CN104760440A - Anti-counterfeiting stained paper and printing method thereof - Google Patents
Anti-counterfeiting stained paper and printing method thereof Download PDFInfo
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- CN104760440A CN104760440A CN201510164501.8A CN201510164501A CN104760440A CN 104760440 A CN104760440 A CN 104760440A CN 201510164501 A CN201510164501 A CN 201510164501A CN 104760440 A CN104760440 A CN 104760440A
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Abstract
The invention relates to anti-counterfeiting stained paper and a printing method thereof. The method comprises the steps of 1, manufacturing texts and/ or patterns; 2, manufacturing a film; 3, manufacturing a screen printing plate; 4, printing non-gold-stamping texts and/ or patterns; 5, coating with isolating resin; 6, coating with gold-stamping base ink, wherein printing blocks with different color on the same base paper by the screen printing plate manufactured in step 3 through UV resin by the method of printing each color at a time to obtain UV ink, and then photocuring the UV ink under the irradiation of the UV rays; 7, performing transfer printing and gold-tamping, namely, respectively performing transfer printing for anti-counterfeiting electric aluminum foils on the UV ink obtained in step 6 through a gold-stamping machine; 8, coating with isolating gloss oil; 9, coating with a tearing surface glue film. The method is anti-counterfeiting, simple to print, and high in production efficiency; the obtained anti-counterfeiting stained paper can be widely applied to packing boxes of various cosmetics, articles of daily use, cigarette, wine and foods, and thus the applicable scope of the stained paper is greatly expanded.
Description
Technical field
The invention belongs to false proof printing field, be specifically related to a kind of false proof marble paper and printing method thereof.
Background technology
Marble paper has the feature of the performances such as intensity is large, high temperature resistant, rub resistance and bright color, and product is widely used on the product such as pottery, glass ornaments.Growing along with commercialization society, not only marble paper printing method needs to improve, and its function also needs to give generalization simultaneously.In prior art, the multinomial dry run of the many needs of printing process of marble paper, consuming time longer, reduce productivity effect, and traditional marble paper is printed on the many employings of the gold stamping step of transfer printing does not possess anti-fraud functional electrochemical aluminum foil, after electrochemical aluminum foil traditional is at present gold stamping, its color immobilizes, still keep the gold of scalding; If when needing in addition false proof, then do not have antiforge function, be easy to by people counterfeit.
Therefore, those skilled in the art need to provide a kind of have anti-fraud functional, print false proof marble paper that is simple, that enhance productivity and printing method thereof.
Summary of the invention
For above-mentioned deficiency, the technical problem to be solved in the present invention be to provide a kind of have anti-fraud functional, print false proof marble paper that is simple, that enhance productivity and printing method thereof.
To achieve these goals, the present invention is achieved through the following technical solutions:
A printing method for false proof marble paper, this printing method comprises the steps:
(1), word and/or pattern is made;
(2), film is made: the word of the different colours made according to step (1) and/or pattern, make the method for same film, make film respectively according to same color;
(3), make printing screen version: according to the word of different colours and/or the film of design producing, make the method for same printing screen version according to same color, make printing screen version respectively;
(4) print non-gold stamping word and/or pattern: adopt the screen printing plate made in step (3), non-gold stamping word and/or pattern are printed on dry membranelle base stock;
(5), in the side being printed with non-gold stamping word and/or pattern of membranelle base stock print one deck isolation resin, described isolation resin comes off for preventing the word on membranelle base stock and/or pattern;
(6), ink of the upper gold stamping end: adopt the screen printing plate made in step (3), use UV resin, according to same color printing method once, respectively the pattern of different colours is printed on same membranelle base stock, UV ink, optical curing of UV ink under Ultraviolet radiation;
(7), the gold stamping word of transfer printing and/or pattern: according to the gold stamping word of different colours and/or the needs of pattern, according to same color printing method once, with gilding press by the electrochemical aluminum foil with false proof word and/or security pattern at 110 ~ 140 DEG C, the pressure of 3 ~ 4 normal atmospheres is transferred on the UV ink that step (6) obtains respectively;
(8), upper isolation gloss oil: after completing the printing of above-mentioned pattern, be coated with one deck isolation gold stamping oil;
(9), upper tearable laminate cover.
