CN102922889A - Low-temperature bright golden decal and printing method thereof - Google Patents
Low-temperature bright golden decal and printing method thereof Download PDFInfo
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- CN102922889A CN102922889A CN2012104496524A CN201210449652A CN102922889A CN 102922889 A CN102922889 A CN 102922889A CN 2012104496524 A CN2012104496524 A CN 2012104496524A CN 201210449652 A CN201210449652 A CN 201210449652A CN 102922889 A CN102922889 A CN 102922889A
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Abstract
The invention discloses low-temperature bright golden decal and a printing method thereof. The printing method of the low-temperature bright golden decal successively includes the steps of making patterns, making a film, making a screen printing plate, varnishing golden base ink, transferring bright gold, drying the bright gold, and coating a covering glue film. The low-temperature bright golden decal prepared in the method can achieve low-temperature pasting. When the low-temperature bright golden decal obtained in the preparation method is pasted on a to-be-pasted object, 60-180 DEG C lower-temperature baking pasting is utilized, and energy is obviously saved; as the basking temperature of the low-temperature bright golden decal is low, the requirement of high-temperature resistance of the to-be-pasted object is not high, and the rejection rate of the to-be-pasted object is low; the low-temperature bright golden decal can be tightly attached to a glass surface, a ceramic surface, a paint surface, a metal surface and a plastic surface, and pasting firmness is achieved; production cost is obviously lowered; the low-temperature bright golden decal does not contain heavy metal harmful substances such as lead, cadmium and lithium, and is beneficial for environment protection and customer health; electrochemical aluminum foil of gap portions of the patterns can be recycled, and resources can be saved; and the covering glue film can utilize a polystyrene film which can be tore, and environmental pollution is prevented.
Description
Technical field
The present invention relates to a kind of printing method, specifically a kind of bright gold marble paper printing manufacture method.
Background technology
The bright gold marble paper has performance and the beautiful characteristics of color and luster such as intensity is large, high temperature resistant, rub resistance, and product is widely used on the products such as pottery, glass ornaments.
At present, the high temperature enamel firing process is adopted in the printing of known bright gold marble paper, and its main printing technology step is: computer photograph pattern → film processed → throwing half tone → with silk-screen plate gold paste (content 9%-15% take gold as main noble metal) is printed on a kind of water-soluble membranelle base stock → paint (leaded in the pigment, cadmium, lithium) → last layer gathers the not tearable laminate cover of the third ethene → dry up or naturally dries → bright gold marble paper product.
When using this bright gold marble paper, the normal operation method is: when being pasted on the products such as pottery, glass ornaments, water soaking marble paper 3-5 minute → after attached figuratum glued membrane separates with the water-soluble membranelle base stock → face glued membrane is attached on pottery or the glass surface → venting bubble → dry moisture content → high temperature decoration firing, the face glued membrane volatilizees through pyrolytic, gold paste on the pattern then fusible forms bright gold decorative pattern → finished product at pottery, glass surface.
The main weak point of the low temperature bright gold marble paper of this conventional method preparation comprises: the composition of (1) gold paste mainly is precious metals gold, and price is high, causes production cost, product price height; (2) pigment of this bright gold marble paper employing all contains the heavy metal harmful objects such as lead, cadmium, lithium, unfavorable consumer health; (3) noble metal that is not printed onto in the pattern interval in the gold paste on glass, the pottery can not reclaim, and causes the wasting of resources; (4) laminate cover is not tearable, and is namely not recycling, causes the wasting of resources; (5) energy-output ratio is large: gold paste needs high-temperature baking close attachment being attached on the thing (pottery, glass etc.), clear glass golden flower paper must toast in 520 °-580 ° kiln, pottery bright gold marble paper must toast in the kiln about 900 degree, in bake process, consume a large amount of electric ﹠ gas equal energy sources; (6) high temperature bright gold marble paper is because being subjected to temperature requirement, and using has limitation, can not use and do exquisite pattern decorative on the products such as metal, lucite, and high temperature causes easily that to be attached thing damaged and scrap simultaneously; (7) in high-temperature baking, the class materials such as poly-the third ethene in the laminate cover volatilize through pyrolytic, cause easily atmosphere pollution.
Summary of the invention
One of goal of the invention of the present invention is: for the problem of above-mentioned existence, provide a kind of can be under 60-180 ℃ condition the preparation method of the bright gold marble paper pasted of low-temperature bake.
