CN101318420A - Heat-transferring die, manufacturing process and heat-transferring manufacturing process - Google Patents

Heat-transferring die, manufacturing process and heat-transferring manufacturing process Download PDF

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Publication number
CN101318420A
CN101318420A CNA200710108907XA CN200710108907A CN101318420A CN 101318420 A CN101318420 A CN 101318420A CN A200710108907X A CNA200710108907X A CN A200710108907XA CN 200710108907 A CN200710108907 A CN 200710108907A CN 101318420 A CN101318420 A CN 101318420A
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high temperature
heat transfer
printing
transfer printing
land
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CNA200710108907XA
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白洪城
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Abstract

A thermal transfer film which can carry out continuous thermal transfer in a large area directly forms a single-color or colorful printing pattern with excellent layer film structure intensity on the transferred surfaces of various metal, glass or ceramic substances. The manufacturing technique of the thermal transfer film includes that printing is carried out a whole volume of continuous plastic film material or paper material the surface of which comprises a release layer with the ink of a high temperature-resistance dye by a gravure printer to generate the ink layer of the high temperature-resistance dye; the layer of a high temperature-resistance thermal reaction hot melt adhesive is coated on the surface of the ink layer of the high temperature-resistance dye. The thermal transfer steps include: a. the steps of degreasing, dust removing, purifying of the transferred surface of a substance; b. the step of fictitiously fixing: the thermal transfer film comprising the ink of the high temperature-resistance dye and the layer of the high temperature-resistance thermal reaction hot melt adhesive are taken to carry out thermal transfer on the transferred surface of the step a to lead the ink layer of the high temperature-resistance dye and the layer of the high temperature-resistance thermal reaction hot melt adhesive to be fictitiously fixed on the transferred surface; c. the step of roasting for leading the ink of the high temperature-resistance dye and the layer of the high temperature-resistance thermal reaction hot melt adhesive to be firmly combined with the transferred surface.

Description

A kind of heat transfer film and manufacturing process thereof and hot transfer printing manufacturing process
Technical field
The present invention relates to a kind of heat transfer film and manufacturing process and hot transfer printing manufacturing process of doing large tracts of land, Continuous Heat transfer printing, it is that a kind of printing equipment that utilizes is printed on a high-temperature resisting pigment printing ink in the successional heat transfer film of whole volume, and utilize hot transfer apparatus to make the vacation of high-temperature resisting pigment printing ink be fixed in the transfer surface that is subjected on the article, utilize roasting plant that high-temperature resisting pigment printing ink is combined securely with the transfer surface that is subjected to of article at last.
Background technology
Utilize printing equipment produce fast and in large area on non-absorbent surface such as various metals, glass or pottery color gorgeous, drill literal or the pattern that look accurate and resolution is high, still belong to a research and development target that can't realize at present.
Single just at present known several printing processes and the present invention are relatively, lithographic printing is useful in general stationery or smooth monolithic tinplate sheet surface printing, but inapplicable article surface printing at sheet metal that is package, overlength, block or that contain curved surface surface or other strip.
Screen painting can directly be printed in the metal surface of curved surface, and drying is handled and formed again.But shortcoming is to print the figure of small size, and every seal is of the same colour will wait it to parch, and of the same colour under the wire mark again after parching, the concentration of its printing ink can change at any time because of the solvent evaporation, and the printing quality instability be arranged, and speed reaches cost of labor slowly and crosses high shortcoming.
Ink-jet printing apparatus is applicable to a small amount of various printing, but the cost of equipment costliness, employed be water soluble dyestuffs mostly, this kind water soluble dyestuffs fades soon, can't be sprayed directly on to the non-absorbent material surface of metal or glass.The pattern sophistication of printing is poor, the site is big, usually only is fit to far away the sight and is not suitable for myopia.Especially the speed of spray printing is slow, can't reach the volume production requirement.