Preferably, described isolation resin is modified acroleic acid high molecular polymer, described modified acroleic acid high molecular polymer comprises four monomeric acrylic AA, methyl methacrylate MMA, butyl acrylate BA, hydroxypropyl acrylate HPA, also comprise initator benzoyl peroxide BPO, curing agent and solvent, the quality proportioning of four described monomers is MMA:BA:AA:HPA=37.5:37.5:12.5:12.5; The consumption of initator benzoyl peroxide BPO is 1.75% of four monomer gross masses; The consumption of curing agent is 3% of four monomer gross masses; The mass ratio of the gross mass of described solvent and four monomers is 1:l, and solvent is the mixed liquor of n-butanol and water, and the mass ratio of n-butanol and water is 2:1;
The preparation process of isolation resin is as follows:
1), first in the reaction vessel being configured with agitator and reflux condensing tube, four monomeric acrylic AA, methyl methacrylate MMA, butyl acrylate BA, hydroxypropyl acrylate HPA, solvent and initator is accessed respectively, the addition of described acrylic acid AA, methyl methacrylate MMA, butyl acrylate BA, hydroxypropyl acrylate HPA be respectively its separately quality 1/3, the addition of solvent is 1/2 of its quality, the addition of initator is 1/4 of its quality, the addition of curing agent is 1/3 of its quality, start agitator and be warming up to 100 DEG C, reaction 15min;
2), in reaction vessel, continue the mixture dripping residual monomer and initator, wherein the addition of initator is 1/2 of its quality, and the addition of curing agent is 1/3 of its quality, and time for adding is 3h, drips off rear continuation and stirs 0.5h;
3), in reaction vessel, remaining solvent, initator and curing agent is added again, continue stirring reaction 3h, be cooled to 40 ~ 50 DEG C, under agitation add ammoniacal liquor to the solution in reaction vessel and be neutralized to pH=8 ~ 9, continue reaction 0.5h, namely obtain this isolation resin.
Preferably, described curing agent is DETA and diethylenetriamine.
Preferably, the ultraviolet curing wavelength in step (5) is 300 ~ 420nm, and hardening time continues 2 ~ 6s.
Preferably, the proportioning of described UV resin is: urethane acrylate 5 ~ 8 parts, epoxy acrylate 6 ~ 10 parts, polyester acrylate 30 ~ 48 parts, photo-sensitive monomer 10 ~ 20 parts, light trigger 1 ~ 7 part, coloring pigment 20 ~ 22 parts, filler 1 ~ 4 part.
Preferably, described electrochemical aluminum foil is made up of successively base membrane layer, release layer, dyed layer, aluminium lamination, glue-line, described release layer is printed on base membrane layer by coating process, dyed layer is printed on release layer by coating process, described aluminium lamination is attached to dyed layer by aluminum plating process, false proof word and/or security pattern are printed on aluminium lamination and dyed layer by imprint process, and described glue-line is printed on aluminium lamination by coating process.
Further, described base membrane layer adopts biaxial stretching polyester film PET, and described base membrane layer thickness is 16 μm, and the general thickness of described release layer, dyed layer, aluminium lamination three is 3 μm.
Two of the technical problem to be solved in the present invention is to provide a kind of false proof marble paper adopting above-mentioned printing process to make.
