CN104718249B - 具有低ocs凝胶指数的薄膜 - Google Patents

具有低ocs凝胶指数的薄膜 Download PDF

Info

Publication number
CN104718249B
CN104718249B CN201380037223.9A CN201380037223A CN104718249B CN 104718249 B CN104718249 B CN 104718249B CN 201380037223 A CN201380037223 A CN 201380037223A CN 104718249 B CN104718249 B CN 104718249B
Authority
CN
China
Prior art keywords
polypropylene
range
melt
linear
melt strength
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201380037223.9A
Other languages
English (en)
Chinese (zh)
Other versions
CN104718249A (zh
Inventor
卡佳·克里姆克
赫尔曼·布劳恩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Borealis GmbH
Original Assignee
Borealis GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis GmbH filed Critical Borealis GmbH
Publication of CN104718249A publication Critical patent/CN104718249A/zh
Application granted granted Critical
Publication of CN104718249B publication Critical patent/CN104718249B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/52—Polymerisation initiated by wave energy or particle radiation by electric discharge, e.g. voltolisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/54—Polymerisation initiated by wave energy or particle radiation by X-rays or electrons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2351/06—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L2023/40—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds changing molecular weight
    • C08L2023/42—Depolymerisation, vis-breaking or degradation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/07—Long chain branching

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN201380037223.9A 2012-07-25 2013-07-19 具有低ocs凝胶指数的薄膜 Active CN104718249B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12177878 2012-07-25
EP12177878.1 2012-07-25
PCT/EP2013/065263 WO2014016206A1 (en) 2012-07-25 2013-07-19 Film with low ocs gel index

Publications (2)

Publication Number Publication Date
CN104718249A CN104718249A (zh) 2015-06-17
CN104718249B true CN104718249B (zh) 2017-03-29

Family

ID=48803558

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380037223.9A Active CN104718249B (zh) 2012-07-25 2013-07-19 具有低ocs凝胶指数的薄膜

Country Status (11)

Country Link
US (1) US9376549B2 (enExample)
EP (1) EP2877535B1 (enExample)
JP (1) JP5986314B2 (enExample)
KR (1) KR101531814B1 (enExample)
CN (1) CN104718249B (enExample)
BR (1) BR112015000853A2 (enExample)
CA (1) CA2878305C (enExample)
ES (1) ES2626363T3 (enExample)
IN (1) IN2014DN10848A (enExample)
MX (1) MX366376B (enExample)
WO (1) WO2014016206A1 (enExample)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2877534B1 (en) * 2012-07-25 2017-05-10 Borealis AG Foam produced from polypropylene with low gel content
ES2574437T3 (es) * 2013-06-05 2016-06-17 Borealis Ag Producción en una etapa de una composición de polipropileno
EP3018154B1 (en) 2014-11-05 2019-01-09 Borealis AG Long-chain branched polypropylene for film application
ES2724243T3 (es) 2014-11-05 2019-09-09 Borealis Ag Polipropileno ramificado de cadena larga para aplicación de espuma
EP3018155A1 (en) * 2014-11-05 2016-05-11 Borealis AG Branched polypropylene for film applications
TWI616463B (zh) * 2015-02-04 2018-03-01 Borealis Ag 於擠壓機中製備經改質烯烴聚合物之方法
CN107428884B (zh) * 2015-04-10 2020-11-13 博里利斯股份公司 用于将烯烃聚合物与反应物混合的方法
US20180126697A1 (en) 2015-08-13 2018-05-10 Exxonmobil Chemical Patents Inc. Multi-Layered Sheets Comprising a High Melt Strength Polypropylene
KR102112981B1 (ko) * 2015-10-21 2020-05-21 보레알리스 아게 용융 강도 안정성이 증가한 장쇄 분지형 폴리프로필렌 조성물
EP3450489B1 (en) * 2016-08-18 2024-10-09 Japan Polypropylene Corporation Microporous film comprising a polypropylene resin composition
EP3333221B1 (en) 2016-12-09 2021-03-17 Borealis AG Polypropylene composition for foaming applications
EP3562873B1 (en) * 2016-12-30 2023-09-06 Borealis AG Low emission polypropylene foam sheets
WO2018147944A1 (en) * 2017-02-07 2018-08-16 Exxonmobil Chemical Patents Inc. High melt strength polypropylenes with improved processability
US11572462B2 (en) 2017-02-07 2023-02-07 Exxonmobil Chemical Patents Inc. High melt strength polypropylenes with improved processability
WO2019013872A1 (en) 2017-07-13 2019-01-17 Exxonmobil Chemical Patents Inc. PROCESS FOR PRODUCING CURED POLYPROPYLENE UNDER STRAIN
JP6742044B2 (ja) * 2017-09-21 2020-08-19 株式会社Ｔｂｍ 熱可塑性樹脂組成物およびこれを用いてなる成形品
EP3476888B1 (en) * 2017-10-25 2024-02-14 Borealis AG Filled polypropylene composition with improved thermo-mechanical properties
WO2020231526A1 (en) 2019-05-15 2020-11-19 Exxonmobil Chemical Patents Inc. Polypropylene-based compositions
EP3994186A1 (en) * 2019-07-04 2022-05-11 Borealis AG Long-chain branched propylene polymer composition
CA3186507A1 (en) * 2020-06-26 2021-12-30 Borealis Ag Polypropylene composition for hms pp foam sheet with balanced bending resistance
WO2022175451A1 (en) * 2021-02-18 2022-08-25 Sabic Global Technologies B.V. High melt strength pp blends for foam with high thermostability
FI4067432T3 (fi) 2021-04-01 2024-01-15 Borealis Ag Kalvojen valmistukseen soveltuva polymeerikoostumus
CN114058115B (zh) * 2021-08-31 2023-06-06 成都金发科技新材料有限公司 一种抗菌抗病毒高冲击聚丙烯组合物及其制备方法和应用
US20260055214A1 (en) * 2022-08-19 2026-02-26 Borealis Ag Process for preparing a long chain branched polypropylene composition