The technical solution used in the present invention is such: a kind of low temperature bright gold marble paper printing method is characterized in that: may further comprise the steps successively:
(1), pattern-making;
(2), make film: the pattern of the different colours of making according to step (1), according to the method that same color is made same film, make respectively film;
(3), make the printing screen version: according to the film of the design producing of different colours, make the method for same printing screen version according to same color, make respectively the printing screen version;
(4), China ink at the bottom of the upper bright gold: the printing screen version that adopts step (3) to make, with oil of the gold stamping end, according to same color printing method once, the pattern with different colours is printed on the same base stock respectively, black at the bottom of the bright gold;
(5), the transfer printing bright gold: according to the needs of the bright gold pattern of different colours, according to same color printing method once, with laminating machine with electrochemical aluminum foil respectively transfer printing on China ink at the bottom of the bright gold that step (4) obtains;
(6), dry bright gold: behind each transfer printing bright gold, all carry out drying;
(7), be coated with laminate cover: after step (6) is processed, be coated with one deck laminate cover.
In the above-mentioned steps, according to actual conditions, to base stock before use, behind the transfer printing bright gold, all can suitably be dried to tack-free degree, effect can be better.
Method of the present invention is at first made respectively film and printing screen version for different colours, and adopt electrochemical aluminum foil to substitute the gold gold paste of traditional handicraft, and adopt specific method step to make up, so that the bright gold marble paper that makes can be pasted by low-temperature bake under 60-180 ℃ condition, performance can not only reach the performance of traditional handicraft, some performance even more excellent.
As preferably: in step (6) afterwards, print other pattern: other pattern that does not need bright gold, the printing screen version of making of step (3) is with the water transfer ink, and according to same color printing method once, other pattern with different colours is printed on the base stock respectively.
Further: after printing other pattern that does not need bright gold, all carry out drying at every turn.
As preferably: step (4) afterwards step (5) before China ink at the bottom of the bright gold is carried out drying.Can guarantee like this end China ink effect, be convenient to the carrying out of subsequent process steps, but also natural air drying, but can reduce production efficiency.
As preferably: in the step (5), laminating machine roller heating-up temperature is 40-150 ℃.Through experimental results demonstrate: temperature is lower than 40 ℃ and can not all electrochemical aluminum foil be transferred at the bottom of the bright gold on the China ink, just wastes energy and be higher than 150 ℃, and it is unnecessary to become, even can damage to some extent roller, end China ink etc.
As preferably: in step (7) before, on base stock, be coated with gold stamping oil of one deck as the protection gloss oil.Like this can be so that color more beautiful, more lasting.
Further: carry out drying after being coated with one deck protection gloss oil.
As preferably: laminate cover is tearable laminate cover in the step (7).Adopt tearable front cover glue, can cut the waste.
Further: described tearable laminate cover is the poly-tearable laminate cover of the third ethene.Adopt the laminate cover of poly-the third vinyl material, can prevent the pollution of the environment.
Two of purpose of the present invention provides the low temperature bright gold marble paper that a kind of said method is made.
In sum, owing to adopted technique scheme, the invention has the beneficial effects as follows: (1) adopts the bright gold marble paper of this method preparation, can realize the low temperature stickup, the low temperature bright gold stained paper pasting that this method obtains is on the thing that is stuck the time, adopt 60-180 ℃ of low-temperature bake to paste, significantly energy savings; Because bright gold marble paper baking temperature is low, the article heat-resisting quantity is less demanding to being stuck, and the scrappage of the article that are stuck is low.(2) purposes of low temperature bright gold marble paper product is more extensive: but close attachment on glass surface, ceramic plane, paint face, metal covering, plastic cover, firm pasting.(3) one-tenth of bright gold is grouped into by noble metals such as electrochemical aluminum foil replacement gold, and production cost is significantly reduced.(4) excellent performance of the bright gold marble paper that obtains of this method: adhesive capacity is strong, anti-hundred lattice test: ISO grade: 0, ASTM grade: 5B, and the edge of otch is fully smooth, and the grid edge is without any peeling off; Soaking-resistant: water soaking 10 hours, not fall, the performance of above-mentioned performance and traditional Huang Jinliang golden flower paper is suitable; And, anti-alcohol immersion: alcohol immersion 3 hours, nondiscolouring is not fallen, and the traditional Huang Jinliang golden flower paper of this Performance Ratio is more superior.(5) pigment composition in the China ink is epoxy resin and dyestuff etc. at the bottom of bright gold and the bright gold, does not contain the heavy metal harmful objects such as lead, cadmium, lithium, is conducive to environmental protection and consumer health.(6) electrochemical aluminum foil of pattern gap can economize on resources through recycling.(7) laminate cover preferably adopts tearable poly-the third vinyl film, both economizes on resources, and has avoided again causing environmental pollution.
