CN104688558A - Self-foaming cosmetic composition and preparation method thereof - Google Patents
Self-foaming cosmetic composition and preparation method thereof Download PDFInfo
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- CN104688558A CN104688558A CN201510092160.8A CN201510092160A CN104688558A CN 104688558 A CN104688558 A CN 104688558A CN 201510092160 A CN201510092160 A CN 201510092160A CN 104688558 A CN104688558 A CN 104688558A
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Abstract
The invention discloses a self-foaming cosmetic composition. The self-foaming cosmetic composition is prepared from the ingredients in percentage by mass: 65-99.5% of cosmetic matrix and 0.5-35% of foamer, wherein the foamer is a fluorine containing ether compound, and the cosmetic matrix is prepared from deionized water, alcohols, an aqueous-phase tackifier, a humectant, an anionic surfactant, a zwitterionic surfactant, a non-ionic surfactant, fat and oil, an inorganic salt or macromolecular thickener, an alkaline neutralizing agent, an active ingredient, a preservative and essence. The self-foaming cosmetic composition disclosed by the invention has the advantages that the condition of skin can be obviously improved so as to enable the skin to be tender and bright and smooth wrinkles.
Description
Technical field
The present invention relates to cosmetic field, particularly relate to a kind of from foaming composition and preparation method thereof.
Background technology
Along with the raising that development and the consumer of economic life require cosmetics consumption, traditional cosmetics form seems more and more single, and therefore, inventing a kind of cosmetics being obviously different from traditional form can have great captivation to consumer undoubtedly.
Traditional expansion type cosmetics adopts acid or faintly acid inorganic salt and organic acid reaction mode, obtained product expansion rate is slow, effect is weak, and separate type or pure solid dosage can only be done, and must two-phase mixtures during use, so it uses dosage form to be extremely restricted.In addition, it produces gas and is generally CO
2, epidermis CO
2the increase of concentration, will certainly cause CO in blood
2the increase of concentration, the reduction of blood PH, thus hemoglobin is to O
2affinity decline and discharge O
2.The anoxia of epidermal area hemoglobin can cause erythrosis, easy allergy, the defensive ability/resistance ability of the external environment conditions such as various pathogenic bacteria and variations in temperature is reduced simultaneously, therefore the object of beauty and skin care can not only be played, can damage normal skin on the contrary, permanent use, will inevitably accelerate the aging of skin, and the application target of cosmetics runs in the opposite direction.
Summary of the invention
The technical problem to be solved in the present invention is to provide one can obviously improve skin state, makes skin tender beautiful, desalination wrinkle from foaming composition.
A kind of from foaming composition, be that the cosmetic base of 65-99.5% and the foaming agent of 0.5-35% are formed by mass percent; Wherein, described foaming agent is fluorine-containing ether compound, and described cosmetic base is made up of following five part materials:
Component A:
Deionized water: 75 ~ 96%;
Alcohols: 0.5 ~ 20%;
Aqueous phase viscosifier: 0 ~ 2%;
Wetting agent: 0.5 ~ 20%;
B component:
Anion surfactant: 0.1 ~ 20%;
Zwitterionic surfactant: 0.1 ~ 25%;
Nonionic surfactant: 0.1 ~ 25%;
Oils and fats: 0 ~ 25%;
C component:
Inorganic salt or macromolecule thickener: 0.1 ~ 10%;
D component:
Antalkali: 0.1 ~ 2%;
E component:
Active component: 0 ~ 30%;
Antiseptic: 0.1 ~ 2%;
Essence: 0.01 ~ 0.5%.
Of the present invention from foaming composition, wherein, be that the cosmetic base of 88-99.5% and the foaming agent of 0.5-20% are formed by mass percent; Fluorine-containing ether compound be selected from following several in one or more mixture ten fluorine butyl methyl ether, ten fluorine isobutyl group methyl ethers, perflexane, perfluorodecalin, pentafluoropropane, commercially available prod is as the PhoenoMulse CE-4 of phoenix chemical company of the U.S., French CIT company
the Novec HFE-7100 of BB 61, Minnesota Mining and Manufacturing Company.
Of the present invention from foaming composition, wherein, described deionized water, electrical conductivity is less than 0.3 μ s/cm, and pH value is between 6-7.5;
Described alcohols be following several in the mixture of one or more: glycerol, diglycerol, 1,3-PD, 1,2-PD, 1,3 butylene glycol, xylitol, sorbitol, Polyethylene Glycol.
Of the present invention from foaming composition, wherein, described wetting agent be following several in the mixture of one or more: hyaluronate sodium, sodium lactate, polyvinylpyrrolidone carboxylic acid sodium, collagen protein, betanin, trehalose, Herba Portulacae extract, chondroitin sulfate, cholesterol, polyglutamic acid sodium, sucrose, carbamide, ethoxy urea, acetyl chitosan, Tremella extract;
Described aqueous phase viscosifier be following several in the mixture of one or more: arabic gum, carrageenan, POLY-karaya, locust bean gum, casein, dextrin, gelatin, sodium alginate, methylcellulose, ethyl cellulose, hydroxyethyl-cellulose, hydroxypropyl cellulose, PVA, PVM, PVP, carboxy vinyl cellulose, tracasol, more create glue, tamarind gum, xanthan gum, aluminium-magnesium silicate, bentonite, Strese Hofmann's hectorite., synthesis of clay, silicic acid anhydride.