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104662082A (zh) * 2012-06-28 2015-05-27 北欧化工公司 质量改进的高熔体强度聚丙烯

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4957968A (en) * 1988-08-09 1990-09-18 Monsanto Company Adhesive thermoplastic elastomer blends
DE59710063D1 (de) 1996-02-01 2003-06-18 Borealis Gmbh Schwechat Mannsw Strukturisomere Poly(alkylethylene)
JPH09309966A (ja) 1996-05-23 1997-12-02 Kanegafuchi Chem Ind Co Ltd 改質ポリプロピレン系樹脂組成物からなる発泡体
US6087431A (en) 1997-04-14 2000-07-11 Asahi Kasei Kagyo Kabushiki Kaisha Olefinic thermoplastic elastomer composition
US6204348B1 (en) 1997-05-20 2001-03-20 Borealis Gmbh Modified polypropylenes of improved processability
US6077907A (en) * 1997-07-09 2000-06-20 Borealis Ag Molded polyolefin parts of improved dimensional stability at elevated temperatures and improved stiffness
JPH11302425A (ja) 1998-04-21 1999-11-02 Sekisui Chem Co Ltd 流動性を有する発泡性ポリオレフィン系樹脂組成物
JP2002173564A (ja) 2000-12-06 2002-06-21 Grand Polymer Co Ltd 改質ポリプロピレン樹脂組成物、その製法、およびそれから得られる発泡体
US6646056B2 (en) 2001-10-16 2003-11-11 Solvay Engineered Polymers Thermoplastic elastomer compositions
JP4010141B2 (ja) 2001-12-06 2007-11-21 住友化学株式会社 改質ポリプロピレン樹脂とその製造方法
US20070004861A1 (en) * 2005-07-01 2007-01-04 Kevin Cai High melt strength polypropylene resins and method for making same
EP1892264A1 (en) 2006-08-25 2008-02-27 Borealis Technology Oy Extrusion coated substrate
ATE439393T1 (de) 2006-08-25 2009-08-15 Borealis Tech Oy Geblasene polypropylenfolie
DE502006007538D1 (de) * 2006-08-31 2010-09-09 Treofan Germany Gmbh & Co Kg Biaxial orientierte Elektroisolierfolie
ES2340727T3 (es) * 2007-01-31 2010-06-08 Borealis Technology Oy Uso de polipropileno que tiene ramificaciones de cadena larga para ampliar el margen de procesado en el moldeo por inyeccion-estirado-soplado.
EP2014716A1 (en) * 2007-06-08 2009-01-14 Borealis Technology Oy Polymer composition with high impact resistance and high melt strength
ATE457323T1 (de) 2007-12-18 2010-02-15 Borealis Tech Oy Heterophasisches polypropylen mit hoher schlagfestigkeit
EP2113541A1 (en) * 2008-04-28 2009-11-04 Borealis AG Adhesive propylene polymer composition suitable for extrusion coating of paper substrates
EP2338931A1 (en) 2009-12-23 2011-06-29 Borealis AG Blown grade showing superior stiffness, transparency and processing behaviour
EP2386584A1 (en) 2010-05-11 2011-11-16 Borealis AG Polypropylene composition suitable for extrusion coating
ES2645714T3 (es) 2011-02-28 2017-12-07 Borealis Ag Composición de polipropileno adecuada para el recubrimiento por extrusión
EP2877534B1 (en) * 2012-07-25 2017-05-10 Borealis AG Foam produced from polypropylene with low gel content

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104662082A (zh) * 2012-06-28 2015-05-27 北欧化工公司 质量改进的高熔体强度聚丙烯

Also Published As

Publication number Publication date
BR112015000853A2 (pt) 2017-06-27
JP5986314B2 (ja) 2016-09-06
ES2626363T3 (es) 2017-07-24
CA2878305A1 (en) 2014-01-30
EP2877535B1 (en) 2017-03-15
JP2015522701A (ja) 2015-08-06
CA2878305C (en) 2017-07-04
EP2877535A1 (en) 2015-06-03
MX366376B (es) 2019-07-05
KR20150030767A (ko) 2015-03-20
US9376549B2 (en) 2016-06-28
MX2015000615A (es) 2015-04-14
IN2014DN10848A (enExample) 2015-09-04
KR101531814B1 (ko) 2015-06-25
US20150133590A1 (en) 2015-05-14
CN104718249A (zh) 2015-06-17
WO2014016206A1 (en) 2014-01-30

Similar Documents

Publication Publication Date Title
CN104718249A (zh) 具有低ocs凝胶指数的薄膜
CN104662082B (zh) 质量改进的高熔体强度聚丙烯
CN104508036B (zh) 由具有低凝胶含量的聚丙烯制造的泡沫
CN105246924B (zh) 聚丙烯组合物的一步制造

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant