CN106752292A - A kind of water-in-oil type detergent for ink and preparation method thereof - Google Patents
A kind of water-in-oil type detergent for ink and preparation method thereof Download PDFInfo
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- CN106752292A CN106752292A CN201611157512.4A CN201611157512A CN106752292A CN 106752292 A CN106752292 A CN 106752292A CN 201611157512 A CN201611157512 A CN 201611157512A CN 106752292 A CN106752292 A CN 106752292A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/04—Chemical paint or ink removers with surface-active agents
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Abstract
The invention belongs to cleaning agent technical field, a kind of water-in-oil type detergent for ink and preparation method thereof is specifically disclosed, it is characterised in that count by weight, mainly consist of the following composition：0.5~1.5 part of 15~25 parts of turpentine oil, 13~25 parts of tetrachloro-ethylene, 1~5 part of oleic acid, 5~10 parts of isopropanol, 3~7 parts of dibutyl phthalate, 5~7 parts of fatty acid methyl ester ethoxylate, 2~7 parts of apricot glue, 0.5~1.5 part of four sodium of iminodisuccinic acid, 1~3 part of neopelex, 0.3~1.3 part of sorbitan trioleate, 1~5 part of phenylpropyl alcohol triazole, 3~5 parts of NaOH, 30~70 parts of water, 7~16 parts of auxiliary agent and antioxidant, the auxiliary agent are triethanolamine and n-butanol.The water-in-oil type detergent for ink that the present invention is provided can solve inflammable, the explosive problem of solvent-based ink cleaning agent, mitigate the pollution to production environment and air, shorten scavenging period.
Description
Technical field
The invention belongs to cleaning agent technical field, a kind of water-in-oil type detergent for ink and its preparation are concretely related to
Method.
Background technology
Detergent for ink is used to clean printing plate, ink roller, the ink in metallic roll and blanket.
The cleaning agent that current press is used, some solvents are inherently poisonous, and hydrocarbon in all solvents
Discharge is polluted to air.Cleaning of China's printing industry to ink is still cleaned using gasoline, kerosene equal solvent type mostly
Agent, because these solvent volatilities are strong, there is inflammable, explosive danger during storage and use, is great machine room
Security against fire hidden danger, and production environment and air are polluted, and cleaning performance is not also very good.So needing research
New detergent for ink,
Water-in-oil type cleaning agent refers to that cleaning agent is fabricated into emulsion, and its foreign minister is oil（Oil or solvent）, interior phase is water, its boundary
Face surfactant is used as stabilizer.
The content of the invention
In order to solve the above technical problems, the present invention provides a kind of water-in-oil type detergent for ink and preparation method thereof.To solve
Certainly inflammable, the explosive problem of solvent-based ink cleaning agent, mitigates the pollution to production environment and air, shortens scavenging period.
To reach above-mentioned purpose, the technical solution used in the present invention is：
A kind of water-in-oil type detergent for ink, counts by weight, mainly consists of the following composition：15~25 parts of turpentine oil, four
13~25 parts of vinyl chloride, 1~5 part of oleic acid, 5~10 parts of isopropanol, 3~7 parts of dibutyl phthalate, fatty acid methyl ester ethoxy
5~7 parts of glycolylate, 2~7 parts of apricot glue, 0.5~1.5 part of four sodium of iminodisuccinic acid, neopelex 1~3
Part, 0.3~1.3 part of sorbitan trioleate, 1~5 part of phenylpropyl alcohol triazole, 3~5 parts of NaOH, 30~70 parts of water,
0.5~1.5 part of 7~16 parts of auxiliary agent and antioxidant.
Preferably, in the preferred embodiment, the auxiliary agent is triethanolamine and n-butanol.
Preferably, in the preferred embodiment, the triethanolamine accounts for the water-in-oil type detergent for ink
Parts by weight are 2~7 parts.Triethanolamine can reduce corrosion of the detergent for ink to printing machine, can adjust pH value, and prevent life
Rust；Triethanolamine also has certain help to emulsion intercalation method and cleansing power.
