CN104830141B - Microemulsion printing ink cleaner and preparation method thereof - Google Patents
Microemulsion printing ink cleaner and preparation method thereof Download PDFInfo
- Publication number
- CN104830141B CN104830141B CN201510217989.6A CN201510217989A CN104830141B CN 104830141 B CN104830141 B CN 104830141B CN 201510217989 A CN201510217989 A CN 201510217989A CN 104830141 B CN104830141 B CN 104830141B
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- Prior art keywords
- car wash
- wash water
- microemulsion
- printing
- preparation
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004530 micro-emulsion Substances 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000002904 solvent Substances 0.000 claims abstract description 15
- 239000004094 surface-active agent Substances 0.000 claims abstract description 9
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 5
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 5
- 239000002798 polar solvent Substances 0.000 claims abstract description 5
- 239000007788 liquid Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 abstract description 17
- 229920000136 polysorbate Polymers 0.000 abstract description 7
- 239000002736 nonionic surfactant Substances 0.000 abstract description 6
- 238000013329 compounding Methods 0.000 abstract description 4
- 239000003945 anionic surfactant Substances 0.000 abstract description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 8
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- RGHNJXZEOKUKBD-SQOUGZDYSA-N Gluconic acid Natural products OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- 239000004202 carbamide Substances 0.000 description 4
- 235000013877 carbamide Nutrition 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920002120 photoresistant polymer Polymers 0.000 description 4
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000174 gluconic acid Substances 0.000 description 3
- 235000012208 gluconic acid Nutrition 0.000 description 3
- 239000003350 kerosene Substances 0.000 description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 3
- 229920000053 polysorbate 80 Polymers 0.000 description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 239000004064 cosurfactant Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 125000000468 ketone group Chemical group 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/04—Chemical paint or ink removers with surface-active agents
Abstract
The invention discloses a microemulsion printing ink cleaner and a preparation method thereof. The microemulsion printing ink cleaner comprises the following components by mass: 50 to 60% of a main solvent, 5 to 10% of an auxiliary solvent, 10 to 15% of an emulsifier, 5 to 10% of a surfactant, 5 to 10% of a polar solvent and 5 to 10% of other auxiliary agents. The innovative points of the invention are as follows: compounding of homologues of a Tween series of nonionic surfactant is carried out, so cleaning efficiency of printing ink scales is improved; a great amount of the nonionic surfactant and a small amount of anionic surfactant are compounded to further reduce surface tension of a solution and improve cleaning efficiency; and water is added in the preparation of the cleaner, so cost can be reduced.
Description
Technical field
The present invention relates to a kind of ink for printing-ink on cleaning printing press tool, galley, ink roller and blanket is clear
A kind of lotion, and in particular to microemulsion printing car wash water and preparation method thereof.
Background technology
In recent years, China's printing industry is developed rapidly, meanwhile, car wash water is printed as a kind of auxiliary the most frequently used in printing
Material, its demand is also increasing.The printing car wash water of high-quality is most important for print production.
It is big to petroleum resource consumption using organic solvents such as gasoline, kerosene as traditional printing car wash water of host, exist
The potential safety hazard such as inflammable and explosive, high volatility when using, harm workman is healthy, pollutes printing environment.Aqua type printing is washed
Car is alkaline relatively strong, severe corrosion equipment.And, using in a large number for water also brings transport and packing cost height, equipment drying property
Can the undesirable shortcoming of poor and cleaning performance.
Micro-emulsion type printing car wash water be one kind by surfactant, cosurfactant, oil and water under suitable ratio
Dispersion of Thermodynamically stable, isotropism, low-viscosity, appearance transparent or the translucent, particle diameter for spontaneously forming in 10～100nm
System, its stability is more preferable than emulsion.Compared with traditional printing car wash water, micro-emulsion type printing car wash water in organic solvent content compared with
Low, cleaning performance is good, drying is very fast.From the point of view of market situation, micro-emulsion type printing car wash water has become domestic and international printing-ink
One of main wash agent, correlation technique also comparative maturity, this class abluent can play when manual printing equipment is cleaned
Effect well.For automatic printing equipment, also there is technical deficiency in existing micro-emulsion type printing car wash water.Such as
CN02102265.8 patent applications provide a kind of printing car wash water with ester and organic acid as main component, in the abluent
The common presence of esters and acids makes its unstable properties, and can corrode carbon steel, aluminium alloy printing equipment.
CN200710177421.1 and CN200810122550.5 patent applications provide a kind of printing car wash water, and its effective ingredient is all
It is surfactant, it is low to the rate of corrosion of equipment, but washing power only has 86.2%, and cleaning performance is undesirable.
CN201010100923.6 patent applications provide a kind of printing car wash water, by the cruel salt of the phosphoric acid for compounding, various cosolvents, ooze
Thoroughly agent, metal coating agent and water are constituted, and its cleaning performance is excellent, but stronger swelling action is furnished with to rubber.