Of the present invention from foaming composition, wherein, described anion surfactant be following several in the mixture of one or more: sodium laurate, sodium lauryl sulphate, polyoxyethylene lauryl base sulfate, Hamposyl L, cocoyl sodium taurocholate, POE stearyl ether phosphate, dodecylbenzene sodium sulfonate, N-stearoyl-glutamic acid sodium, hydrogenated coco-glyceride sodium sulfate, POE alkyl ether carboxylic acid, POE alkylaromatic hydrocarbon base ether carboxylate, higher fatty acids sulfonated ester, higher fatty acid alkanol amide sulfuric acid, lauroyl single ethanol amide sodium succinate.
Described zwitterionic surfactant is undecyl carboxy methyl hydroxyethyl imidazoline sodium or cocamido propyl betaine or the mixture of the two;
Described non-ionic surface active agent is following several mixture of one or more: sorbitan monooleate, anhydrous sorbitol list isostearate, sorbitan mono-laurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, diglycerol anhydrous sorbitol five-2-ethylhexanoate, diglycerol anhydrous sorbitol four-2-ethylhexanoate, single erucic acid glyceride, sesquialter olein, glyceryl monostearate, glyceryl monostearate/malate, propylene glycolmonostearate, castor oil hydrogenated derivant, glycerol alkyl ether, polyoxyethylene, methyl polysiloxane copolymer, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-anhydrous sorbitol four oleate, POE-sorbitan monolaurate, POE-sorbitol monooleate, POE-sorbitol five oleate, POE-sorbitol monostearate, POE-glyceryl monostearate, POE-glycerol monoisostearate, POE-glyceryl triisostearate, POE-monoleate, POE-distearate, POE-dioleate, diglycol stearate, POE-lauryl ether, POE-oleyl ether, POE-stearyl ether, POE-mountain Yu base ether, POE2-octyldodecyl ether, POE-cholestane alcohol ether, POE-octyl phenyl ether, POE-nonylplenyl ether, POE-dinonyl phenyl ether, Pluronic, POE/POP2-decyl myristyl ether, POE/POP-single-butyl ether, POE/POP-hydrogenated lanolin, POE/POP-glycerin ether, POE-Oleum Ricini, POE-castor oil hydrogenated, POE-castor oil hydrogenated list isostearate, POE-castor oil hydrogenated three isostearate, POE-castor oil hydrogenated list pyroglutamic acid list isostearic acid diester, POE-castor oil hydrogenated maleate, POE-sorbitol Cera Flava, cocoanut fatty acid diethanolamide, lauric monoethanolamide, fatty acid isopropanol amide, POE-methyl glycol fatty acid ester, POE-alkylamine, POE-fatty acid amide, sucrose fatty acid ester, POE-nonyl phenyl formaldehyde condensation products, alkyl ethoxy dimethyl amine, three oleyl alcohol phosphate esters.
Described oils and fats be following several in the mixture of one or more: vitamins, natural oil, wax class, hydrocarbon ils, higher alcohol, synthesis ester oil, silicone.
Of the present invention from foaming composition, wherein, described macromolecule thickener be following several in the mixture or derivatives thereof of one or more: sodium polyacrylate, polyethyl acrylate, polyacrylamide, polymine, cationic polymer;
Described nertralizer be following several in the mixture of one or more: potassium hydroxide, sodium hydroxide, 2-amino-2-methyl-1-propanol, 2-amino-2-methyl-1, ammediol, triethanolamine, diethanolamine, monoethanolamine, triisopropanolamine, TRIS, L-arginine, 1B, N-alkyltaurate;
Antiseptic be following several in the mixture of one or more: methyl parahydroxybenzoate, Methylisothiazolinone, phenoxyethanol;
Described active component be following several in the mixture of one or more: tocopherol acetas, ascorbic acid, arbutin, Radix Ginseng extract, Aloe extract, Radix Astragali extract.
Of the present invention from foaming composition, wherein, the described dosage form from foaming composition be following several in one: solution system, solubilizing systems, emulsification system, dispersion, water-oily double-deck system, water-oil-powder Three-tider architecture, ointment, gel, aerosol;
The described occupation mode from foaming composition is astringent, emulsion, cream frost, elite, jelly, gel, ointment, facial film, foundation cream, sun-proof, shampoo, clean, take a shower, mascara or makeup removal products.
Of the present invention from foaming composition, wherein said cosmetic composition is that it is prepared from by the raw material of following mass percent from foaming clean gel:
Deionized water: surplus;
EDETATE SODIUM: 0.1%;
Glycerol: 2%;
PEG-120 methyl dioleate: 0.3%;
Sodium laureth sulfate: 15%;
Decyl glucoside: 5%;
Pyrrolidone sodium carboxylate: 1%;
Cocamido propyl betaine: 5%;
Polyquaternary ammonium salt-7:1%;
Acrylic acid (ester) analog copolymer: 4%;
Sodium chloride: 0.2%;
Sodium hydroxide: 0.08%;
Essence: 0.35%;
Antiseptic: 0.4%;
Novec HFE-7100：10％。
Preparation method from foaming composition of the present invention, comprises the steps:
(1) all for component A raw materials are dropped into emulsifying pot, be warmed up to 85 DEG C, stir or homogenizing, make A phase materials dissolve completely;
(2) under stirring state, B group material is added in component A successively, if there is oil phase, finally add the oil phase dissolved, and low speed homogenizing 1-5 minute;
(3) add C component under stirring, and low speed homogenizing is to disperseing completely;
(4) under stirring, neutralizing with D phase nertralizer, is 6-8 to pH value;
(5) cool to 40 DEG C or following, add essence, antiseptic, active component, stir, obtain base material, take the dish out of the pot for subsequent use;
(6) before fill, foaming agent is added base material and mix homogeneously, shorten this step operating time as far as possible;
(7) the material body mixed is carried out fill, container tightness will be got well, and selects disposable plastic packaging bag.