Preferably, in the preferred embodiment, the n-butanol accounts for the weight of the water-in-oil type detergent for ink
Amount number is 5~9 parts.N-butanol can strengthen the stability and penetration of cleaning agent, strengthen cleaning performance.
Preferably, in the preferred embodiment, the antioxidant is BHT.The uncles of 2,6- bis-
Butyl paracresol is used as antioxidant, and oxidation resistance is stronger, heat-resisting and good stability, and has certain antibacterial action, can
Detergent for ink is prevented in prolonged storage process mesometamorphism.
In addition, the invention provides a kind of preparation method of water-in-oil type detergent for ink, comprising the following steps：
（1）The NaOH and the water are first added in reaction vessel, with 30~40r/min, stirring is completely dissolved it,
Obtain sodium hydrate aqueous solution；
（2）15~25 parts of turpentine oil, 13~25 parts of tetrachloro-ethylenes, 1~5 part of oleic acid, 5~10 parts of isopropanols, 3 are weighed by weight
~7 parts of dibutyl phthalates are added in the sodium hydrate aqueous solution, at 20~30 DEG C, with the speed of 160~190r/min
Degree 10~20min of stirring, obtains double solvents；
（3）Weigh 2~7 parts of apricot glue, 0.5~1.5 part of sodium of iminodisuccinic acid four, 5~7 parts of fatty acid methyl ester ethoxylations
Thing, 1~3 part of neopelex, 0.3~1.3 part of sorbitan trioleate and 1~5 part of phenylpropyl alcohol triazole, fully
It is dissolved in the double solvents, at 20~30 DEG C, mixing speed is 200~230r/min, stirs 15~25min, must be mixed
Reagent；
（4）Add the triethanolamine in the mix reagent, adjust its pH value 7.5~8.5；
（5）Plus the n-butanol and the antioxidant are to stirring 20min, 5~15min of ultrasonic disperse in the mix reagent,
Mixing stands 1.5~2h, obtains water-in-oil type detergent for ink.
Beneficial effects of the present invention：The water-in-oil type detergent for ink that the present invention is provided can solve solvent-based ink cleaning
Inflammable, the explosive problem of agent, mitigates the pollution to production environment and air, shortens scavenging period.
Water-in-oil type cleaning agent leaning solvent can be not only completely eliminated in some harmful substances to printing worker's
Alarming talk, prevents pollution of the organic solvent to air, and can greatly improve the flash-point of cleaning agent, improves the fire-fighting of machine room
Safety, improves the quality of total environment.So-called water-in-oil type cleaning agent refers to that cleaning agent is made into emulsion, its foreign minister for oil then
（Oil or solvent）, interior phase is water, and its interface surfactant is used as stabilizer.Due to the presence for having water, the oil of foreign minister or
The developability of solvent weakens significantly, and the content of organic volatile greatly reduces in air.And the presence of water makes the sudden strain of a muscle of solution
Point is carried significantly；Increased the security against fire of machine room.
The biological degradabilities such as apricot glue, the sodium of iminodisuccinic acid four, fatty acid methyl ester ethoxylate are good, belong to nontoxic
Material, strong detergency can not only effectively remove metal weight dirt grease, also easily with various additive compounds, be conducive to increasing emulsion
Stability, improves the using effect of cleaning agent.
The detergent for ink cleaning that the present invention is provided, than very fast, does not influence with rate of drying on blanket and rubber roll,
Solvent used by it meets the requirement of environmental protection.
Specific embodiment
Technical scheme of the present invention is further described with reference to specific embodiment.
Embodiment 1：
Embodiments of the invention 1 provide a kind of water-in-oil type detergent for ink, count by weight, mainly by following component group
Into：15 parts of turpentine oil, 13 parts of tetrachloro-ethylene, 1 part of oleic acid, 5 parts of isopropanol, 3 parts of dibutyl phthalate, fatty acid methyl ester
5 parts of ethoxylate, 2 parts of apricot glue, 0.5 part of four sodium of iminodisuccinic acid, 1 part of neopelex, Sorbitan
0.3 part of alcohol trioleate, 1 part of phenylpropyl alcohol triazole, 3 parts of NaOH, 30 parts of water, 2 parts of triethanolamine, 5 parts and 2,6- of n-butanol
0.5 part of BHT.
