CN104529123B - 使用再循环催化剂的湿空气氧化方法 - Google Patents
使用再循环催化剂的湿空气氧化方法 Download PDFInfo
- Publication number
- CN104529123B CN104529123B CN201410643263.4A CN201410643263A CN104529123B CN 104529123 B CN104529123 B CN 104529123B CN 201410643263 A CN201410643263 A CN 201410643263A CN 104529123 B CN104529123 B CN 104529123B
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- Prior art keywords
- catalyst
- aqueous mixture
- wet oxidation
- levels
- catalytic wet
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- 239000003054 catalyst Substances 0.000 title claims abstract description 140
- 238000000034 method Methods 0.000 title claims abstract description 84
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 65
- 230000003647 oxidation Effects 0.000 title claims abstract description 59
- 239000000203 mixture Substances 0.000 claims abstract description 109
- 238000009279 wet oxidation reaction Methods 0.000 claims abstract description 88
- 230000008569 process Effects 0.000 claims abstract description 38
- 238000012545 processing Methods 0.000 claims abstract description 18
- 239000007800 oxidant agent Substances 0.000 claims abstract description 9
- 238000001556 precipitation Methods 0.000 claims abstract description 8
- 239000010949 copper Substances 0.000 claims description 46
- 229910052802 copper Inorganic materials 0.000 claims description 42
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 38
- 238000004064 recycling Methods 0.000 claims description 35
- 239000003002 pH adjusting agent Substances 0.000 claims description 31
- 230000003197 catalytic effect Effects 0.000 claims description 30
- 239000002253 acid Substances 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 15
- 238000004891 communication Methods 0.000 claims description 14
- 239000000243 solution Substances 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 238000006555 catalytic reaction Methods 0.000 claims description 10
- 239000003513 alkali Substances 0.000 claims description 9
- 238000011144 upstream manufacturing Methods 0.000 claims description 9
- 238000005352 clarification Methods 0.000 claims description 8
- 230000033228 biological regulation Effects 0.000 claims description 7
- 238000000926 separation method Methods 0.000 claims description 7
- 230000004044 response Effects 0.000 claims description 6
- 239000006228 supernatant Substances 0.000 claims description 5
- 238000001514 detection method Methods 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 38
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 27
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 20
- 229910052742 iron Inorganic materials 0.000 description 20
- 230000006378 damage Effects 0.000 description 19
- 239000001301 oxygen Substances 0.000 description 18
- 229910052760 oxygen Inorganic materials 0.000 description 18
- 239000007789 gas Substances 0.000 description 17
- 229910052720 vanadium Inorganic materials 0.000 description 15
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 14
- 230000001066 destructive effect Effects 0.000 description 13
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 12
- 230000029219 regulation of pH Effects 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 230000001590 oxidative effect Effects 0.000 description 11
- 229910052723 transition metal Inorganic materials 0.000 description 11
- 150000003624 transition metals Chemical class 0.000 description 11
- 238000002474 experimental method Methods 0.000 description 10
- 239000002912 waste gas Substances 0.000 description 9
- 239000003518 caustics Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000002002 slurry Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 5
- 239000005751 Copper oxide Substances 0.000 description 5
- 229910000431 copper oxide Inorganic materials 0.000 description 5
