Summary of the invention
The object of the present invention is to provide a kind of high rigidity terrace, this product have high temperature resistant, corrosion-resistant, colour-fast, do not ftracture, fungi-proofing mildew-resistant, intensity is high, decorative pattern is wide in variety feature.Take full advantage of the composition in kind of waste, save the energy, and utilization of waste material, make various natural resources obtain a point utilization.
In order to solve the problem, the invention provides a kind of high rigidity terrace, wherein, described terrace Raw and ratio of weight and number thereof are: cement 20-30 weight part, grouan processing waste 30-50 weight part, 4-40 object glass cullet 10-20 weight part, flyash 10-15 weight part, carbide slurry 10-15 weight part, flexibilizing agent 1-3 weight part, pigment 1-2 weight part, sterilant 0.1-2 weight part, hardening accelerator 0.5-1 weight part, anti-aging agent 0.1-0.5 weight part, coupling agent 0.2-0.6 weight part, emulsifying agent 1-2 weight part, flow agent 0.5-1 weight part, epoxy resin 3-10 weight part and epoxy curing agent 3-10 weight part.
Wherein, described terrace Raw and ratio of weight and number thereof are: cement 20-25 weight part, grouan processing waste 30-40 weight part, 4-40 object glass cullet 10-15 weight part, flyash 10-13 weight part, carbide slurry 10-13 weight part, flexibilizing agent 2-3 weight part, pigment 1-2 weight part, sterilant 0.1-1 weight part, hardening accelerator 0.5-1 weight part, anti-aging agent 0.1-0.5 weight part, coupling agent 0.2-0.6 weight part, emulsifying agent 1-2 weight part, flow agent 0.5-1 weight part, epoxy resin 3-7 weight part and epoxy curing agent 3-5 weight part.
Wherein, described terrace Raw and ratio of weight and number thereof are: cement 25-30 weight part, grouan processing waste 30-50 weight part, 4-40 object glass cullet 10-20 weight part, flyash 10-15 weight part, carbide slurry 10-15 weight part, flexibilizing agent 1-2 weight part, pigment 1-2 weight part, sterilant 0.1-2 weight part, hardening accelerator 0.5-1 weight part, anti-aging agent 0.1-0.5 weight part, coupling agent 0.2-0.6 weight part, emulsifying agent 1-2 weight part, flow agent 0.5-1 weight part, epoxy resin 3-10 weight part and epoxy curing agent 3-10 weight part.
Wherein, described terrace Raw and ratio of weight and number thereof are: cement 22 weight part, grouan processing waste 35 weight part, 4-40 object glass cullet 12 weight part, flyash 10 weight part, carbide slurry 10 weight part, flexibilizing agent 2 weight part, pigment 1 weight part, sterilant 0.5 weight part, hardening accelerator 0.5 weight part, anti-aging agent 0.2 weight part, coupling agent 0.2 weight part, emulsifying agent 1 weight part, flow agent 0.5 weight part, epoxy resin 5.1 weight part and epoxy curing agent 5.1 weight part.
Wherein, described terrace Raw and ratio of weight and number thereof are: cement 26 weight part, grouan processing waste 30 weight part, 4-40 object glass cullet 10 weight part, flyash 11 weight part, carbide slurry 12 weight part, flexibilizing agent 1 weight part, pigment 1 weight part, sterilant 0.5 weight part, hardening accelerator 0.5 weight part, anti-aging agent 0.2 weight part, coupling agent 0.2 weight part, emulsifying agent 1 weight part, flow agent 0.5 weight part, epoxy resin 7.1 weight part and epoxy curing agent 7.1 weight part.
Wherein, described cement is 425# silicate cement;
Wherein, described grouan processing waste composition is the several of silicon-dioxide, calcium carbonate, pure aluminium silicate and potassium silicate; Wherein, described granite waste material is the fragment and powder that produce in the process of processing grouan, described grouan processing waste composition is the silicon-dioxide of 70-78 weight part, the potassium silicate of the calcium carbonate of 15-21 weight part, the pure aluminium silicate of 0.1-3 weight part and 0.1-2 weight part; And after processing classification further, become 4-120 object particle.