In addition, present embodiments providing a kind of preparation method of water-in-oil type detergent for ink, comprise the following steps：
（1）3 parts of NaOH and 30 parts of water are first added in reaction vessel, with 30r/min, stirring is completely dissolved it, obtains hydrogen
Aqueous solution of sodium oxide；
（2）15 parts of turpentine oil, 13 parts of tetrachloro-ethylenes, 1 part of oleic acid, 5 parts of isopropanols, 3 parts of phthalic acids two are weighed by weight
Butyl ester is added in sodium hydrate aqueous solution, at 20 DEG C, 10min is stirred with the speed of 160r/min, obtains double solvents；
（3）Weigh 2 parts of apricot glue, 0.5 part of sodium of iminodisuccinic acid four, 5 parts of fatty acid methyl ester ethoxylates, 1 part 12
Sodium alkyl benzene sulfonate, 0.3 part of sorbitan trioleate and 1~5 part of phenylpropyl alcohol triazole, are completely dissolved in double solvents,
At 20 DEG C, mixing speed is 200r/min, stirs 15min, obtains mix reagent；
（4）Add 2 parts of triethanolamines in mix reagent, adjust its pH value 7.5；
（5）5 parts of n-butanols and 0.5 part of BHT are added to stirring 20min, ultrasonic disperse in mix reagent
5min, mixing stands 1.5h, obtains water-in-oil type detergent for ink.
Embodiment 2：
Embodiments of the invention 2 provide a kind of water-in-oil type detergent for ink, count by weight, mainly by following component group
Into：25 parts of turpentine oil, 25 parts of tetrachloro-ethylene, 5 parts of oleic acid, 10 parts of isopropanol, 7 parts of dibutyl phthalate, fatty acid methyl ester
7 parts of ethoxylate, 7 parts of apricot glue, 1.5 parts of four sodium of iminodisuccinic acid, 3 parts of neopelex, Sorbitan
1.3 parts of alcohol trioleate, 5 parts of phenylpropyl alcohol triazole, 5 parts of NaOH, 70 parts of water, 7 parts of triethanolamine, 9 parts and 2,6- of n-butanol
1.5 parts of BHT.
In addition, present embodiments providing a kind of preparation method of water-in-oil type detergent for ink, comprise the following steps：
（1）5 parts of NaOH and 70 parts of water are first added in reaction vessel, with 40r/min, stirring is completely dissolved it, obtains hydrogen
Aqueous solution of sodium oxide；
（2）25 parts of turpentine oil, 25 parts of tetrachloro-ethylenes, 5 parts of oleic acid, 10 parts of isopropanols, 7 parts of phthalic acids two are weighed by weight
Butyl ester is added in sodium hydrate aqueous solution, at 30 DEG C, 20min is stirred with the speed of 190r/min, obtains double solvents；
（3）Weigh 7 parts of apricot glue, 1.5 parts of sodium of iminodisuccinic acid four, 7 parts of fatty acid methyl ester ethoxylates, 3 part 12
Sodium alkyl benzene sulfonate, 1.3 parts of sorbitan trioleates and 5 parts of phenylpropyl alcohol triazoles, are completely dissolved in double solvents, 30
DEG C, mixing speed is 230r/min, stirs 25min, obtains mix reagent；
（4）Add 7 parts of triethanolamines in mix reagent, adjust its pH value 8.5；
（5）9 parts of n-butanols and 1.5 parts of BHTs are added to stirring 20min, ultrasonic disperse in mix reagent
15min, mixing stands 2h, obtains water-in-oil type detergent for ink.