- 238000010790 dilution Methods 0.000 description 5
- 239000012895 dilution Substances 0.000 description 5
- 239000002351 wastewater Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000011021 bench scale process Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- AEJIMXVJZFYIHN-UHFFFAOYSA-N copper;dihydrate Chemical compound O.O.[Cu] AEJIMXVJZFYIHN-UHFFFAOYSA-N 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 235000006408 oxalic acid Nutrition 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 3
- 238000002309 gasification Methods 0.000 description 3
- 238000012544 monitoring process Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000009296 electrodeionization Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 238000009527 percussion Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000011260 aqueous acid Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000007274 generation of a signal involved in cell-cell signaling Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000007210 heterogeneous catalysis Methods 0.000 description 1
- 239000002815 homogeneous catalyst Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 229910001055 inconels 600 Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000001404 mediated effect Effects 0.000 description 1
- 239000003863 metallic catalyst Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000010841 municipal wastewater Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- -1 publilc health Chemical class 0.000 description 1
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- 230000003134 recirculating effect Effects 0.000 description 1
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- 238000012163 sequencing technique Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000010801 sewage sludge Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/06—Treatment of sludge; Devices therefor by oxidation
- C02F11/08—Wet air oxidation
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Catalysts (AREA)
- Treatment Of Sludge (AREA)
Abstract
Description
Claims (16)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US88596607P | 2007-01-22 | 2007-01-22 | |
US60/885966 | 2007-01-22 | ||
CN200880002713.4A CN101687672B (zh) | 2007-01-22 | 2008-01-22 | 使用再循环催化剂的湿空气氧化方法 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200880002713.4A Division CN101687672B (zh) | 2007-01-22 | 2008-01-22 | 使用再循环催化剂的湿空气氧化方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104529123A CN104529123A (zh) | 2015-04-22 |
CN104529123B true CN104529123B (zh) | 2017-06-09 |
Family
ID=39644795
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200880002713.4A Active CN101687672B (zh) | 2007-01-22 | 2008-01-22 | 使用再循环催化剂的湿空气氧化方法 |
CN201410643263.4A Active CN104529123B (zh) | 2007-01-22 | 2008-01-22 | 使用再循环催化剂的湿空气氧化方法 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200880002713.4A Active CN101687672B (zh) | 2007-01-22 | 2008-01-22 | 使用再循环催化剂的湿空气氧化方法 |
Country Status (6)
Country | Link |
---|---|
US (1) | US8501011B2 (zh) |
JP (1) | JP2010516446A (zh) |
CN (2) | CN101687672B (zh) |
BR (1) | BRPI0806724A2 (zh) |
RU (1) | RU2458865C2 (zh) |
WO (1) | WO2008091578A1 (zh) |
Families Citing this family (25)
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US9193613B2 (en) | 2006-10-03 | 2015-11-24 | Siemens Energy, Inc. | pH control to enable homogeneous catalytic wet air oxidation |
US9315401B2 (en) | 2007-01-22 | 2016-04-19 | Siemens Energy, Inc. | Wet air oxidation process using recycled copper catalyst |
US8671985B2 (en) | 2011-10-27 | 2014-03-18 | Pentair Residential Filtration, Llc | Control valve assembly |
US9010361B2 (en) | 2011-10-27 | 2015-04-21 | Pentair Residential Filtration, Llc | Control valve assembly |
US9695070B2 (en) | 2011-10-27 | 2017-07-04 | Pentair Residential Filtration, Llc | Regeneration of a capacitive deionization system |
