A kind of high rigidity terrace and preparation method thereof
Technical field
The present invention relates to a kind of terrace, more particularly to a kind of high rigidity terrace and preparation method thereof.
Background technology
Epoxide terrace is currently widely used for factory, hospital, waits on the ground surface finishing of public place, but most epoxide terrace
To water requirement than asking high, it is impossible to add water, to dry, so as to bring inconvenience to construction.Most of terrace colors are limited, without more
Decorative pattern is planted less, it is more stiff.
The content of the invention
It is an object of the invention to provide a kind of high rigidity terrace, the product has high temperature resistant, corrosion-resistant, colour-fast, no
The characteristics of ftractureing, be fungi-proofing mould proof, intensity is high, decorative pattern is wide in variety.The composition in kind of discarded object is taken full advantage of, has saved energy
Source, and twice laid, various natural resources are made to have obtained a point utilization.
In order to solve the above problems, the invention provides a kind of high rigidity terrace, wherein, raw material and its again in the terrace
Measuring portion rate is:Cement 20-30 parts by weight, granite production waste material 30-50 parts by weight, the cullet 10-20 weight of 4-40 mesh
Part, flyash 10-15 parts by weight, carbide slurry 10-15 parts by weight, flexibilizing agent 1-3 parts by weight, pigment 1-2 parts by weight, bactericide
0.1-2 parts by weight, early strength agent 0.5-1 parts by weight, age resistor 0.1-0.5 parts by weight, coupling agent 0.2-0.6 parts by weight, emulsifying agent
1-2 parts by weight, levelling agent 0.5-1 parts by weight, epoxy resin 3-10 parts by weight and epoxy curing agent 3-10 parts by weight.
Wherein, raw material and its ratio of weight and number are in the terrace:Cement 20-25 parts by weight, granite production waste material 30-
40 parts by weight, the cullet 10-15 parts by weight of 4-40 mesh, flyash 10-13 parts by weight, carbide slurry 10-13 parts by weight, flexibilizing agent
2-3 parts by weight, pigment 1-2 parts by weight, bactericide 0.1-1 parts by weight, early strength agent 0.5-1 parts by weight, age resistor 0.1-0.5 weight
Part, coupling agent 0.2-0.6 parts by weight, emulsifying agent 1-2 parts by weight, levelling agent 0.5-1 parts by weight, epoxy resin 3-7 parts by weight and
Epoxy curing agent 3-5 parts by weight.
Wherein, raw material and its ratio of weight and number are in the terrace:Cement 25-30 parts by weight, granite production waste material 30-
50 parts by weight, the cullet 10-20 parts by weight of 4-40 mesh, flyash 10-15 parts by weight, carbide slurry 10-15 parts by weight, flexibilizing agent
1-2 parts by weight, pigment 1-2 parts by weight, bactericide 0.1-2 parts by weight, early strength agent 0.5-1 parts by weight, age resistor 0.1-0.5 weight
Part, coupling agent 0.2-0.6 parts by weight, emulsifying agent 1-2 parts by weight, levelling agent 0.5-1 parts by weight, epoxy resin 3-10 parts by weight and
Epoxy curing agent 3-10 parts by weight.
Wherein, raw material and its ratio of weight and number are in the terrace:The parts by weight of cement 22, the granite production weight of waste material 35
Part, the parts by weight of cullet 12 of 4-40 mesh, the parts by weight of flyash 10, the parts by weight of carbide slurry 10, the parts by weight of flexibilizing agent 2, the weight of pigment 1
Measure part, the parts by weight of bactericide 0.5, the parts by weight of early strength agent 0.5, the parts by weight of age resistor 0.2, the parts by weight of coupling agent 0.2, emulsifying agent 1
Parts by weight, the parts by weight of levelling agent 0.5, the parts by weight of epoxy resin 5.1 and the parts by weight of epoxy curing agent 5.1.
Wherein, raw material and its ratio of weight and number are in the terrace:The parts by weight of cement 26, the granite production weight of waste material 30
Part, the parts by weight of cullet 10 of 4-40 mesh, the parts by weight of flyash 11, the parts by weight of carbide slurry 12, the parts by weight of flexibilizing agent 1, the weight of pigment 1
Measure part, the parts by weight of bactericide 0.5, the parts by weight of early strength agent 0.5, the parts by weight of age resistor 0.2, the parts by weight of coupling agent 0.2, emulsifying agent 1
Parts by weight, the parts by weight of levelling agent 0.5, the parts by weight of epoxy resin 7.1 and the parts by weight of epoxy curing agent 7.1.
