CN110157234A - A kind of environmentally-friendly water-based detergent for ink and preparation method thereof - Google Patents
A kind of environmentally-friendly water-based detergent for ink and preparation method thereof Download PDFInfo
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- CN110157234A CN110157234A CN201910510099.2A CN201910510099A CN110157234A CN 110157234 A CN110157234 A CN 110157234A CN 201910510099 A CN201910510099 A CN 201910510099A CN 110157234 A CN110157234 A CN 110157234A
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- environmentally
- based detergent
- friendly water
- ink
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/005—Chemical paint or ink removers containing organic solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/04—Chemical paint or ink removers with surface-active agents
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention is undesirable for water-base ink cleaning agent cleaning effect currently on the market, the strong basicity auxiliary agent of addition leads to the surface for corroding cleaning workpiece, and it is easy the disadvantages of polluting the environment, it is high to propose a kind of cleaning efficiency, it is not perishable, environmentally-friendly water-based detergent for ink of easily biological-degradable and preparation method thereof.The constituent and its mass percent of water-base ink cleaning agent of the invention are as follows: anionic-cationic surfactant mixed system object 5% ~ 10%, polar solvent 6% ~ 15%, solubilizer 2% ~ 5%, other 5% ~ 10% excess waters of auxiliary agent.
Description
Technical field:
The present invention relates to a kind of ink that ink is printed on cleaning printing press tool, printing mother matrix, ink roller and blanket
Cleaning agent.More specifically, being a kind of environmentally-friendly water-based detergent for ink.
Background technique:
Printing industry must consider the use of ink as component part important in production in its printing process
And cleaning process.For traditional detergent for ink mainly using organic solvents such as kerosene as main solvent, flash-point is low, inflammable and explosive equal danger
Danger, is gradually eliminated.But half novel water-base ink cleaning agent mainly by oil, water mix, although improving flash-point, than gasoline,
Kerosene safety, but demulsifying phenomenon can occur for use process, and have oil gas evolution, influence safety in production, pollution environment.Therefore raw
Gasoline can be abandoned by producing aqueous cleaning agent, and the organic solvents such as kerosene prevent from firing problem, and can be reduced the generation of VOCs.
Aqua type detergent for ink has become the main aspect of domestic and international market research at present, although technology tends into
Ripe but expensive, cleaning rate is slow, and corrosivity is high, not degradable, therefore general effect is undesirable.Water-base ink cleaning agent
Key problem in technology be that suitable surfactant and alkaline assistant is selected to reduce solution surface tension, while adding suitable alkali
Property auxiliary agent improve to the cleaning efficiency of ink dirt.
Summary of the invention:
The present invention for the existing water-base ink cleaning agent cleaning effect in market it is bad, and can not simultaneously cleaning equipment, printing
The disadvantages of plate, blanket and printing mother matrix, propose a kind of clean and the good environment protection water-based detergent for ink of anticorrosion ability.
The specific technical solution of the present invention is as follows:
A kind of environmentally-friendly water-based detergent for ink is matched by following components and is made by mass percentage:
Preferably, the surfactant select anion surface active or nonionic surfactant or they answer
Match.
Preferably, the anionic surfactant includes methyl sodiosul foaliphatate (MES) and α-sodium olefin sulfonate
(AOS)；The nonionic surfactant alkyl glycosides (APG), polysorbate 40 (Tween-40) and polyoxyethylene sorbitan monoleate
(Tween-80)。
Preferably, the surfactant selects a kind of anionic surfactant and three kinds of nonionic surfactants
Compounding.
Preferably, the polar solvent is D- limonene.
Preferably, the alkaline assistant selects laminated crystal of sodium disilicate, sodium oxalate, disodium ethylene diamine tetraacetate (EDTA-
Mixture one or more of 2Na).
Preferably, the solubilizer is urea.
Preferably, the chelating agent is sodium gluconate.
Preferably, the corrosion inhibitor is benzotriazole, toluic acid sodium, one of methenamine.
The preparation method of the environmentally-friendly water-based detergent for ink of the present invention, method includes the following steps:
1) each component is weighed in the above ratio, at normal temperature, first by surfactant, alkaline assistant, which is added to the water, sufficiently to be stirred
It mixes, after being completely dissolved each component；
2) solubilizer, chelating agent and corrosion inhibitor are added, is eventually adding after polar solvent is sufficiently stirred, what is obtained is uniform clear
Clear prescribed liquid is environmentally-friendly water-based detergent for ink.
The present invention has the following beneficial effects: compared with prior art
The environment protection water-based detergent for ink of the present invention, it is female using safe and cleaning of graphic arts equipment, printing plate, printing simultaneously
Version, ink roller and detergent for ink of blanket and preparation method thereof.
Compared with patented technology before, the present invention uses nonionic surfactant polysorbate 40, polyoxyethylene sorbitan monoleate two
Kind homologue is mixed, and adds function admirable, cost is relatively low.The physicochemical properties of surfactant homologue are between pure
In surfactant, two kinds of material molecular structures are similar, but the reduction degree meeting after homologue mixing to solution surface tension
Higher than the effect of one pack system.