Embodiment 3：
Embodiments of the invention 3 provide a kind of water-in-oil type detergent for ink, count by weight, mainly by following component group
Into：20 parts of turpentine oil, 19 parts of tetrachloro-ethylene, 3 parts of oleic acid, 7.5 parts of isopropanol, 5 parts of dibutyl phthalate, fatty acid methyl
6 parts of ester ethoxylate, 4.5 parts of apricot glue, 1 part of four sodium of iminodisuccinic acid, 2 parts of neopelex, dehydration mountain
0.8 part of pears alcohol trioleate, 3 parts of phenylpropyl alcohol triazole, 4 parts of NaOH, 50 parts of water, 4.5 parts of triethanolamine, 7 parts of n-butanol and
1 part of DBPC 2,6 ditertiary butyl p cresol.
In addition, present embodiments providing a kind of preparation method of water-in-oil type detergent for ink, comprise the following steps：
（1）4 parts of NaOH and 50 parts of water are first added in reaction vessel, with 35r/min, stirring is completely dissolved it, obtains hydrogen
Aqueous solution of sodium oxide；
（2）20 parts of turpentine oil, 19 parts of tetrachloro-ethylenes, 3 parts of oleic acid, 7.5 parts of isopropanols, 5 parts of phthalic acids are weighed by weight
Dibutyl ester is added in sodium hydrate aqueous solution, at 25 DEG C, 15min is stirred with the speed of 175r/min, obtains double solvents；
（3）Weigh 4.5 parts of apricot glue, 1 part of sodium of iminodisuccinic acid four, 6 parts of fatty acid methyl ester ethoxylates, 2 part 12
Sodium alkyl benzene sulfonate, 0.8 part of sorbitan trioleate and 3 parts of phenylpropyl alcohol triazoles, are completely dissolved in double solvents, 25
DEG C, mixing speed is 215r/min, stirs 20min, obtains mix reagent；
（4）Add 4.5 parts of triethanolamines in mix reagent, adjust its pH value 8；
（5）7 parts of n-butanols and 1 part of BHT are added to stirring 20min, ultrasonic disperse in mix reagent
10min, mixing stands 1.7h, obtains water-in-oil type detergent for ink.
The cleansing power of water-in-oil type detergent for ink prepared by embodiment 1-3 is according to ROHS Directive2011/65/
EU examination criterias are carried out, and test the content of harmful substance on once purged workpiece, and testing result is as shown in table 1.
Table 1：Testing result
Remarks：（1）MDL=method detecting limits
（2）ND=Not Detective (being not detected by) ＜ MDL
（3）mg/kg=ppm=1×10-6
The prepared water-in-oil type cleaning agent of the present invention is free of harmful substance, friendly to production and atmospheric environment, and cleansing power is strong.
Claims (6)
1. a kind of water-in-oil type detergent for ink, it is characterised in that count by weight, mainly consist of the following composition：Turpentine
Oil 15~25 parts, 13~25 parts of tetrachloro-ethylene, 1~5 part of oleic acid, 5~10 parts of isopropanol, 3~7 parts of dibutyl phthalate,
5~7 parts of fatty acid methyl ester ethoxylate, 2~7 parts of apricot glue, 0.5~1.5 part of four sodium of iminodisuccinic acid, dodecyl
1~3 part of benzene sulfonic acid sodium salt, 0.3~1.3 part of sorbitan trioleate, 1~5 part of phenylpropyl alcohol triazole, 3~5 parts of NaOH,
0.5~1.5 part of 30~70 parts of water, 7~16 parts of auxiliary agent and antioxidant.
2. water-in-oil type detergent for ink according to claim 1, it is characterised in that：The auxiliary agent is for triethanolamine and just
Butanol.
3. water-in-oil type detergent for ink according to claim 1, it is characterised in that：The triethanolamine accounts for the oil bag
The parts by weight of water type detergent for ink are 2~7 parts.
4. water-in-oil type detergent for ink according to claim 1, it is characterised in that：The n-butanol accounts for the Water-In-Oil
The parts by weight of type detergent for ink are 5~9 parts.
