CN104631148B - Preparation of polypropylene fiber fabric and liquid multi-combination printing and dyeing pretreatment process - Google Patents

Preparation of polypropylene fiber fabric and liquid multi-combination printing and dyeing pretreatment process Download PDF

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CN104631148B
CN104631148B CN201510065890.9A CN201510065890A CN104631148B CN 104631148 B CN104631148 B CN 104631148B CN 201510065890 A CN201510065890 A CN 201510065890A CN 104631148 B CN104631148 B CN 104631148B
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fabric
sodium hydroxide
sodium
time
polypropylene fiber
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CN104631148A (en
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陈菊媛
陈菊珍
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Suzhou Chenheng Weaving Co ltd
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Suzhou Chenheng Weaving Co ltd
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Abstract

The invention discloses a preparation and liquid multi-combination printing and dyeing pretreatment process of a polypropylene fiber fabric, which comprises the following selected warp and weft materials in parts by mass: 40-90 parts of polypropylene fiber, 20-40 parts of combed cotton and 8-18 parts of superfine denier polyester, wherein in the sizing process, a liquid polyblend auxiliary agent is added into the sizing agent, and the pH value of the liquid polyblend auxiliary agent for dyeing is 2 g/L: 8.5 plus or minus 1; in the auxiliary agent: the sodium hydroxide, the chelating agent and the sodium hexametaphosphate are respectively calculated according to the parts by weight: sodium hydroxide: 0.5-1.5 parts of chelating agent: 0.2-0.5 parts, sodium hexametaphosphate: 0.2-1 part, wherein the mass ratio of the total mass of the sodium hydroxide, the chelating agent and the sodium hexametaphosphate to the water is 2: 50; and after the sizing process is finished, keeping the temperature for 50-80min according to the concentration of the dye of the fabric; the invention can lead the fabric to have the advantages of high elasticity, high strength, heat preservation, heat resistance and light resistance, and simultaneously, the fabric can quickly permeate and diffuse to fibers in the subsequent dye liquor, thereby effectively preventing the generation of cylinder difference, color spots, color difference and color fixing spots in the printing and dyeing process.

Description

The preparation of a kind of polypropylene fiber fabric and liquid many conjunctions printing and dyeing pretreating process
Technical field
The invention belongs to textile technology field, the preparation of a kind of polypropylene fiber fabric and the pre-place of liquid many conjunctions printing and dyeing Science and engineering skill.
Background technology
Polypropylene fiber is also known as polypropylene fibre.Abundant raw material source, production technology is simple, and product price compares, and other close Become fiber cheap;The physical and mechanical properties feature of fiber is: intensity high (chopped fiber is 4~6 g denier, long filament is 5~8 grams/ Denier), wet strength and dry strength are essentially identical, proportion little (0.91), wear-resistant corrosion-resistant etc.;Owing to polypropylene has production technology letter The advantages such as single, product is inexpensive, and intensity is high, and relative density is light, so polypropylene develops quickly.Current polypropylene has been synthetic fibers The fourth-largest kind, is fiber the lightest in general chemical fiber.
The maximum advantage of polypropylene fiber is that quality is light, its density only 0.91g/cm3 be general chemical fiber Midst density Light kind, so the higher area coverage that the polypropylene of same weight obtains than other fibers;Intensity is high, and elongation is big, just Beginning modulus is higher, excellent spring.So polypropylene wearability is good.Additionally, wet strong being substantially equal to of polypropylene is done by force, so it is to make Fishing net, the ideal material of hawser.
Polypropylene fiber light weight warmth retention property is good, moisture absorption hardly, but wicking capacity is very strong, and moisture absorbing and sweat releasing effect is obvious;Polypropylene Hygroscopicity the least, moisture absorption hardly, the regain under the conditions of general atmosphere is close to zero;But it has core sucting action, can pass through Capillary tube transmission steam in fabric, but itself does not play any Absorption, and the dyeability of polypropylene is poor, and chromatograph is the most complete;Existing Have in technology, on market substitute alkali be dye for reactive dyestuffs in exhaustion in the high cost of soda, use inconvenience and developing to open A kind of new product sent out, with calcium hydroxide as dispensing, while being effectively reduced dyeing alkaline agent cost, and can improve dyeing One-time success rate, hence it is evident that reduce dyeing integrated cost.