Degradable anionic surfactant MES and nonionic surfactant APG is compounded, and is significantly reduced molten
The surface tension of liquid improves the dissolving power of each component and the stability of solution.A kind of anionic surfactant adds two kinds
After homologue nonionic surfactant and nonionic surfactant APG are compounded, surfactant is only relied on to ink
Removal rate is as high as 90%, and effect is substantially better than single nonionic and anionic surfactant compounding.
Polar solvent D- limonene selected by the present invention is that one kind is pollution-free, and cleaning efficiency is high, the good auxiliary agent of stability,
Good emulsifying effectiveness can be generated with added surfactant, to improve the cleaning efficiency to ink, is added to D- lemon
After lemon alkene, solution can achieve 98% to ink removal rate, and stability of solution is further enhanced, and be discharged into water also easily
In degradation.
Compared to water-base ink cleaning agent on the market, inventive formulation pH value is alkalescent, is not made to each printing equipment
At corrosion, and the surfactant and polar solvent that are added stablize cleaning agent two months or more, without any powder
It is precipitated, is used convenient for storage.
Formula is scientific and reasonable for water-base ink cleaning agent of the present invention, and preparation method is simple, and production cost is low, and cleaning efficiency
It is high.Simultaneously compared with traditional detergent for ink, selected various reagents all will not be to printing equipment, printing plate, printing
Mother matrix, ink roller and blanket cause to corrode the automatic cleaning, it can be achieved that each section.
Specific embodiment:
Raw material used in the present invention and equipment are commercial goods, in order to be easy to understand the present invention, are tied below
Specific example is closed, the present invention is further explained.
Test one:
Polar solvent Selection experiment is carried out, data are as follows:
Conclusion: by above-mentioned test as it can be seen that from the aspect of save the cost and cleaning effect, polar solvent selects D- lemon
Alkene.Test two:
Polar solvent additive amount Selection experiment is carried out, data are as follows:
Conclusion: by above-mentioned test as it can be seen that polar solvent add mass percent in 6-15% cleaning effect preferable, stability
School is good.For the mass percent of polar solvent addition at 10%, cleaning effect is best, and stability of solution is fine.
Embodiment 1
In this example, environmentally-friendly water-based detergent for ink is formulated by the ingredient in following table.
1 embodiment of table, 1 each group distribution ratio
Each component is weighed in the above ratio, at normal temperature, first Tween40, Tween80 is mixed, fatty acid is then added
Methyl ester sulfonate, alkyl glycosides 1214 add laminated crystal of sodium disilicate sodium metasilicate, and disodium ethylene diamine tetraacetate adds water to fill
Urea, sodium gluconate and benzotriazole is added after point being stirred, be eventually adding D- limonene stirring and dissolving it is complete after, obtain
To uniform clear liquid be detergent for water-based print ink.
The present invention is through testing and analyzing, and cleaning efficiency reaches 100%, and indices meet the standard of national aqueous cleaning agent,
Specific detection data see the table below 2:
2 embodiment of table, 1 products obtained therefrom performance detection
Embodiment 2
In this example, environmentally-friendly water-based detergent for ink is formulated by the ingredient in following table.
3 embodiment of table, 2 each group distribution ratio
Preparation method is identical as example 1.Cleaning effect is identical as example 1 as performance indicator, and indices meet national water
The standard of based cleaning agent, specific detection data see the table below 4
4 embodiment of table, 2 products obtained therefrom performance detection
Embodiment 3
In this example, environmentally-friendly water-based detergent for ink is formulated by the ingredient in following table.
5 embodiment of table, 3 each group distribution ratio
Preparation method is identical as example 1.Cleaning effect is substantially identical as example 1 as performance indicator, and indices meet state
The standard of family's aqueous cleaning agent.
Claims (10)
1. a kind of environmentally-friendly water-based detergent for ink, which is characterized in that matched by following components and be made by mass percentage:
Surfactant 5% ~ 10%
Polar solvent 6% ~ 15%
Alkaline assistant 1% ~ 5%
Solubilizer 2% ~ 5%
Chelating agent 1% ~ 3%
Corrosion inhibitor 0.5% ~ 3%
Water surplus.
2. environmentally-friendly water-based detergent for ink according to claim 1, it is characterised in that: the surfactant selects yin
Ion surface active, nonionic surfactant or their compounding.
3. environmentally-friendly water-based detergent for ink according to claim 2, it is characterised in that: the anionic surfactant
Including methyl sodiosul foaliphatate and α-sodium olefin sulfonate；The nonionic surfactant alkyl glycosides, polysorbate 40 and
Polyoxyethylene sorbitan monoleate.
4. environmentally-friendly water-based detergent for ink according to claim 3, it is characterised in that: the surfactant selects one
The compounding of kind anion surface active and three kinds of nonionic surfactants.
5. environmentally-friendly water-based detergent for ink according to claim 1 to 4, it is characterised in that: the polar solvent is
D- limonene.
6. environmentally-friendly water-based detergent for ink according to claim 5, it is characterised in that: the alkaline assistant selects stratiform
Crystalline sodium disilicate, sodium oxalate, the mixture of one or more of disodium ethylene diamine tetraacetate.