Non-direct method of printing, the at present known metal surface PVC film that has is decorated alternative methods such as (PVC DecorateFilm Fastened on Metal Sheet Surfaces), water transfer printing (Water Transfer Printing) manufacturing process, thermal dye sublimation transfer printing (Thermal Dye Sublimation printing) and hot transfer printing (HeatTransfer-Printing) manufacturing process.
Pasting PVC film decorative metal thin plate, to be subject to the PVC film strength not good, being not suitable for further machine-shaping again after finishing, and becomes defective work otherwise the decorative pattern on the PVC film might be damaged by mould.In addition, PVC can produce dioxin when incinerating, and the human or animal sucks the excessive carcinogenic worry that has, and national governments begin forbidding one after another at present.
Water transfer printing manufacturing process must be subjected to the metal of transfer printing, ceramic surface to spray priming paint earlier, otherwise removal ink is difficult for adhering to fully in the transfer printing.Need wash, dry after the transfer printing, spray protective paint beginning announcement at last and finish.The water transfer printing is suitable for whole only dapple pattern transfer, only is not suitable for containing literal in the pattern of institute's transfer printing, otherwise the literal in the pattern distortion can occur and make us being difficult to accepting.In addition, the bake out temperature of water transfer printing operation can not be too high, and drying time often needs 2 to 3 hours, and is so not only consuming time but also expend the energy.
Thermal dye sublimation transfer printing must carry out powder body coating or baking vanish in the transfer surface that is subjected to of metal, pottery earlier, could carry out thermal dye sublimation transfer printing to it then.Shortcoming is, heat-transferring printing paper and be subjected between the transfer surface then the image resolution ratio at this place immediately eye-catching difference can take place, to become defective work just in case there is a place not to be adjacent to.In addition, the thermal dye sublimation transfer printing color changes very responsive to transfer printing temperature, time, the poor of every minute and second arranged slightly, promptly causes the difference on the color.
Heat-transferring method is applied to various ABS, PP, plastics, timber at present, product surfaces such as coating metal is arranged.Its principle is in advance multicolour pattern to be imprinted on (by release processing) on the resistant substrates film, cooperate special-purpose transfer apparatus again, be transferred to the surface of product with the method for thermoprint, the closely cooperating of caloric transfer printing technology consistent, good material prescription of fine qualities and equipment.
Yet hot transfer printing is applied in metal, glass, and the nonabsorbable surface of pottery etc., must smear interface agent, resin or other coating in advance, just can make printing ink set stably.Present heat transfer film is to adopt wire mark to make, pattern area is little, be applied in clothes, cloth matter bag, cap, boudoir, mug, porcelain dish, ceramic tile, watch case, mouse pad, plate mat, hanging year calendar, medal, silk banner, work board, doorplate, mirror case, metal wine pot ... still can Deng commodity, but if will be applied to large stretch of building materials, the for example transfer printing of colored unrestrained plate, big glass sheets or monoblock ceramic tile etc., technical still remaining broken through.
Summary of the invention
The technical problem to be solved in the present invention is to break through the restriction of known technology, a kind of heat transfer film and the manufacturing process that can directly do large tracts of land, Continuous Heat transfer printing at various metals, glass or ceramic articles is provided, and enabling not, limit for length's degree ground directly forms the good printed patterns of tunic structural strength at article surface straight or curved surface.
For solving the problems of the technologies described above, the present invention proposes a kind of heat transfer film of doing large tracts of land, Continuous Heat transfer printing, comprising: the high temperature resistance diaphragm of mould release coating is contained on a surface, contains a high temperature resistance diaphragm and a mould release coating; One high temperature resistant printing ink layer is connected in the one side of this mould release coating; And a high temperature heat-resistant reaction type hot-fusible glue-line, be connected on this high temperature resistant printing ink layer.
The invention allows for a kind of heat transfer film manufacturing process of doing large tracts of land, Continuous Heat transfer printing, it comprises: a preparation process, prepare the high temperature resistance diaphragm that the mould release coating is contained on a surface, and make it contain a high temperature resistance diaphragm and a mould release coating at least; One print steps utilizes the surface printing one high temperature resistant printing ink layer of a printing equipment in this mould release coating; And an application step, utilize a coating apparatus to be coated with a high temperature heat-resistant reaction type hot-fusible glue on this high temperature resistant printing ink layer, thereby on this high temperature resistant printing ink layer, form a high temperature heat-resistant reaction type hot-fusible glue-line.