The specific embodiment
Below the present invention is described in detail.
In order to make purpose of the present invention, technical scheme and advantage clearer, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, is not intended to limit the present invention.
Embodiment 1:
A kind of printing method of low temperature bright gold marble paper may further comprise the steps successively:
(1), pattern-making: the pattern of computer photograph red (a kind of color);
(2), film processed: according to the pattern of computer photograph, make a film;
(3), plate-making: make a printing screen version;
(4), get also dry base stock: temperature 40-48 ℃ of commercially available water-soluble membranelle base stock, drying time: 2 hours;
(5), China ink at the bottom of the upper bright gold: the printing screen version of making of step (3), and with oil of the gold stamping end, pattern is printed on the base stock after step (4) is processed, this oil of gold stamping end is that the gold stamping end of DR-is oily available from Shenzhen Dao Er chemistry painting industry Co., Ltd;
(6), China ink at the bottom of the dry bright gold: temperature 48-50 ℃, drying time: 1 hour;
(7), the transfer printing bright gold: with commercially available laminating machine with commercially available electrochemical aluminum foil transfer printing on China ink at the bottom of the dried bright gold of step (6), laminating machine cylinder heating-up temperature is 40 ℃;
(8), dry bright gold: temperature 35-40 ℃, drying time: 2.5 hours;
(9), upper protection gloss oil: be coated with gold stamping oil of one deck as the protection gloss oil, this gold stamping oil is gold stamping oil of DR-available from available from Shenzhen Dao Er chemistry painting industry Co., Ltd;
(10), dry-run protection gloss oil: temperature 25-28 ℃, drying time: 3 hours;
(11), upper tearable laminate cover: last layer gathers the tearable laminate cover of the third ethene.
(12), dry laminate cover: temperature 40-42 ℃, drying time: 1.2 hours, and get final product.
Embodiment 2
A kind of low temperature bright gold marble paper printing method may further comprise the steps successively:
(1), pattern-making: adopting three kinds of color patterns of computer photograph, is respectively green, blue and orange;
(2), film processed: according to the pattern of the different colours of computer photograph, according to the method that same color is made same film, make respectively three kinds of films;
(3), plate-making: according to the film of the pattern of different colours, make the method for same printing screen version according to same color, make respectively three printing screen versions.Wherein, two needs bright golds, one does not need bright gold;
(4), get also dry base stock: temperature 30-32 ℃ of commercially available water-soluble membranelle base stock, drying time: 2 hours;
(5), China ink at the bottom of upper the first bright gold: with first silk-screen plate that needs bright gold of step (3) step making, with oil of the gold stamping end, the pattern of the first color (green) is printed on the first base stock of step (4), this oil of gold stamping end is the two components of EP-17 oil of the gold stamping end available from Shenzhen Dao Er chemistry painting industry Co., Ltd;
(6), China ink of the dry end: temperature 20-21 ℃, drying time: 4.5 hours;
(7), transfer printing the first bright gold: according to the needs of the bright gold pattern of the first color, with laminating machine with commercially available electrochemical aluminum foil transfer printing on China ink at the bottom of the dried bright gold of step (6), laminating machine cylinder heating-up temperature is 150 ℃;
(8), dry the first bright gold: temperature 15-16 ℃, drying time: 4.5 hours;
(9), China ink at the bottom of upper the second bright gold: oily with the gold stamping end with second silk-screen plate that needs bright gold that step (3) is made, the pattern of the second color (blueness) is printed on the base stock of step (4); This oil of gold stamping end is available from Shunde District, Foshan City seal color printing brush Science and Technology Ltd., and the gold stamping end of product YC-220 by name is oily;
(10), China ink at the bottom of dry the second: temperature 32-35 ℃, drying time: 3.2 hours;
(11), transfer printing the second bright gold: according to the needs of the bright gold pattern of the second color, with laminating machine with the electrochemical aluminum foil transfer printing on China ink at the bottom of the dried the second bright gold of step (10), laminating machine cylinder heating-up temperature is 100 ℃;
(12), dry the second bright gold: temperature 48-50 ℃, drying time: 1 hour;
(13), print the pattern of the third color (orange), this pattern does not need bright gold: with the 3rd silk-screen plate that does not need bright gold of step (3) making, with commercially available light water transfer ink, will not need the pattern of the third color (orange) of bright gold to be printed on the base stock of step (4).
