CN104800121A - Nephrite-containing daily commodity composition, as well as preparation method and application thereof - Google Patents
Nephrite-containing daily commodity composition, as well as preparation method and application thereof Download PDFInfo
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Abstract
The invention discloses a nephrite-containing daily commodity composition, as well as a preparation method and application thereof. The daily commodity composition comprises the following raw materials by weight percentage: 10 to 40 percent of nephrite, 0.005 to 0.01 percent of gold, 0.001 to 0.01 percent of silver, 0.1 to 5 percent of moringa extract, and 0.25 to 0.3 percent of natural preservatives, wherein the particle diameters of nephrite, gold and silver are 5 to 20 nm, 30 to 80 nm, and 25 to 50 nm respectively; the natural preservatives comprise 5 to 40 percent of a scutellaria extract, 5 to 40 percent of a hibiscus flower extract, and 20 to 60 percent of an olive leaf extract. The nephrite-containing daily commodity composition has the advantages that the friction coefficient is lower; the use feeling and the infrared ray reflectivity are excellent; the efficiencies of whitening, nourishing and repairing are high.
Description
Technical field
The invention belongs to skin care item and cosmetic technical field, more specifically, the present invention relates to a kind of the article of everyday use composition and method of making the same and the application that contain nephrite.
Background technology
In general, jade is roughly divided into jadeite and nephrite, and jadeite is the plumbous pyroxenite group mineral belonging to pyroxenite race, it is the monoclinic system material be made up of silicic acid, aluminium oxide, sodium carbonate, be the compact block of hardness as crystal, gloss is black, dark green, green, is transparent or translucent.Say common " jade ", that mainly refers to jadeite.
Nephrite is the monoclinic system pyribole minerals of inosilicate, tremolite jade and serpentinization hyperalkaline nephrite is divided in magnesia marble, their quality is with its fine structures shape, namely determined by bundle group and fibroplastic fineness so that the tremolite-Actinolitum is brilliant, known fiber is more superfine, and quality is more excellent.
About such jade, according to the report in German medical circle document, jadeite and nephrite are two kinds of different Ores, they are as most gem, and containing silicon and oxygen, but jadeite is crystal formation with granular pattern relatively, so the difference of nephrite is being formed by cellulosic, countless crystal as hair and particle aggregate, particularly be different from the sodium in jadeite and aluminum constituent, nephrite is that namely calcium, magnesium, ferrum are as main constituent with three kinds of mineral useful to human body.Study was recently published nephrite and great impact is brought on hypertension, diabetes, causing circulatory obstacle, heart disease and the treatment of disease that caused by nephropathy.In addition, know according to new agriculture book on Chinese herbal medicine, Tang materia medica, Compendium of Materia Medica etc., jade is ground into sesame seed to take greatly, to moisten the vital organs of the human body, not only have and make the effect that in body, the long-term refuse accumulated is discharged completely, and owing to removing heat in stomach and effective to digestive system, bronchus is panted and body heat to raise the anemia that heart feels bad effective; During the broiling summer, jade carving master worker injured by cutter at work because of carelessness, can not inflammation, and the time of healing is faster than normal, and therefore, when face or health have scar, wipe a few days with nephrite at scar position, scar can disappear.The main constituent of nephrite almost has no side effect, and plays remarkable usefulness to human body.
Although but known nephrite has medical science usefulness as above remarkable to human body, due to its rareness, only as the parts such as necklace, ring, bracelet at one's side decoration jewel ornament use.Practical situation is, particularly in the processing of nephrite, needs a lot of time and effort, and needs the attention of very thin degree, therefore if not the practician having protracted experience, just nephrite can not be carried out meticulous processing.Because be high price product, so due to the burden of economy, also almost not to utilizing nephrite to develop as general the articles for daily use.Therefore, people's an urgent demand is to the research and development of the various the articles for daily use or medical supplies and health cosmetic products etc. in order to utilize nephrite more valuably.
As the impact on skin, be not only ultraviolet, near infrared ray is also more and more considered problem.Therefore, require that one can be covered near infrared basic ingredient and is used in cosmetics or article of everyday use.In addition, cosmetics or article of everyday use also pay much attention to sense of touch.Known object of giving UV absorbing properties to cosmetics or article of everyday use cooperation zinc oxide.But Zinc oxide particles is in the ultramicronized situation of below 100nm, there is the problem producing friction sense, sense of touch variation.In existing document, also there is the zinc oxide that is combined with 0.5 μm ~ 20 μm as the cosmetics of infrared shield material.But the average friction coefficient of this Zinc oxide particles is large, thus when a large amount of cooperation, there is the problem producing friction sense, use sense difference and so on.Further, the total visible light transmittance of this Zinc oxide particles is low, there is the problem that the transparency is poor, occur whiting and so on.
How to utilize effect that nephrite is known, with the use of other additive, prepare a kind of can not make sense of touch worsen and the article of everyday use compositions of the excellent performances such as the transparency, infrared ray, ultraviolet reflection be very important.
Summary of the invention
Based on this, in order to overcome the defect of above-mentioned prior art, the invention provides a kind of article of everyday use compositions containing nephrite, this article of everyday use compositions can not make sense of touch worsen, and the excellent performances such as the transparency, infrared ray, ultraviolet reflection.