Wherein, the cement is 425# portland cements;
Wherein, the granite production waste material composition is the several of silica, calcium carbonate, alumina silicate and potassium silicate;Its
In, described granite waste material for processing granite during caused fragment and powder, the granite produce waste material into
Part be 70-78 parts by weight silica, the calcium carbonate of 15-21 parts by weight, the alumina silicate of 0.1-3 parts by weight and 0.1-2 weight
The potassium silicate of part;And become the particle of 70-80 mesh after further processed classification.
Wherein, the flyash composition is the one or more in silica, calcium carbonate, alumina silicate.Flyash refers to
The flue dust of power plant, for particle between 200-400 mesh, composition is silica, the carbonic acid of 0-10 parts by weight of 60-82 parts by weight
The alumina silicate of calcium and 0-10 parts by weight.
Wherein, the carbide slurry main component is 80-93 parts by weight calcium hydroxide and 2-4 weight parts of calcium carbonate;It is wherein electric
Stone mud refers to solid refuse caused by the acetylene production workshop of PVC manufacturing enterprises, and Main Ingredients and Appearance is the hydroxide of 80-93 parts by weight
The calcium carbonate of calcium and 2-4 parts by weight.
The flexibilizing agent be LNBR, carboxyl end of the liquid acrylonitrile-butadiene rubber, polysulfide rubber, liquid silastic, polyethers,
Polysulfones, polyimides, polyvinyl alcohol, nano-calcium carbonate, the one or more of nano titanium oxide;Preferably, flexibilizing agent is elected as
LNBR, the either mixture of polyvinyl alcohol or polysulfide rubber and nano titanium oxide, polysulfide rubber and nanometer two
The proportioning of titanium oxide is 2:1.
Wherein, the bactericide is the one or two of sodium rice zinc oxide and Nano Silver zinc complex;Preferably, bactericide
Elect nano zine oxide as, either Nano Silver zinc complex or the mixture of sodium rice zinc oxide and Nano Silver zinc complex, sodium rice
The proportioning of zinc oxide and Nano Silver zinc complex is 1:1.
Wherein, the early strength agent is the one or two of calcium chloride and sodium sulphate;Preferably, early strength agent is calcium chloride, or
Person's sodium sulphate.
Wherein, the age resistor is the antioxidant 264 of Bayer A.G's production;
Wherein, the coupling agent be titante coupling agent, aluminate coupling agent and aluminium titanium composite coupler one kind or
It is several;Preferably, coupling agent is that titante coupling agent, either aluminate coupling agent or aluminate coupling agent and aluminium titanium are answered
The proportioning of the mixture of conjunction coupling agent, aluminate coupling agent and aluminium titanium composite coupler is 2:1.
Wherein, the emulsifying agent is preferably OP-10.
Wherein, the levelling agent is preferably acrylic compounds levelling agent;
Wherein, the epoxy resin is the one or more in EP-12, EP-13, EP-16 and EP-20;Preferably, epoxy
Resin is EP-12, either EP-13 or EP-16 and EP-20 mixing, and EP-16 and EP-20 proportioning are 1:2.
Wherein, the epoxy curing agent is the one or more of tertiary amine, imidazolium compounds and BF3 complex compounds;It is preferred that
, epoxy curing agent is the mixture of tertiary amine, either imidazolium compounds or imidazolium compounds and BF3 complex compounds, imidazoles
Compound and the proportioning of BF3 complex compounds are 0.5:3.
Wherein, the pigment is the pigment commonly used in the art such as titanium dioxide, carbon black, iron oxide red or iron oxide yellow.
In order to solve the above-mentioned technical problem, present invention also offers a kind of preparation method of described high rigidity terrace, its
In, the preparation method comprises the following steps:The raw material is added into the 1-4 times of water measured by proportioning first and is mixed into slurry
Material, the slurry being stirred is layered on to the ground cleaned out, and gas is excluded using vibration pump vibrations, then dried in the air in room temperature
Put 3-5 days, sanding and polishing produces.
The beneficial effects of the invention are as follows:The present invention have high temperature resistant, it is corrosion-resistant, colour-fast, do not ftracture, be fungi-proofing mould proof, strong
The characteristics of degree is high, decorative pattern is wide in variety;Raw material uses substantial amounts of solid refuse, caused waste material in being produced as granite, calcium carbide
Mud and flyash, solves the problems, such as the recycling of substantial amounts of discarded object;The single varieties of conventional product are overcome, without decorative pattern
Feature;Cost is cheap, is especially suitable for promoting, and has higher market popularization value.