5. water-in-oil type detergent for ink according to claim 1, it is characterised in that：The antioxidant is the tertiary fourths of 2,6- bis-
Base paracresol.
6. a kind of water-in-oil type detergent for ink preparation method as described in claim any one of 1-4, it is characterised in that including
Following steps：
（1）The NaOH and the water are first added in reaction vessel, with 30~40r/min, stirring is completely dissolved it,
Obtain sodium hydrate aqueous solution；
（2）15~25 parts of turpentine oil, 13~25 parts of tetrachloro-ethylenes, 1~5 part of oleic acid, 5~10 parts of isopropanols, 3 are weighed by weight
~7 parts of dibutyl phthalates are added in the sodium hydrate aqueous solution, at 20~30 DEG C, with the speed of 160~190r/min
Degree 10~20min of stirring, obtains double solvents；
（3）Weigh 2~7 parts of apricot glue, 0.5~1.5 part of sodium of iminodisuccinic acid four, 5~7 parts of fatty acid methyl ester ethoxylations
Thing, 1~3 part of neopelex, 0.3~1.3 part of sorbitan trioleate and 1~5 part of phenylpropyl alcohol triazole, fully
It is dissolved in the double solvents, at 20~30 DEG C, mixing speed is 200~230r/min, stirs 15~25min, must be mixed
Reagent；
（4）Add the triethanolamine in the mix reagent, adjust its pH value 7.5~8.5；
（5）Plus the n-butanol and the antioxidant are to stirring 20min, 5~15min of ultrasonic disperse in the mix reagent,
Mixing stands 1.5~2h, obtains water-in-oil type detergent for ink.
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| CN201611157512.4A CN106752292A (en) | 2016-12-15 | 2016-12-15 | A kind of water-in-oil type detergent for ink and preparation method thereof |
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| CN201611157512.4A CN106752292A (en) | 2016-12-15 | 2016-12-15 | A kind of water-in-oil type detergent for ink and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019011263A (en) * | 2017-06-29 | 2019-01-24 | 小林製薬株式会社 | Water-in-oil type emulsified composition |
| CN113293065A (en) * | 2021-05-15 | 2021-08-24 | 山东工业陶瓷研究设计院有限公司 | Pure organic terpineol slurry cleaning agent and preparation method thereof |
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| CN1083501A (en) * | 1993-08-24 | 1994-03-09 | 湖南省印刷科技研究所 | Printing ink washing agent |
| CN104449026A (en) * | 2014-12-26 | 2015-03-25 | 青岛海芬海洋生物科技有限公司 | Coder ink cleaning solution |
| CN104497693A (en) * | 2014-11-25 | 2015-04-08 | 苏州中亚油墨有限公司 | New printing ink cleaner and preparation method thereof |
| CN104830141A (en) * | 2015-04-30 | 2015-08-12 | 南京信息工程大学 | Microemulsion printing ink cleaner and preparation method thereof |
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2016
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1083501A (en) * | 1993-08-24 | 1994-03-09 | 湖南省印刷科技研究所 | Printing ink washing agent |
| CN104497693A (en) * | 2014-11-25 | 2015-04-08 | 苏州中亚油墨有限公司 | New printing ink cleaner and preparation method thereof |
| CN104449026A (en) * | 2014-12-26 | 2015-03-25 | 青岛海芬海洋生物科技有限公司 | Coder ink cleaning solution |
| CN104830141A (en) * | 2015-04-30 | 2015-08-12 | 南京信息工程大学 | Microemulsion printing ink cleaner and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019011263A (en) * | 2017-06-29 | 2019-01-24 | 小林製薬株式会社 | Water-in-oil type emulsified composition |
| CN113293065A (en) * | 2021-05-15 | 2021-08-24 | 山东工业陶瓷研究设计院有限公司 | Pure organic terpineol slurry cleaning agent and preparation method thereof |
| CN113293065B (en) * | 2021-05-15 | 2023-09-01 | 山东工业陶瓷研究设计院有限公司 | Pure organic terpineol slurry cleaning agent and preparation method thereof |
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