In order to realize foregoing invention object, this invention takes following technical scheme:
An article of everyday use compositions containing nephrite, described article of everyday use compositions is made up of the raw material comprising following percentage by weight:
The particle diameter of described nephrite is 5 ~ 20nm; The particle diameter of described gold is 30 ~ 80nm; The particle diameter of described silver is 25 ~ 50nm; Described natural antiseptic agent is the Chinese medicine extract containing Radix Scutellariae extract 5-40%, Flos Hibisci Mutabilis extract 5-40%, Olive leaf P.E 20-60%.
Wherein in some embodiments, the particle diameter of described nephrite is 5 ~ 10nm, and the particle diameter of described gold is 30 ~ 50nm, and the particle diameter of described silver is 25 ~ 35nm.
Wherein in some embodiments, described nephrite is one or both in serpentine, the tremolite, and the negative value of described serpentine and the tremolite is δ
18o.
Wherein in some embodiments, in semi-quantitative analysis, the percentage composition of described nephrite is: silicon 34, magnesium 10, calcium 4.9, ferrum 0.23, aluminum 0.16, copper 0.17, cobalt 0.046, manganese 0.14, stannum 0.024, beryllium 0.00072, silver 0.0013, titanium 0.0038, nickel 0.0028, chromium 0.0030, other 0.
Wherein in some embodiments, the microstructure of described nephrite is hair felty texture, micro-blade blastic texture, micro-nematoblastic texture, micro-fiber-cryptocrystalline blastic texture, micro-blade-cryptocrystalline blastic texture, radial structure or broom shape structure.
Wherein in some embodiments, the microstructure of described nephrite is radial structure.
Wherein in some embodiments, described Moringa extract by by by drying and the tree root of Moringa of grinding, seed or blade are added in the solvent of ethanol/water=9/1, countercurrent extraction at 80 DEG C and obtaining.
Wherein in some embodiments, described natural antiseptic agent is prepared by following methods: after being pulverized by Chinese medicine, sieve, soak 1-2h together with Extraction solvent after, extract with high pressure homogenization method machine at normal temperatures, extracting solution is after centrifugalize, by macroporous resin adsorption, with the ethanol repeatedly eluting of 10-95%, collect eluent, be evaporated to extractum shape, obtain final product; Described Extraction solvent is water, ethanol or ethanol water.
Wherein in some embodiments, described article of everyday use compositions also comprises component conventional in article of everyday use or cosmetic field.
Present invention also offers the preparation method of the above-mentioned article of everyday use compositions containing nephrite, comprise the following steps:
By nephrite, gold and silver mixing, grind together; Component conventional in Moringa extract and article of everyday use or cosmetic field is added again after grinding, 60 ~ 70 DEG C are uniformly mixed, and then utilize mixer for well-distribution to make to reach even, after de-bubbled, filtration, add natural antiseptic agent again, utilize heat exchanger etc. to carry out cooling and reaching goods.
Present invention also offers the application of the above-mentioned article of everyday use compositions containing nephrite, described application comprises cosmetic field, as nourished late frost, the face frost that compacts, visage block cream, ultra light sun block lotion, conditioning powder cream base, repair eye cream, facial film, face mask cream, hands film, foot film, hand cream, spats frost, moisturizing liquid, lipstick, described application also comprises daily necessities field, as fancy soap, toothpaste, collutory, shampoo, bath gel etc.
Article of everyday use compositions containing nephrite of the present invention can not make sense of touch worsen, and the excellent performances such as the transparency, infrared ray, ultraviolet reflection, and this article of everyday use compound has the effects such as whitening, nourishing, reparation, antiinflammatory.
Be easier to understand the above-mentioned of the application and other features, aspect and advantage with reference to following detailed description.
Detailed description of the invention
The detailed description of the following preferred implementation method of the present invention of participation in the election and the embodiment comprised more easily can understand present disclosure.Can mention a large amount of term in following description and claims, these terms are defined as following implication.
Singulative comprises plural number and object is discussed, unless clearly indicated in addition in context.
" optional " or " optionally " refers to that the item that describes thereafter or event can occur or not occur, and this description comprises situation that event occurs and the situation that event does not occur.
Approximate term in description and claims is used for modifying quantity, represents that the present invention is not limited to this concrete quantity, also comprises close to this quantity acceptable and can not cause the part of the correction of the change of relevant basic function.Accordingly, modify a numerical value with " approximately ", " about " etc., mean and the invention is not restricted to this exact numerical.In some example, approximate term may correspond to the precision of the instrument measuring numerical value.In present specification and claims, scope limits and can combine and/or exchange, if do not illustrate that these scopes comprise contained all subranges therebetween in addition.
A first aspect of the present invention provides a kind of article of everyday use compositions containing nephrite, and described article of everyday use compositions is made up of the raw material comprising following percentage by weight:
The particle diameter of described nephrite is 5 ~ 20nm; The particle diameter of described gold is 30 ~ 80nm; The particle diameter of described silver is 25 ~ 50nm; Described natural antiseptic agent is the Chinese medicine extract containing Radix Scutellariae extract 1-40%, Flos Hibisci Mutabilis extract 1-40%, Olive leaf P.E 1-80%.