The present invention has proposed a kind of hot transfer printing manufacturing process of doing large tracts of land, Continuous Heat transfer printing again, and it comprises: a. degrease, dust removal step purify the transfer surface that is subjected to of a transfer printing thing; B. false fixing step, take a heat transfer film that contains a high temperature resistant printing ink layer and a high temperature heat-resistant reaction type hot-fusible glue-line, utilize a hot roller rolling to make this high temperature resistant printing ink layer be able to be fixed in the transfer surface that is subjected to of transfer printing thing by this high temperature heat-resistant reaction type hot-fusible glue-line vacation; C. baking procedure utilizes a roasting plant to toast, and makes this high temperature resistant printing ink layer and high temperature heat-resistant reaction type hot-fusible glue-line be fused to the transfer surface that is subjected to of this transfer printing thing.
Therefore, among the present invention, its heat transfer film can be directly directly forms good monochrome of tunic structural strength or colored printing pattern at the transfer surface that is subjected to of various metals, glass or ceramic articles.The manufacturing process of its heat transfer film, be to contain on the continuity plastic foil material of shape layer or paper wood on a whole volume surface to utilize intaglio printing or other printing equipment to print continuously with high-temperature resisting pigment printing ink, produce a monochromatic or colored high-temperature resisting pigment ink lay, and be coated with a high temperature heat-resistant reaction type hot-fusible glue-line on the surface of high-temperature resisting pigment ink lay.Its hot transfer printing step comprises: a. degrease, dust removal step, in order to purify the transfer surface that is subjected to of article; B. false fixing step, take a heat transfer film that contains a high-temperature resisting pigment printing ink and a high temperature heat-resistant reaction type hot-fusible glue-line, the transfer surface that is subjected to the article of a step is implemented hot transfer printing, makes high-temperature resisting pigment ink lay and high temperature heat-resistant reaction type hot-fusible glue-line in that be able to by transfer surface earlier false fixing; C. baking procedure makes high-temperature resisting pigment ink lay and high temperature heat-resistant reaction type hot-fusible glue-line be able to combine securely with the transfer surface that is subjected to of article.
Description of drawings
Fig. 1 is heat transfer film of the present invention and heat transfer film manufacturing process embodiment schematic diagram.
Fig. 2 is heat transfer film of the present invention and heat transfer film manufacturing process variations embodiment schematic diagram.
Fig. 3 is a hot transformation of ownership fabrication technique embodiment schematic diagram of the present invention.
Description of reference numerals:
1: the high temperature resistance diaphragm of mould release coating is contained on the surface
2: printing equipment 3: coating apparatus
10: high temperature resistance diaphragm 11: the mould release coating
12: roasting plant 15: coating apparatus
20: high temperature resistant printing ink layer 30: high temperature heat-resistant reaction type hot-fusible glue
40: heat transfer film 41: blank film
50: heat transfer film 60: the transfer printing thing
61: finished product 70: roasting plant
150: the thermostable transparent glue-line
The specific embodiment
Heat transfer film of the present invention 40 structures and manufacturing technology steps embodiment schematic diagram as Fig. 1 illustrates comprise:
1. preparation process prepares the high temperature resistance diaphragm 1 that contains the mould release coating in a surface, makes it contain a high temperature resistance diaphragm 10 and a mould release coating 11 at least;
2. print steps utilizes the surface printing one high temperature resistant printing ink layer 20 of a printing equipment 2 in mould release coating 10; And
3. application step is utilized a coating apparatus 3 coatings one high temperature heat-resistant reaction type hot-fusible glue 30 on high temperature resistant printing ink layer 20, thereby form a high temperature heat-resistant reaction type hot-fusible glue-line on high temperature resistant printing ink layer 20.
