CN104513039B - Aqueous imitation stone coating, coat and product - Google Patents
Aqueous imitation stone coating, coat and product Download PDFInfo
- Publication number
- CN104513039B CN104513039B CN201310455697.7A CN201310455697A CN104513039B CN 104513039 B CN104513039 B CN 104513039B CN 201310455697 A CN201310455697 A CN 201310455697A CN 104513039 B CN104513039 B CN 104513039B
- Authority
- CN
- China
- Prior art keywords
- weight portion
- granule
- mineral varnish
- true mineral
- sand
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses an aqueous imitation stone coating, a coat and a product. The aqueous imitation stone coating includes color real stone paint particles, the color real stone paint particles are prepared through the steps of stirring a color real stone point in a tangent point liquid, chopping to form particles and filtering to prepare the tangent point liquid, the color real stone paint includes a real stone paint base material and color sand, and the tangent point liquid includes 0.3-1 part by weight of calcium chloride and 99.7-99 parts by weight of water. The invention also discloses the coat formed by coating the aqueous imitation stone coating, and the product including the coat. The coating, the coat and the product have the pattern of stones, also have the texture, the impression, the qualitative sense, the touch feeling and the rough feeling of the stones, and can meet indoor and exterior wall substitution stone decoration demands.
Description
Technical field
The present invention relates to paint field is and in particular to a kind of aqueouss stone-like coating, coating and product.
Background technology
Outer surface of building stone decoration, simple and tasteful, it is loved by the people, but stone decoration is limited by several aspects
System: the exploitation welding of stone material: earth's surface stone material is because air slaking are serious, be not suitable for manufacturing sheet material crackle more, level off hilltops or Wa Kuang hole
To exploit ratchel, to be sawn into sheet material.Welding, polluted source；Stone lumber weight, needs steel to hang and installs, costly；Stone material
It is not good enough that installation safety hung by steel: steel has potential safety hazard after hanging corrosion, and maintenance cost is high.
Now, true mineral varnish and two kinds of stone material emulation coatings of water-soluble colorful coating are widely used.True mineral varnish has following excellent
Point: there is stone material quality；During using double-colored or trichroism spraying effect, the stone material fidelity of true mineral varnish is higher.But true mineral varnish
Shortcoming be also apparent from: rough surface, easy dust dirt, metope is dirty serious；The surface more overstriking of double-colored or trichroism true mineral varnish
Rough, metope is more dirty, is difficult wipe clean.
Water-soluble colorful coating is that varicolored emulsion paint is separated into granule in emulsion continuous phase and forms, spraying application
Afterwards, these colors are mutually inlayed thus having the visual effect of stone material, have very high imitative stone visual effect.But aqueous colorful
The decorative pattern rough sense lacking stone material in small, broken bits, there is no the quality of stone material: far see like stone material, closely seeing and feeling false, handss touch not to be had
Stone material quality, does not only have soul in a word seemingly.
Therefore, still need in this area provides a kind of new stone material emulation coating, existing imitative stone material visual effect, has imitative stone again
Material sense effect.
Content of the invention
It is an object of the invention to provide a kind of new stone material emulation coating.
Another object of the present invention is to providing the coating being obtained by above-mentioned stone material emulation coating and product, existing imitative stone material
Visual effect, has imitative stone texture effect again.
A first aspect of the present invention, provides a kind of aqueouss stone-like coating, and described coating comprises colored true mineral varnish granule, described
Colored true mineral varnish granule stirs in the liquid of point of contact by colored true mineral varnish, is chopped into granule, be filtered to remove point of contact liquid after make,
Wherein said colored true mineral varnish comprises true mineral varnish base material and colored sand, and described point of contact liquid comprises 0.3-1 weight portion calcium chloride
With 99.7-99 weight portion water.
In another preference, the particle diameter of described colored true mineral varnish granule is 0.5-8mm.
In another preference, described true mineral varnish base material comprises: acrylic emulsion 4-10 weight portion, ph regulator 0.1-
0.2 weight portion, coalescents 0.1-0.2 weight portion, thickening agent 0.1-0.2 weight portion, cosolvent 0.2-0.4 weight portion, anti-corrosion
Antifungus agent 0.1-0.2 weight portion, defoamer 0.2-0.4 weight portion, 3.5% sodium alginate aqueous solution 10-20 weight portion, hollow glass
Glass pearl 1-2 weight portion, water 5-15 weight portion.