In the present invention, described term " nephrite " is the monoclinic system pyribole minerals of inosilicate, and use the Qilian in nephrite beautiful in the present invention, they have fine structure, and fiber is superfine, best in quality.The particle diameter of the nephrite in the present invention is in 5 ~ 20 nanometers.Particle diameter is that the microgranule of 5 ~ 20 nanometers more can interact with alkalescence anion water under close to the hot temperature of body temperature and produces trace red place far away microwave, and is more easily less readily available for absorption by the skin.Preferably, the particle diameter of described nephrite is 5 ~ 10nm.As some of them preferred implementation of the present invention, described nephrite is one or both in serpentine, the tremolite, and the negative value of described serpentine and the tremolite is δ
18o.More preferably, in semi-quantitative analysis, the percentage composition of described nephrite is: silicon 34, magnesium 10, calcium 4.9, ferrum 0.23, aluminum 0.16, copper 0.17, cobalt 0.046, manganese 0.14, stannum 0.024, beryllium 0.00072, silver 0.0013, titanium 0.0038, nickel 0.0028, chromium 0.0030, other 0.
In the present invention, the processing mode of nephrite is: it is that 0.5 ~ 2 atmospheric pressure micro-filtration (MF) obtains requiring the nephrite-sterilization treatment of particle diameter-utilize solvent to be in harmonious proportion that filtration of demineralized water (preliminary impurity screening)-oven dry removes moisture-utilize solvent mediation-operating pressure.
As some of them preferred implementation of the present invention, the microstructure of described nephrite is hair felty texture, micro-blade blastic texture, micro-nematoblastic texture, micro-fiber-cryptocrystalline blastic texture, micro-blade-cryptocrystalline blastic texture, radial structure or broom shape structure.Different microstructural nephrite can have a certain impact to the performance of article of everyday use compositions.More preferably, the microstructure of described nephrite is radial structure.When nephrite is radial structure, its structure be easier to by nanometer gold and nanometer silver coated, thus realize beneficial effect of the present invention better.
In the present invention, described term " gold " is the molecule of particle diameter 30 ~ 80nm, is nanometer gold, and it has high electron density, dielectric property and catalytic action, can be combined, and do not affect its biological activity with multiple biomacromolecule.Preferably, the particle diameter of described gold is 30 ~ 50nm.
In the present invention, described term " silver " is the molecule of particle diameter 25 ~ 50nm, is nanometer silver, has strong suppression and killing action, and can not produce drug resistance to tens of kinds of pathogenic microorganism such as escherichia coli, gonococcus, chlamydia trachomatiss.Preferably, the particle diameter of described silver is 25 ~ 35nm.
In the present invention, described term " Moringa extract " is extract the extract from Moringa oleifera.Moringa is the little tree of India this locality, but cultivates all over the world and transplant in many very universal environment.In the present invention, described Moringa extract is prepared by following method, described method comprises: by twice countercurrent extraction at 80 DEG C, in 17.5L ethanol 90, namely, ratio=9/1 of ethanol/water, extracts dry and one or more in the tree root of the Moringa of grinding, blade, whole seed of 2.5kg; At environment after 50 DEG C of coolings, reclaim the solution through extracting by solid/liquid separation; Drying sample, thus obtain 243g extract, wherein the feature of this extract is the oil of 36% content and the total polyphenols of 0.02% content, represent with the g of the pyrogallol of 100g dry extract, described oil comprises the triglyceride of (i) 10% and the polar lipid of fatty acid and (ii) 10%, and wherein said whole seed is the not removed seed of crust.
In the present invention, described term " natural antiseptic agent " is nonirritant, avirulent non-chemically synthetic preservative, and it is the Chinese medicine extract containing Radix Scutellariae extract 5-40%, Flos Hibisci Mutabilis extract 5-40%, Olive leaf P.E 20 ~ 60%.Described natural antiseptic agent is prepared by following methods: after being pulverized by Chinese medicine, sieve, soak 1-2h together with Extraction solvent after, extract with high pressure homogenization method machine at normal temperatures, extracting solution after centrifugalize, by macroporous resin adsorption, with the ethanol repeatedly eluting of 10-95%, collect eluent, be evaporated to extractum shape, obtain final product; Described Extraction solvent is water, ethanol or ethanol water.Natural antiseptic agent of the present invention can suppress gram positive bacteria, gram negative bacteria, yeast and mycete, has wider antimicrobial spectrum.This natural antiseptic agent is not containing the material of chemosynthesis, and have no side effect, skin irritation is little, and stable in properties is safe and reliable.In addition, Radix Scutellariae extract, except having antibacterial effect, also has antiinflammatory, free radical resisting effect; Flos Hibisci Mutabilis extract, except having antibacterial effect, also has white-skinned face function; Olive leaf P.E, except having antibacterial effect, also has very strong free radical resisting effect.So natural antiseptic agent compositions of the present invention is except having antimicrobial preservative efficacy, and tool free radical resisting and whitening and skin-protecting effect simultaneously, this is that chemosynthesis antiseptic institute is incomparable.
