CN100480343C - Ultraviolet light curable ink - Google Patents
Ultraviolet light curable ink Download PDFInfo
- Publication number
- CN100480343C CN100480343C CN 200410027270 CN200410027270A CN100480343C CN 100480343 C CN100480343 C CN 100480343C CN 200410027270 CN200410027270 CN 200410027270 CN 200410027270 A CN200410027270 A CN 200410027270A CN 100480343 C CN100480343 C CN 100480343C
- Authority
- CN
- China
- Prior art keywords
- curable ink
- percentage composition
- quality percentage
- resin
- tripropylene glycol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 35
- 239000011347 resin Substances 0.000 claims description 27
- 229920005989 resin Polymers 0.000 claims description 27
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 12
- 239000013530 defoamer Substances 0.000 claims description 11
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical group C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 9
- 239000000178 monomer Substances 0.000 claims description 8
- GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical class OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 claims description 7
- 230000001235 sensitizing effect Effects 0.000 claims description 6
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 claims description 5
- UGVRJVHOJNYEHR-UHFFFAOYSA-N 4-chlorobenzophenone Chemical compound C1=CC(Cl)=CC=C1C(=O)C1=CC=CC=C1 UGVRJVHOJNYEHR-UHFFFAOYSA-N 0.000 claims description 5
- NQSMEZJWJJVYOI-UHFFFAOYSA-N Methyl 2-benzoylbenzoate Chemical compound COC(=O)C1=CC=CC=C1C(=O)C1=CC=CC=C1 NQSMEZJWJJVYOI-UHFFFAOYSA-N 0.000 claims description 5
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical group C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 5
- 150000002576 ketones Chemical class 0.000 claims description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 3
- HCQHIEGYGGJLJU-UHFFFAOYSA-N didecyl hexanedioate Chemical compound CCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCC HCQHIEGYGGJLJU-UHFFFAOYSA-N 0.000 claims description 3
- 230000032050 esterification Effects 0.000 claims description 3
- 238000005886 esterification reaction Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical class OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 3
- 150000003512 tertiary amines Chemical class 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 2
- 238000007639 printing Methods 0.000 abstract description 13
- 238000007650 screen-printing Methods 0.000 abstract description 12
- 241000533950 Leucojum Species 0.000 abstract description 6
- 230000005855 radiation Effects 0.000 abstract description 3
- 241001125020 Geomys bursarius Species 0.000 abstract 1
- 239000003814 drug Substances 0.000 abstract 1
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 238000007493 shaping process Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 21
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 15
- 239000010936 titanium Substances 0.000 description 15
- 229910052719 titanium Inorganic materials 0.000 description 15
- 235000019504 cigarettes Nutrition 0.000 description 10
- 238000012856 packing Methods 0.000 description 9
- 239000012752 auxiliary agent Substances 0.000 description 7
- 230000037303 wrinkles Effects 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 235000015256 Chionanthus virginicus Nutrition 0.000 description 3
- 241000234283 Galanthus nivalis Species 0.000 description 3
- ZDHCZVWCTKTBRY-UHFFFAOYSA-N omega-Hydroxydodecanoic acid Natural products OCCCCCCCCCCCC(O)=O ZDHCZVWCTKTBRY-UHFFFAOYSA-N 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- VEOIIOUWYNGYDA-UHFFFAOYSA-N 2-[2-(6-aminopurin-9-yl)ethoxy]ethylphosphonic acid Chemical compound NC1=NC=NC2=C1N=CN2CCOCCP(O)(O)=O VEOIIOUWYNGYDA-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920006146 polyetheresteramide block copolymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
Abstract
The invention is a kind of ultraviolet radiation solidify printing ink., the quality percentage of the of the invention as follow: the first kind of ultraviolet solidify printing ink is 20%-30%, the second kind of ultraviolet solidify printing ink is 20%-38%, acrylate resin is 8%-30%, active thinner is 5%-30%, medicament causing light is 4%-32. the invention can be used widely in the top packaging and can form thin goffer such as shaping snowflake pattern felt unshaped. Under the sun, it can flash the light, besides, the invention has good ability of clinging and rigid. Used in silk screen printing, shined under the ultraviolet radiation, the invention. Invention name.
Description
[technical field]
The invention relates to a kind of printing ink, especially about a kind of UV curable ink that is used for silk screen printing.