Wherein, described flyash composition is one or more in silicon-dioxide, calcium carbonate, pure aluminium silicate.Flyash refers to the flue dust of power plant, and particle is between 200-400 order, and composition is the pure aluminium silicate of the silicon-dioxide of 60-82 weight part, the calcium carbonate of 0-10 weight part and 0-10 weight part.
Wherein, described carbide slurry main component is 80-93 weight part hydrogen hydrolith and 2-4 weight parts of calcium carbonate; Wherein carbide slurry refers to the solid refuse that the acetylene workshop of PVC manufacturing enterprise produces, and major ingredient is the hydrogen hydrolith of 80-93 weight part and the calcium carbonate of 2-4 weight part.
Described flexibilizing agent be liquid acrylonitrile butadiene rubber, carboxyl end of the liquid acrylonitrile-butadiene rubber, thiorubber, liquid silastic, polyethers, polysulfones, polyimide, polyvinyl alcohol, nano-calcium carbonate, nano titanium oxide one or more; Preferably, flexibilizing agent elects liquid acrylonitrile butadiene rubber as, or polyvinyl alcohol, or the mixture of thiorubber and nano titanium oxide, and the proportioning of thiorubber and nano titanium oxide is 2:1.
Wherein, described sterilant is one or both of sodium rice zinc oxide and nanometer silver zinc complex; Preferably, nano zine oxide elected as by sterilant, or nanometer silver zinc complex, or the mixture of sodium rice zinc oxide and nanometer silver zinc complex, and the proportioning of sodium rice zinc oxide and nanometer silver zinc complex is 1:1.
Wherein, described hardening accelerator is one or both of calcium chloride and sodium sulfate; Preferably, hardening accelerator is calcium chloride, or sodium sulfate.
Wherein, described anti-aging agent is the antioxidant 264 that Bayer A.G produces;
Wherein, described coupling agent is one or more of titante coupling agent, aluminate coupling agent and aluminium titanium composite coupler; Preferably, coupling agent is titante coupling agent, or aluminate coupling agent, or the mixture of aluminate coupling agent and aluminium titanium composite coupler, and the proportioning of aluminate coupling agent and aluminium titanium composite coupler is 2:1.
Wherein, described emulsifying agent is preferably OP-10.
Wherein, described flow agent is preferably acrylic acid or the like flow agent;
Wherein, described epoxy resin is one or more in EP-12, EP-13, EP-16 and EP-20; Preferably, epoxy resin is EP-12, or EP-13, or the mixing of EP-16 and EP-20, and the proportioning of EP-16 and EP-20 is 1:2.
Wherein, described epoxy curing agent is one or more of tertiary amine, imidazolium compounds and BF3 complex compound; Preferably, epoxy curing agent is tertiary amine, or imidazolium compounds, or the mixture of imidazolium compounds and BF3 complex compound, and the proportioning of imidazolium compounds and BF3 complex compound is 0.5:3.
Wherein, described pigment is this area common pigments such as titanium dioxide, carbon black, red iron oxide or iron oxide yellow.
In order to solve the problems of the technologies described above, present invention also offers a kind of preparation method of described high rigidity terrace, wherein, described preparation method comprises the following steps: first the water that described raw material adds 1-4 times amount by proportioning is mixed form slurry, the described slurry be stirred is layered on the ground cleaned out, and use vibration pump to shake to get rid of gas, then hang 3-5 days in room temperature, sanding and polishing and get final product.
The invention has the beneficial effects as follows: the present invention have high temperature resistant, corrosion-resistant, colour-fast, do not ftracture, fungi-proofing mildew-resistant, intensity is high, decorative pattern is wide in variety feature; Raw material adopts a large amount of solid refuses, the waste material produced in producing as grouan, and carbide slurry and flyash, solve the recycling problem of a large amount of wastes; The kind overcoming product is in the past single, does not have dapple feature; With low cost, be applicable to very much promoting, have higher market popularization value.