Embodiment
Embodiment 1
The composition of raw materials of the present embodiment is:The parts by weight of cement 22, granite production waste material 35 parts by weight, the broken glass of 4-40 purposes
The parts by weight of glass 12, the parts by weight of flyash 10, the parts by weight of carbide slurry 10, the parts by weight of flexibilizing agent 2, the parts by weight of pigment 1, bactericide 0.5
Parts by weight, the parts by weight of early strength agent 0.5, the parts by weight of age resistor 0.2, the parts by weight of coupling agent 0.2, the parts by weight of emulsifying agent 1, levelling agent
0.5 parts by weight, the parts by weight of epoxy resin 5.1 and the parts by weight of epoxy curing agent 5.1;
Wherein, the cement is 425# portland cements.
Wherein, caused fragment and powder during described granite waste material is processing granite, the granite
Produce the silica that waste material composition is 78 parts by weight, the calcium carbonate of 15 parts by weight, the alumina silicate of 0.1 parts by weight and 0.1 weight
The potassium silicate of part, and become the particle of 80 mesh after further processed classification.
Wherein, flyash refers to the flue dust of power plant, and for particle between 200-400 mesh, composition is the dioxy of 60 parts by weight
The alumina silicate of SiClx, the calcium carbonate of 0.1 parts by weight and 10 parts by weight.
Wherein carbide slurry refers to solid refuse caused by the acetylene production workshop of PVC manufacturing enterprises, and Main Ingredients and Appearance is 80 weights
Measure the calcium hydroxide of part and the calcium carbonate of 4 parts by weight.
Wherein, flexibilizing agent elects LNBR as.
Wherein, bactericide elects nano zine oxide as.
Wherein, the early strength agent is calcium chloride.
Wherein, the age resistor is the antioxidant 264 of Bayer A.G's production.
Wherein, the coupling agent is titante coupling agent.
Wherein, the emulsifying agent is OP-10.
Wherein, the levelling agent is acrylic compounds levelling agent.
Wherein, epoxy resin EP-12.
Wherein, epoxy curing agent is tertiary amine.
Wherein, pigment is the pigment commonly used in the art such as titanium dioxide, carbon black, iron oxide red or iron oxide yellow.
Wherein, the preparation method comprises the following steps:The water mixing that the raw material is added to 4 times of amounts by proportioning first is equal
It is even into slurry, the slurry being stirred is layered on to the ground cleaned out, and gas, Ran Hou are excluded using vibration pump vibrations
Room temperature is hung 3 days, and sanding and polishing produces.
Embodiment 2
The composition of raw materials of the present embodiment is:The parts by weight of cement 26, granite production waste material 30 parts by weight, the broken glass of 4-40 purposes
The parts by weight of glass 10, the parts by weight of flyash 11, the parts by weight of carbide slurry 12, the parts by weight of flexibilizing agent 1, the parts by weight of pigment 1, bactericide 0.5
Parts by weight, the parts by weight of early strength agent 0.5, the parts by weight of age resistor 0.2, the parts by weight of coupling agent 0.2, the parts by weight of emulsifying agent 1, levelling agent
0.5 parts by weight, the parts by weight of epoxy resin 7.1 and the parts by weight of epoxy curing agent 7.1;
Wherein, the cement is 425# portland cements.
Wherein, caused fragment and powder during the granite production waste material is processing granite, the colored hilllock
Rock produces the silica that waste material composition is 78 parts by weight, the calcium carbonate of 21 parts by weight, the alumina silicate of 0.1 parts by weight and 0.1 weight
The potassium silicate of part is measured, and becomes the particle of 80 mesh after further processed classification;
Wherein, flyash refers to the flue dust of power plant, and for particle between 200-400 mesh, composition is the dioxy of 60 parts by weight
The alumina silicate of SiClx, the calcium carbonate of 10 parts by weight and 10 parts by weight.
Wherein, carbide slurry refers to solid refuse caused by the acetylene production workshop of PVC manufacturing enterprises, and Main Ingredients and Appearance is 80 weights
Measure the calcium hydroxide of part and the calcium carbonate of 2 parts by weight.
Wherein, flexibilizing agent elects polyvinyl alcohol as.
Wherein, bactericide elects Nano Silver zinc complex as.