[background technology]
The ornamental printing of at present imitative metal etch etc. substantially all is to adopt silk screen print method, mainly uses in a large number in packings such as cigarette, wine, makeup, healthcare products.The UV curable ink that is used for silk screen printing is various in style, and still, the performance of the printing ink of prior art is single, and decorative effect is also single, generally can only print off the pattern of Shamian Island effect.UV-light silk screen printing crepe printing ink needs to use earlier low pressure mercury lamp, carry out after-sun curing with medium pressure mercury lamp again and could produce wrinkle, its radiation condition slightly changes, the pattern of the wrinkle that produces has significant difference, for this reason, the homogeneity of printing is relatively poor, complex process, and the pattern texture of formation is comparatively coarse.
[summary of the invention]
The present invention is intended to solve that above-mentioned UV curable ink performance is single, and decorative effect is also single, forms that the pattern quality is relatively poor, the problem of complex process.
For addressing the above problem, the invention provides a kind of UV curable ink, it comprises that the quality percentage composition is first kind of UV-cured resin of 25%-30%, the quality percentage composition is second kind of UV-cured resin of 20%-38%, the quality percentage composition is the acrylate resin of 8%-20%, the quality percentage composition is the reactive thinner of 5%-30%, the quality percentage composition is the light trigger of 4%-32%, wherein said first kind of UV-cured resin is that base monomer is the resin and 1 of Propenoic acid, 2-methyl, isobutyl ester, the mixture of 6-hexanediyl ester, described second kind of UV-cured resin is ketone resin, the mixture of 1,6 hexanediol diacrylate and tripropylene glycol diacrylate.
Described base monomer is that the resin of Propenoic acid, 2-methyl, isobutyl ester is that 1:1 mixes with 1,6 hexanediol diacrylate by mass ratio.
Described ketone resin, the mixing quality of 1,6 hexanediol diacrylate and tripropylene glycol diacrylate is than being 1:0.5:0.5.
This UV curable ink also contains photosensitive sensitizing agent, and its quality percentage composition is 9%-20%.
Photosensitive sensitizing agent is a Viscoat 295 esterification tertiary amine.
Reactive thinner is a tripropylene glycol diacrylate, ethoxylated trimethylolpropane triacrylate, Viscoat 295, didecyl adipate, 1,6 hexanediol diacrylate, or ethoxylated neopentylglycol double methacrylate, or the mixture of aforementioned substances.
Reactive thinner is tripropylene glycol diacrylate or ethoxylated trimethylolpropane triacrylate or the mixture of the two, and the quality percentage composition of tripropylene glycol diacrylate or ethoxylated trimethylolpropane triacrylate respectively is 5%-15%.
Light trigger is 1-hydroxyl-cyclohexyl-phenyl ketone, methyl o-benzoylbenzoate, or 4-chlorobenzophenone, or its mixture, described 1-hydroxyl-cyclohexyl-phenyl ketone, methyl o-benzoylbenzoate, or the quality percentage composition of 4-chlorobenzophenone respectively is 4%-8%.
This UV curable ink also contains flow agent or defoamer, and the quality percentage composition of described flow agent or defoamer respectively is 0.5%-1.5%.
Compare with the UV curable ink of prior art, UV curable ink of the present invention can be widely used in high-grade packing aspect, can form superfine wrinkle effect, have a snowflake pattern of the effect of superfine frosted again, under the irradiation of sunlight, reflection refractive power effect is arranged, and its sticking power and folding resistance are all good.And printing ink of the present invention is applied to silk screen printing, but once shaped behind ultra violet lamp do not need to add miscellaneous equipment in addition, technology is easy.
[embodiment]
UV curable ink of the present invention, each component title and quality percentage composition thereof are in its prescription:
First kind of UV-cured resin 25%-35%
Second kind of UV-cured resin 20%-38%
Pure acrylic acid acid resin 8%-20%
Reactive thinner 5%-30%
Light trigger 4%-32%
Photosensitive sensitizing agent 9%-20%
Flow agent 0.5%-1.5%
Defoamer 0.5%-1.5%
Other auxiliary agent
First kind of UV-cured resin wherein, be called resin UV-09, its production technique is: with the DEGALANPQ611 of Romo Co.,Ltd's production, its base monomer is a Propenoic acid, 2-methyl, isobutyl ester, with UV (ultraviolet light polymerization) monomer HDDA, its chemical name is a 1,6 hexanediol diacrylate, forms than mixed dissolution with the quality of 1:1.
Second kind of UV-cured resin, be called resin UV-010, its blending process is: use ketone resin, as: L2-HARZ (Ketonharz) or L2-RESIN (Ketone-Formaldehyde-Resin), produce by German LEUNA-Harze company, with UV monomer HDDA (1,6 hexanediol diacrylate) and monomer TPGDA, its chemical name is a tripropylene glycol diacrylate, forms than mixed dissolution with the quality of 1:0.5:0.5.