(14), dry the third pattern printing ink: temperature 32-35 ℃, drying time: 3.2 hours;
(15), upper protection gloss oil: after finishing whole pattern printings, be coated with gold stamping the oil of one deck embodiment 1 as the protection gloss oil, this gold stamping oil is two gold stamping the oil of component of PU-available from available from Shenzhen Dao Er chemistry painting industry Co., Ltd;
(16), dry-run protection gloss oil: temperature 36-28 ℃, drying time: 2.8 hours;
(17), the poly-tearable laminate cover of the third ethene of upper tearable laminate cover: last layer embodiment 1;
(18), dry laminate cover: the poly-tearable laminate cover of the third ethene of drying steps (17), and get final product.
Embodiment 3
A kind of printing method of low temperature bright gold marble paper may further comprise the steps successively:
Step (9), the step (10) of cancellation embodiment 1, all the other steps are identical with embodiment 1.
Embodiment 4
A kind of printing method of low temperature bright gold marble paper may further comprise the steps successively:
Step (15), the step (16) of cancellation embodiment 2, all the other steps are identical with embodiment 2.
Embodiment 5
Temperature is 15-16 ℃ when dry base stock, end China ink and bright gold, is 5 hours drying time, and all the other steps are identical with embodiment 1.
Embodiment 6
Temperature is 48-50 ℃ when dry base stock, end China ink and bright gold, is 1 hour drying time, and all the other steps are identical with embodiment 2.
Embodiment 7
Temperature is 35-36 ℃ when dry base stock, end China ink and bright gold, is 3 hours drying time, and all the other steps are identical with embodiment 2.
Claims (10)
1. low temperature bright gold marble paper printing method is characterized in that: may further comprise the steps successively:
(1), pattern-making;
(2), make film: the pattern of the different colours of making according to step (1), according to the method that same color is made same film, make respectively film;
(3), make the printing screen version: according to the film of the design producing of different colours, make the method for same printing screen version according to same color, make respectively the printing screen version;
(4), China ink at the bottom of the upper bright gold: the printing screen version that adopts step (3) to make, with oil of the gold stamping end, according to same color printing method once, the pattern with different colours is printed on the same base stock respectively, black at the bottom of the bright gold;
(5), the transfer printing bright gold: according to the needs of the bright gold pattern of different colours, according to same color printing method once, with laminating machine with electrochemical aluminum foil respectively transfer printing on China ink at the bottom of the bright gold that step (4) obtains;
(6), dry bright gold: behind each transfer printing bright gold, all carry out drying;
(7), be coated with laminate cover: after step (6) is processed, be coated with one deck laminate cover.
2. a kind of low temperature bright gold marble paper printing method according to claim 1 is characterized in that: step (4) afterwards step (5) before China ink at the bottom of the bright gold is carried out drying
3. a kind of low temperature bright gold marble paper printing method according to claim 1 is characterized in that:
In the step (5), laminating machine roller heating-up temperature is 40-150 ℃.
4. a kind of low temperature bright gold marble paper printing method according to claim 1, it is characterized in that: in step (6) afterwards, print other pattern: other pattern that does not need bright gold, the printing screen version of making of step (3) is with the water transfer ink, according to same color printing method once, other pattern with different colours is printed on the base stock respectively.
5. a kind of low temperature bright gold marble paper printing method according to claim 4 is characterized in that: after printing other pattern that does not need bright gold, all carry out drying at every turn.
6. a kind of low temperature bright gold marble paper printing method according to claim 1 is characterized in that: after finishing whole pattern printings, be coated with gold stamping oil of one deck.
7. a kind of low temperature bright gold marble paper printing method according to claim 6 is characterized in that: carry out drying after being coated with gold stamping oil of one deck.
8. a kind of low temperature bright gold marble paper printing method according to claim 1, it is characterized in that: in the step (7), laminate cover is tearable laminate cover.
9. a kind of low temperature bright gold marble paper printing method according to claim 8 is characterized in that: described tearable laminate cover is the poly-tearable laminate cover of the third ethene.
10. the low temperature bright gold marble paper of claim 1-9 any one preparation.
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Address after: 646300 Luzhou City, Sichuan province Zhejiang Naxi District Industrial Park B District Lanan Avenue three Xingye Road Patentee after: Luzhou Jin Xin Science and Technology Ltd. Address before: 646300 Luzhou City, Sichuan province Zhejiang Naxi District Industrial Park B District Lanan Avenue three Xingye Road Patentee before: Luzhou Jinxin Printing Co., Ltd. |