes 42% propiconazole mancozeb wettable powder.
Embodiment 5 70% propiconazole mancozeb water dispersible granules
Propiconazole 30%, mancozeb 40%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 3%, lignosulfonates 3 %, lauryl sodium sulfate 4%, ammonium sulfate 2%, bentonite 18%,, mixed 70% propiconazole mancozeb water dispersible granule.
Embodiment 6 50% propiconazole mancozeb water dispersible granules
Propiconazole 20%, mancozeb 30%, tea are withered 3%, polyoxyethylene carboxylate 3%, soapberry powder 4%, sodium bicarbonate 4%, white carbon 20%, starch 16%, mixed 50% propiconazole mancozeb water dispersible granule.
Embodiment 7 30% propiconazole mancozeb water dispersible granules
Propiconazole 6%, mancozeb 24%, alkylphenol-polyethenoxy are phonetic 5%, Nekal BX 4%, citric acid 1%, starch 10%, white carbon 20%, bentonite 30%, mixed 30% propiconazole mancozeb water dispersible granule.
Embodiment 8 20% propiconazole mancozeb water dispersible granules
Propiconazole 10%, mancozeb 10%, alkyl benzene sulfonate calcium salt 5%, DBSA 2%, calcium chloride 1%, starch 20%, diatomite 52%, the mixed 20% propiconazole mancozeb water dispersible granule that gets.
Practice example two: propiconazole and mancozeb are composite to the apple mildew Toxicity Determination
Test medicine provides by Shaanxi means of agricultural production trade Co., Ltd of U.S. nation.
After the effective inhibition concentration scope of each medicament was confirmed in prerun, each medicament was established 5 dosage respectively by active constituent content and is handled, and established the clear water contrast.Carry out with reference to " agricultural chemicals indoor bioassay test rule bactericide ", adopt the mycelial growth rate method to measure the virulence of medicament apple mildew.Measure colony diameter with the right-angled intersection method behind the 72h, calculate and respectively handle clean amount of growth, mycelial growth inhibition rate.
Clean amount of growth (mm)=measurement colony diameter-5
The clean amount of growth of the clean amount of growth-processed group of control group
Mycelial growth inhibition rate (%)=----------------* 100
The clean amount of growth of control group
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (mg/L) converts logarithm value (x) to, tries to achieve virulence regression equation (y=a+bx) with method of least squares, and calculates the EC of every kind of medicament thus
50Value.Calculate the different proportioning synergy ratios (SR) of two medicaments according to the Wadley method simultaneously, SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect.Computing formula is following:
EC
50(theoretical value)
SR=?─────────────
EC
50(observed value)
a?+?b
EC
50(theoretical value)=-----------
a b
────?+?────
The EC of A
50The EC of B
50
Wherein: a, b are respectively propiconazole and mancozeb shared ratio in combination
A is a propiconazole
B is a mancozeb
Result of the test is as shown in table 1:
Table 1 propiconazole, mancozeb and composite toxicity test analysis of results table thereof to apple mildew
Can know that by table 1 propiconazole, mancozeb are to the EC of apple mildew
50Be respectively 1.66mg/L and 50.38mg/L.The virulence of propiconazole is higher than the virulence of mancozeb.The synergy ratio of propiconazole and mancozeb proportioning 1:1,1:5,1:10,1:15,1:20 is respectively 1.64,1.98,2.45,2.07,1.67; Explaining that propiconazole and mancozeb are mixed in 1:1～1:20 scope all shows obvious synergistic effect; Wherein synergy ratio SR is maximum when propiconazole and mancozeb weight ratio are 1:10, and synergistic effect is the most obvious.
Embodiment uses three propiconazoles and the mancozeb and the composite control alternaria leaf spot of apple test of pesticide effectiveness thereof
This EE is the Luochuan County suburb in Shaanxi Province, and test medicine is researched and developed, provided by Shaanxi means of agricultural production trade Co., Ltd of U.S. nation, contrast medicament 80% mancozeb wettable powder (commercial), 25% propiconazole emulsifiable concentrate (commercial).