Pure acrylic acid ester resin is EB750, the EB745 etc. that the 6530-B40 that produces of Changxing, Taiwan company or Belgian EB company produce.
The thinner of reactive thinner for participating in reacting.Commonly used have TPGDA (chemical name is a tripropylene glycol diacrylate), TMPTA (chemical name is a Viscoat 295), DDA (chemical name is a didecyl adipate), HDDA (chemical name is a 1,6 hexanediol diacrylate), PEEA, EO-TMPTA (chemical name is an ethoxylated trimethylolpropane triacrylate), PO-TMPTA (chemical name is propenoxylated Viscoat 295), GPTA, a PO-NPGDA (chemical name is the ethoxylated neopentylglycol double methacrylate) etc.Preferred use TPGDA (tripropylene glycol diacrylate), or EO-TMPTA (ethoxylated trimethylolpropane triacrylate), each 5%-15% (weight).
Light trigger can be 1104,1056 and 1046, and its chemical name is respectively 1-hydroxyl-cyclohexyl-phenyl ketone, methyl o-benzoylbenzoate, and 4-chlorobenzophenone, its quality percentage composition respectively are 4%-8%.
Photosensitive sensitizing agent is P115, and its main component is a Viscoat 295 esterification tertiary amine.Be by Viscoat 295 and diethylamine by certain mass ratio, reaction 2-6 hour under 30-80 ℃ temperature and making.
For improving ink performance, add flow agent, defoamer, also can add other auxiliary agent, be beneficial to improve the stability, formability of printing ink etc., as stopper, smooth agent, dispersion agent etc., also can add various pigment, be beneficial to form the pattern of various colors.
Printing ink of the present invention is mainly used the silk screen printing moulding.By silk screen printing in decorated surface, on the packing as cigarette, wine, makeup etc., with conveying belt the ultraviolet lamp that this combination with decorative surfaces transmits by 80W/cm is shone more than one or one, but just once shaped in this way, and at this combination with decorative surfaces formation snowflake pattern.Adjust the transmission speed of conveying belt, can form different snowflake patterns.
Embodiment is as follows:
Example one
The prescription of UV curable ink and quality percentage composition are as follows:
UV-09 self-control 25%
UV-010 self-control 20%
6530-B40 Taiwan Changxing company produces 8%
TPGDA Sartomer company produces 5%
EO-TMPTA Sartomer company produces 5%
1056 Chang Zhouhua titanium companies produce 4%
1046 Chang Zhouhua titanium companies produce 4%
1104 Chang Zhouhua titanium companies produce 4%
P115 self-control 9%
Add flow agent or defoamer each 0.5%, and other auxiliary agent in right amount, by this prescription each components dissolved is mixed, be printed in the surface of Cigarette case by silk screen printing, and be 80W/cm with certain transfer rate via a power the ultra violet lamp utmost point short period of time by conveying belt, so, on the packing box surface of cigarette just once shaped have a pattern of even snowflower effect, formed pattern has superfine wrinkle effect and superfine frosted finish effect simultaneously, under the irradiation of sunlight, reflection refractive power effect is arranged, and its sticking power and folding resistance are all good.
Example two
The prescription of UV curable ink and quality percentage composition are as follows:
UV-09 self-control 30%
UV-010 self-control 29%
6530-B40 Taiwan Changxing company produces 14%
TPGDA Sartomer company produces 10%
EO-TMPTA Sartomer company produces 10%
1056 Chang Zhouhua titanium companies produce 4%
1046 Chang Zhouhua titanium companies produce 4%
1104 Chang Zhouhua titanium companies produce 4%
P115 self-control 9%
Add flow agent or defoamer each 1.0%, and other auxiliary agent in right amount, by this prescription each components dissolved is mixed, be printed in the surface of Cigarette case by silk screen printing, and be 80W/cm with certain transfer rate via two power the ultra violet lamp utmost point short period of time by conveying belt, so, on the packing box surface of cigarette just once shaped have a pattern of even snowflower effect, formed pattern has superfine wrinkle effect and superfine frosted finish effect simultaneously, under the irradiation of sunlight, reflection refractive power effect is arranged, and its sticking power and folding resistance are all good.