By above step, volume production goes out the heat transfer film 40 of large tracts of land, infinite in length apace.Wherein the described high temperature resistance diaphragm 1 that contains the mould release coating of step 1 can be a release liners, also can be a PET mould release membrance, provides step 2 printing in the mode of package.
The printing equipment 2 of step 2 can be the printing equipment of general letterpress, flexible board printing machine or intaglio press and so on, with continuous literal, image or the pattern that prints limited or endless of high temperature resistant printing ink, print off monochrome or colored high temperature resistant printing ink layer 20 on the surface of mould release coating 10.Meet the seal amount big, when requiring printing quality exquisite, can select intaglio press for use because the printing ink expressive force of intaglio printing is strong, tone is abundant, and the ink lay that is printed off is thick far beyond general relief printing plate or lithographic plate also.Selecting the order ground of high-temperature resisting pigment printing ink for use, is to make the high temperature resistant printing ink layer 20 of hot transfer printing can not change color through high-temperature baking; The preferably can select for use high temperature resistant hold concurrently can anti-ultraviolet high temperature resistant printing ink, and the color of transfer printing product also can prolongedly not taken off in the stronger environment of light.
The high temperature heat-resistant reaction type hot-fusible glue 30 of step 3 can be selected a high temperature-resistant polymer thermal-reactive PUR for use.Selecting the order ground of high temperature heat-resistant reaction type hot-fusible glue for use, is in order to allow glue-line pass through high-temperature bakings, to decide behind article surface with high temperature resistant printing ink layer 20, be easy to keep stable physical property in general normal temperature temperature.
Please refer to heat transfer film of the present invention 40 structures that Fig. 2 illustrates and the alternate embodiment schematic diagram of manufacturing technology steps, comprising:
1. preparation process prepares the high temperature resistance diaphragm 1 that contains the mould release coating in a surface, makes it contain a high temperature resistance diaphragm 10 and a mould release coating 11;
2. application step utilizes a coating apparatus 15 that a thermostable transparent glue is coated mould release coating 11 surfaces, utilizes a roasting plant 12 that thermostable transparent glue is dried then and constitutes a thermostable transparent glue-line 150;
3. print steps utilizes a printing equipment 2 printings one high temperature resistant printing ink layer 20 in thermostable transparent glue-line 150 surfaces; And
4. application step utilizes a coating apparatus 3 coatings one high temperature heat-resistant reaction type hot-fusible glue 30 on this high temperature resistant printing ink layer 20.
By above step, volume production goes out large tracts of land, infinite in length and has the heat transfer film 50 of protective layer fast.The so-called protection layer is to constitute by the thermostable transparent glue-line 150 that the coating of present embodiment step 2 produces.The thermostable transparent glue-line 150 of step 2 is dried after can adopting general high-strength transparence UV glue or the coating of high temperature heat-resistant reaction-type transparent glue, becomes the protective layer of high temperature resistant printing ink layer 20 after the transfer printing.
Heat transfer film 40 of the present invention can be selected the utilization in the mode of package, and the embodiment of its hot transfer step such as Fig. 3 illustrates, comprising:
A. degrease, dust removal step purify the transfer surface that is subjected to of a transfer printing thing 60;
B. false fixing step, take containing of a package high temperature resistant printing ink the layer 20 and heat transfer film 40 of a high temperature heat-resistant reaction type hot-fusible glue-line 30, utilize hot roller to implement hot transfer printing on the surface of transfer printing thing 60, simultaneously the blank film after the transfer printing 41 (high temperature resistance diaphragm 10 and parting agent layer 11) is synchronously batched recovery with 200 ℃~250 ℃ temperature.Thus, can implement hot transfer printing, make high temperature resistant printing ink layer 20 be able to be fixed in the transfer surface that is subjected to of transfer printing thing 60 by 30 vacations of high temperature heat-resistant reaction type hot-fusible glue-line to transfer printing things such as metal, glass or pottery 60 surfaces continuous, no length restriction;
C. baking procedure, utilize a roasting plant 70 with 150 ℃~250 ℃ bakings 5 minutes~10 minutes, what make that high temperature resistant printing ink layer 20 and high temperature heat-resistant reaction type hot-fusible glue-line 30 be fused to transfer printing thing 60 is subjected to the transfer printing table, form that a density is good, firm, weatherability is good, attractive in appearance and wear-resisting finished product 61.If transfer printing thing 60 is sheet metals of package, but the transfer surface that is subjected to of this step has more advantages such as anti-bending, Reshapable processing and package.