7. environmentally-friendly water-based detergent for ink according to claim 6, it is characterised in that: the solubilizer is urea.
8. environmentally-friendly water-based detergent for ink according to claim 7, it is characterised in that: the chelating agent is gluconic acid
Sodium.
9. environmentally-friendly water-based detergent for ink according to claim 8, it is characterised in that: the corrosion inhibitor is three nitrogen of benzo
Azoles, toluic acid sodium, one of methenamine.
10. the preparation method of any environmentally-friendly water-based detergent for ink of claim 1-9, this method includes following step
It is rapid:
1) each component is weighed in the above ratio, at normal temperature, first by surfactant, alkaline assistant, which is added to the water, to be sufficiently stirred,
After being completely dissolved each component；
2) solubilizer, chelating agent and corrosion inhibitor are added, is eventually adding after polar solvent is sufficiently stirred, obtained uniform clarification is saturating
Prescribed liquid is environmentally-friendly water-based detergent for ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201910510099.2A CN110157234A (en) | 2019-06-13 | 2019-06-13 | A kind of environmentally-friendly water-based detergent for ink and preparation method thereof |
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| CN201910510099.2A CN110157234A (en) | 2019-06-13 | 2019-06-13 | A kind of environmentally-friendly water-based detergent for ink and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111592940A (en) * | 2020-05-21 | 2020-08-28 | 上海毅诺生物科技有限公司 | Multi-surface cleaning agent containing sodium cumene sulfonate compounded hydrotrope and preparation method thereof |
| CN113105781A (en) * | 2021-04-12 | 2021-07-13 | 南京信息工程大学 | Efficient environment-friendly water-based ink cleaning agent and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101434764A (en) * | 2007-11-15 | 2009-05-20 | 中国石油化工股份有限公司 | Printing ink cleaning agent |
| CN101735684A (en) * | 2008-11-13 | 2010-06-16 | 胡秋滨 | Office waste paper deinking agent |
| CN102391713A (en) * | 2011-10-25 | 2012-03-28 | 华南理工大学 | Deinking agent containing modified product of lignin and preparation method thereof |
| CN103602138A (en) * | 2013-11-20 | 2014-02-26 | 张家港任发化工材料有限公司 | Water-based cleaning agent for printing ink |
| CN104031461A (en) * | 2014-04-28 | 2014-09-10 | 南京信息工程大学 | Water-based printing ink cleaning compound and preparation method thereof |
| US20150038597A1 (en) * | 2011-02-28 | 2015-02-05 | Richard Eric Nemeth | Wet sanding compositions |
| CN106147372A (en) * | 2016-09-27 | 2016-11-23 | 合肥天翔环境工程有限公司 | Detergent for ink containing D limonene and preparation method thereof |
| CN108546450A (en) * | 2018-07-18 | 2018-09-18 | 南京信息工程大学 | Environmentally-friendly water-based detergent for ink and preparation method thereof |
-
2019
- 2019-06-13 CN CN201910510099.2A patent/CN110157234A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101434764A (en) * | 2007-11-15 | 2009-05-20 | 中国石油化工股份有限公司 | Printing ink cleaning agent |
| CN101735684A (en) * | 2008-11-13 | 2010-06-16 | 胡秋滨 | Office waste paper deinking agent |
| US20150038597A1 (en) * | 2011-02-28 | 2015-02-05 | Richard Eric Nemeth | Wet sanding compositions |
| CN102391713A (en) * | 2011-10-25 | 2012-03-28 | 华南理工大学 | Deinking agent containing modified product of lignin and preparation method thereof |
| CN103602138A (en) * | 2013-11-20 | 2014-02-26 | 张家港任发化工材料有限公司 | Water-based cleaning agent for printing ink |
| CN104031461A (en) * | 2014-04-28 | 2014-09-10 | 南京信息工程大学 | Water-based printing ink cleaning compound and preparation method thereof |
| CN106147372A (en) * | 2016-09-27 | 2016-11-23 | 合肥天翔环境工程有限公司 | Detergent for ink containing D limonene and preparation method thereof |
| CN108546450A (en) * | 2018-07-18 | 2018-09-18 | 南京信息工程大学 | Environmentally-friendly water-based detergent for ink and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 杨淑武等: "环保型油墨清洗剂的研究进展", 《包装工程》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111592940A (en) * | 2020-05-21 | 2020-08-28 | 上海毅诺生物科技有限公司 | Multi-surface cleaning agent containing sodium cumene sulfonate compounded hydrotrope and preparation method thereof |
| CN113105781A (en) * | 2021-04-12 | 2021-07-13 | 南京信息工程大学 | Efficient environment-friendly water-based ink cleaning agent and preparation method thereof |
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Inventor after: Guo Zhaobing Inventor after: Guo Shixiang Inventor after: Zhou Yiming Inventor after: Sun Haoyuan Inventor after: Mei Fengxian Inventor before: Guo Zhaobing Inventor before: Zhou Yiming Inventor before: Mei Fengxian |