But, although substitute alkali has above-mentioned advantage on the market, but in use there is also some problems, substitute alkali pair The colour fixation of polypropylene fiber structure-activity dyestuff has obvious selectivity;Reactive dye are made alkaline agent with substitute alkali and are contaminated, and are permitted Low 5%-10% when the high colour-fast rate of many dyestuffs makees alkaline agent than natrium carbonicum calcinatum, some dyestuff dye-uptake is understable, dyeing color The dyeing deviation of light and soda, still there is main problem for substitute alkali containing a large amount of color patterns difference etc., substitute alkali fixation rate with With the deviation of soda form and aspect, the coffee of bright the reddest colorant match, purple even depth are not as soda, and form and aspect are excessive with soda difference, Effect is undesirable;Meanwhile, the in use easy calcium deposit that formed in dye vat of the calcium hydroxide in substitute alkali is difficult to remove, greatly Have impact on greatly follow-up printing quality.
Summary of the invention
The technical problem to be solved is, the shortcoming overcoming prior art, it is provided that a kind of polypropylene fiber fabric Preparation and liquid many conjunctions printing and dyeing pretreating process, it is possible to make fabric have high resiliency, high intensity, fast light advantage warming, heat-resisting, Meanwhile, it is capable to rapid osmotic diffuses to fiber on fabric in follow-up dye liquor, effectively prevent that cylinder in dyeing process is poor, color Flower, aberration and the generation of fixation speckle.
In order to solve above technical problem, the present invention provides the preparation of a kind of polypropylene fiber fabric and close of liquid to print and dye in advance more Process technique, selection through weft material be according to the mass fraction: polypropylene fiber 40-90 part, combed cotton 20-40 part, super fine denier Terylene 8-18 part, the preparation section of described fabric lining is scutching cotton, comb and parallel cotton fibers prior to spinning, drafting, rove, spun yarn and weaving operation, wherein: institute State operation of weaving cotton cloth and include warping, Vacuum shaping, sizing and jet operation;
In described sizing operation, adding liquid many conjunctions auxiliary agent in slurry, described liquid many conjunctions auxiliary agent is sodium hydroxide, chelating Agent and the aqueous solution of sodium hexameta phosphate, this liquid pH value closing dyeing used additives is 2g/L:8.5 ± 1 more, wherein;
Described sodium hydroxide, chelating agen and sodium hexameta phosphate are respectively as follows: according to the mass fraction
Sodium hydroxide: 0.5-1.5 part, chelating agen: 0.2-0.5 part, sodium hexameta phosphate: 0.2-1 part, described sodium hydroxide, The gross mass of chelating agen and sodium hexameta phosphate and the mass ratio of water are 2:50;And after slashing technique terminates according to fabric wait contaminate Material concentration insulation 50-80min;
Described Vacuum shaping concretely comprises the following steps:Being pushed by fabric in steaming silk case and water filling in case, water injection rate control is Not having 1/3rd of fabric height, silk case is steamed in preheating makes its internal temperature reach 20-35 DEG C;Utilize water ring vacuum pump to case Internal carry out for the first time evacuation, and box house is heated so that low-temperature saturated steam is penetrated in fabric, heating 0.6-0.8h keeps case body temperature to stand 45-50min after reaching 80-90 DEG C;Casing after standing is carried out second time take out Vacuum, and again inside heating compartment, heat time heating time, 30-45min, kept case body temperature to be 86-95 DEG C;After heating terminates It is incubated and stands 25-30min, i.e. completing the Vacuum shaping of fabric.