Example three
The prescription of UV curable ink and quality percentage composition are as follows:
UV-09 self-control 35%
UV-010 self-control 38%
6530-B40 Taiwan Changxing company produces 20%
TPGDA Sartomer company produces 15%
EO-TMPTA Sartomer company produces 15%
1056 Chang Zhouhua titanium companies produce 4%
1046 Chang Zhouhua titanium companies produce 4%
1104 Chang Zhouhua titanium companies produce 4%
P115 self-control 9%
Add flow agent or defoamer each 1.5%, and other auxiliary agent in right amount, by this prescription each components dissolved is mixed, be printed in the surface of Cigarette case by silk screen printing, and be 80W/cm with certain transfer rate via three power the ultra violet lamp utmost point short period of time by conveying belt, so, on the packing box surface of cigarette just once shaped have a pattern of even snowflower effect, formed pattern has superfine wrinkle effect and superfine frosted finish effect simultaneously, under the irradiation of sunlight, reflection refractive power effect is arranged, and its sticking power and folding resistance are all good.
Example four
The prescription of UV curable ink and quality percentage composition are as follows:
UV-09 self-control 30%
UV-010 self-control 30%
EB750 Belgium EB company produces 15%
TPGDA Sartomer company produces 10%
EO-TMPTA Sartomer company produces 10%
1056 Chang Zhouhua titanium companies produce 4%
1046 Chang Zhouhua titanium companies produce 4%
1104 Chang Zhouhua titanium companies produce 4%
P115 system 9%
Add flow agent or defoamer each 0.5%, and other auxiliary agent in right amount, by this prescription each components dissolved is mixed, be printed in the surface of Cigarette case by silk screen printing, and be 80W/cm with certain transfer rate via two power the ultra violet lamp utmost point short period of time by conveying belt, can form the snowflake pattern on the packing box surface equally, its sticking power and folding resistance are all good.
Example five
The prescription of UV curable ink and quality percentage composition are as follows:
UV-09 self-control 30%
UV-010 self-control 30%
EB745 Belgium EB company produces 15%
TPGDA Sartomer company produces 10%
EO-TMPTA Sartomer company produces 10%
1056 Chang Zhouhua titanium companies produce 4%
1046 Chang Zhouhua titanium companies produce 4%
1104 Chang Zhouhua titanium companies produce 4%
P115 self-control 9%
Add flow agent or defoamer each 0.5%, and other auxiliary agent in right amount, by this prescription each components dissolved is mixed, be printed in the surface of Cigarette case by silk screen printing, and be 80W/cm with certain transfer rate via two power the ultra violet lamp utmost point short period of time by conveying belt, can form the snowflake pattern on the packing box surface equally, its sticking power and folding resistance are all good.
In above-mentioned prescription, add various pigment, can form the pattern of various colors.
Printing ink of the present invention is widely applicable for high-grade packing aspect, the surface not only had superfine wrinkle effect but also Effect with superfine frosted under the irradiation of sunlight, has reflection refractive power effect, its adhesive force and folding Property is all good. And printing ink of the present invention is applied to serigraphy, is the uviol lamp of 80W/cm at power Irradiation is lower, but one-shot forming, simple process.
Claims (9)
1. UV curable ink, it comprises that the quality percentage composition is first kind of UV-cured resin of 25%-30%, the quality percentage composition is second kind of UV-cured resin of 20%-38%, the quality percentage composition is the acrylate resin of 8%-20%, the quality percentage composition is the reactive thinner of 5%-30%, the quality percentage composition is the light trigger of 4%-32%, wherein said first kind of UV-cured resin is that base monomer is the resin and 1 of Propenoic acid, 2-methyl, isobutyl ester, the mixture of 6-hexanediyl ester, described second kind of UV-cured resin is ketone resin, the mixture of 1,6 hexanediol diacrylate and tripropylene glycol diacrylate.
2. UV curable ink as claimed in claim 1 is characterized in that: described base monomer is that resin and the 1,6 hexanediol diacrylate of Propenoic acid, 2-methyl, isobutyl ester is to mix at 1: 1 by mass ratio.
3. UV curable ink as claimed in claim 1 is characterized in that: described ketone resin, the mixing quality ratio of 1,6 hexanediol diacrylate and tripropylene glycol diacrylate is 1: 0.5: 0.5.
4. UV curable ink as claimed in claim 1 is characterized in that: this UV curable ink also contains photosensitive sensitizing agent, and its quality percentage composition is 9%-20%.
5. UV curable ink as claimed in claim 4 is characterized in that: described photosensitive sensitizing agent is a Viscoat 295 esterification tertiary amine.