Article of everyday use compositions of the present invention also comprises component conventional in article of everyday use or cosmetic field.If the arbitrary coloring pigment, extender pigment, water composition, the oil components that use in the art.Other components of cosmetic field can also be added, as micromolecule hyaluronic acid, coenzyme Q10, Panthenol, allantoin, silkworm silk decoding peptide, the raw peptide of blue copper, salmon nasal cartilages extract (non-synthetic EGF) etc.
Be not particularly limited as above-mentioned coloring pigment, can enumerate such as: inorganic white pigment (such as titanium dioxide etc.); Inorganic red series pigments (such as ferrum oxide (iron oxide red), iron titanate etc.); Inorganic brown series pigments (such as gamma-iron oxide etc.); Inorganic yellow series pigments (such as iron oxide yellow, loess etc.); Inorganic black series pigments (such as Black Rouge, titanium suboxide etc.); Inorganic violet pigment (such as manganese violet, cobalt violet etc.); Inorganic green series pigments (such as chromium oxide, chromic oxide gel, cobalt titanate etc.); Inorganic blue series pigment (such as ultramarine, Prussian blue etc.); Pearl pigment (such as coated by titanium dioxide Muscovitum, coated by titanium dioxide bismuth oxychloride, coated by titanium dioxide Talcum, painted coated by titanium dioxide Muscovitum, bismuth oxychloride, guanin etc.); Metallic powdery pigment (such as aluminium powder, copper powders etc.); The organic pigments such as zirconium, barium or aluminum color lake (such as red No. 201, red No. 202, red No. 204, red No. 205, red No. 220, red No. 226, red No. 228, red No. 405, orange No. 203, orange No. 204, yellow No. 205, the organic pigment such as yellow No. 401 and blue No. 404; No. 3, redness, No. 104, redness, No. 106, redness, No. 227, redness, No. 230, redness, No. 401, redness, redness No. 505, orange No. 205, No. 4, yellow, Sunset Yellow FCF, No. 202, yellow, No. 203, yellow, No. 3, green and No. 1, blueness etc.); Natural pigment (such as chlorophyll, beta-carotene etc.) etc.
Be not particularly limited as above-mentioned extender pigment, such as Muscovitum, synthetic mica, sericite, Talcum, Kaolin, calcium carbonate, magnesium carbonate, barium sulfate, aluminium oxide etc. can be enumerated.
Be not particularly limited as above-mentioned water composition and oil components, such as oil component can be contained, surfactant, wetting agent, higher alcohol, metal ion blocks agent, natural and synthesis macromolecule, water solublity and oil-soluble macromolecule, UV absorbent, various extracting solution, inorganic and organic pigment, inorganic and organic clay, through the inorganic and organic pigment of metallic soap process or silicone-treated, the coloring agent such as organic dyestuff, antiseptic, antioxidant, color element, thickening agent, pH adjusting agent, spice, creeping chill agent, antiperspirant, antibacterial, the compositions such as activating skin agent.Specifically, can coordinate arbitrarily in following cited gradation composition one kind or two or more, manufacture article of everyday use compositions of the present invention by conventional method.Use level for these gradation compositions is not particularly limited, as long as the scope for not damaging effect of the present invention.
Be not particularly limited as above-mentioned oil components, can enumerate such as: American Avocado Tree oil, Camellia oil, turtle oil, macadimia nut oil, Semen Maydis oil, ermine oil, olive oil, Oleum Brassicae campestris, elgen, Oleum sesami, peach kernel oil, Semen Tritici aestivi germ oil, Flos Camelliae Japonicae caul-fat, Oleum Ricini, Semen Lini oil, safflower oil, Oleum Gossypii semen, perilla oil, soybean oil, Oleum Arachidis hypogaeae semen, Oleum Camelliae, Semen Torreyae oil, Testa oryzae oil, Chinese wood oil, Japanese tung oil, Jojoba oil (jojoba oil), germ oil, triglycerin, tricaprylin, three different tripalmitins, cocoa butter, Oleum Cocois, house oil, hydrogenated coconut oil, Petiolus Trachycarpi oil, Adeps Bovis seu Bubali, Adeps caprae seu ovis, hydrogenated tallow, palm kernel oil, Adeps Sus domestica, neatsfoot stock, Rhus succedanea kernel oil, hydrogenated oil and fat, hoof oil, haze tallow, castor oil hydrogenated, Cera Flava, candelilla wax, cotton wax, Brazil wax, bayberry wax, insect wax, spermaceti, montan wax, bran wax, lanoline, kapok wax, acetic acid lanoline, liquid lanolin, sugarcane wax, isopropyl lanolate, lauric acid hexyl ester, reduction lanoline, jojoba wax, hard lanoline, shellac wax, POE lanoline alcohol ether, POE lanolin alcohol acetas, POE cholesterol ethers, lanoceric acid Polyethylene Glycol, POE hydrogenated lanolin alcohol ether, liquid paraffin, ceresine, pristane, alkane, pure white ceresine, Squalene, vaseline, microwax etc.