The investigation alternaria leaf spot of apple state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 3 times.Investigated the apple mildew disease index respectively and calculated preventive effect in 7 days, 14 days, 30 days after the dispenser for the third time.Experimental result is as follows:
Table 2 propiconazole, mancozeb and the composite control alternaria leaf spot of apple test of pesticide effectiveness thereof
| Handle medicament | Extension rate | 7 days preventive effects (%) behind the last medicine | 14 days preventive effects (%) behind the last medicine | 30 days preventive effects (%) behind the last medicine |
| 80% propiconazole mancozeb wettable powder | 1200 times | 89.68 | 94.34 | 93.93 |
| 50% propiconazole mancozeb water dispersible granule | 700 times | 89.34 | 94.14 | 94.56 |
| 80% mancozeb wettable powder | 400 times | 58.82 | 65.27 | 65.45 |
| 25% propiconazole emulsifiable concentrate | 500 times | 65.53 | 73.46 | 73.49 |
Can be found out that by table 2 can effectively prevent and treat alternaria leaf spot of apple after propiconazole and mancozeb are composite, control efficiency all is superior to contrasting medicament, the lasting period is long.In the test scope of medication, the target crop is had no adverse effects, and apple mildew, ring spot are had preventive effect preferably.
Practice example four: propiconazole and mancozeb and the composite wheat rust test of pesticide effectiveness of preventing and treating thereof
This EE is in the Lantian County, Xian City, Shanxi Province, and test medicine is researched and developed, provided by Shaanxi means of agricultural production trade Co., Ltd of U.S. nation, contrast medicament 80% mancozeb wettable powder (commercial), 25% propiconazole emulsifiable concentrate (commercial).
The investigation wheat rust state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigated the wheat rust disease index respectively and calculated preventive effect in 7 days, 14 days, 30 days after the dispenser for the second time.Experimental result is as follows:
Table 3 propiconazole, mancozeb and the composite wheat rust test of pesticide effectiveness of preventing and treating thereof
| Handle medicament | The preparation dosage | 7 days preventive effects (%) behind the medicine for the second time | 14 days preventive effects (%) behind the medicine for the second time |
| 70% propiconazole mancozeb wettable powder | 35 gram/mus | 90.26 | 95.42 |
| 30% propiconazole mancozeb water dispersible granule | 60 gram/mus | 89.85 | 94.75 |
| 80% mancozeb wettable powder | 95 gram/mus | 62.85 | 70.55 |
| 25% propiconazole emulsifiable concentrate | 40 gram/mus | 71.37 | 78.58 |
Can find out by table 3, ability effectively preventing wheat rust after propiconazole and mancozeb are composite, control efficiency all is superior to contrasting medicament, and dosage is little, and the lasting period is long.In the test scope of medication, the target crop there is not harm.
Practice example five: propiconazole, mancozeb and the composite control wheat powdery mildew test of pesticide effectiveness thereof
This EE is the Bozhou City Lixin County in Anhui Province, and test medicine is researched and developed, provided by Shaanxi means of agricultural production trade Co., Ltd of U.S. nation, contrast medicament 80% mancozeb wettable powder (commercial), 25% propiconazole emulsifiable concentrate (commercial).
Investigation wheat powdery mildew state of an illness radix, total number of sheets, the sick number of sheets and sick leaf-size class number before the medicine, in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 2 times, investigates disease index respectively and calculates preventive effect in 7 days, 14 days after the dispenser for the second time.Experimental result is as follows:
Table 4 propiconazole, mancozeb and the composite control wheat powdery mildew test of pesticide effectiveness thereof
| Handle medicament | The preparation dosage | 7 days preventive effects (%) behind the medicine for the second time | 14 days preventive effects (%) behind the medicine for the second time |
| 55% propiconazole mancozeb wettable powder | 45 gram/mus | 91.83 | 95.26 |
| 70% propiconazole mancozeb water dispersible granule | 35 gram/mus | 90.57 | 94.85 |
| 80% mancozeb wettable powder | 95 gram/mus | 63.43 | 71.46 |
| 25% propiconazole emulsifiable concentrate | 40 gram/mus | 68.53 | 76.44 |
Can find out that by table 4 can effectively prevent and treat wheat powdery mildew after propiconazole and mancozeb are composite and take place, control efficiency all is superior to contrasting medicament, in this test scope of medication, the target crop is had no adverse effects.