CN201310502068.5 patent applications provide a kind of printing car wash water, and ethylene glycol therein and sodium hydroxide can etched plates
Material surface resin class photoresists.In terms of comprehensive, it is existing printing car wash water in use, except cleaning performance it is not ideal enough
Outward, also there is more or less impact to equipment, plate and blanket.And on market in most of micro-emulsion type printing car wash water
Contain a large amount of water, this causes the packaging and cost of transportation of printing car wash water to increase considerably.With full-automatic printer progressively
Promote, printing car wash water will not only ensure that equipment, sheet material and blanket are immune, and should be able to also simultaneously meet printing and set
The requirement of standby, printing board material and blanket to cleaning performance.
The content of the invention
Present invention aims to the disadvantages mentioned above of the existing printing car wash water in market, proposes that one kind can simultaneously clean print
Brush equipment, printing plate and blanket, low water content, the microemulsion printing car wash water of property and excellent effect.
Realization the technical scheme is that：
A kind of microemulsion prints car wash water, and its component and its mass percent are：
Wherein, the main solvent in component is from 200# solvent naphthas or/and aerial kerosene.
Secondary solvent is from isopropanol or/and dibutyl phthalate.
Emulsifying agent selects AEO-9 or/and OP-10.
Surfactant selects LAS, tween 80, the mixture of one or more in tween 85.
Polar solvent is from n-butyl alcohol or/and ethylene glycol monobutyl ether.
Other selection of auxiliary triethanolamine, BTA, carbamide, the mixture of one or more in gluconic acid.
Preferred version one, its component and its mass percent are：
Preferred version two, its component and its mass percent are：
Present invention also offers described microemulsion prints the preparation method of car wash water, each component is weighed according to the above ratio,
Under room temperature, first main solvent, secondary solvent and polar solvent are stirred, obtain double solventss, by emulsifying agent, surfactant
Add and be sufficiently stirred in double solventss, after each component is completely dissolved, add other auxiliary agents, the uniform clear liquid for obtaining
Body or light yellow clear liquid are microemulsion printing car wash water, by it by volume 1 with water when using:8～10 ratio stirring
It is uniform.
Compared with prior art, its remarkable advantage is the present invention：
(1) novelty of the invention is to carry out answering between homologue using non-ionic surfactant Tween series
Match somebody with somebody, improve the cleaning efficiency to ink dirt.
(2) with the compounding between a large amount of nonionic surfactants and a small amount of anion surfactant in the present invention,
The surface tension of solution is further reduced, cleaning efficiency is improved.
(3) secondary solvent for being soluble in solvent naphtha with gluconic acid, carbamide and triethanolamine etc. substitutes sodium hydroxide, silicon
The alkali inorganic substance insoluble in solvent naphtha such as sour sodium, sodium carbonate, the step that makes to add water is deferred to by process for preparation and uses link, both
Cleaning performance is ensure that, the packing cost and cost of transportation of printing car wash water are greatly reduced again.
Specific embodiment
Raw material used in the present invention and equipment, are commercial goods, for a better understanding of the present invention, below by tool
The embodiment of body is illustrating technical scheme.
Embodiment 1-5
Microemulsion of the present invention prints car wash water, and its component and its mass percent are as shown in table 1：
Table 1
Each component is weighed in above ratio, it is at normal temperatures, first that main solvent (200# solvent naphthas, aerial kerosene), auxiliary is molten
Agent (isopropanol) and polar solvent (n-butyl alcohol, ethylene glycol monobutyl ether) are sufficiently stirred for, and double solventss are obtained, by emulsifying agent (AEO-
9, OP-10), surfactant (LAS, tween 80, tween 85) is stirring evenly and then adding into double solventss, is sufficiently stirred for, and treats each
After component is completely dissolved, other auxiliary agents (triethanolamine, BTA, carbamide, gluconic acid) are added, what is obtained is uniform
Clear liquid or light yellow clear liquid are microemulsion printing car wash water.
With reference to the method for QB/T2117-95, the detection of washing power, Jing analyses, gained are carried out to the car wash water in the application
The washing power of car wash water reaches 100%.In the case where surface active agent tween -80, tween 85 is added without, car wash water cannot
The solution of stable and uniform is formed, washing power is 95%～96%.
QB/T2117-95 is as follows to the detection method of washing power：In certain mass M0Rustless steel test piece with 40 ± 2 DEG C do
It is dried in dry case after 30min, is cooled to room temperature, weigh accurate extremely ± 0.2mg, the ink scraped with pocket knife between 0.08-0.19g is applied
The predetermined portion in strip is smeared, with filter paper the unnecessary greasy dirt in both sides and base is wiped, be dried in 40 ± 2 DEG C of drying baker
After 30min, it is placed in exsiccator and is cooled to room temperature, claims its quality to be designated as M1, Jing pendulum wash process drying after quality be designated as M2.Go
Dirty efficiency X is calculated as follows：
In formula：X--- washing power, %；
M0- test piece quality, g；
M1- smear the quality before greasy dirt test piece cleaning, g；
M2- smear the quality after greasy dirt test piece cleaning, g.