The present invention is from foaming composition difference from prior art:
In chemical industry and surgery medical product, have the ether compound of fluorine, its Kaifeng after run into air can in 2-3 minute Quick-gasifying, tolerance is huge, and this gas to skin not only without any infringement, on the contrary its formed gas cell can take a large amount of oxygen in.Principle accordingly, inventor is applied to cosmetic field them, coats after on skin, can form a thick layer of careful careful foam fast, and the dosage form of this novelty obviously can attract the curiosity of consumer greatly, thus planned purchases; Meanwhile, the oxygen that the gas cell formed carries, can make epidermis moment oxygen enrichment, thus hemoglobin oxygen content is increased, accelerate cell metabolism, after washing away, it is soft and smooth flexible that skin can become light; The increase of oxygen content also can promote that skin is to the absorption of active substance in cosmetics, and then accelerates to realize the object that whitening anti-aging etc. makes to apply some make up.Again simultaneously, because this type of foaming agent need coordinate the use of a certain proportion of foaming characteristic surfactant etc., so when washing away, deep layer cleaning can be carried out to skin, thus reach attractive in appearance, skin protection, oxygen enrichment, clean quadruple effect unification effect.
The foaming agent Novec HFE-7100 oxygen carrying capacity that the present invention adopts, can obviously improve skin state, make skin tender beautiful, desalination wrinkle.
Be not any raw material and ratio have effect of the present invention from foaming composition, adopt various raw material of the present invention and ratio obtained after foaming composition is used in skin, can bubble by rapid, high volume, the dense careful foam of one deck within general 2-3 minute, can be formed.Oxygen that bubble is taken can increase skin oxygen saturation, promotes the absorption of active substance, strengthens cell viability, and desalination wrinkle, makes the more aobvious youth of skin beautiful; Meanwhile, due to the existence of clean class surfactant, wash away these materials along with from skin, the clean of deep layer can be carried out to skin, thus reach attractive in appearance, skin protection, oxygen enrichment, clean quadruple effect unification effect.
Detailed description of the invention
Embodiment 1
A kind of from foam mask, it is made up of the raw material of following mass percent:
Deionized water: surplus;
Butanediol: 5%;
Betanin: 2%;
HANSHENGJIAO: 0.2%;
Glycerin polyether-26:2%;
Sodium lauroyl sarcosine: 9%;
Decyl glucoside: 6%;
Cocamido propyl betaine: 5%;
LAA: 3%;
Acrylic acid (ester) analog copolymer: 2%;
Sodium hydroxide: 0.45%;
Essence: 0.1%;
Antiseptic: 0.3%;
Herba Portulacae extract: 2%;
Palmitoyl Tetrapeptide-7:0.0005%;
Tocopherol acetas: 0.5%;
PhoenoMulse CE-4：10％。
Embodiment 2
A kind of from foam mask, be with the difference of embodiment 1: foaming agent is
bB 61.
Embodiment 3
A kind of from foam mask, be with the difference of embodiment 1: foaming agent is Novec HFE-7100.
Evaluation methodology and benchmark:
For each assessment item, based on following scoring benchmark with 5 grade scorings, evaluated by the following metewand of its scoring meansigma methods.
Scoring:
5 points: very excellent;
4 points: excellent;
2 points: poor;
1 point: non-constant.
Metewand:
◎: evaluation of estimate (meansigma methods) is more than 4.0 and less than 5.0 points;
Zero: evaluation of estimate (meansigma methods) is more than 3.0 and less than 4.0 points;
△: evaluation of estimate (meansigma methods) is more than 2.0 and less than 3.0 points;
×: evaluation of estimate (meansigma methods) is more than 1.0 and less than 2.0 points.
Comparative example 1 is that foaming agent is NovecHFE-7100, but addition is 5%, and the addition of deionized water compares the present invention increases by 5% except foaming agent other components except deionized water are identical with the present invention with ratio; Comparative example 2 is except foaming agent other components except deionized water are identical with the present invention with ratio, and do not add foaming agent, the addition of deionized water compares the present invention increases by 10%, and evaluation result is as follows:
| Evaluation index | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 |
| Coating skinfeel | ◎ | ◎ | ◎ | ◎ | ◎ |
| Cream time | ○ | △ | ◎ | × | × |
| Foam effect | ○ | △ | ◎ | ○ | × |
| Cleaning capacity | ◎ | ◎ | ◎ | ○ | △ |
| Wrinkle removing effect | ◎ | ○ | ◎ | ○ | △ |
Known, in embodiment three kinds of foaming agent, the cream time (about 2 minutes) of Novec HFE-7100 and foaming effect best, PhoenoMulse CE-4 takes second place,
bB 61 third.Reference examples chooses Novec HFE-7100, and consumption reduces, and its cream time is similar to PhoenoMulse CE-4, and foaming effect obviously weakens, and oxygen carrying capacity also weakens simultaneously, and correspondingly, wrinkle removing effect is also corresponding to be weakened.The surfactant of embodiment and reference examples is constant, corresponding cleaning effect is also substantially constant, but along with the obvious reduction of foaming dosage, cleaning ability also can reduce, visible foaming agent is influential to cleaning capacity, but with do not add compared with foaming agent, no matter be cleaning capacity or wrinkle removing effect, all can promote to some extent.