Heat transfer film provided by the present invention and manufacturing process when comparing with other known technology, have following advantage:
1. use hot transfer printing pad pasting of the present invention, the article that have the nonabsorbable surface at metal, glass and pottery etc. do not need powder body coating or baking vanish, get final product the direct heat transfer printing, hot transfer printing is after overbaking, the common hard tunic that constitutes of high temperature resistant printing ink and High-temp.-resistant hot-melt adhesive, can combine with being subjected to transfer surface securely, produce the advantage of wear-resisting, weather-proof and anti-bending.
2. traditional heat transfer film and transfer printing operation only are conceived to operate transfer printing operation artificial, small size; and heat transfer film of the present invention and manufacturing process; energy revolutionaryly carries out transfer printing processing to the large-area metal thin slice of package; produce on its surface be beautifully printed, the protective layer of limit for length's degree not, be that at present any known skill institute can not.
3. range of application of the present invention can reach in hot transfer printing various metallic plates, stick, sheet, package and molded product surface.No matter be iron, aluminium, zinc, copper, galvanized iron, magnesium alloy, aluminium alloy, almag or titanium alloy etc., be suitable for all.
More than describing in detail is specifying of providing at preferred embodiment of the present invention, only this embodiment is not in order to limit claim of the present invention, allly do not break away from equivalence that skill spirit of the present invention does and implement or change, all should be contained in the claim of this case.

Claims (17)

1. the heat transfer film that can do large tracts of land, Continuous Heat transfer printing is characterized in that, comprising:
The high temperature resistance diaphragm of mould release coating is contained on one surface, contains a high temperature resistance diaphragm and a mould release coating;
One high temperature resistant printing ink layer is connected in the one side of this mould release coating; And
One high temperature heat-resistant reaction type hot-fusible glue-line is connected on this high temperature resistant printing ink layer.
2. can make the heat transfer film of large tracts of land, Continuous Heat transfer printing according to claim 1, it is characterized in that, the high temperature resistance diaphragm that the mould release coating is contained on this surface is a release liners.
3. can make the heat transfer film of large tracts of land, Continuous Heat transfer printing according to claim 1, it is characterized in that, the high temperature resistance diaphragm that the mould release coating is contained on this surface is a PET mould release membrance.
4. can make the heat transfer film of large tracts of land, Continuous Heat transfer printing according to claim 1, it is characterized in that, still be connected a thermostable transparent glue-line between this is high temperature resistant printing ink layer and this mould release coating.
5. as making the heat transfer film of large tracts of land, Continuous Heat transfer printing as described in the claim 4, it is characterized in that this thermostable transparent glue-line is that transparent UV glue or a high temperature heat-resistant reaction-type transparent glue form.
6. the heat transfer film manufacturing process that can do large tracts of land, Continuous Heat transfer printing is characterized in that, comprising:
One preparation process prepares the high temperature resistance diaphragm that the mould release coating is contained on a surface, makes it contain a high temperature resistance diaphragm and a mould release coating at least;
One print steps utilizes the surface printing one high temperature resistant printing ink layer of a printing equipment in this mould release coating; And
One application step utilizes a coating apparatus to be coated with a high temperature heat-resistant reaction type hot-fusible glue on this high temperature resistant printing ink layer, thereby forms a high temperature heat-resistant reaction type hot-fusible glue-line on this high temperature resistant printing ink layer.
7. as making the heat transfer film manufacturing process of large tracts of land, Continuous Heat transfer printing as described in the claim 6, it is characterized in that the high temperature resistance diaphragm that the mould release coating is contained on the prepared surface of this preparation process is a release liners.
