CN104736506B - 环烷烃氧化催化剂以及生产醇和酮的方法 - Google Patents

环烷烃氧化催化剂以及生产醇和酮的方法 Download PDF

Info

Publication number
CN104736506B
CN104736506B CN201280074884.4A CN201280074884A CN104736506B CN 104736506 B CN104736506 B CN 104736506B CN 201280074884 A CN201280074884 A CN 201280074884A CN 104736506 B CN104736506 B CN 104736506B
Authority
CN
China
Prior art keywords
hydroperoxide
oxygen
hydroperoxides
reaction
cycloalkane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201280074884.4A
Other languages
English (en)
Chinese (zh)
Other versions
CN104736506A (zh
Inventor
F.德坎波
W.周
P.吴
K.薛
Y.刘
M.何
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
East China Normal University
Polyamide High Performance GmbH
École Normale Supérieure de Lyon
Original Assignee
East China Normal University
École Normale Supérieure de Lyon
Rhodia Operations SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by East China Normal University, École Normale Supérieure de Lyon, Rhodia Operations SAS filed Critical East China Normal University
Publication of CN104736506A publication Critical patent/CN104736506A/zh
Application granted granted Critical
Publication of CN104736506B publication Critical patent/CN104736506B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/385—Saturated compounds containing a keto group being part of a ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
    • C07C27/10—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons
    • C07C27/16—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons with other oxidising agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C35/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201280074884.4A 2012-07-26 2012-07-26 环烷烃氧化催化剂以及生产醇和酮的方法 Expired - Fee Related CN104736506B (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2012/079172 WO2014015491A1 (en) 2012-07-26 2012-07-26 Cycloalkane oxidation catalysts and method to produce alcohols and ketones

Publications (2)

Publication Number Publication Date
CN104736506A CN104736506A (zh) 2015-06-24
CN104736506B true CN104736506B (zh) 2017-04-12

Family

ID=49996500

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280074884.4A Expired - Fee Related CN104736506B (zh) 2012-07-26 2012-07-26 环烷烃氧化催化剂以及生产醇和酮的方法

Country Status (11)

Country Link
US (1) US9708238B2 (cg-RX-API-DMAC7.html)
EP (1) EP2877439B1 (cg-RX-API-DMAC7.html)
JP (1) JP6068638B2 (cg-RX-API-DMAC7.html)
KR (1) KR101953948B1 (cg-RX-API-DMAC7.html)
CN (1) CN104736506B (cg-RX-API-DMAC7.html)
BR (1) BR112015001573B1 (cg-RX-API-DMAC7.html)
IN (1) IN2015DN00388A (cg-RX-API-DMAC7.html)
RU (1) RU2583055C1 (cg-RX-API-DMAC7.html)
SG (1) SG11201500522VA (cg-RX-API-DMAC7.html)
UA (1) UA111907C2 (cg-RX-API-DMAC7.html)
WO (1) WO2014015491A1 (cg-RX-API-DMAC7.html)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2707291C2 (ru) * 2014-12-22 2019-11-26 Родиа Операсьон Катализаторы окисления циклоалканов и способ получения спиртов и кетонов
EP3746418A1 (en) 2018-01-30 2020-12-09 Basf Se Method for oxidation of cycloalkanes

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002028774A2 (en) * 2000-09-29 2002-04-11 Showa Denko K. K. Crystalline mww-type titanosilicate , its preparation and use thereof for producing epoxides
CN101039892A (zh) * 2004-08-17 2007-09-19 索罗蒂亚公司 环烷烃氧化和环烷基氢过氧化物分解的催化剂
CN101733164A (zh) * 2009-12-21 2010-06-16 中国科学院长春应用化学研究所 用于环己烷液相催化氧化制备环己醇和环己酮的催化体系和用法
CN102079695A (zh) * 2009-11-27 2011-06-01 中国石油化工股份有限公司 一种催化氧化环己烷的方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL9201756A (nl) 1992-10-09 1994-05-02 Univ Delft Tech Werkwijze voor de gekatalyseerde ontleding van organische hydroperoxiden.
US6548718B2 (en) * 2000-04-27 2003-04-15 Shell Oil Company Process for catalytic hydroxylation of, saturated or unsaturated, aliphatic compounds
US20040034258A1 (en) * 2000-09-29 2004-02-19 Showa Denko K.K. Crystalline MWW-type titanosilicate catalyst for producing oxidized compound, production process for the catalyst, and process for producing oxidized compound by using the catalyst
US20040158103A1 (en) 2003-02-11 2004-08-12 Solutia Inc. Cyclohexane oxidation catalysts
CA2590668C (en) * 2004-12-28 2015-11-17 Neste Oil Oyj Catalytic materials and method for the preparation thereof
US7868201B2 (en) 2005-07-01 2011-01-11 Exxonmobil Research And Engineering Company Process and catalyst for oxidation of hydrocarbons
JP2010159245A (ja) * 2008-09-19 2010-07-22 Sumitomo Chemical Co Ltd 酸化化合物の製造方法
JP2010138032A (ja) * 2008-12-11 2010-06-24 Sumitomo Chemical Co Ltd チタノシリケートの製造方法
CN102452895B (zh) * 2010-10-29 2015-03-18 中国石油化工股份有限公司 一种含锡钛硅分子筛催化环烷烃的方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002028774A2 (en) * 2000-09-29 2002-04-11 Showa Denko K. K. Crystalline mww-type titanosilicate , its preparation and use thereof for producing epoxides
CN101039892A (zh) * 2004-08-17 2007-09-19 索罗蒂亚公司 环烷烃氧化和环烷基氢过氧化物分解的催化剂
CN102079695A (zh) * 2009-11-27 2011-06-01 中国石油化工股份有限公司 一种催化氧化环己烷的方法
CN101733164A (zh) * 2009-12-21 2010-06-16 中国科学院长春应用化学研究所 用于环己烷液相催化氧化制备环己醇和环己酮的催化体系和用法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Unique trans-Selectivity of Ti-MWW in Epoxidation of cis/trans-alkenes with Hydrogen Peroxide;Peng Wu et al.;《J.Phys.Chem》;20020103;第106卷(第4期);第748-753页 *