Practice example six: propiconazole and mancozeb and the composite rice sheath blight disease test of pesticide effectiveness of preventing and treating thereof
This EE is in Si Xi town, Shanggao County, Jiangxi Province, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 80% mancozeb wettable powder (commercial), 25% propiconazole emulsifiable concentrate (commercial).
In the dispenser of paddy rice tree their early stage, dispenser in per 7 days once, dispenser is 3 times altogether, investigation disease index before the dispenser was investigated disease index respectively in 7 days, 15 days, 30 days after the dispenser for the third time, and the calculation correction preventive effect, result of the test is following:
Table 5 propiconazole and mancozeb and the composite rice sheath blight disease test of pesticide effectiveness of preventing and treating thereof
| Handle medicament | The preparation dosage | 7 days preventive effects (%) behind the last medicine | 15 days preventive effects (%) behind the last medicine | 30 days preventive effects (%) behind the last medicine |
| 42% propiconazole mancozeb wettable powder | 60 gram/mus | 89.25 | 94.25 | 93.43 |
| 20% propiconazole mancozeb water dispersible granule | 80 gram/mus | 88.56 | 93.77 | 92.97 |
| 80% mancozeb wettable powder | 95 gram/mus | 62.57 | 69.15 | 69.64 |
| 25% propiconazole emulsifiable concentrate | 50 gram/mus | 70.63 | 78.63 | 77.58 |
Can find out by table 5, propiconazole, mancozeb ability effectively preventing rice sheath blight disease, control efficiency all is superior to contrasting medicament, in the test scope of medication, the target crop is not had harm.
Claims (7)
1. bactericidal composition that contains propiconazole and mancozeb, the weight ratio that it is characterized in that microbicide compositions effective active composition propiconazole and mancozeb is 1～40 ︰ 1～80.
2. the bactericidal composition that contains propiconazole and mancozeb according to claim 1 is characterized in that: wherein the weight ratio of propiconazole and mancozeb is 1～30 ︰ 5～70.
3. the bactericidal composition that contains propiconazole and mancozeb according to claim 2 is characterized in that: wherein the weight ratio of propiconazole and mancozeb is 1～20 ︰ 10～60.
4. the bactericidal composition that contains propiconazole and mancozeb according to claim 1 is characterized in that: microbicide compositions is processed wetting powder, water dispersible granules.
5. the bactericidal composition that contains propiconazole and mancozeb according to claim 1 is characterized in that: wherein the effective active component content accounts for 1～80% of gross weight.
6. the bactericidal composition that contains propiconazole and mancozeb according to claim 5 is characterized in that: wherein the effective active component content accounts for 10～70% of gross weight.
7. the bactericidal composition that contains propiconazole and mancozeb according to claim 1 is used to prevent and treat powdery mildew, rust, banded sclerotial blight, ring spot, spot defoliation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101159267A CN102742584A (en) | 2010-03-02 | 2010-03-02 | Bactericidal composition containing propiconazol and mancozeb |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101159267A CN102742584A (en) | 2010-03-02 | 2010-03-02 | Bactericidal composition containing propiconazol and mancozeb |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102742584A true CN102742584A (en) | 2012-10-24 |
Family
ID=47023360
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010101159267A Pending CN102742584A (en) | 2010-03-02 | 2010-03-02 | Bactericidal composition containing propiconazol and mancozeb |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102742584A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2532700A (en) * | 2013-11-26 | 2016-05-25 | Upl Ltd | A method for controlling rust |
| CN106508935A (en) * | 2016-08-31 | 2017-03-22 | 柳州市惠农化工有限公司 | Pesticide composition containing 2-methylsulfonyl-5-(2,4-dichlorophenyl)-1,3,4-oxadiazole and mancozeb |