8. as making the heat transfer film manufacturing process of large tracts of land, Continuous Heat transfer printing as described in the claim 6, it is characterized in that the high temperature resistance diaphragm that the mould release coating is contained on the prepared surface of this preparation process is a PET mould release membrance.
9. as making the heat transfer film manufacturing process of large tracts of land, Continuous Heat transfer printing as described in the claim 6, it is characterized in that, after this preparation process, before this print steps, still comprise an application step, coating one thermostable transparent glue and constitute a thermostable transparent glue-line on this mould release coating.
10. as making the heat transfer film manufacturing process of large tracts of land, Continuous Heat transfer printing as described in the claim 9, it is characterized in that this thermostable transparent glue-line is by being coated with a transparent UV glue or a high temperature heat-resistant reaction-type transparent glue forms.
11. as making the heat transfer film manufacturing process of large tracts of land, Continuous Heat transfer printing as described in the claim 9, it is characterized in that, this printing equipment be selected from a letterpress, a flexible board printing machine or an intaglio press one of them.
12. the hot transfer printing manufacturing process that can do large tracts of land, Continuous Heat transfer printing is characterized in that, comprising:
A. degrease, dust removal step purify the transfer surface that is subjected to of a transfer printing thing;
B. false fixing step, take a heat transfer film that contains a high temperature resistant printing ink layer and a high temperature heat-resistant reaction type hot-fusible glue-line, utilize a hot roller rolling to make this high temperature resistant printing ink layer be able to be fixed in the transfer surface that is subjected to of transfer printing thing by this high temperature heat-resistant reaction type hot-fusible glue-line vacation;
C. baking procedure utilizes a roasting plant to toast, and makes this high temperature resistant printing ink layer and high temperature heat-resistant reaction type hot-fusible glue-line be fused to the transfer surface that is subjected to of this transfer printing thing.
13., it is characterized in that this transfer printing thing is a sheet metal as making the hot transfer printing manufacturing process of large tracts of land, Continuous Heat transfer printing as described in the claim 12.
14., it is characterized in that this transfer printing thing is a glass plate as making the hot transfer printing manufacturing process of large tracts of land, Continuous Heat transfer printing as described in the claim 12.
15., it is characterized in that this transfer printing thing is a ceramic wafer as making the hot transfer printing manufacturing process of large tracts of land, Continuous Heat transfer printing as described in the claim 12.
16., it is characterized in that this baking procedure is to toast 5 minutes to 10 minutes with 150 ℃ to 250 ℃ as making the hot transfer printing manufacturing process of large tracts of land, Continuous Heat transfer printing as described in the claim 12.
17., it is characterized in that this heat transfer film is that the mode with package provides as making the hot transfer printing manufacturing process of large tracts of land, Continuous Heat transfer printing as described in the claim 12.
