CN104562130B - 轻金属或其合金表面氧化钛基陶瓷膜层的制造方法 - Google Patents
轻金属或其合金表面氧化钛基陶瓷膜层的制造方法 Download PDFInfo
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- CN104562130B CN104562130B CN201410419742.8A CN201410419742A CN104562130B CN 104562130 B CN104562130 B CN 104562130B CN 201410419742 A CN201410419742 A CN 201410419742A CN 104562130 B CN104562130 B CN 104562130B
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 83
- 238000000034 method Methods 0.000 title claims abstract description 43
- 239000000919 ceramic Substances 0.000 title claims abstract description 42
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 33
- 239000000956 alloy Substances 0.000 title claims abstract description 33
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 31
- 239000002184 metal Substances 0.000 title claims abstract description 31
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 26
- 239000003792 electrolyte Substances 0.000 claims abstract description 48
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 36
- 230000003647 oxidation Effects 0.000 claims abstract description 35
- 238000004070 electrodeposition Methods 0.000 claims abstract description 34
- 238000005516 engineering process Methods 0.000 claims abstract description 21
- 230000008569 process Effects 0.000 claims abstract description 18
- 239000002253 acid Substances 0.000 claims abstract description 13
- 150000003608 titanium Chemical class 0.000 claims abstract description 13
- 210000004027 cell Anatomy 0.000 claims description 30
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical class [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 13
- 239000010936 titanium Substances 0.000 claims description 13
- 229910052719 titanium Inorganic materials 0.000 claims description 13
- 238000011282 treatment Methods 0.000 claims description 12
- 239000002826 coolant Substances 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 230000005611 electricity Effects 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 7
- 210000005056 cell body Anatomy 0.000 claims description 6
- 239000004033 plastic Substances 0.000 claims description 6
- 229920003023 plastic Polymers 0.000 claims description 6
- 229910044991 metal oxide Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- 238000000151 deposition Methods 0.000 claims description 4
- 230000008021 deposition Effects 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 239000010935 stainless steel Substances 0.000 claims description 4
- 229910001220 stainless steel Inorganic materials 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 238000002425 crystallisation Methods 0.000 claims description 3
- 230000008025 crystallization Effects 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 239000005300 metallic glass Substances 0.000 claims description 3
- 238000005868 electrolysis reaction Methods 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- 239000000110 cooling liquid Substances 0.000 claims 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 18
- 229910052782 aluminium Inorganic materials 0.000 description 18
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 18
- 239000004411 aluminium Substances 0.000 description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 13
- 229910052760 oxygen Inorganic materials 0.000 description 13
- 239000001301 oxygen Substances 0.000 description 13
- 239000011248 coating agent Substances 0.000 description 12
- 238000000576 coating method Methods 0.000 description 12
- 229910000838 Al alloy Inorganic materials 0.000 description 10
- 239000000243 solution Substances 0.000 description 9
- 229910000831 Steel Inorganic materials 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- 230000008859 change Effects 0.000 description 8
- 239000010959 steel Substances 0.000 description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 7
- 239000011777 magnesium Substances 0.000 description 7
- 229910052749 magnesium Inorganic materials 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- 235000006408 oxalic acid Nutrition 0.000 description 6
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- 239000004408 titanium dioxide Substances 0.000 description 6
- 238000002441 X-ray diffraction Methods 0.000 description 5
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- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
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- 238000005238 degreasing Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229910052573 porcelain Inorganic materials 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 3