Be not particularly limited as lipophile non-ionic surface active agent, can enumerate such as: the sorbitan aliphatic ester classes such as sorbitan monooleate, sorbitan list isostearate, Span-20, sorbitan monopalmitate, sorbitan monostearate, Span-83, sorbitan trioleate, five-2 ethyl hexanoic acid diglycerol sorbitan, four-2 ethyl hexanoic acid diglycerol sorbitan; Single oleic acid glyceride, single erucic acid glyceride, sesquialter olein, glyceryl monostearate, α, the glycerol polyglycerol fatty acid classes such as α '-oleic acid pyroglutamic acid glyceride (α, α '-glyceryl oleate pyroglutamate), glycerol monostearate malic acid; The methyl glycol fatty acid ester classes such as propylene glycolmonostearate; Castor oil hydrogenated derivant, alkyl glycerylether etc.
Be not particularly limited as hydrophilic non-ionic surfactant, can enumerate such as: the POE sorbitan aliphatic ester classes such as POE sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-sorbitan four oleate; The POE sorbitan fatty acid esters such as POE-is sorbityl monododecanoate, POE-sorbitol monooleate, POE-Sorbitol five oleate, POE-sorbitan monostearate; The POE glycerine fatty acid esters such as POE-glyceryl monostearate, POE-glycerol monoisostearate, POE-glyceryl triisostearate; The POE fatty acid esters such as polysorbate 80, POE distearate, the mono-dioleate of POE, diglycol stearate; The POE alkyl ethers such as POE lauryl ether, POE oleyl ether, POE stearyl ether, POE docosyl ether, POE2-octyldodecyl ether, POE cholestane alcohol ether; The POE alkyl phenyl ethers such as POE octyl phenyl ether, POE nonylplenyl ether, POE dinonyl phenyl ether; The general Buddhist nun's gram type classes that flow such as the addition polymers of polypropylene glycol and oxirane; The POEPOP alkyl ethers such as POEPOP cetyl ether, POEPOP2-decyl myristyl ether, POEPOP monobutyl ether, POEPOP hydrogenated lanolin, POEPOP glycerin ether; The POE Oleum Ricini castor oil hydrogenated derivants such as POE Oleum Ricini, POE castor oil hydrogenated, POE castor oil hydrogenated list isostearate, POE castor oil hydrogenated three isostearate, POE castor oil hydrogenated list pyroglutamic acid list isostearic acid diester, POE castor oil hydrogenated maleate; The POE Cera Flava lanolin derivatives such as POE Sorbitol Cera Flava; The alkanolamides such as cocoanut fatty acid diethanolamide, lauric monoethanolamide, fatty acid isopropanol amide; POE methyl glycol fatty acid ester, POE alkylamine, POE fatty acid amide, sucrose fatty acid ester, POE nonyl phenyl formaldehyde condensation products, alkyl ethoxy dimethyl amine, three oleyl alcohol phosphate esters etc.
As other surfactant, can with anion surfactants such as range fit no problem in stability and skin irritation such as fatty acid soaps, high alkyl sulfate salt, POE triethanolamine lauryl sulfate, alkyl ether sulphate salts; The cationic surfactants such as alkyl trimethyl ammonium salt, Fixanol, alkyl quaternary ammonium salts, alkyl dimethyl benzyl ammonium salt, POE alkylamine, alkylamine salt, polyamine derivative of fatty acid; And the amphoteric surfactant such as imidazoline system amphoteric surfactant, betaine series surfactants.
As other surfactant, can with anion surfactants such as range fit no problem in stability and skin irritation such as fatty acid soaps, high alkyl sulfate salt, POE triethanolamine lauryl sulfate, alkyl ether sulphate salts; The cationic surfactants such as alkyl trimethyl ammonium salt, Fixanol, alkyl quaternary ammonium salts, alkyl dimethyl benzyl ammonium salt, POE alkylamine, alkylamine salt, polyamine derivative of fatty acid; And the amphoteric surfactant such as imidazoline system amphoteric surfactant, betaine series surfactants.
Be not particularly limited as above-mentioned wetting agent, such as xylitol, Sorbitol, maltose alcohol, chondroitin sulfate, hyaluronic acid, mucoitin sulfuric acid, trichosanic acid, Atelocollagen, cholesteryl-12-hydroxy stearic acid ester, sodium lactate, bile salt, short chain soluble collagen, diglycerol (EO) PO addition product, rosa roxburghii extract, yarrow extract, melilotus extract etc. can be enumerated.
Be not particularly limited as above-mentioned higher alcohol, can enumerate such as: the straight chain alcohols such as lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oily enol, cetearyl alcohol; The branched-chain alcohos such as single stearyl glycerin ether (batilol), 2-decyl tetradecyl alcohol, lanolin alcohol, cholesterol, plant sterol, hexyl dodecanol, isooctadecanol, octyldodecanol; Etc..
Block agent as metal ion to be not particularly limited, such as 1-hydroxyl ethane-1 can be enumerated, the acid of 1-diphosphonic acid, 1-hydroxyl ethane-1,1-diphosphonic acid tetrasodium salt, sodium citrate, sodium polyphosphate, Polymeric sodium metaphosphate., gluconic acid, phosphoric acid, citric acid, ascorbic acid, succinic acid, EDTA etc.