Wherein, early strength agent is sodium sulphate.
Wherein, the age resistor is the antioxidant 264 of Bayer A.G's production.
Wherein, coupling agent is aluminate coupling agent.
Wherein, the emulsifying agent is preferably OP-10.
Wherein, the levelling agent is preferably acrylic compounds levelling agent;
Wherein, epoxy resin EP-13.
Wherein, epoxy curing agent is imidazolium compounds.
Wherein, pigment is the pigment commonly used in the art such as titanium dioxide, carbon black, iron oxide red or iron oxide yellow.
Wherein, the preparation method comprises the following steps:The water mixing that the raw material is added to 2 times of amounts by proportioning first is equal
It is even into slurry, the slurry being stirred is layered on to the ground cleaned out, and gas, Ran Hou are excluded using vibration pump vibrations
Room temperature is hung 5 days, and sanding and polishing produces.
Embodiment 3
The composition of raw materials of the present embodiment is:The parts by weight of cement 20, granite production waste material 30 parts by weight, the broken glass of 4-40 purposes
The parts by weight of glass 20, the parts by weight of flyash 15, the parts by weight of carbide slurry 15, the parts by weight of flexibilizing agent 3, the parts by weight of pigment 1, the weight of bactericide 2
Measure part, the parts by weight of early strength agent 1, the parts by weight of age resistor 0.5, the parts by weight of coupling agent 0.2, the parts by weight of emulsifying agent 1, the weight of levelling agent 0.5
Measure part, the parts by weight of epoxy resin 3 and the parts by weight of epoxy curing agent 3;
Wherein, the cement is 425# portland cements.
Wherein, caused fragment and powder during the granite production waste material is processing granite, the colored hilllock
Rock produces the silica that waste material composition is 70 parts by weight, the calcium carbonate of 15 parts by weight, the alumina silicate of 0.1 parts by weight and 0.1 weight
The potassium silicate of part is measured, and becomes the particle of 70 mesh after further processed classification.
Wherein, flyash refers to the flue dust of power plant, and for particle between 200-400 mesh, composition is the dioxy of 72 parts by weight
The alumina silicate of SiClx, the calcium carbonate of 0.1 parts by weight and 0.5 parts by weight.
Wherein, wherein carbide slurry refers to solid refuse caused by the acetylene production workshop of PVC manufacturing enterprises, and Main Ingredients and Appearance is
The calcium carbonate of the calcium hydroxide of 93 parts by weight and 2 parts by weight.
The flexibilizing agent is the mixture of polysulfide rubber and nano titanium oxide, and polysulfide rubber and nano titanium oxide are matched somebody with somebody
Than for 2:1.
Wherein, the bactericide is the mixture of sodium rice zinc oxide and Nano Silver zinc complex, sodium rice zinc oxide and nanometer
The proportioning of silver-colored zinc complex compound is 1:1.
Wherein, the early strength agent is calcium chloride.
Wherein, the age resistor is the antioxidant 264 of Bayer A.G's production.
Wherein, the coupling agent is the mixture of aluminate coupling agent and aluminium titanium composite coupler, aluminate coupling agent and
The proportioning of aluminium titanium composite coupler is 2:1.
Wherein, the emulsifying agent is OP-10.
Wherein, the levelling agent is acrylic compounds levelling agent.
Wherein, the epoxy resin is EP-16 and EP-20 mixing, and EP-16 and EP-20 proportioning are 1:2.
Wherein, the mixture of the epoxy curing agent imidazolium compounds and BF3 complex compounds, imidazolium compounds and BF3
The proportioning of complex compound is 0.5:3.
Wherein, pigment is the pigment commonly used in the art such as titanium dioxide, carbon black, iron oxide red or iron oxide yellow.
Wherein, preparation method comprises the following steps:The water that the raw material is added to 1 times of amount by proportioning first is mixed into
Slurry, the slurry being stirred is layered on to the ground cleaned out, and gas is excluded using vibration pump vibrations, then in room temperature
Hang 3 days, sanding and polishing produces.
Performance detection is tested
1-3 of embodiment of the present invention high rigidity terrace is subjected to performance detection respectively, as a result as shown in table 1.
From the data of table 1:1-3 of embodiment of the present invention high rigidity terrace items detection project is with reference to GMQB/
02610-2000 examination criterias, examination and test of products result show that physical properties are significantly increased.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and
Within principle, any modification, equivalent substitution and improvements made etc., it should be included in the scope of the protection.