In addition, when the ratio of foaming agent and kind constant when, applicant has also made the change test of other compositions, comparative example is the multiple combination from foamed cosmetics of the prior art, find that all comparative examples are marked all below 4 points from bubble time, foam effect, cleaning capacity, wrinkle removing effect, general at about 2 points, the combination of various ratio of the present invention and kind is all better than other prior art.Especially, when foaming agent is Novec HFE-7100, all indexs all can reach optimum, be any prior art can not and, there is obvious advantage.
Embodiment 4
From foaming clean gel
Embodiment 5
From foaming essence
Embodiment 6
From foaming paste frost
Embodiment 7
From foaming foundation cream (BB is white or CC is white)
Embodiment 8
A kind of from foaming composition, be that the cosmetic base of 95% and the foaming agent of 5% are formed by mass percent; Wherein, described foaming agent is fluorine-containing ether compound, and described cosmetic base is made up of following five part materials:
Component A:
Deionized water: 96%;
Alcohols: 0.5%;
Aqueous phase viscosifier: 1.4%;
Wetting agent: 0.89%;
B component:
Anion surfactant: 0.1%;
Zwitterionic surfactant: 0.2%;
Nonionic surfactant: 0.1%;
Oils and fats: 0.4%;
C component:
Inorganic salt or macromolecule thickener: 0.1%;
D component:
Antalkali: 0.1%;
E component:
Active component: 0.1%;
Antiseptic: 0.1%;
Essence: 0.01%.
Fluorine-containing ether compound is the mixture of following 8 kinds of materials of same ratio: ten fluorine butyl methyl ethers, ten fluorine isobutyl group methyl ethers, perflexane, perfluorodecalin, pentafluoropropane, the PhoenoMulse CE-4 of phoenix chemical company of the U.S., French CIT company
the Novec HFE-7100 of BB 61, Minnesota Mining and Manufacturing Company.
Described deionized water, electrical conductivity is less than 0.3 μ s/cm, and pH value is between 6-7.5;
Described alcohols be following several in mixture: 1,3 butylene glycol, xylitol, sorbitol, Polyethylene Glycol, mixed proportion can adjust according to practical situation, if mixed proportion is 4:1:2:0.5.
Described wetting agent be following several in the mixture of one or more: sodium lactate, polyvinylpyrrolidone carboxylic acid sodium, collagen protein, trehalose, chondroitin sulfate, cholesterol, polyglutamic acid sodium, sucrose, carbamide, ethoxy urea, Tremella extract; Any mixture wherein can, such as mixed weight ratio is the mixture of the cholesterol of 1:5:2:7:2:3, polyglutamic acid sodium, sucrose, carbamide, ethoxy urea, Tremella extract;
Described aqueous phase viscosifier be following several in the mixture of one or more: arabic gum, carrageenan, POLY-karaya, locust bean gum, casein, dextrin, gelatin, sodium alginate, methylcellulose, ethyl cellulose, hydroxyethyl-cellulose, hydroxypropyl cellulose, PVA, PVM, PVP, carboxy vinyl cellulose, tracasol, more create glue, tamarind gum, xanthan gum, aluminium-magnesium silicate, bentonite, Strese Hofmann's hectorite., synthesis of clay, silicic acid anhydride; Any combination wherein can realize, the mass ratio that such as effectiveness comparison is good be 4:3:1:5 tracasol, more create the mixture of glue, tamarind gum, Strese Hofmann's hectorite..
Described anion surfactant be following several in the mixture of one or more: fatty acid soaps is as sodium laurate etc., high alkyl sulfate salt is as sodium lauryl sulphate, alkyl ether sulphate salts is as polyoxyethylene lauryl base sulfate, N-acyl group sarcosine is as Hamposyl L, higher fatty acids acyl group sulfonate is as cocoyl sodium taurocholate, phosphate ester salt is as POE stearyl ether phosphate, alkylbenzenesulfonate is as dodecylbenzene sodium sulfonate, N-acyl glutamate is as N-stearoyl-glutamic acid sodium, high-grade aliphatic ester sulfate is as hydrogenated coco-glyceride sodium sulfate, POE alkyl ether carboxylic acid, POE alkylaromatic hydrocarbon base ether carboxylate, higher fatty acids sulfonated ester, higher fatty acid alkanol amide sulfuric acid, lauroyl single ethanol amide sodium succinate etc.Test proves, above one or more all meet, and can not enumerate specific embodiment in view of length is limited.
Described zwitterionic surfactant be following several in the mixture of one or more: imidazolines amphoteric surfactant is if undecyl carboxy methyl hydroxyethyl imidazoline sodium, betaines surfactant are as cocamido propyl betaine etc.
Described non-ionic surface active agent is following several mixture of one or more: the sorbitan fatty acid ester classes such as sorbitan monooleate, anhydrous sorbitol list isostearate, sorbitan mono-laurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, diglycerol anhydrous sorbitol five-2-ethylhexanoate, diglycerol anhydrous sorbitol four-2-ethylhexanoate; The glycerol polyglyceryl fatty acid ester classes such as single erucic acid glyceride, sesquialter olein, glyceryl monostearate, glyceryl monostearate/malate; The methyl glycol fatty acid ester classes such as propylene glycolmonostearate, and castor oil hydrogenated derivant, glycerol alkyl ether, polyoxyethylene. methyl polysiloxane copolymer.The POE sorbitan fatty acid ester classes such as POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-anhydrous sorbitol four oleate; The POE Span classes such as POE-sorbitan monolaurate, POE-sorbitol monooleate, POE-sorbitol five oleate, POE-sorbitol monostearate; The POE glycerine fatty acid esters such as POE-glyceryl monostearate, POE-glycerol monoisostearate, POE-glyceryl triisostearate; The POE fatty acid esters such as polysorbate 80, POE distearate, POE dioleate, diglycol stearate; The POE alkyl ether such as POE lauryl ether, POE oleyl ether, POE stearyl ether, POE mountain Yu base ether, POE2-octyldodecyl ether, POE cholestane alcohol ether; The POE alkyl phenyl ethers such as POE octyl phenyl ether, POE nonylplenyl ether, POE dinonyl phenyl ether; The POE/POP alkyl ethers such as the pluaronic type POE/POP cetyl ether such as Pluronic, POE/POP2-decyl myristyl ether, POE/POP single-butyl ether, POE/POP hydrogenated lanolin, POE/POP glycerin ether; The POE Oleum Ricini castor oil hydrogenated derivants such as POE Oleum Ricini, POE castor oil hydrogenated, POE castor oil hydrogenated list isostearate, POE castor oil hydrogenated three isostearate, POE castor oil hydrogenated list pyroglutamic acid list isostearic acid diester, POE castor oil hydrogenated maleate; POE Cera Flava/the lanolin derivatives such as POE sorbitol Cera Flava; The alkanolamides such as cocoanut fatty acid diethanolamide, lauric monoethanolamide, fatty acid isopropanol amide, and POE methyl glycol fatty acid ester, POE alkylamine, POE fatty acid amide, sucrose fatty acid ester, POE nonyl phenyl formaldehyde condensation products, alkyl ethoxy dimethyl amine, three oleyl alcohol phosphate esters etc.
Described oils and fats is the oils and fats allowing in any cosmetics to use, and citing is as vitamins, natural oil, wax class, hydrocarbon ils, higher alcohol, synthesis ester oil, silicone etc.
Described macromolecule thickener be following several in the mixture or derivatives thereof of one or more: sodium polyacrylate, polyethyl acrylate, polyacrylamide, polymine, cationic polymer;
Described nertralizer be following several in the mixture of one or more: the hydroxide of the alkali metal such as potassium hydroxide, sodium hydroxide class; 2-amino-2-methyl-1-propanol, 2-amino-2-methyl-1; the basic nitrogen compounds such as ammediol, triethanolamine, diethanolamine, monoethanolamine, triisopropanolamine, TRIS, L-arginine, 1B, N-alkyltaurate.These nertralizers can be used alone one or are used in combination of two or more.
Antiseptic be following several in the mixture of one or more: methyl parahydroxybenzoate, Methylisothiazolinone, phenoxyethanol;
Described active component be following several in the mixture of one or more: antioxidant (tocopherol acetas), astringent, whitening agent (ascorbic acid, arbutin etc.), anti-sensitizer, shining skin agent, various extract (Radix Ginseng, Aloe, the Radix Astragali etc.), antiinflammatory (allantoin, glycyrrhizic acid dipotassium etc.) etc.
Above various selection in the present invention proves all passable through test, in view of length is limited, can not one action embodiment enumerate.
Dosage form of the present invention be following several in one: solution system, solubilizing systems, emulsification system, dispersion, water-oily double-deck system, water-oil-powder Three-tider architecture, ointment, gel, aerosol.
Described from foaming composition be astringent, emulsion, cream frost, elite, jelly, gel, ointment, facial film, foundation cream, sun-proof, shampoo, clean, take a shower, mascara or makeup removal products.
The present invention illustrate and just have chosen in the some forms of cosmetics several, other all spontaneous foaming characteristic formula of this type of fluorine-containing ether compounds that utilize are all within this scope.
The present invention, from the preparation method of foaming composition, comprises the steps:
(1) all for component A raw materials are dropped into emulsifying pot, be warmed up to 85 DEG C, stir or homogenizing, make A phase materials dissolve completely;
(2) under stirring state, B group material is added in component A successively, if there is oil phase, finally add the oil phase dissolved, and low speed homogenizing 1-5 minute;
(3) add C component under stirring, and low speed homogenizing is to disperseing completely;
(4) under stirring, neutralizing with D phase nertralizer, is 6-8 to pH value;
(5) cool to 40 DEG C or following, add essence, antiseptic, active component, stir, obtain base material, take the dish out of the pot for subsequent use;
(6) before fill, foaming agent is added base material and mix homogeneously, shorten this step operating time as far as possible;
(7) the material body mixed is carried out fill, container tightness will be got well, and selects disposable plastic packaging bag.
Embodiment 9
A mascara containing foaming agent, it is made up of the raw material of following mass percent:
Deionized water: surplus;
Butanediol: 2.0%;
Methyl parahydroxybenzoate: 0.2%;
Pantothenylol: 0.5%;
Sorbitol: 1.0%;
Nicotiamide: 0.5%;
EDTA-2Na：0.1％；
Xanthan gum: 0.15%;
Hydroxyethyl-cellulose: 0.2%;
Iron black (with) water (with) sodium polyacrylate: 12.0%;
Cera alba: 8.0%;
Ceresine: 5.0%;
Candelilla wax: 3.0%;
Stearic acid: 3.0%;
Microwax: 3.0%;
Sorbitan sesquioleate: 1.0%;
Tocopherol acetas: 0.2%;
Hydrogenated polycyclopentadiene: 2.0%;
Squalane: 2.0%;
Propyl p-hydroxybenzoate: 0.1%;
Isomery dodecane: 1.0%;
Polysorbate-60:1.1%;
Cetearyl glucoside: 0.9%;
Jojoba oil: 1.0%;
Distearyl dimethylammonium Strese Hofmann's hectorite.: 0.8%;
Rice bran wax: 0.4%;
Polyisobutylene: 1.1%;
Polydimethylsiloxane: 1.0%;
Dimethiconol: 0.5%;
Triethanolamine: 1.35%;
Cellulose: 4.5%;
Phenoxyethanol: 0.3%;
Novec HFE-7100：1.0％。
Described deionized water, electrical conductivity is less than 0.3 μ s/cm, and pH value is between 6-7.5.
The preparation method of the mascara containing foaming agent of the present invention, comprises the steps:
(1) by deionized water, butanediol, methyl parahydroxybenzoate, pantothenylol, sorbitol, nicotiamide, EDTA-2Na, xanthan gum, hydroxyethyl-cellulose, iron black (with) water (with) sodium polyacrylate is mixed to form mixture I, by cera alba, ceresine, candelilla wax, stearic acid, microwax, sorbitan sesquioleate, tocopherol acetas, hydrogenated polycyclopentadiene, squalane, propyl p-hydroxybenzoate, isomery dodecane, polysorbate-60, cetearyl glucoside, Jojoba oil, distearyl dimethylammonium Strese Hofmann's hectorite., rice bran wax, polyisobutylene, polydimethylsiloxane, dimethiconol is mixed to form mixtures II, heating blends I and mixtures II are to 85-90 DEG C respectively,
(2) respectively mixture I and mixtures II are stirred;
(3) mixtures II is joined in mixture I, homogenizing 10 minutes;
(4) triethanolamine is added, homogenizing 3 minutes in the material obtained in step (3);
(5) cool to 50 DEG C, add cellulose, stir;
(6) cool to 40 DEG C, add phenoxyethanol, stir;
(7) cool to less than 25 DEG C, add Novec HFE-7100, stir, get final product discharging.
Embodiment 10
A kind of from foaming sunscreen, it is made up of the raw material of following mass percent:
Deionized water: surplus;
Glycerol: 2.0%;
Butanediol: 4.0%;
Propylene glycol: 0.5%;
Methyl parahydroxybenzoate: 0.2%;
EDTA-2Na：0.1％；
Phosphoric acid monohexadecyl ester potassium: 1.2%;
Decyl glucoside: 1.0%;
Allantoin: 0.1%;
Xanthan gum: 0.2%;
Glycyrrhizic acid dipotassium: 0.1%;
Ethylhexyl methoxy cinnamate: 7.5%;
Titanium dioxide: 5.0%;
C12-15 alcohol benzoate: 4.0%;
C12-20 alkyl androstanediol: 3.0%;
Polydimethylsiloxane: 2.0%;
Caprylic/capric triglyceride: 3.0%;
Dicaprylyl carbonate: 3.0%;
MBBT: 4.0%;
Uvinul T 150: 2.1%;
The own ester of diethylamino oxybenzene formylbenzoate: 1.9%;
Polyglycereol-4 isostearate: 1.5%;
C14-22 alcohol: 0.5%;
Cetearyl alcohol: 1.5%;
VP/ eicosene copolymer: 0.8%;
Poly-hydroxy stearic acid: 0.2%;
Ring five polydimethylsiloxane: 2.0%;
Tocopherol acetas: 0.3%;
Ring four polydimethylsiloxane: 1.0%;
Dimethiconol: 0.4%;
Propyl p-hydroxybenzoate: 0.2%;
Aluminium stearate: 0.3%;
2-Methylpentadecane: 1.0%;
Polysorbate: 0.5%;
Sodium acrylate/sodium acryloyldimethyl taurate copolymers: 0.2%;
Phenoxyethanol: 0.3%;
Bisabolol: 0.1%;
Ginger-root extract: 0.1%;
Novec HFE-7100：4.0％；
Described deionized water, electrical conductivity is less than 0.3 μ s/cm, and pH value is between 6-7.5.
Preparation method from foaming sunscreen of the present invention, comprises the steps:
(1) by deionized water, glycerol, butanediol, propylene glycol, methyl parahydroxybenzoate, EDTA-2Na, Phosphoric acid monohexadecyl ester potassium, decyl glucoside, allantoin, xanthan gum and glycyrrhizic acid dipotassium are mixed to form mixture I, by ethylhexyl methoxy cinnamate, titanium dioxide, C12-15 alcohol benzoate, C12-20 alkyl androstanediol, polydimethylsiloxane, caprylic/capric triglyceride, dicaprylyl carbonate, MBBT, Uvinul T 150, the own ester of diethylamino oxybenzene formylbenzoate, polyglycereol-4 isostearate, C14-22 alcohol, cetearyl alcohol, VP/ eicosene copolymer, poly-hydroxy stearic acid, ring five polydimethylsiloxane, tocopherol acetas, ring four polydimethylsiloxane, dimethiconol, propyl p-hydroxybenzoate, aluminium stearate, 2-Methylpentadecane and polysorbate are mixed to form mixtures II, heating blends I and mixtures II are to 85-90 DEG C respectively,
(2) respectively mixture I and mixtures II are stirred;
(3) mixtures II is added in mixture I, homogenizing 10 minutes;
(4) sodium acrylate/sodium acryloyldimethyl taurate copolymers is added, homogenizing 3 minutes;
(5) cool to 50 DEG C, add phenoxyethanol, stir
(6) cool to 40 DEG C, add bisabolol, ginger-root extract, stir;
(7) cool to less than 25 DEG C, add Novec HFE-7100, stir, get final product discharging.
Also do contrast test in research process, adopt the result of use of the cosmetic composition of other ratios or compositions all not have of the present invention effective.
Above-described embodiment is only be described the preferred embodiment of the present invention; not scope of the present invention is limited; under not departing from the present invention and designing the prerequisite of spirit; the various distortion that those of ordinary skill in the art make technical scheme of the present invention and improvement, all should fall in protection domain that claims of the present invention determines.
Claims (9)
1. from a foaming composition, it is characterized in that: be that the cosmetic base of 65-99.5% and the foaming agent of 0.5-35% are formed by mass percent; Wherein, described foaming agent is fluorine-containing ether compound, and described cosmetic base is made up of following five part materials:
Component A:
Deionized water: 75 ~ 96%;
Alcohols: 0.5 ~ 20%;
Aqueous phase viscosifier: 0 ~ 2%;
Wetting agent: 0.5 ~ 20%;
B component:
Anion surfactant: 0.1 ~ 20%;
Zwitterionic surfactant: 0.1 ~ 25%;
Nonionic surfactant: 0.1 ~ 25%;
Oils and fats: 0 ~ 25%;
C component:
Inorganic salt or macromolecule thickener: 0.1 ~ 10%;
D component:
Antalkali: 0.1 ~ 2%;
E component:
Active component: 0 ~ 30%;
Antiseptic: 0.1 ~ 2%;
Essence: 0.01 ~ 0.5%.
2. according to claim 1 from foaming composition, it is characterized in that: be that the cosmetic base of 80-99.5% and the foaming agent of 0.5-20% are formed by mass percent; Fluorine-containing ether compound be selected from following several in one or more mixture ten fluorine butyl methyl ether, ten fluorine isobutyl group methyl ethers, perflexane, perfluorodecalin, pentafluoropropane, commercially available prod is as the PhoenoMulse CE-4 of phoenix chemical company of the U.S., French CIT company
the NovecHFE-7100 of BB 61, Minnesota Mining and Manufacturing Company.
3. according to claim 1 from foaming composition, it is characterized in that: described deionized water, electrical conductivity is less than 0.3 μ s/cm, and pH value is between 6-7.5;
Described alcohols be following several in the mixture of one or more: glycerol, diglycerol, 1,3-PD, 1,2-PD, 1,3 butylene glycol, xylitol, sorbitol, Polyethylene Glycol.
4. according to claim 1 from foaming composition, it is characterized in that: described wetting agent be following several in the mixture of one or more: hyaluronate sodium, sodium lactate, polyvinylpyrrolidone carboxylic acid sodium, collagen protein, betanin, trehalose, Herba Portulacae extract, chondroitin sulfate, cholesterol, polyglutamic acid sodium, sucrose, carbamide, ethoxy urea, acetyl chitosan, Tremella extract;
Described aqueous phase viscosifier be following several in the mixture of one or more: arabic gum, carrageenan, POLY-karaya, locust bean gum, casein, dextrin, gelatin, sodium alginate, methylcellulose, ethyl cellulose, hydroxyethyl-cellulose, hydroxypropyl cellulose, PVA, PVM, PVP, carboxy vinyl cellulose, tracasol, more create glue, tamarind gum, xanthan gum, aluminium-magnesium silicate, bentonite, Strese Hofmann's hectorite., synthesis of clay, silicic acid anhydride.