Also Published As

Publication number Publication date
KR101953948B1 (ko) 2019-03-04
RU2583055C1 (ru) 2016-05-10
BR112015001573B1 (pt) 2020-10-27
WO2014015491A1 (en) 2014-01-30
US20150175514A1 (en) 2015-06-25
EP2877439A1 (en) 2015-06-03
CN104736506A (zh) 2015-06-24
KR20150065654A (ko) 2015-06-15
JP6068638B2 (ja) 2017-01-25
BR112015001573A2 (pt) 2017-08-01
JP2015528805A (ja) 2015-10-01
SG11201500522VA (en) 2015-04-29
IN2015DN00388A (cg-RX-API-DMAC7.html) 2015-06-12
EP2877439B1 (en) 2018-02-14
UA111907C2 (uk) 2016-06-24
US9708238B2 (en) 2017-07-18
EP2877439A4 (en) 2016-03-16

Similar Documents

Publication Publication Date Title
US6759540B2 (en) Crystalline MWW-type titanosilicate catalyst for producing oxidized compound, production process for the catalyst, and process for producing oxidized compound by using the catalyst
CA2140863C (en) Catalysts and their use in oxidation of saturated hydrocarbons
JP4851998B2 (ja) チタノシリケートの製造方法およびオキシムの製造方法
US7038069B2 (en) Process for oxidizing carbon-carbon double bond and process for producing oxidized compounds
JP4938558B2 (ja) チタノシリケートの製造方法およびオキシムの製造方法
WO2018128959A1 (en) A process for the preparation of adipic acid
JP2019073523A (ja) シクロアルカンの酸化触媒並びにアルコール及びケトンの製造方法
JP4977836B2 (ja) シクロアルカン類の酸化およびシクロアルキルヒドロパーオキシドの分解のための触媒
US9708238B2 (en) Cycloalkane oxidation catalysts and method to produce alcohols and ketones
JP2010138032A (ja) チタノシリケートの製造方法
CN107118125A (zh) 一种环己酮肟的制备方法
WO2018128960A1 (en) A process for the preparation of adipic acid
JP4522672B2 (ja) 環状脂肪族オキシムの製造法
JP4577003B2 (ja) オキシムの製造方法
JP4069608B2 (ja) 炭素−炭素二重結合の酸化方法及び該酸化方法を用いた酸化化合物の製造方法
JP4783071B2 (ja) オキシムの製造方法
US20040034258A1 (en) Crystalline MWW-type titanosilicate catalyst for producing oxidized compound, production process for the catalyst, and process for producing oxidized compound by using the catalyst
JP4035611B2 (ja) シクロオクテンオキサイドの製造方法
JP7711066B2 (ja) シクロヘキサノール及びシクロヘキサノンを製造する方法
JP2012214441A (ja) オキシムの製造方法
JP2000026439A (ja) プロピレンオキサイドの製造方法
JPH10251177A (ja) シクロヘキサノールの製造方法
JP2012214440A (ja) オキシムの製造方法
JP2000026387A (ja) シクロヘキサノンオキシムの製造方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20200728

Address after: Paris France

Co-patentee after: ECOLE NORMALE SUPERIEURE DE LYON

Patentee after: POLYAMIDE HIGH PERFORMANCE GmbH

Co-patentee after: EAST CHINA NORMAL University

Address before: Paris France

Co-patentee before: ECOLE NORMALE SUPERIEURE DE LYON

Patentee before: RHODIA OPERATIONS

Co-patentee before: EAST CHINA NORMAL University

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20170412