Be not particularly limited as above-mentioned water-soluble macromolecule, can enumerate such as: department of botany's macromolecules such as arabic gum, Tragacanth, galactan, guar gum, carob, karaya, carrageenan, pectin, Qiong Zhi, Fructus cydoniae oblongae seed (marmelo ， Fructus cydoniae oblongae), Algin (brown alga extract), starch (rice, Semen Maydis, Rhizoma Solani tuber osi, Semen Tritici aestivi), glycyrrhizic acid; The department of microbiology macromolecules such as xanthan gum, glucosan, succinic acid glucosan, amylopectin; The animal system macromolecules such as collagen protein, casein, albumin, gelatin.
Be not particularly limited as semi-synthetic water soluble polymer, can enumerate such as: the starch-series macromolecules such as carboxymethyl starch, methylhydroxy propyl group starch; The cellulose polymer such as methylcellulose, celluloid, ethyl cellulose, methylhydroxypropylcellulose, hydroxy ethyl cellulose, cellulose sodium sulfate, hydroxy propyl cellulose, sodium carboxymethyl cellulose (CMC), crystalline cellulose, cellulose powder; The alginic acid such as sodium alginate, propylene glycol alginate system macromolecule; Etc..
Be not particularly limited as synthesizing water-solubility macromolecule, can enumerate such as: the ethylene base system macromolecules such as polyvinyl alcohol, polyvinylmethyl ethers, polyvinylpyrrolidone; Polyethylene Glycol 20,000,40,000,60,000 macromolecule such as system such as polyoxyethylene such as grade; Poloxalkol copolymerization system macromolecule; The acrylic acid series macromolecules such as sodium polyacrylate, polyethyl acrylate, polyacrylamide; Polyethylene imine based, cationic polymer etc.
Be not particularly limited as Inorganic water-soluble macromolecule, such as bentonite, Magnesiumaluminumsilicate (VEEGUM), LAPONITE, Strese Hofmann's hectorite., silicic acid anhydride etc. can be enumerated.
A second aspect of the present invention provides the preparation method of the above-mentioned article of everyday use compositions containing nephrite, comprises the following steps:
By nephrite, gold and silver mixing, grind together; Component conventional in Moringa extract and article of everyday use or cosmetic field is added again after grinding, 60 ~ 70 DEG C are uniformly mixed, and then utilize mixer for well-distribution to make to reach even, after de-bubbled, filtration, add natural antiseptic agent again, utilize heat exchanger etc. to carry out cooling and reaching goods.
The preparation method of article of everyday use compositions of the present invention, by first dropping into unclassified stores again by after nephrite, gold and silver-colored mixed grinding, due to the good ductility of Jin Heyin, by grinding, nanometer gold and nanometer silver can be coated on nephrite, thus realize the technique effect that sense of touch of the present invention is good, infrared ray, ultraviolet reflection are good better.
A third aspect of the present invention provides the application of the above-mentioned article of everyday use compositions containing nephrite, described application comprises cosmetic field, as nourished late frost, the face frost that compacts, visage block cream, ultra light sun block lotion, conditioning powder cream base, repair eye cream, facial film, face mask cream, hands film, foot film, hand cream, spats frost, moisturizing liquid, lipstick, described application also comprises daily necessities field, as fancy soap, toothpaste, collutory, shampoo, bath gel etc.
The particle diameter of the nephrite microgranule in article of everyday use compositions of the present invention is at 5 ~ 20nm, belong to nanoscale, particle diameter is little, there is good permeability and far infrared Microwave emission, to be easier to absorb by the skin of human body, after skin surface is absorbed into subcutaneous tissue, the interaction of the nano_scale particle of nephrite and anion and body temperature produces far infrared microwave, thus produce faint thermo-magnetic effect and slightly to heat up heating, the metabolism of blood circulation promoting and cell, strengthen cell viability and cell tissue absorbing power, be of value to tissue regeneration, effective delaying skin failure, and have certain bactericidal effect, and by adding nanometer gold and nanometer silver, synergism can be played together with nephrite, thus it is good to realize sense of touch of the present invention, infrared ray, the technique effect that ultraviolet reflection is good, and there is whitening, nourish, repair, the effects such as antiinflammatory.
Hereinafter, by embodiment, the present invention is explained in more detail, but should be understood that these embodiments are only example and nonrestrictive.If do not have other to illustrate, raw materials used is all commercially available.
The present invention is described in detail referring to several example.
The formula of embodiment 1 ~ 7 and comparative example 1 ~ 4 is as shown in table 1.The particle diameter of the nephrite used in comparative example 1, Jin Heyin (A, B, C) is respectively 3um, 10um and 20um, and the nephrite in comparative example 2, gold and silver join together with other components to be prepared and obtains.Only containing nephrite in comparative example 3, not containing Jin Heyin, only containing nephrite and gold in comparative example 4, not containing silver.
The mean diameter of the raw material of following examples uses laser diffraction and scattering formula particle size distribution device to measure.Determinator uses BeckmanCoulter LS13320 type, using its intermediate value footpath (D50 value) as mean diameter.
