CN104626665A - 一种具有高粘度的阻燃型硅芯管 - Google Patents
一种具有高粘度的阻燃型硅芯管 Download PDFInfo
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 26
- 229920001903 high density polyethylene Polymers 0.000 claims abstract description 21
- 239000004700 high-density polyethylene Substances 0.000 claims abstract description 21
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000007787 solid Substances 0.000 claims abstract description 13
- 229920001296 polysiloxane Polymers 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- 239000000314 lubricant Substances 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
- ACOGMWBDRJJKNB-UHFFFAOYSA-N acetic acid;ethene Chemical group C=C.CC(O)=O ACOGMWBDRJJKNB-UHFFFAOYSA-N 0.000 claims description 6
- 239000003963 antioxidant agent Substances 0.000 claims description 6
- 230000003078 antioxidant effect Effects 0.000 claims description 6
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 6
- 239000003085 diluting agent Substances 0.000 claims description 6
- 229920001038 ethylene copolymer Polymers 0.000 claims description 6
- 239000004014 plasticizer Substances 0.000 claims description 6
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical group CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 3
- 150000004703 alkoxides Chemical class 0.000 claims description 3
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 3
- KLKFAASOGCDTDT-UHFFFAOYSA-N ethoxymethoxyethane Chemical compound CCOCOCC KLKFAASOGCDTDT-UHFFFAOYSA-N 0.000 claims description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 3
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical group [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 3
- -1 phthalic acid ester Chemical class 0.000 claims description 3
- 229940126214 compound 3 Drugs 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 238000005461 lubrication Methods 0.000 abstract 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
- B32B1/08—Tubular products
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C08L31/04—Homopolymers or copolymers of vinyl acetate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
- C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09J131/04—Homopolymers or copolymers of vinyl acetate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
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- Chemical & Material Sciences (AREA)
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- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明涉及一种具有高粘度的阻燃型硅芯管,从外到内依次包括高密度聚乙烯层和固体润滑层,其特征为在高密度聚乙烯层和固体润滑层之间设有粘结层,在高密度聚乙烯层外设有阻燃层;本发明所具有的优点是在高密度聚乙烯层和固体润滑层中加入粘结层,可以增加高密度聚乙烯层和固体润滑层粘结性,在高密度聚乙烯层的上面增加阻燃层,从而可以达到一定的阻燃效果。
Description
技术领域
本发明涉及管子领域,特别涉及一种具有高粘度的阻燃型硅芯管。
背景技术
硅芯管是一种内壁带有硅胶质固体润滑剂的新型复合管道,密封性能好,耐化学腐蚀,工程造价低,广泛运用于高速公路,铁路等的光电缆通信网络系统。HDPE硅芯管是一种内壁带有硅胶质固体润滑剂的新型复合管道,简称硅管。广泛运用于光电缆通信网络系统。而现有的硅芯管,在使用时高密度聚乙烯层和芯层之间容易脱开,而且遇到高温易燃烧。
发明内容
针对上述缺点,本发明目的在于提供一种具有高粘度和阻燃功能的硅芯管。
为实现上述目的,本发明采用的技术方案是:一种具有高粘度的阻燃型硅芯管,从外到内依次包括高密度聚乙烯层和固体润滑层,其特征为在高密度聚乙烯层和固体润滑层之间设有粘结层,在高密度聚乙烯层外设有阻燃层;
所述粘结层中包括如下重量百分比的组份:
醋酸乙烯共聚物(EVA) 50~60;
增粘剂 10~20 ;
稀释剂 10~20 ;
抗氧剂 10~15 ;
增塑剂 5~10;
其中增粘剂为3MAC78增粘剂;抗氧剂为抗氧剂1010;增塑剂为邻苯二甲酸酯;
所述稀释剂中包括如下重量百分比的组份:
二乙氧基甲烷 55~65;
二甲苯 7~10;
乙醇 10~15;
乙二醇 5~10;
烷氧基化合物 3~5;
环己酮 2~5;
阻燃层中包括如下重量百分比的组份:
醋酸乙烯共聚物(EVA) 60~80;
阻燃剂 20~40;
其中阻燃剂为氧化锑。
本发明与现有技术相比所具有的优点是:本发明通过在高密度聚乙烯层和固体润滑层中加入粘结层,可以增加高密度聚乙烯层和固体润滑层粘结性,在高密度聚乙烯层的上面增加阻燃层,从而可以达到一定的阻燃效果。
附图说明
图1是本发明的结构示意图。
附图标记为:
1、高密度聚乙烯层; 2、固体润滑层、 3、粘结层、 4、阻燃层。
具体实施方式
下面将结合附图以及具体实施例来详细说明本发明,其中的示意性实施例以及说明仅用来解释本发明,但并不作为对本发明的限定。
如图1所示,一种具有高粘度的阻燃型硅芯管,从外到内依次包括高密度聚乙烯层1和固体润滑层2,其特征为在高密度聚乙烯层1和固体润滑层2之间设有粘结层3,在高密度聚乙烯层1外设有阻燃层4;
所述粘结层中包括如下重量百分比的组份:
醋酸乙烯共聚物(EVA) 50;
增粘剂 20;
稀释剂 10;
抗氧剂 10 ;
增塑剂 10;
其中增粘剂为3MAC78增粘剂(东莞市艺辉胶粘剂有限公司);抗氧剂为抗氧剂1010;增塑剂为邻苯二甲酸酯;
所述稀释剂中包括如下重量百分比的组份:
二乙氧基甲烷 55;
二甲苯 10;
乙醇 15;
乙二醇 10;
烷氧基化合物 5;
环己酮 5;
阻燃层中包括如下重量百分比的组份:
醋酸乙烯共聚物(EVA) 80;
阻燃剂 20;
其中阻燃剂为氧化锑。
Claims (1)
1.一种具有高粘度的阻燃型硅芯管,从外到内依次包括高密度聚乙烯层(1)和固体润滑层(2),其特征在于,在高密度聚乙烯层(1)和固体润滑层(2)之间设有粘结层(3),在高密度聚乙烯层(1)外设有阻燃层(4);
所述粘结层中包括如下重量百分比的组份:
醋酸乙烯共聚物(EVA) 50~60;
增粘剂 10~20 ;
稀释剂 10~20 ;
抗氧剂 10~15 ;
增塑剂 5~10;
其中增粘剂为3MAC78增粘剂;抗氧剂为抗氧剂1010;增塑剂为邻苯二甲酸酯;
所述稀释剂中包括如下重量百分比的组份:
二乙氧基甲烷 55~65;
二甲苯 7~10;
乙醇 10~15;
乙二醇 5~10;
烷氧基化合物 3~5;
环己酮 2~5;
阻燃层中包括如下重量百分比的组份:
醋酸乙烯共聚物(EVA) 60~80;
阻燃剂 20~40;
其中阻燃剂为氧化锑。
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108129863A (zh) * | 2017-11-22 | 2018-06-08 | 新宇电缆集团股份有限公司 | 一种防火型耐高温电缆阻燃层 |
CN111016336A (zh) * | 2019-12-23 | 2020-04-17 | 苏州茂顺成通信技术有限公司 | 一种阻燃hdpe电力顶管 |
-
2013
- 2013-11-15 CN CN201310569008.5A patent/CN104626665A/zh active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108129863A (zh) * | 2017-11-22 | 2018-06-08 | 新宇电缆集团股份有限公司 | 一种防火型耐高温电缆阻燃层 |
CN111016336A (zh) * | 2019-12-23 | 2020-04-17 | 苏州茂顺成通信技术有限公司 | 一种阻燃hdpe电力顶管 |
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