Embodiment
Embodiment 1
The composition of raw materials of the present embodiment is: cement 22 weight part, grouan processing waste 35 weight part, 4-40 object glass cullet 12 weight part, flyash 10 weight part, carbide slurry 10 weight part, flexibilizing agent 2 weight part, pigment 1 weight part, sterilant 0.5 weight part, hardening accelerator 0.5 weight part, anti-aging agent 0.2 weight part, coupling agent 0.2 weight part, emulsifying agent 1 weight part, flow agent 0.5 weight part, epoxy resin 5.1 weight part and epoxy curing agent 5.1 weight part;
Wherein, described cement is 425# silicate cement.
Wherein, described granite waste material is the fragment and powder that produce in the process of processing grouan, described grouan processing waste composition is the silicon-dioxide of 78 weight parts, the potassium silicate of the calcium carbonate of 15 weight parts, the pure aluminium silicate of 0.1 weight part and 0.1 weight part, and 80 object particles are become after processing classification further.
Wherein, flyash refers to the flue dust of power plant, and particle is between 200-400 order, and composition is the pure aluminium silicate of the silicon-dioxide of 60 weight parts, the calcium carbonate of 0.1 weight part and 10 weight parts.
Wherein carbide slurry refers to the solid refuse that the acetylene workshop of PVC manufacturing enterprise produces, and major ingredient is the hydrogen hydrolith of 80 weight parts and the calcium carbonate of 4 weight parts.
Wherein, flexibilizing agent elects liquid acrylonitrile butadiene rubber as.
Wherein, nano zine oxide elected as by sterilant.
Wherein, described hardening accelerator is calcium chloride.
Wherein, described anti-aging agent is the antioxidant 264 that Bayer A.G produces.
Wherein, described coupling agent is titante coupling agent.
Wherein, described emulsifying agent is OP-10.
Wherein, described flow agent is acrylic acid or the like flow agent.
Wherein, epoxy resin is EP-12.
Wherein, epoxy curing agent is tertiary amine.
Wherein, pigment is this area common pigments such as titanium dioxide, carbon black, red iron oxide or iron oxide yellow.
Wherein, described preparation method comprises the following steps: first the water that described raw material adds 4 times amount by proportioning is mixed form slurry, and the described slurry be stirred is layered on the ground cleaned out, and uses vibration pump to shake eliminating gas, then 3 days are hung in room temperature, sanding and polishing and get final product.
Embodiment 2
The composition of raw materials of the present embodiment is: cement 26 weight part, grouan processing waste 30 weight part, 4-40 object glass cullet 10 weight part, flyash 11 weight part, carbide slurry 12 weight part, flexibilizing agent 1 weight part, pigment 1 weight part, sterilant 0.5 weight part, hardening accelerator 0.5 weight part, anti-aging agent 0.2 weight part, coupling agent 0.2 weight part, emulsifying agent 1 weight part, flow agent 0.5 weight part, epoxy resin 7.1 weight part and epoxy curing agent 7.1 weight part;
Wherein, described cement is 425# silicate cement.
Wherein, described grouan processing waste is the fragment and powder that produce in the process of processing grouan, described grouan processing waste composition is the silicon-dioxide of 78 weight parts, the potassium silicate of the calcium carbonate of 21 weight parts, the pure aluminium silicate of 0.1 weight part and 0.1 weight part, and 80 object particles are become after processing classification further;
Wherein, flyash refers to the flue dust of power plant, and particle is between 200-400 order, and composition is the pure aluminium silicate of the silicon-dioxide of 60 weight parts, the calcium carbonate of 10 weight parts and 10 weight parts.
Wherein, carbide slurry refers to the solid refuse that the acetylene workshop of PVC manufacturing enterprise produces, and major ingredient is the hydrogen hydrolith of 80 weight parts and the calcium carbonate of 2 weight parts.
Wherein, flexibilizing agent elects polyvinyl alcohol as.
Wherein, nanometer silver zinc complex elected as by sterilant.
Wherein, hardening accelerator is sodium sulfate.