Beneficial effect of the present invention is:
1), the present invention first adopts water-transfer printing paper to transfer on stock by required common language and/or pattern (also namely not needing gold stamping word and/or pattern), recycling gilding press by false proof electrochemical aluminum foil at 110 ~ 140 DEG C, 3 ~ 4 normal atmosphere pressures are transferred on the UV ink after photocuring respectively, gold stamping pattern can be obtained, and then upper isolation gloss oil and tearable laminate cover, wherein isolate gloss oil and there is low-corrosiveness, therefore gold stamping face coat can not be destroyed, and with tearable laminate cover, there is good separation property, tearable laminate cover is then convenient to water and is transferred on body, after taking this film off by low-temperature bake, word and/or the pattern of complete display can be retained on body.
The present invention adopts ultraviolet to carry out photocuring, does not need consuming time and lengthy and tedious drying course, greatly saves the printing time, improves printing production efficiency; Simultaneously first by serigraphy transfer word and/or pattern, then shift gold stamping pattern by gilding press, not only printing efficiency is high, and has enriched the print content of marble paper, adds product category.
2), the present invention adopts UV ink, not only saves time, and also more saves ink simultaneously, printing environment is also comparatively pure and fresh, and smell is little, decreases the pollution to environment, and not containing heavy metal harmful objects such as lead, cadmium, lithiums, be conducive to environmental protection and consumer health; And the curability that UV ink surface layer is good and conjunctiva not only can improve post-press finishing characteristic, and also improve the presentation quality of product; In addition, UV ink also has good high temperature resistant, water-fast and ethanol-tolerant performance.
3), present invention employs false proof electrochemical aluminum foil, described false proof electrochemical aluminum foil is namely with the electrochemical aluminum foil of false proof word and/or security pattern, electrochemical aluminum foil in the present invention adopts the mode of impression to be printed on electrochemical aluminum foil by anti-counterfeiting information, thus make gold stamping after the higher and complete display of security pattern brightness, have good stereo visual effect, antifalse effect is good.
4) laminate cover, in the present invention preferably adopts tearable poly-third vinyl film, both economizes on resources, and turn avoid and cause environmental pollution.
5) the isolation resin property index, in the present invention is as follows: viscosity (25% solid content) is 40s, fineness < 20pm, and tinting strength, tinting power is 98%, and glossiness is 75%, and alkaline-resisting water resistance is three grades, stable storing.Thus improve definition and the stability of pattern in the present invention further.
Detailed description of the invention
For making the object, technical solutions and advantages of the present invention clearly, below in conjunction with embodiment, the present invention is described in further detail.
In the present embodiment, gold stamping oil is purchased from the prosperous printing material factory of Wuxi City, and model is 58-130; Ultraviolet curing formulation number is HR-206-1050zw, UV lamp wavelength is 300 ~ 410nm, and main crest is 365nm.
Embodiment 1
First prepare UV resin and isolation resin, mass fraction pressed by UV resin, by urethane acrylate 5 parts, epoxy acrylate 6 parts, polyester acrylate 45 parts, photo-sensitive monomer 15 parts, light trigger 5 parts, coloring pigment 20 parts, filler 4 parts.
Then, according to the following steps, a kind of method of false proof marble paper is printed:
(1), pattern-making: the pattern utilizing computer photograph two kinds of colors (red, blue).
(2), make film: according to the pattern of the different colours that step (1) makes, make the method for same film according to same color, make two films respectively;
(3), make printing screen version: make two printing screen plates, wherein, red needs are gold stamping, and blue not needing is gold stamping;
(4), get dry commercially available water-soluble membranelle base stock printing and do not need gold stamping pattern; Adopt the screen printing plate made in step (3), use light water transfer ink, to gold stamping blue color patterns do not needed to be printed on base stock, republish the unlikely isolation resin come off of pattern on one deck protection base stock, described isolation resin be modified acroleic acid high molecular polymer;
(5), ink of the upper gold stamping end: adopt the screen printing plate made in step (3), use UV resin, the pattern of redness is printed on the isolation resin side of membranelle base stock in step (4), obtains UV ink;
(6), ink of the dry gold stamping end: optical curing of UV ink under Ultraviolet radiation, the solid speed of light can reach 4000/hour;
(7), transfer printing is gold stamping: utilize gilding press by the electrochemical aluminum foil with false proof word and security pattern at 110 DEG C, the pressure of four normal atmospheres is transferred on the UV ink that step (6) obtains;
(8), upper isolation gloss oil: after completing the printing of above-mentioned pattern, be coated with one deck gold stamping oil;
(9), dry isolation gloss oil: utilize UV-light photocuring machine to carry out photocuring drying, with the ultraviolet of 365nm wavelength, keep continue 3s hardening time.