US9637397B2 (en) | 2011-10-27 | 2017-05-02 | Pentair Residential Filtration, Llc | Ion removal using a capacitive deionization system |
US8961770B2 (en) | 2011-10-27 | 2015-02-24 | Pentair Residential Filtration, Llc | Controller and method of operation of a capacitive deionization system |
JP6011916B2 (ja) * | 2012-07-31 | 2016-10-25 | 株式会社リコー | 流体浄化装置 |
WO2014080739A1 (ja) * | 2012-11-20 | 2014-05-30 | 公立大学法人大阪市立大学 | 有機ハロゲン化合物の水熱酸化処理方法及びその触媒 |
JP2016515927A (ja) * | 2013-03-15 | 2016-06-02 | シーメンス エナジー インコーポレイテッド | 均一触媒湿式酸化を可能にするためのpH制御 |
JP2016521203A (ja) * | 2013-04-18 | 2016-07-21 | シーメンス エナジー インコーポレイテッド | 再循環される銅、バナジウム、又は鉄触媒を用いる湿式空気酸化法 |
MY182092A (en) | 2015-03-12 | 2021-01-18 | Ciris Energy Inc | Discriminate mass transfer in a wet oxidation system |
WO2017058543A1 (en) | 2015-09-30 | 2017-04-06 | Siemens Energy, Inc. | Multi-stage activated carbon systems and processes with recycled streams |
AT518626B1 (de) * | 2016-04-27 | 2022-10-15 | Kanzler Dipl Ing Walter | Verfahren zur Oxidation von Kohlenwasserstoffen in verdünnten wässrigen Lösungen |
WO2017196557A1 (en) | 2016-05-13 | 2017-11-16 | Siemens Energy, Inc. | Low temperature wet air oxidation |
US10680242B2 (en) | 2016-05-18 | 2020-06-09 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing positive electrode active material, and lithium ion battery |
CN109153015B (zh) * | 2016-05-25 | 2021-08-27 | 国际壳牌研究有限公司 | 制备催化剂的方法及其用途 |
US11168011B2 (en) | 2016-05-25 | 2021-11-09 | Shell Oil Company | Process for the treatment of waste water |
US20180013151A1 (en) | 2016-07-08 | 2018-01-11 | Semiconductor Energy Laboratory Co., Ltd. | Positive electrode active material, power storage device, electronic device, and method for manufacturing positive electrode active material |
EP3503994B1 (de) * | 2016-08-23 | 2024-03-06 | Swan Analytische Instrumente AG | Vorrichtung und verfahren zur elektrodeionisation einer flüssigkeit |
CN109399846A (zh) * | 2017-08-18 | 2019-03-01 | 中国科学院大连化学物理研究所 | 一种催化湿式氧化处理高浓度霜脲氰废水的方法 |
DE102018110299A1 (de) * | 2018-04-27 | 2019-10-31 | Linde Aktiengesellschaft | Verfahren und Anlage zur Behandlung einer Ablauge einer Laugewäsche |
EP3826967A1 (en) | 2018-08-28 | 2021-06-02 | Siemens Energy, Inc. | Wet air oxidation of a spent material with spent caustic addition |
KR20230060503A (ko) | 2020-09-04 | 2023-05-04 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 양극 활물질의 제작 방법 |
CN116462303A (zh) * | 2023-04-28 | 2023-07-21 | 湖南中天元环境工程有限公司 | 一种催化湿式氧化复配均相催化剂及其制备方法和应用 |
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2008
- 2008-01-22 RU RU2009131754/05A patent/RU2458865C2/ru active
- 2008-01-22 US US12/523,962 patent/US8501011B2/en active Active
- 2008-01-22 CN CN200880002713.4A patent/CN101687672B/zh active Active
- 2008-01-22 WO PCT/US2008/000784 patent/WO2008091578A1/en active Search and Examination
- 2008-01-22 CN CN201410643263.4A patent/CN104529123B/zh active Active
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Patent Citations (3)
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US4094780A (en) * | 1975-08-14 | 1978-06-13 | Mitsui Toatsu Chemicals Inc. | Process for the liquid phase oxidation of organic substance-containing effluents |
US4294706A (en) * | 1979-05-16 | 1981-10-13 | Osaka Gas Company, Limited | Process for treating waste water |
CN86108846A (zh) * | 1985-12-03 | 1987-07-29 | 大阪瓦斯株式会社 | 温式氧化法处理废水的流程 |
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BRPI0806724A2 (pt) | 2011-09-06 |
JP2010516446A (ja) | 2010-05-20 |
WO2008091578A1 (en) | 2008-07-31 |
US20100126937A1 (en) | 2010-05-27 |
CN101687672B (zh) | 2016-03-30 |
RU2009131754A (ru) | 2011-02-27 |
CN101687672A (zh) | 2010-03-31 |
RU2458865C2 (ru) | 2012-08-20 |
CN104529123A (zh) | 2015-04-22 |
US8501011B2 (en) | 2013-08-06 |
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