CNA200710108907XA 2007-06-04 2007-06-04 Heat-transferring die, manufacturing process and heat-transferring manufacturing process Pending CN101318420A (en)

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WO2011003249A1 (en) 2009-07-06 2011-01-13 珠海东诚光固化材料有限公司 Ultraviolet curing transfer film, manufacturing method therefor and application thereof
CN102092228A (en) * 2010-12-30 2011-06-15 叶逸仁 Preparation method of hot-laminated membrane with peripheral lines
CN102145606A (en) * 2010-02-10 2011-08-10 林骏煌 Heat transfer printing method for optical reading point printing and printing structure
CN102267300A (en) * 2011-06-17 2011-12-07 郑国义 Method for preparing microdot anti-counterfeiting films
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CN101746171B (en) * 2008-12-17 2012-01-25 锣洋科技股份有限公司 Anti-abrasion transfer-printing framework
WO2011003249A1 (en) 2009-07-06 2011-01-13 珠海东诚光固化材料有限公司 Ultraviolet curing transfer film, manufacturing method therefor and application thereof
CN102145606A (en) * 2010-02-10 2011-08-10 林骏煌 Heat transfer printing method for optical reading point printing and printing structure
CN102145606B (en) * 2010-02-10 2013-09-18 林骏煌 Heat transfer printing method for optical reading point printing and printing structure
CN102310674A (en) * 2010-07-01 2012-01-11 锣洋科技股份有限公司 Decoration film, decoration device, and method for manufacturing decoration device
CN102092228A (en) * 2010-12-30 2011-06-15 叶逸仁 Preparation method of hot-laminated membrane with peripheral lines
CN102092228B (en) * 2010-12-30 2013-04-17 叶逸仁 Preparation method of hot-laminated membrane with peripheral lines
CN102267300A (en) * 2011-06-17 2011-12-07 郑国义 Method for preparing microdot anti-counterfeiting films
CN102501670A (en) * 2011-11-15 2012-06-20 黎田建 Environmentally-friendly hot transfer film and finished product thereof
CN103158385A (en) * 2011-12-19 2013-06-19 江阴市天顺彩印有限公司 Fluorescence film for heat transfer printing on glass surface or ceramic surface and preparation method thereof
CN103419538B (en) * 2013-07-23 2016-12-28 霍浩麟 A kind of PET polyester transfer film is transferred to the production technology of sheet metal
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CN105034561A (en) * 2014-04-15 2015-11-11 Cict株式会社 Glass thermal transferring apparatus for display device and method thereof
CN104077959B (en) * 2014-05-23 2017-08-01 晋江市深沪键升印刷有限公司 A kind of Ke's formula thermal transfer trademark, moulding process and former
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CN105479962A (en) * 2014-09-19 2016-04-13 丹阳市华兴纸箱有限公司 Manufacturing process for heat transfer film
CN105966098A (en) * 2016-05-16 2016-09-28 Tcl移动通信科技(宁波)有限公司 Electronic product shell and processing method for forming colorful concave-convex patterns on electronic product shell
CN106183515A (en) * 2016-07-11 2016-12-07 鹏码实业(上海)有限公司 A kind of heat transfer colour ribbon for metal material and preparation method thereof
CN106891635A (en) * 2017-01-18 2017-06-27 深圳市恒久瑞电子科技有限公司 A kind of transfer processing method of surrounding curved surface 3D cover plates
CN106891635B (en) * 2017-01-18 2019-03-05 深圳市恒久瑞电子科技有限公司 A kind of transfer processing method of surrounding curved surface 3D cover board
CN106827849A (en) * 2017-01-19 2017-06-13 厦门东正彩印刷有限公司 A kind of thermal transfer for glass or ceramic surface inorganic pigment picture and text film
CN109677146A (en) * 2017-10-18 2019-04-26 王铭贤 Heat transfer film manufacturing method and heat transfer film
CN108277668B (en) * 2018-01-02 2021-04-16 上海态镀贸易有限公司 Dinner plate printing method
CN108277668A (en) * 2018-01-02 2018-07-13 上海态镀贸易有限公司 A kind of service plate printing method
CN108454251A (en) * 2018-01-02 2018-08-28 上海态镀贸易有限公司 A kind of mug printing method
CN108034384A (en) * 2018-01-31 2018-05-15 上海宏盾防伪材料有限公司 A kind of transferable heatproof flame-retardant shielding layer film and preparation method thereof
CN109823030A (en) * 2018-12-30 2019-05-31 深圳博华仕科技有限公司 A kind of micro-fluidic chip print makes system and print makes method
CN109774329A (en) * 2019-03-11 2019-05-21 江苏天顺印业有限公司 A kind of method and device making illusion-colour grating heat transfer film
CN110370831A (en) * 2019-07-10 2019-10-25 深圳市杰瑞表面技术有限公司 A method of nanometer film layer is transferred on glass
CN114312092A (en) * 2021-12-30 2022-04-12 湖南鼎一致远科技发展有限公司 Thermal printing method suitable for multiple media
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CN116704874A (en) * 2023-08-07 2023-09-05 山东新华医疗器械股份有限公司 Chemical indicator and preparation method thereof
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