(10), the tearable laminate cover of last layer: adopt the poly-tearable laminate cover of third ethene.
(11), dry tearable laminate cover.Adopt heat drying, temperature 35 DEG C, 3 hours time.
By above step, obtain the marble paper of two kinds of colors (red, blue) pattern.
Embodiment 2
First prepare UV resin and isolation resin, mass fraction pressed by UV resin, by urethane acrylate 6 parts, epoxy acrylate 8 parts, polyester acrylate 42 parts, photo-sensitive monomer 14 parts, light trigger 4 parts, coloring pigment 22 parts, filler 4 parts.
Then, according to the following steps, a kind of method of false proof marble paper is printed:
(1), pattern-making: the pattern utilizing computer photograph three kinds of colors (red, blue, green).
(2), make film: according to the pattern of the different colours that step (1) makes, make the method for same film according to same color, make three films respectively;
(3), make printing screen version: make three printing screen plates, wherein, red, blue needs are gold stamping, green not needing is gold stamping;
(4), get dry commercially available water-soluble membranelle base stock printing and do not need gold stamping pattern; Adopt the screen printing plate made in step (3), use light water transfer ink, to gold stamping green pattern do not needed to be printed on base stock, republish the unlikely isolation resin come off of pattern on one deck protection base stock, described isolation resin be modified acroleic acid high molecular polymer;
(5), the first ink of gold stamping end upper: adopt the screen printing plate made in step (3), use UV resin, the pattern of redness is printed on the isolation resin side of membranelle base stock in step (4), UV ink;
(6), ink of the dry gold stamping end: optical curing of UV ink under Ultraviolet radiation, the solid speed of light can reach 4000/hour;
(7), transfer printing is gold stamping: utilize gilding press by the electrochemical aluminum foil with false proof word and security pattern at 140 DEG C, the pressure of four normal atmospheres is transferred on the UV ink that step (6) obtains;
(8), upper the second gold stamping end ink: adopt the screen printing plate made in step (3), use UV resin, the pattern of blueness is printed on base stock, UV ink;
(9), ink of the dry gold stamping end: optical curing of UV ink under Ultraviolet radiation, the solid speed of light can reach 4000/hour;
(10), transfer printing is gold stamping: utilize gilding press by the electrochemical aluminum foil with false proof word and security pattern at 130 DEG C, the pressure of three normal atmospheres is transferred on the UV ink that step (9) obtains;
(11), upper isolation gloss oil: after completing the printing of above-mentioned pattern, be coated with one deck gold stamping oil;
(12), dry isolation gloss oil: utilize UV-light photocuring machine to carry out photocuring drying, with the ultraviolet of 365nm wavelength, keep continue 4s hardening time.
(13), the tearable laminate cover of last layer: adopt the poly-tearable laminate cover of third ethene.
(14), dry tearable laminate cover.Adopt heat drying, temperature 35 DEG C, 3 hours time.
By above step, obtain the marble paper of two kinds of colors (red, blue, green) pattern.
Embodiment 3
First prepare UV resin and isolation resin, mass fraction pressed by UV resin, by urethane acrylate 7 parts, epoxy acrylate 7 parts, polyester acrylate 43 parts, photo-sensitive monomer 16 parts, light trigger 3 parts, coloring pigment 21 parts, filler 3 parts.
Then, according to the following steps, a kind of method of false proof marble paper is printed:
(1), pattern-making: the pattern utilizing computer photograph three kinds of colors (red, blue, green).