Wherein component raw material is as follows:
A1: serpentine nephrite, particle diameter is 5nm, hair felty texture, and negative value is δ
18o, in semi-quantitative analysis, the percentage composition of described nephrite is: silicon 34, magnesium 10, calcium 4.9, ferrum 0.23, aluminum 0.16, copper 0.17, cobalt 0.046, manganese 0.14, stannum 0.024, beryllium 0.00072, silver 0.0013, titanium 0.0038, nickel 0.0028, chromium 0.0030, other 0.Following A2 ~ A7 negative value is identical with semi-quantitative analysis numerical value.
A2: serpentine nephrite, particle diameter is 10nm, radial structure
A3: tremolite nephrite, particle diameter is 20nm, micro-nematoblastic texture
A4: serpentine nephrite, particle diameter is 10nm, micro-fiber-cryptocrystalline blastic texture
A5: serpentine nephrite, particle diameter is 10nm, broom shape structure
A6: serpentine nephrite, particle diameter is 10nm, micro-blade blastic texture
A7: serpentine nephrite, particle diameter is 10nm, micro-blade-cryptocrystalline blastic texture
B1: nanometer gold, particle diameter is 30nm
B2: nanometer gold, particle diameter is 50nm
B3: nanometer gold, particle diameter is 80nm
C1: nanometer silver, particle diameter is 25nm
C2: nanometer silver, particle diameter is 35nm
C3: nanometer silver, particle diameter is 50nm
D: Moringa extract
E: natural antiseptic agent, containing the Chinese medicine extract of Radix Scutellariae extract 30%, Flos Hibisci Mutabilis extract 20%, Olive leaf P.E 50%.
The formula of the article of everyday use compositions of table 1 embodiment 1 ~ 7 and comparative example 1 ~ 4
Embodiment 1 ~ 7, and the performance measurement of the article of everyday use compositions of comparative example 1 ~ 4 the results are shown in Table shown in 2.
1, the mensuration of average friction coefficient
Microscope slide is pasted the two-sided tape that 25mm is wide, puts article of everyday use compositions, utilize powder puff to expand and open, use Kato Tech system friction sense tester (KES-SE type) measures average friction coefficient when loading 25g load.
2, the mensuration of total visible light transmittance
Article of everyday use compositions is joined in bottle, utilizes paint mixing unit (Paint Conditioner) to vibrate 90 minutes, obtain dispersion liquid.Use scraping strip coating machine #6 that obtained dispersion liquid is applied to microscope slide, use spectrophotometer (Japanese light splitting V-570 type) measures total light transmittance during wavelength 400nm and 550nm.
3, the mensuration of near infrared ray reflective rate
Article of everyday use compositions is joined in the aluminium lid of diameter 35mm, dark about 10mm, utilize forcing press under 15tf load, carry out compacting in 20 seconds, obtain test film, use spectrophotometer (Japanese light splitting V-570 type) obtained test film to be carried out to the mensuration of spectral reflectance under wavelength 1000nm and 2000nm.
The performance test results of the article of everyday use compositions of table 2 embodiment 1 ~ 7 and comparative example 1 ~ 4
From above data, relative to one of nephrite and gold, silver with the use of, or only use nephrite, the nephrite of Nano grade, gold, silver three with the use of time, there is lower coefficient of friction, excellent use sense, infrared reflectivity, illustrate that nephrite, gold and silver-colored three have significant synergism.In addition, when the microstructure of nephrite is radial, relative to other microstructure, there is more excellent performance.When nephrite is coated by gold, silver, when being mixed with relative to three and other compositions, also there is more excellent performance.In addition, the article of everyday use compositions containing nephrite of the present invention also has effect of whitening, nourishing, reparation.
Aforesaid example is only illustrative, for explaining some features of feature of the present invention.Appended claim is intended to the scope wide as far as possible that requirement it is contemplated that, and the embodiment presented herein is only the explanation of the embodiment of the selection of combination according to all possible embodiment.Therefore, the purpose of applicant is the selectional restriction that appended claim is not illustrated the example of feature of the present invention.And progress in science and technology is not replaced to be formed due to the inaccurate reason of language performance by the possible equivalent considered at present or son, and these changes also should be interpreted as being covered by appended claim in the conceived case.
Claims (10)
1. the article of everyday use compositions containing nephrite, it is characterized in that, described article of everyday use compositions is made up of the raw material comprising following percentage by weight:
The particle diameter of described nephrite is 5 ~ 20nm; The particle diameter of described gold is 30 ~ 80nm; The particle diameter of described silver is 25 ~ 50nm; Described natural antiseptic agent is the Chinese medicine extract containing Radix Scutellariae extract 5-40%, Flos Hibisci Mutabilis extract 5-40%, Olive leaf P.E 20-60%.
2. the article of everyday use compositions containing nephrite according to claim 1, it is characterized in that, the particle diameter of described nephrite is 5 ~ 10nm, and the particle diameter of described gold is 30 ~ 50nm, and the particle diameter of described silver is 25 ~ 35nm.