Technique effect: owing to the present invention uses above technical scheme, use polypropylene fiber, combed cotton and superfine denier polyester Blending so that fabric has high resiliency, high intensity, fast light advantage warming, heat-resisting;It is to carry out fiber that Vacuum shaping processes Humid heat treatment, appropriate humid heat treatment is to the effect of having greatly improved of the physical and mechanical properties of fiber, after fiber absorbs moisture, meeting Releasing heat, now, fiber molecule warm-up movement weakens, and internal structure stability strengthens, and now gives yarn a certain degree of heat Amount compensates, and keeps continuing and stable of this state, makes yarn ectonexine can be significantly improved the entirety of fabric by equal heat treatment Performance;
Owing to, in the dyeing process of textile, dyestuff enters the process of fibrous inside and is divided into:Absorption,Diffusion and Set, yet with the performance deficiency of soda, absorption and diffusion process interfere impact, it is impossible to reach high-level printing and dyeing effect Really, and after in the present invention, sodium hydroxide, chelating agen and sodium hexameta phosphate fully dissolve, when carrying out printing and dyeing operation as auxiliary agent, energy Enough in dye liquor and on cloth cover rapid osmotic diffuse to fiber, effectively prevent that cylinder in dyeing process is poor, color colored, aberration and fixation The generation of speckle;
Printing and dyeing pretreatment designed by the present invention, due to liquid many conjunctions auxiliary agent quick diffusion performance, greatly reduces Dye adsorption diffusion time, it is used alone soda it is generally required to the time of 5min completes, and employs that liquid closes dyeing and use more Auxiliary agent pretreatment then have only to 2min i.e. can the effect of this excellence, shortening time of whole operation reaches 60%, thus significantly The energy consumption in dyeing process and workload are saved;
The technical scheme that the present invention limits further is:
Further, the preparation of aforesaid polypropylene fiber fabric and liquid many conjunctions printing and dyeing pretreating process, described liquid is many Conjunction auxiliary agent is the aqueous solution of sodium hydroxide, chelating agen and sodium hexameta phosphate, and described sodium hydroxide, chelating agen and sodium hexameta phosphate are pressed Mass fraction meter is respectively as follows:
Sodium hydroxide: 1.0 parts, chelating agen: 0.35 part, sodium hexameta phosphate: 0.65 part, described sodium hydroxide, chelating agen and The gross mass of sodium hexameta phosphate and the mass ratio of water are 2:50.
The preparation of aforesaid polypropylene fiber fabric and liquid many conjunctions printing and dyeing pretreating process, described liquid many conjunctions auxiliary agent is hydrogen The aqueous solution of sodium oxide, chelating agen and sodium hexameta phosphate, described sodium hydroxide, chelating agen and sodium hexameta phosphate are according to the mass fraction It is respectively as follows:
Sodium hydroxide: 0.8 part, chelating agen: 0.4 part, sodium hexameta phosphate: 0.55 part, described sodium hydroxide, chelating agen and six The gross mass of Polymeric sodium metaphosphate. and the mass ratio of water are 2:50.
The preparation of aforesaid polypropylene fiber fabric and liquid many conjunctions printing and dyeing pretreating process, until dye strength 0-when 0.3%, Temperature retention time is 50min;
Until dye strength 0.3-when 1.5%, temperature retention time is 60min;
Until dye strength 1.5-when 4%, temperature retention time is 80min;
In printing and dyeing preprocessing process, according to treating the concentration of fuel, by strictly controlling temperature retention time, efficiently solve third Synthetic fibre fabric lining in terms of the deviation of fixation rate and form and aspect with the performance gap of soda, according to different printing and dyeing concentration, design Different pretreatment temperature retention times, is all significantly improved in terms of fixation rate in the printing and dyeing degree of depth.
The preparation of aforesaid polypropylene fiber fabric and liquid many conjunctions printing and dyeing pretreating process, described Vacuum shaping concrete steps For:Being pushed by fabric in steaming silk case and water filling in case, water injection rate controls as not having 1/3rd of fabric height, and preheating is steamed Silk case makes its internal temperature reach 28 DEG C;Utilize water ring vacuum pump to carrying out for the first time evacuation in casing, and in casing Portion heats so that penetrated into by low-temperature saturated steam in fabric, and heating 0.7h is quiet after keeping case body temperature to reach 85 DEG C Put 48min;Casing after standing is carried out second time evacuation, and again inside heating compartment, heat time heating time, 36min, protected Holding case body temperature is 90 DEG C;Heating is incubated after terminating and stands 26min, i.e. completes the Vacuum shaping of fabric.
The preparation of aforesaid polypropylene fiber fabric and liquid many conjunctions printing and dyeing pretreating process, in described spun yarn step, back zone Drafting multiple is 1.31, and yarn twist factor is 380, and ingot speed is 16000r/min;In described winder step, speed is 1000m/ Min, pressurize 6-10N.
The preparation of aforesaid polypropylene fiber fabric and liquid many conjunctions printing and dyeing pretreating process, in described warping step, speed For 280m/min, ambient temperature 24 DEG C, relative humidity 68%, rolling density is 0.53-0.56g/cm3, break end time delay 1s;
In described air-jet weaving step, time main jet time is 100 °, main jet air pressure 2.1Mpa;
The auxiliary spray time: the most auxiliary spray: 240-360 °, air pressure is increased to 4.4Mpa, the most auxiliary spray: 550-800 °, gas Pressure drop is to 1.6Mpa.
Detailed description of the invention
Embodiment 1
The preparation of a kind of polypropylene fiber fabric that the present embodiment provides and liquid many conjunctions printing and dyeing pretreating process, the warp of selection Weft material is according to the mass fraction: polypropylene fiber 56 parts, combed cotton 28 parts, superfine denier polyester 12 parts, described fabric lining Preparation section is scutching cotton, comb and parallel cotton fibers prior to spinning, drafting, rove, spun yarn and weaving operation, wherein: described in operation of weaving cotton cloth include warping, vacuum Sizing, sizing and jet operation;
In described sizing operation, adding liquid many conjunctions auxiliary agent in slurry, described liquid many conjunctions auxiliary agent is sodium hydroxide, chelating Agent and the aqueous solution of sodium hexameta phosphate, this liquid pH value closing dyeing used additives is 2g/L:8.5 ± 1 more, wherein;
Described sodium hydroxide, chelating agen and sodium hexameta phosphate are respectively as follows: according to the mass fraction
Sodium hydroxide: 1.0 parts, chelating agen: 0.35 part, sodium hexameta phosphate: 0.65 part, described sodium hydroxide, chelating agen and The gross mass of sodium hexameta phosphate and the mass ratio of water are 2:50;Until dye strength 0.3-when 1.5%, temperature retention time is 60min;
Described Vacuum shaping concretely comprises the following steps:Being pushed by fabric in steaming silk case and water filling in case, water injection rate control is Not having 1/3rd of fabric height, silk case is steamed in preheating makes its internal temperature reach 25 DEG C;Utilize water ring vacuum pump to casing Inside carry out evacuation for the first time, and box house is heated so that low-temperature saturated steam is penetrated in fabric, heating 0.6-0.8h keeps case body temperature to stand 48min after reaching 82 DEG C;Casing after standing is carried out second time evacuation, and Again inside heating compartment, heat time heating time 42min, keep case body temperature be 88 DEG C;Heating is incubated and stands after terminating 26min, i.e. completes the Vacuum shaping of fabric;
In described spun yarn step, back zone drafting multiple is 1.31, and yarn twist factor is 380, and ingot speed is 16000r/min;Institute Stating in winder step, speed is 1000m/min, and pressurize 7N;
In described warping step, speed is 280m/min, ambient temperature 24 DEG C, relative humidity 68%, and rolling density is 0.54g/cm3, break end time delay 1s;
In described air-jet weaving step, time main jet time is 100 °, main jet air pressure 2.1Mpa;
The auxiliary spray time: the most auxiliary spray: 280 °, air pressure is increased to 4.4Mpa, the most auxiliary spray: 560 °, air pressure is down to 1.6Mpa。
Embodiment 2
The preparation of a kind of polypropylene fiber fabric that the present embodiment provides and liquid many conjunctions printing and dyeing pretreating process, the warp of selection Weft material is according to the mass fraction: polypropylene fiber 65 parts, combed cotton 36 parts, superfine denier polyester 11 parts, described fabric lining Preparation section is scutching cotton, comb and parallel cotton fibers prior to spinning, drafting, rove, spun yarn and weaving operation, wherein: described in operation of weaving cotton cloth include warping, vacuum Sizing, sizing and jet operation;
In described sizing operation, adding liquid many conjunctions auxiliary agent in slurry, described liquid many conjunctions auxiliary agent is sodium hydroxide, chelating Agent and the aqueous solution of sodium hexameta phosphate, this liquid pH value closing dyeing used additives is 2g/L:8.5 ± 1 more, wherein;
Described sodium hydroxide, chelating agen and sodium hexameta phosphate are respectively as follows: according to the mass fraction
The aqueous solution of sodium hydroxide, chelating agen and sodium hexameta phosphate, described sodium hydroxide, chelating agen and sodium hexameta phosphate are pressed Mass fraction meter is respectively as follows:
Sodium hydroxide: 0.8 part, chelating agen: 0.4 part, sodium hexameta phosphate: 0.55 part, described sodium hydroxide, chelating agen and six The gross mass of Polymeric sodium metaphosphate. and the mass ratio of water are 2:50;Until dye strength 1.5-when 4%, temperature retention time is 80min;
Described Vacuum shaping concretely comprises the following steps:Being pushed by fabric in steaming silk case and water filling in case, water injection rate control is Not having 1/3rd of fabric height, silk case is steamed in preheating makes its internal temperature reach 28 DEG C;Utilize water ring vacuum pump to casing Inside carry out evacuation for the first time, and box house is heated so that low-temperature saturated steam is penetrated in fabric, heating 0.7h keeps case body temperature to stand 48min after reaching 85 DEG C;Casing after standing is carried out second time evacuation, and again Inside heating compartment, heat time heating time 36min, keep case body temperature be 90 DEG C;Heating is incubated after terminating and stands 26min, I.e. complete the Vacuum shaping of fabric;
In described spun yarn step, back zone drafting multiple is 1.31, and yarn twist factor is 380, and ingot speed is 16000r/min;Institute Stating in winder step, speed is 1000m/min, and pressurize 8N.
In described warping step, speed is 280m/min, ambient temperature 24 DEG C, relative humidity 68%, and rolling density is 0.56g/cm3, break end time delay 1s;
In described air-jet weaving step, time main jet time is 100 °, main jet air pressure 2.1Mpa;
The auxiliary spray time: the most auxiliary spray: 320 °, air pressure is increased to 4.4Mpa, the most auxiliary spray: 650 °, air pressure is down to 1.6Mpa。
Above example is only the technological thought that the present invention is described, it is impossible to limit protection scope of the present invention with this, every The technological thought proposed according to the present invention, any change done on the basis of technical scheme, each fall within scope Within.

Claims (7)

1. the preparation technology of a polypropylene fiber fabric, it is characterised in that selection through weft material be according to the mass fraction: third Synthetic fibre fiber 40-90 part, combed cotton 20-40 part, superfine denier polyester 8-18 part, the preparation section of described fabric lining is scutching cotton, comb Cotton, drafting, rove, spun yarn and weaving operation, wherein: described weaving operation includes that warping, Vacuum shaping, sizing and jet are knitted Make;
In described sizing operation, in slurry add liquid many conjunctions auxiliary agent, described liquid many conjunctions auxiliary agent be sodium hydroxide, chelating agen and The aqueous solution of sodium hexameta phosphate, the pH value of this liquid many conjunctions auxiliary agent is 2g/L:8.5 ± 1, wherein;
Described sodium hydroxide, chelating agen and sodium hexameta phosphate are respectively as follows: according to the mass fraction
Sodium hydroxide: 0.5-1.5 part, chelating agen: 0.2-0.5 part, sodium hexameta phosphate: 0.2-1 part, described sodium hydroxide, chelating The gross mass of agent and sodium hexameta phosphate and the mass ratio of water are 2:50;And treat that dyestuff is dense according to fabric after slashing technique terminates Degree insulation 50-80min;
Described Vacuum shaping concretely comprises the following steps: pushed by fabric in steaming silk case and water filling in case, and water injection rate controls as not have face / 3rd of material height, silk case is steamed in preheating makes its internal temperature reach 20-35 DEG C;Water circulation vacuum pump is utilized to enter in casing Row evacuation for the first time, and box house is heated so that low-temperature saturated steam is penetrated in fabric, heat 0.6- 0.8h keeps case body temperature to stand 45-50min after reaching 80-90 DEG C;Casing after standing is carried out second time evacuation, and Again inside heating compartment, heat time heating time, 30-45min, kept case body temperature to be 86-95 DEG C;Heating is incubated and quiet after terminating Put 25-30min, i.e. complete the Vacuum shaping of fabric.
The preparation technology of polypropylene fiber fabric the most according to claim 1, it is characterised in that described liquid many conjunctions auxiliary agent is The aqueous solution of sodium hydroxide, chelating agen and sodium hexameta phosphate, mass fraction pressed by described sodium hydroxide, chelating agen and sodium hexameta phosphate Meter is respectively as follows:
Sodium hydroxide: 1.0 parts, chelating agen: 0.35 part, sodium hexameta phosphate: 0.65 part, described sodium hydroxide, chelating agen and six are inclined The gross mass of sodium phosphate and the mass ratio of water are 2:50.
The preparation technology of polypropylene fiber fabric the most according to claim 1, it is characterised in that described liquid many conjunctions auxiliary agent is The aqueous solution of sodium hydroxide, chelating agen and sodium hexameta phosphate, mass fraction pressed by described sodium hydroxide, chelating agen and sodium hexameta phosphate Meter is respectively as follows:
Sodium hydroxide: 0.8 part, chelating agen: 0.4 part, sodium hexameta phosphate: 0.55 part, described sodium hydroxide, chelating agen and six phosphorus partially The acid gross mass of sodium is 2:50 with the mass ratio of water.
The preparation technology of polypropylene fiber fabric the most according to claim 1, it is characterised in that:
Until dye strength 0-when 0.3%, temperature retention time is 50min;
Until dye strength 0.3-when 1.5%, temperature retention time is 60min;
Until dye strength 1.5-when 4%, temperature retention time is 80min.
The preparation technology of polypropylene fiber fabric the most according to claim 1, it is characterised in that described Vacuum shaping specifically walks Suddenly being: pushed by fabric in steaming silk case and water filling in case, water injection rate controls as not having 1/3rd of fabric height, and preheating is steamed Silk case makes its internal temperature reach 28 DEG C;Utilize water circulation vacuum pump to carrying out for the first time evacuation in casing, and in casing Portion heats so that penetrated into by low-temperature saturated steam in fabric, and heating 0.7h is quiet after keeping case body temperature to reach 85 DEG C Put 48min;Casing after standing is carried out second time evacuation, and again inside heating compartment, heat time heating time, 36min, kept Case body temperature is 90 DEG C;Heating is incubated after terminating and stands 26min, i.e. completes the Vacuum shaping of fabric.
The preparation technology of polypropylene fiber fabric the most according to claim 1, it is characterised in that in described spun yarn step, after District's drafting multiple is 1.31, and yarn twist factor is 380, and ingot speed is 16000r/min.
The preparation technology of polypropylene fiber fabric the most according to claim 1, it is characterised in that in described warping step, car Speed is 280m/min, ambient temperature 24 DEG C, relative humidity 68%, and rolling density is 0.53-0.56g/cm3, break end time delay 1s;
In described air-jet weaving step, the main jet time is 100 °, main jet air pressure 2.1MPa;
The auxiliary spray time: the most auxiliary spray: 240-360 °, air pressure is increased to 4.4MPa, the most auxiliary spray: 550-800 °, air pressure drop To 1.6MPa.
CN201510065890.9A 2015-02-09 2015-02-09 Preparation of polypropylene fiber fabric and liquid multi-combination printing and dyeing pretreatment process Expired - Fee Related CN104631148B (en)

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