(2), make film: according to the pattern of the different colours that step (1) makes, make the method for same film according to same color, make three films respectively;
(3), make printing screen version: make three printing screen plates, wherein, red, blue needs are gold stamping, green not needing is gold stamping;
(4), get dry commercially available water-soluble membranelle base stock printing and do not need gold stamping pattern; Adopt the screen printing plate made in step (3), use light water transfer ink, to gold stamping green pattern do not needed to be printed on base stock, republish the unlikely isolation resin come off of pattern on one deck protection base stock, described isolation resin be modified acroleic acid high molecular polymer;
(5), the first ink of gold stamping end upper: adopt the screen printing plate made in step (3), use UV resin, the pattern of redness is printed on the isolation resin side of membranelle base stock in step (4), UV ink;
(6), ink of the dry gold stamping end: optical curing of UV ink under Ultraviolet radiation, the solid speed of light can reach 4000/hour;
(7), transfer printing is gold stamping: utilize gilding press by the electrochemical aluminum foil with security pattern at 120 DEG C, the pressure of four normal atmospheres is transferred on the UV ink that step (6) obtains;
(8), upper the second gold stamping end ink: adopt the screen printing plate made in step (3), use oil at the bottom of UV, the pattern of blueness is printed on base stock, UV ink;
(9), ink of the dry gold stamping end: optical curing of UV ink under Ultraviolet radiation, the solid speed of light can reach 4000/hour;
(10), transfer printing is gold stamping: utilize gilding press by the electrochemical aluminum foil with security pattern at 120 DEG C, the pressure of four normal atmospheres is transferred on the UV ink that step (9) obtains;
(11), upper isolation gloss oil: after completing the printing of above-mentioned pattern, be coated with one deck gold stamping oil;
(12), dry isolation gloss oil: utilize UV-light photocuring machine to carry out photocuring drying, with the ultraviolet of 365nm wavelength, keep continue 4s hardening time.
(13), the tearable laminate cover of last layer: adopt the poly-tearable laminate cover of third ethene.
(14), dry tearable laminate cover.Adopt heat drying, temperature 35 DEG C, 3 hours time.
By above step, obtain the marble paper of two kinds of colors (red, blue, green) pattern.
It should be noted that and the present invention includes but be not limited only to above-described embodiment.For wherein oil ratio example at the bottom of UV adjustment, gold stamping oily is selected, the change etc. of the alternation of signs of photo solidification machine type or false proof mode all belongs to protection scope of the present invention.
Claims (9)
1. a printing method for false proof marble paper, is characterized in that, this printing method comprises the steps:
(1), word and/or pattern is made;
(2), film is made: the word of the different colours made according to step (1) and/or pattern, make the method for same film, make film respectively according to same color;
(3), make printing screen version: according to the word of different colours and/or the film of design producing, make the method for same printing screen version according to same color, make printing screen version respectively;
(4) print non-gold stamping word and/or pattern: adopt the screen printing plate made in step (3), non-gold stamping word and/or pattern are printed on dry membranelle base stock;
(5), in the side being printed with non-gold stamping word and/or pattern of membranelle base stock print one deck isolation resin, described isolation resin comes off for preventing the word on membranelle base stock and/or pattern;
(6), ink of the upper gold stamping end: adopt the screen printing plate made in step (3), use UV resin, according to same color printing method once, respectively the pattern of different colours is printed on same membranelle base stock, UV ink, optical curing of UV ink under Ultraviolet radiation;
(7), the gold stamping word of transfer printing and/or pattern: according to the gold stamping word of different colours and/or the needs of pattern, according to same color printing method once, with gilding press by the electrochemical aluminum foil with false proof word and/or security pattern at 110 ~ 140 DEG C, the pressure of 3 ~ 4 normal atmospheres is transferred on the UV ink that step (6) obtains respectively;
(8), upper isolation gloss oil: after completing the printing of above-mentioned pattern, be coated with one deck isolation gold stamping oil;
(9), upper tearable laminate cover.