5. according to claim 1 from foaming composition, it is characterized in that: described anion surfactant be following several in the mixture of one or more: sodium laurate, sodium lauryl sulphate, polyoxyethylene lauryl base sulfate, Hamposyl L, cocoyl sodium taurocholate, POE stearyl ether phosphate, dodecylbenzene sodium sulfonate, N-stearoyl-glutamic acid sodium, hydrogenated coco-glyceride sodium sulfate, POE alkyl ether carboxylic acid, POE alkylaromatic hydrocarbon base ether carboxylate, higher fatty acids sulfonated ester, higher fatty acid alkanol amide sulfuric acid, lauroyl single ethanol amide sodium succinate,
Described zwitterionic surfactant is undecyl carboxy methyl hydroxyethyl imidazoline sodium or cocamido propyl betaine or the mixture of the two;
Described non-ionic surface active agent is following several mixture of one or more: sorbitan monooleate, anhydrous sorbitol list isostearate, sorbitan mono-laurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, diglycerol anhydrous sorbitol five-2-ethylhexanoate, diglycerol anhydrous sorbitol four-2-ethylhexanoate, single erucic acid glyceride, sesquialter olein, glyceryl monostearate, glyceryl monostearate/malate, propylene glycolmonostearate, castor oil hydrogenated derivant, glycerol alkyl ether, polyoxyethylene, methyl polysiloxane copolymer, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-anhydrous sorbitol four oleate, POE-sorbitan monolaurate, POE-sorbitol monooleate, POE-sorbitol five oleate, POE-sorbitol monostearate, POE-glyceryl monostearate, POE-glycerol monoisostearate, POE-glyceryl triisostearate, POE-monoleate, POE-distearate, POE-dioleate, diglycol stearate, POE-lauryl ether, POE-oleyl ether, POE-stearyl ether, POE-mountain Yu base ether, POE2-octyldodecyl ether, POE-cholestane alcohol ether, POE-octyl phenyl ether, POE-nonylplenyl ether, POE-dinonyl phenyl ether, Pluronic, POE/POP2-decyl myristyl ether, POE/POP-single-butyl ether, POE/POP-hydrogenated lanolin, POE/POP-glycerin ether, POE-Oleum Ricini, POE-castor oil hydrogenated, POE-castor oil hydrogenated list isostearate, POE-castor oil hydrogenated three isostearate, POE-castor oil hydrogenated list pyroglutamic acid list isostearic acid diester, POE-castor oil hydrogenated maleate, POE-sorbitol Cera Flava, cocoanut fatty acid diethanolamide, lauric monoethanolamide, fatty acid isopropanol amide, POE-methyl glycol fatty acid ester, POE-alkylamine, POE-fatty acid amide, sucrose fatty acid ester, POE-nonyl phenyl formaldehyde condensation products, alkyl ethoxy dimethyl amine, three oleyl alcohol phosphate esters,
Described oils and fats be following several in the mixture of one or more: vitamins, natural oil, wax class, hydrocarbon ils, higher alcohol, synthesis ester oil, silicone.
6. according to claim 1 from foaming composition, it is characterized in that: described macromolecule thickener be following several in the mixture or derivatives thereof of one or more: sodium polyacrylate, polyethyl acrylate, polyacrylamide, polymine, cationic polymer;
Described nertralizer be following several in the mixture of one or more: potassium hydroxide, sodium hydroxide, 2-amino-2-methyl-1-propanol, 2-amino-2-methyl-1, ammediol, triethanolamine, diethanolamine, monoethanolamine, triisopropanolamine, TRIS, L-arginine, 1B, N-alkyltaurate;
Antiseptic be following several in the mixture of one or more: methyl parahydroxybenzoate, Methylisothiazolinone, phenoxyethanol;
Described active component be following several in the mixture of one or more: tocopherol acetas, ascorbic acid, arbutin, Radix Ginseng extract, Aloe extract, Radix Astragali extract.
7. according to claim 1 from foaming composition, it is characterized in that:
The described dosage form from foaming composition be following several in one: solution system, solubilizing systems, emulsification system, dispersion, water-oily double-deck system, water-oil-powder Three-tider architecture, ointment, gel, aerosol;
The described occupation mode from foaming composition is astringent, emulsion, cream frost, elite, jelly, gel, ointment, facial film, foundation cream, sun-proof, shampoo, clean, take a shower, mascara or makeup removal products.
8. according to claim 3 from foaming composition, it is characterized in that: described cosmetic composition is clean the gel that certainly foam, and it is prepared from by the raw material of following mass percent:
Deionized water: surplus;
EDETATE SODIUM: 0.1%;
Glycerol: 2%;
PEG-120 methyl dioleate: 0.3%;
Sodium laureth sulfate: 15%;
Decyl glucoside: 5%;
Pyrrolidone sodium carboxylate: 1%;
Cocamido propyl betaine: 5%;
Polyquaternary ammonium salt-7:1%;
Acrylic acid (ester) analog copolymer: 4%;
Sodium chloride: 0.2%;
Sodium hydroxide: 0.08%;
Essence: 0.35%;
Antiseptic: 0.4%;
Novec HFE-7100：10％。
9. the preparation method from foaming composition in claim 1-8 described in any one claim, is characterized in that: comprise the steps:
(1) all for component A raw materials are dropped into emulsifying pot, be warmed up to 85 DEG C, stir or homogenizing, make A phase materials dissolve completely;
(2) under stirring state, B group material is added in component A successively, if there is oil phase, finally add the oil phase dissolved, and low speed homogenizing 1-5 minute;
(3) add C component under stirring, and low speed homogenizing is to disperseing completely;
(4) under stirring, neutralizing with D phase nertralizer, is 6-8 to pH value;
(5) cool to 40 DEG C or following, add essence, antiseptic, active component, stir, obtain base material, take the dish out of the pot for subsequent use;
(6) before fill, foaming agent is added base material and mix homogeneously, shorten this step operating time as far as possible;
(7) the material body mixed is carried out fill, container tightness will be got well, and selects disposable plastic packaging bag.
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