6. UV curable ink as claimed in claim 1, it is characterized in that: described reactive thinner is a tripropylene glycol diacrylate, ethoxylated trimethylolpropane triacrylate, Viscoat 295, didecyl adipate, 1,6 hexanediol diacrylate, or ethoxylated neopentylglycol double methacrylate, or the mixture of aforementioned substances.
7. UV curable ink as claimed in claim 6, it is characterized in that: described reactive thinner is tripropylene glycol diacrylate or ethoxylated trimethylolpropane triacrylate or the mixture of the two, and the quality percentage composition of tripropylene glycol diacrylate or ethoxylated trimethylolpropane triacrylate respectively is 5%-15%.
8. UV curable ink as claimed in claim 1, it is characterized in that: described light trigger is 1-hydroxyl-cyclohexyl-phenyl ketone, methyl o-benzoylbenzoate, or 4-chlorobenzophenone, or its mixture, described 1-hydroxyl-cyclohexyl-phenyl ketone, methyl o-benzoylbenzoate, or the quality percentage composition of 4-chlorobenzophenone respectively is 4%-8%.
9. UV curable ink as claimed in claim 1 is characterized in that: this UV curable ink also contains flow agent or defoamer, and the quality percentage composition of described flow agent or defoamer respectively is 0.5%-1.5%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410027270 CN100480343C (en) | 2004-05-17 | 2004-05-17 | Ultraviolet light curable ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410027270 CN100480343C (en) | 2004-05-17 | 2004-05-17 | Ultraviolet light curable ink |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1580149A CN1580149A (en) | 2005-02-16 |
| CN100480343C true CN100480343C (en) | 2009-04-22 |
Family
ID=34582029
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410027270 Expired - Fee Related CN100480343C (en) | 2004-05-17 | 2004-05-17 | Ultraviolet light curable ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100480343C (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1959530B (en) * | 2006-11-24 | 2010-05-12 | 中国乐凯胶片集团公司 | Ultraviolet light solidified coating in use for post processing of imaging material |
| CN101805541B (en) * | 2010-04-09 | 2013-04-17 | 上海化工研究院 | Ultraviolet curing ink and production method thereof |
| CN101921541B (en) * | 2010-09-27 | 2012-02-08 | 杭州中富彩新材料科技有限公司 | Preparation method of water-based UV gloss oil |
| CN101922129B (en) * | 2010-09-29 | 2012-01-04 | 杭州中富彩新材料科技有限公司 | Preparation method of paper printing environmental-friendly UV (Ultraviolet) gloss oil |
| CN102729587B (en) * | 2011-04-02 | 2015-10-14 | 深圳劲嘉彩印集团股份有限公司 | Gravure printing apparatus, gravure process and packing box |
| CN102774222A (en) * | 2011-05-10 | 2012-11-14 | 上海协承昌化工有限公司 | Forming process for pattern layer on surface of aluminum-plastic substrate |
| CN102286230B (en) * | 2011-09-15 | 2013-10-09 | 哈尔滨大东方新材料科技股份有限公司 | Ultraviolet curable ink and preparation method thereof |
| WO2013054317A1 (en) * | 2011-10-09 | 2013-04-18 | Hewlett-Packard Industrial Printing Ltd. | Photo-curable ink composition |
| CN102555561B (en) * | 2011-12-26 | 2013-03-06 | 湖北中信京华彩印股份有限公司 | Method for printing cigarette packet snowflake patterns by using improved intaglio printing press |
| CN102555565B (en) * | 2011-12-30 | 2013-12-11 | 深圳市柏星龙创意包装股份有限公司 | High-gloss three-dimensional gilding method |
| CN102643576B (en) * | 2012-04-27 | 2013-07-03 | 武汉虹之彩包装印刷有限公司 | Ultraviolet light cured silk screen snowflake printing ink and preparation method thereof |
| CN103978795B (en) * | 2014-04-14 | 2016-06-01 | 东莞当纳利印刷有限公司 | A kind of silk print frost flower technique |
| CN106634180A (en) * | 2016-12-22 | 2017-05-10 | 天津环球磁卡股份有限公司 | Thick film light-cured resin ink |
| CN108165086A (en) * | 2018-02-05 | 2018-06-15 | 浙江美浓材料科技有限公司 | A kind of gravure snowflake printing ink and preparation method thereof |
| CN112898818A (en) * | 2021-03-30 | 2021-06-04 | 惠州市至上新材料有限公司 | UV wrinkle printing ink capable of forming lines in two ways and preparation method and application thereof |
-
2004
- 2004-05-17 CN CN 200410027270 patent/CN100480343C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1580149A (en) | 2005-02-16 |
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