The microemulsion that the application is prepared prints car wash water pH value 7～8 or so, and partial neutral is corrosion-free to equipment.With
200# solvent naphthas can to the full extent protect blanket as host.Additionally, TWEEN Series surfactant is gentleer,
To blanket non-corrosiveness.For the photoresists of plate, generally, hydroxyl, aldehyde radical, ketone group and the organic acid pair contained in car wash water
Photoresists have a corrosion, however the car wash water in the application add water use when above-mentioned group content drop to less than 1%, to sense
The impact of optical cement is very little.And, the auxiliary agent such as triethanolamine, carbamide, BTA has protective effect to photoresists.The application
In carry out the compounding between homologue using non-ionic surfactant Tween series first, improve ink dirt cleaning effect
Rate；With the preparation method between a large amount of nonionic surfactants and a small amount of anion surfactant, further reduce molten
The surface tension of liquid, improves cleaning efficiency.In terms of comprehensive, it is respectively provided with terms of ink cleaning efficiency, the infection to equipment
Clear superiority.
Claims (3)
1. a kind of microemulsion prints car wash water, it is characterised in that：Its component and its mass percent are：
2. a kind of microemulsion prints car wash water, it is characterised in that its component and its mass percent are：
3. the preparation method of car wash water is printed according to the arbitrary described microemulsion of claim 1～2, it is characterised in that：Claim in proportion
Each component is taken, at normal temperatures, is first sufficiently stirred for main solvent, secondary solvent and polar solvent, double solventss are obtained, by emulsifying
Agent, surfactant are added and are sufficiently stirred in double solventss, after being completely dissolved each component, add other auxiliary agents, to be dissolved
After completely, the uniform clear liquid for obtaining or light yellow clear liquid are microemulsion printing car wash water, when using by its with
Water by volume 1:8～10 ratio stirs.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510217989.6A CN104830141B (en) | 2015-04-30 | 2015-04-30 | Microemulsion printing ink cleaner and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510217989.6A CN104830141B (en) | 2015-04-30 | 2015-04-30 | Microemulsion printing ink cleaner and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104830141A CN104830141A (en) | 2015-08-12 |
| CN104830141B true CN104830141B (en) | 2017-04-12 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510217989.6A Expired - Fee Related CN104830141B (en) | 2015-04-30 | 2015-04-30 | Microemulsion printing ink cleaner and preparation method thereof |
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| Country | Link |
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| CN (1) | CN104830141B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105838133B (en) * | 2016-06-14 | 2019-03-19 | 苏州科利尔环保科技有限公司 | Emulsion detergent for ink and preparation method thereof |
| CN106221954B (en) * | 2016-07-12 | 2019-05-28 | 北京石油化工学院 | A kind of cleaning agent and its application method for chemical industry cracker heat exchanger |
| CN106085628B (en) * | 2016-07-12 | 2019-05-28 | 北京石油化工学院 | A kind of cleaning agent and its application method for crude oil stabilizer heat exchanger |
| CN106190673B (en) * | 2016-07-12 | 2019-05-28 | 北京石油化工学院 | A kind of cleaning agent and its application method for atmospheric and vacuum distillation unit heat exchanger |
| CN106752292A (en) * | 2016-12-15 | 2017-05-31 | 温州乐发教育科技有限公司 | A kind of water-in-oil type detergent for ink and preparation method thereof |
| CN107858037B (en) * | 2017-11-02 | 2021-08-20 | 中国标准化研究院 | O/W micro-emulsion type printing ink environment-friendly cleaning agent |
| CN108299939A (en) * | 2018-04-10 | 2018-07-20 | 东莞市本旺实业有限公司 | Paint stripper can be recycled in one kind |
| CN108410250B (en) * | 2018-05-04 | 2022-04-08 | 南京信息工程大学 | Environment-friendly novel micro-emulsion printing ink cleaning agent and preparation method thereof |
| CN108727895B (en) * | 2018-05-04 | 2022-04-08 | 南京信息工程大学 | Environment-friendly semi-water-based printing ink cleaning agent and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101638532B (en) * | 2009-08-29 | 2011-07-20 | 茂名学院 | Water-solubility printing ink washing agent |
| CN103694772A (en) * | 2013-12-12 | 2014-04-02 | 林晓丽 | Printing press cleaning agent |
| CN103865314B (en) * | 2014-02-27 | 2016-04-27 | 安徽颍美彩印包装有限公司 | A kind of printing ink washing agent and preparation method thereof |
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Effective date of registration: 20220530 Address after: 510000 first floor, building 7, Anheng second lane, JIEKOU Street Town, Conghua District, Guangzhou City, Guangdong Province (self compiled room A103) Patentee after: Zhongying doctor group (Guangzhou) Co.,Ltd. Address before: 210044 No. 219, Ning six road, Nanjing, Jiangsu Patentee before: Nanjing University of Information Science and Technology |
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Denomination of invention: Microemulsion printing car washing water and its preparation method Effective date of registration: 20220623 Granted publication date: 20170412 Pledgee: Bank of China Limited by Share Ltd. Guangzhou Liwan branch Pledgor: Zhongying doctor group (Guangzhou) Co.,Ltd. Registration number: Y2022440000134 |
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