2. the printing method of a kind of false proof marble paper according to claim 1, it is characterized in that, described isolation resin is modified acroleic acid high molecular polymer, described modified acroleic acid high molecular polymer comprises four monomeric acrylic AA, methyl methacrylate MMA, butyl acrylate BA, hydroxypropyl acrylate HPA, also comprise initator benzoyl peroxide BPO, curing agent and solvent, the quality proportioning of four described monomers is MMA:BA:AA:HPA=37.5:37.5:12.5:12.5; The consumption of initator benzoyl peroxide BPO is 1.75% of four monomer gross masses, and the consumption of curing agent is 3% of four monomer gross masses; The mass ratio of the gross mass of described solvent and four monomers is 1:l, and solvent is the mixed liquor of n-butanol and water, and the mass ratio of n-butanol and water is 2:1;
The preparation process of isolation resin is as follows:
1), first in the reaction vessel being configured with agitator and reflux condensing tube, four monomeric acrylic AA, methyl methacrylate MMA, butyl acrylate BA, hydroxypropyl acrylate HPA, solvent and initator is accessed respectively, the addition of described acrylic acid AA, methyl methacrylate MMA, butyl acrylate BA, hydroxypropyl acrylate HPA be respectively its separately quality 1/3, the addition of solvent is 1/2 of its quality, the addition of initator is 1/4 of its quality, the addition of curing agent is 1/3 of its quality, start agitator and be warming up to 100 DEG C, reaction 15min;
2), in reaction vessel, continue the mixture dripping residual monomer and initator and curing agent, wherein the addition of initator is 1/2 of its quality, and the addition of curing agent is 1/3 of its quality, and time for adding is 3h, drips off rear continuation and stirs 0.5h;
3), in reaction vessel, remaining solvent, initator and curing agent is added again, continue stirring reaction 3h, be cooled to 40 ~ 50 DEG C, under agitation add ammoniacal liquor to the solution in reaction vessel and be neutralized to pH=8 ~ 9, continue reaction 0.5h, namely obtain this isolation resin.
3. the printing method of a kind of false proof marble paper according to claim 1, is characterized in that, the ultraviolet curing wavelength in step (6) is 300 ~ 420nm, and hardening time continues 2 ~ 6s.
4. the printing method of a kind of false proof marble paper according to claim 1, it is characterized in that, the proportioning of described UV resin is: urethane acrylate 5 ~ 8 parts, epoxy acrylate 6 ~ 10 parts, polyester acrylate 30 ~ 48 parts, photo-sensitive monomer 10 ~ 20 parts, light trigger 1 ~ 7 part, coloring pigment 20 ~ 22 parts, filler 1 ~ 4 part.
5. the printing method of a kind of false proof marble paper according to claim 1, it is characterized in that, described electrochemical aluminum foil is made up of successively base membrane layer, release layer, dyed layer, aluminium lamination, glue-line, described release layer is printed on base membrane layer by coating process, dyed layer is printed on release layer by coating process, described aluminium lamination is attached to dyed layer by aluminum plating process, false proof word and/or security pattern are printed on aluminium lamination and dyed layer by imprint process, and described glue-line is printed on aluminium lamination by coating process.
6. the printing method of a kind of false proof marble paper according to claim 1, is characterized in that, described curing agent is DETA.
7. the printing method of a kind of false proof marble paper according to claim 5, is characterized in that, described base membrane layer adopts biaxial stretching polyester film PET, and the thickness of described base membrane layer is 16 μm, and the gross thickness of described release layer, dyed layer, aluminium lamination three is 3 μm.
8. the printing method of a kind of false proof marble paper according to claim 1, is characterized in that, described tearable laminate cover is the poly-tearable laminate cover of third ethene.
9. the false proof marble paper prepared of claim 1 ~ 8 any one.
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