| EP3986133A4 (en) * | 2019-06-24 | 2023-06-28 | UPL Limited | Synergistic fungicide composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080085935A1 (en) * | 2006-10-04 | 2008-04-10 | Dow Agrosciences Llc | Bisdithiocarbamate fungicide stabilizers |
| FR2917947A1 (en) * | 2007-06-29 | 2009-01-02 | Action Pin Sa | Phytosanitary composition, useful for preventive medication and curative of the mildew in e.g. vine, beet, and sunflower, comprises mancozeb, at least terpene derivative and at least one copper compound |
-
2010
- 2010-03-02 CN CN2010101159267A patent/CN102742584A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080085935A1 (en) * | 2006-10-04 | 2008-04-10 | Dow Agrosciences Llc | Bisdithiocarbamate fungicide stabilizers |
| FR2917947A1 (en) * | 2007-06-29 | 2009-01-02 | Action Pin Sa | Phytosanitary composition, useful for preventive medication and curative of the mildew in e.g. vine, beet, and sunflower, comprises mancozeb, at least terpene derivative and at least one copper compound |
Non-Patent Citations (3)
| Title |
|---|
| 劳恒 等: "几种药剂防治香蕉叶斑病药效试验报告", 《广西植保》, vol. 18, no. 4, 30 December 2005 (2005-12-30), pages 1 - 2 * |
| 杜云安 等: "几种药剂防治香蕉叶斑病效果比较", 《安徽农业科学》, vol. 37, no. 27, 20 September 2009 (2009-09-20) * |
| 檀根甲 等: "化学药剂对水稻纹枯病菌的影响", 《安徽农业科学》, vol. 28, no. 02, 25 April 2000 (2000-04-25) * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2532700A (en) * | 2013-11-26 | 2016-05-25 | Upl Ltd | A method for controlling rust |
| CN105744834A (en) * | 2013-11-26 | 2016-07-06 | Upl 有限公司 | A method for controlling rust |
| GB2532700B (en) * | 2013-11-26 | 2016-08-31 | Upl Ltd | A method for controlling rust |
| CN106508935A (en) * | 2016-08-31 | 2017-03-22 | 柳州市惠农化工有限公司 | Pesticide composition containing 2-methylsulfonyl-5-(2,4-dichlorophenyl)-1,3,4-oxadiazole and mancozeb |
| EP3986133A4 (en) * | 2019-06-24 | 2023-06-28 | UPL Limited | Synergistic fungicide composition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101755808B (en) | Fungicidal composition containing hexaconazole and prochloraz manganese | |
| CN102138563A (en) | Antibacterial composition containing polyoxin | |
| CN102742584A (en) | Bactericidal composition containing propiconazol and mancozeb | |
| CN102047890B (en) | Sterilization composition containing Azoxystrobin and Epoxiconazole | |
| CN101828567A (en) | Bactericidal composition containing propiconazole and propineb | |
| CN102067856B (en) | Bactericidal composition containing polyoxin and oxazole compounds | |
| CN101999380B (en) | Difenoconazole- and propineb-containing pesticidal composition | |
| CN101999364A (en) | Hexaconazole-containing germicide composition | |
| CN101999362B (en) | Fenoxanil and epoxiconazole-containing bactericidal composition | |
| CN102232382A (en) | Bactericidal composition containing trifloxystrobin and thiocarbamates | |
| CN101779649B (en) | Bactericidal composition containing phenol cycloheximide and thiophanate-methyl | |
| CN101731226A (en) | Bactericidal composition containing ethirimol and penconazole | |
| CN101755792B (en) | Fungicidal composition containing kresoxim methyl and thiophanate methyl | |
| CN101971839A (en) | Bactericidal composition containing cyproconazole | |
| CN102057932B (en) | Bactericidal composite containing thiophanate-methyl | |
| CN101836639A (en) | Sterilization composition containing kresoxim and thiabendazole | |
| CN101720767A (en) | Bactericidal composition containing dithianone and prochloraz manganese | |
| CN101715772B (en) | Bactericidal composition containing carbendazim and ethirimol | |
| CN101843249A (en) | Sterilizing compound containing propiconazole and thiabendazole | |
| CN101926342A (en) | Sterilization compound containing propiconazol and zineb | |
| CN101822257A (en) | Bactericidal composition with pyriproxyfen and epoxiconazole | |
| CN101779657B (en) | Bactericidal composite containing flusilazole and ethirimol | |
| CN101779658A (en) | Bactericidal composite containing flusilazole and propineb | |
| CN101720780B (en) | Bactericidal composition containing flusilazole and probenazole | |
| CN101971840A (en) | Bactericidal composition containing cyproconazole and metiram |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20121024 |