3. the article of everyday use compositions containing nephrite according to claim 1, it is characterized in that, the microstructure of described nephrite is hair felty texture, micro-blade blastic texture, micro-nematoblastic texture, micro-fiber-cryptocrystalline blastic texture, micro-blade-cryptocrystalline blastic texture, radial structure or broom shape structure.
4. the article of everyday use compositions containing nephrite according to claim 3, it is characterized in that, the microstructure of described nephrite is radial structure.
5. the article of everyday use compositions containing nephrite according to claim 1, is characterized in that, described nephrite is one or both in serpentine, the tremolite, and the negative value of described serpentine and the tremolite is δ
18o.
6. the article of everyday use compositions containing nephrite according to claim 1, it is characterized in that, in semi-quantitative analysis, the percentage composition of described nephrite is: silicon 34, magnesium 10, calcium 4.9, ferrum 0.23, aluminum 0.16, copper 0.17, cobalt 0.046, manganese 0.14, stannum 0.024, beryllium 0.00072, silver 0.0013, titanium 0.0038, nickel 0.0028, chromium 0.0030, other 0.
7. the article of everyday use compositions containing nephrite according to claim 1, it is characterized in that, described Moringa extract by by by drying and the tree root of Moringa of grinding, seed or blade are added in the solvent of ethanol/water=9/1, countercurrent extraction at 80 DEG C and obtaining; Described natural antiseptic agent is prepared by following methods: after being pulverized by Chinese medicine, sieve, soak 1-2h together with Extraction solvent after, extract with high pressure homogenization method machine at normal temperatures, extracting solution after centrifugalize, by macroporous resin adsorption, with the ethanol repeatedly eluting of 10-95%, collect eluent, be evaporated to extractum shape, obtain final product; Described Extraction solvent is water, ethanol or ethanol water.
8. the article of everyday use compositions containing nephrite according to any one of claim 1-7, is characterized in that, described article of everyday use compositions also comprises component conventional in article of everyday use or cosmetic field.
9. a preparation method for the article of everyday use compositions containing nephrite, is characterized in that, comprise the following steps: by nephrite, gold and silver mixing, grind together; Component conventional in Moringa extract and article of everyday use or cosmetic field is added again after grinding, 60 ~ 70 DEG C are uniformly mixed, and then utilize mixer for well-distribution to make to reach even, after de-bubbled, filtration, add natural antiseptic agent again, utilize heat exchanger etc. to carry out cooling and reaching goods.
10. the application of article of everyday use compositions in cosmetics or daily necessities field containing nephrite described in any one of claim 1-8, it is characterized in that, described cosmetics are for nourishing late frost, the face frost that compacts, visage block cream, ultra light sun block lotion, conditioning powder cream base, repairing eye cream, facial film, face mask cream, hands film, foot film, hand cream, spats frost, moisturizing liquid or lipstick, and described article of everyday use is fancy soap, toothpaste, collutory, shampoo, bath gel or cleaning supplies.
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| CN107661233A (en) * | 2017-10-23 | 2018-02-06 | 广州市西瑶玉池科技有限公司 | A kind of anhydrous toothpaste of the mineral element containing the tremolite and preparation method thereof |
| CN107661228A (en) * | 2017-10-20 | 2018-02-06 | 广州市西瑶玉池科技有限公司 | A kind of multiple-effect toothpaste of the mineral element containing the tremolite |
| CN107822920A (en) * | 2017-10-23 | 2018-03-23 | 广州市西瑶玉池科技有限公司 | A kind of inflammation-diminishing toothpaste of the mineral element containing the tremolite |
| CN107837217A (en) * | 2017-10-23 | 2018-03-27 | 广州市西瑶玉池科技有限公司 | A kind of anti-apolexis composition of mineral element containing the tremolite and its application |
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| CN107951731A (en) * | 2018-01-16 | 2018-04-24 | 广州市美姿贺化妆品有限公司 | Application of the nanometer gold in late frost and the late frost that is made from it and preparation method thereof |
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| CN107661228A (en) * | 2017-10-20 | 2018-02-06 | 广州市西瑶玉池科技有限公司 | A kind of multiple-effect toothpaste of the mineral element containing the tremolite |
| CN107875049A (en) * | 2017-10-20 | 2018-04-06 | 广州市西瑶玉池科技有限公司 | A kind of mothproof sound of baby talk cream of the mineral element containing the tremolite |
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| CN107822920A (en) * | 2017-10-23 | 2018-03-23 | 广州市西瑶玉池科技有限公司 | A kind of inflammation-diminishing toothpaste of the mineral element containing the tremolite |
| CN107837217A (en) * | 2017-10-23 | 2018-03-27 | 广州市西瑶玉池科技有限公司 | A kind of anti-apolexis composition of mineral element containing the tremolite and its application |
| CN107951731A (en) * | 2018-01-16 | 2018-04-24 | 广州市美姿贺化妆品有限公司 | Application of the nanometer gold in late frost and the late frost that is made from it and preparation method thereof |
| CN112826837A (en) * | 2021-03-15 | 2021-05-25 | 福建广生健康科技有限公司 | Traditional Chinese medicine composition for treating hair/scalp diseases and application thereof |
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