- 229910001069 Ti alloy Inorganic materials 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
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- 239000003973 paint Substances 0.000 description 3
- 239000001103 potassium chloride Substances 0.000 description 3
- 235000011164 potassium chloride Nutrition 0.000 description 3
- GROMGGTZECPEKN-UHFFFAOYSA-N sodium metatitanate Chemical compound [Na+].[Na+].[O-][Ti](=O)O[Ti](=O)O[Ti]([O-])=O GROMGGTZECPEKN-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000003746 surface roughness Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 230000003321 amplification Effects 0.000 description 2
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- 229910052802 copper Inorganic materials 0.000 description 2
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- 229910052593 corundum Inorganic materials 0.000 description 2
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- 238000005406 washing Methods 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 244000248349 Citrus limon Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- 229910003310 Ni-Al Inorganic materials 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
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- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
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- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
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- 230000007704 transition Effects 0.000 description 1
Landscapes
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
Description
实施例1 | 实施例2 | 实施例3 | 实施例4 |
电解液温度(℃) | 15 | 25 | 20 | 20 |
5.5 | 8.5 | 6.5 | 6.5 | |
交流脉冲电压(V) | 350 | 500 | 380 | 380 |
pH值 | 2.5 | 3.5 | 3.0 | 3.0 |
氧化和沉积时间(分钟) | 1 | 3 | 1.5 | 2.5 |
膜层厚度(μm) | 5 | 15 | 8 | 12 |
陶瓷膜层颜色 | 浅灰色 | 深灰色 | 较浅灰色 | 较深灰色 |
维卡硬度 | 637 | 800 | 700 | 760 |
表面粗糙度(μm) | 0.05 | 0.01 | 0.03 | 0.02 |
盐雾试验(小时) | ﹥5000 | ﹥5000 | ﹥5000 | ﹥5000 |
实施例5 | 实施例6 | |
电解液温度(℃) | 25 | 25 |
7.0 | 7.0 | |
交流脉冲电压(V) | 380 | 380 |
pH值 | 3.0 | 3.0 |
氧化和沉积时间(分钟) | 2 | 2 |
膜层厚度(μm) | 12 | 12 |
陶瓷膜层颜色 | 较深灰色 | 深灰色 |
维卡硬度 | 720 | 800 |
表面粗糙度(μm) | 0.02 | 0.01 |
盐雾试验(小时) | ﹥5000 | ﹥5000 |
Claims (10)
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CN201410419742.8A CN104562130B (zh) | 2014-08-22 | 2014-08-22 | 轻金属或其合金表面氧化钛基陶瓷膜层的制造方法 |
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CN201410419742.8A CN104562130B (zh) | 2014-08-22 | 2014-08-22 | 轻金属或其合金表面氧化钛基陶瓷膜层的制造方法 |
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CN104562130B true CN104562130B (zh) | 2017-06-16 |
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CN107387254A (zh) * | 2017-07-26 | 2017-11-24 | 安庆雅德帝伯活塞有限公司 | 一种ecc涂层发动机活塞 |
CN107247299A (zh) * | 2017-07-28 | 2017-10-13 | 信利光电股份有限公司 | 一种盖板及电子设备 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1623013A (zh) * | 2002-03-27 | 2005-06-01 | 岛屿涂层有限公司 | 用于在金属和合金上形成陶瓷涂层的方法和装置及由此方法制得的涂层 |
CN101092730A (zh) * | 2007-06-25 | 2007-12-26 | 大连海事大学 | 一种低能耗微弧氧化方法和装置 |
WO2008120046A1 (en) * | 2007-04-02 | 2008-10-09 | Gostevs, Vladimirs | Method of forming a protective ceramic coating on the surface of metal products |
CN101709496A (zh) * | 2009-11-30 | 2010-05-19 | 郑州大学 | 一种镁基生物活性涂层的微弧氧化-电沉积制备方法 |
CN201915159U (zh) * | 2010-12-07 | 2011-08-03 | 江阴职业技术学院 | Za43高铝锌基合金微弧氧化装置 |
KR20130118018A (ko) * | 2012-04-19 | 2013-10-29 | (주) 유원컴텍 | 동력 전달 기어의 표면 처리 방법 |
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2014
- 2014-08-22 CN CN201410419742.8A patent/CN104562130B/zh not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1623013A (zh) * | 2002-03-27 | 2005-06-01 | 岛屿涂层有限公司 | 用于在金属和合金上形成陶瓷涂层的方法和装置及由此方法制得的涂层 |
WO2008120046A1 (en) * | 2007-04-02 | 2008-10-09 | Gostevs, Vladimirs | Method of forming a protective ceramic coating on the surface of metal products |
CN101092730A (zh) * | 2007-06-25 | 2007-12-26 | 大连海事大学 | 一种低能耗微弧氧化方法和装置 |
CN101709496A (zh) * | 2009-11-30 | 2010-05-19 | 郑州大学 | 一种镁基生物活性涂层的微弧氧化-电沉积制备方法 |
CN201915159U (zh) * | 2010-12-07 | 2011-08-03 | 江阴职业技术学院 | Za43高铝锌基合金微弧氧化装置 |
KR20130118018A (ko) * | 2012-04-19 | 2013-10-29 | (주) 유원컴텍 | 동력 전달 기어의 표면 처리 방법 |
Non-Patent Citations (2)
Title |
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"A12O3/TiO2复合膜的结构及光催化性能";张欣宇 等,;《电镀与精饰》;20070115;第29卷(第1期);第13页左栏倒数第2段、右栏倒数第1段,第14页左栏第1段,图1 * |
"Deposition of layered bioceramic hydroxyapatite/TiO2 coatings on titanium alloys using a hybrid technique of micro-arc oxidation and electrophoresis";X. Nie 等,;《Surface and Coatings Technology》;20000228;第125卷(第1-3期);第407–414页 * |
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