Wherein, described anti-aging agent is the antioxidant 264 that Bayer A.G produces.
Wherein, coupling agent is aluminate coupling agent.
Wherein, described emulsifying agent is preferably OP-10.
Wherein, described flow agent is preferably acrylic acid or the like flow agent;
Wherein, epoxy resin is EP-13.
Wherein, epoxy curing agent is imidazolium compounds.
Wherein, pigment is this area common pigments such as titanium dioxide, carbon black, red iron oxide or iron oxide yellow.
Wherein, described preparation method comprises the following steps: first the water that described raw material adds 2 times amount by proportioning is mixed form slurry, and the described slurry be stirred is layered on the ground cleaned out, and uses vibration pump to shake eliminating gas, then 5 days are hung in room temperature, sanding and polishing and get final product.
Embodiment 3
The composition of raw materials of the present embodiment is: cement 20 weight part, grouan processing waste 30 weight part, 4-40 object glass cullet 20 weight part, flyash 15 weight part, carbide slurry 15 weight part, flexibilizing agent 3 weight part, pigment 1 weight part, sterilant 2 weight part, hardening accelerator 1 weight part, anti-aging agent 0.5 weight part, coupling agent 0.2 weight part, emulsifying agent 1 weight part, flow agent 0.5 weight part, epoxy resin 3 weight part and epoxy curing agent 3 weight part;
Wherein, described cement is 425# silicate cement.
Wherein, described grouan processing waste is the fragment and powder that produce in the process of processing grouan, described grouan processing waste composition is the silicon-dioxide of 70 weight parts, the potassium silicate of the calcium carbonate of 15 weight parts, the pure aluminium silicate of 0.1 weight part and 0.1 weight part, and 70 object particles are become after processing classification further.
Wherein, flyash refers to the flue dust of power plant, and particle is between 200-400 order, and composition is the pure aluminium silicate of the silicon-dioxide of 72 weight parts, the calcium carbonate of 0.1 weight part and 0.5 weight part.
Wherein, wherein carbide slurry refers to the solid refuse that the acetylene workshop of PVC manufacturing enterprise produces, and major ingredient is the hydrogen hydrolith of 93 weight parts and the calcium carbonate of 2 weight parts.
Described flexibilizing agent is the mixture of thiorubber and nano titanium oxide, and the proportioning of thiorubber and nano titanium oxide is 2:1.
Wherein, described sterilant is the mixture of sodium rice zinc oxide and nanometer silver zinc complex, and the proportioning of sodium rice zinc oxide and nanometer silver zinc complex is 1:1.
Wherein, described hardening accelerator is calcium chloride.
Wherein, described anti-aging agent is the antioxidant 264 that Bayer A.G produces.
Wherein, described coupling agent is the mixture of aluminate coupling agent and aluminium titanium composite coupler, and the proportioning of aluminate coupling agent and aluminium titanium composite coupler is 2:1.
Wherein, described emulsifying agent is OP-10.
Wherein, described flow agent is acrylic acid or the like flow agent.
Wherein, described epoxy resin is the mixing of EP-16 and EP-20, and the proportioning of EP-16 and EP-20 is 1:2.
Wherein, the mixture of described epoxy curing agent imidazolium compounds and BF3 complex compound, the proportioning of imidazolium compounds and BF3 complex compound is 0.5:3.
Wherein, pigment is this area common pigments such as titanium dioxide, carbon black, red iron oxide or iron oxide yellow.
Wherein, preparation method comprises the following steps: first the water that described raw material adds 1 times amount by proportioning is mixed form slurry, and the described slurry be stirred is layered on the ground cleaned out, and uses vibration pump to shake eliminating gas, then 3 days are hung in room temperature, sanding and polishing and get final product.
Performance Detection is tested
The high rigidity terrace of embodiment of the present invention 1-3 is carried out Performance Detection respectively, and result is as shown in table 1.
The every test item of high rigidity terrace of the data from table 1: embodiment of the present invention 1-3 is with reference to GMQB/02610-2000 examination criteria, and examination and test of products result shows that physical properties is significantly increased.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.