In another preference, described ph regulator is organic amine ph regulator；Described coalescents are 12 lipidols；
Described thickening agent is hydroxyethyl cellulose；Described cosolvent be propylene glycol, ethylene glycol, ethylene glycol diether, 200# solvent naphtha or its
Mixture；Described Antisepticize and mildew preventive is isothiazolinone derivatives preservative, benzimidazole esters preservative or its mixture；Institute
Stating defoamer is mineral oil type antifoaming agent, organic silicon defoamer or its mixture.
In another preference, described coating also comprises emulsion phase, and described emulsion phase comprises: silicone acrylic emulsion 20-30 weight
Part, ph regulator 0.1-0.2 weight portion, coalescents 1-2 weight portion, cosolvent 1-2 weight portion, defoamer 0.2-0.3 weight
Part, Antisepticize and mildew preventive 1-2 weight portion, water 10-15 weight portion, thickening agent 0.5-1 weight portion.
In another preference, described silicone acrylic emulsion is organosilicon-modified acrylate emulsion；Described ph regulator is to have
Machine amine ph regulator；Described coalescents are 12 lipidols；Described cosolvent be propylene glycol, ethylene glycol, ethylene glycol diether,
200# solvent naphtha or its mixture；Described Antisepticize and mildew preventive is isothiazolinone derivatives preservative, benzimidazole esters are anti-corrosion
Agent or its mixture；Described defoamer is mineral oil type antifoaming agent, organic silicon defoamer or its mixture；Described thickening agent is hydroxyl
Ethyl cellulose and association type alkali swollen thickener.
In another preference, described colour sand is selected from the group:
Black sand 4 weight portion, milky white sand 80 weight portion, pale red sand 16 weight portion；
Black sand 4 weight portion, milky white sand 80 weight portion, Lycoperdon polymorphum Vitt sand 16 weight portion；
Black sand 4 weight portion, milky white sand 80 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, reddish brown sand 10 weight portion；
Black sand 4 weight portion, milky white sand 10 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, pale yellow sand 80 weight portion；
Black sand 4 weight portion, milky white sand 10 weight portion, brownish red sand 6 weight portion, pale red sand 80 weight portion；
Black sand 4 weight portion, milky white sand 50 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, pale yellow sand 40 weight portion；
Black sand 4 weight portion, milky white sand 50 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, pale red sand 40 weight portion；
Black sand 4 weight portion, milky white sand 10 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, shallow palm fibre sand 80 weight portion；
Black sand 4 weight portion, milky white sand 50 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, shallow palm fibre sand 40 weight portion；
Milky white sand 50 weight portion, reddish brown sand 6 weight portion, pale red sand 40 weight portion, grayish green sand 4 weight portion；
Milky white sand 50 weight portion, reddish brown sand 6 weight portion, pale yellow sand 40 weight portion, ash indigo plant sand 4 weight portion；
Milky white sand 50 weight portion, reddish brown sand 6 weight portion, grayish green sand 4 weight portion, shallow palm fibre sand 40 weight portion；
Milky white sand 50 weight portion, grayish green sand 10 weight portion, shallow palm fibre sand 40 weight portion；
Black sand 4 weight portion, reddish brown sand 6 weight portion, pale red sand 60 weight portion, ash indigo plant sand 10 weight portion, shallow
Brown sand 20 weight portion；
Black sand 4 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, yellow ash sand 30 weight portion, pale yellow sand 60 weight portion；
Black sand 4 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, reddish brown sand 10 weight portion, grayish green sand 20 weight portion, shallow
Brown sand 60 weight portion；
Milky white sand 20 weight portion, reddish brown sand 20 weight portion, grayish green sand 60 weight portion；
Milky white sand 20 weight portion, reddish brown sand 20 weight portion, ash indigo plant sand 60 weight portion；
Black sand 10 weight portion, milky white sand 30 weight portion, Lycoperdon polymorphum Vitt sand 40 weight portion, reddish brown sand 6 weight portion, shallow
Brown sand 24 weight portion；
Black sand 6 weight portion, milky white sand 10 weight portion, Lycoperdon polymorphum Vitt sand 60 weight portion, pale yellow sand 24 weight portion.
In another preference, described colored true mineral varnish granule is the mixing of the colour true mineral varnish granule of several different colours
Thing, is selected from the group:
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 80 weight portion, pale red true mineral varnish granule 16 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 80 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 16 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 80 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, palm fibre
Red true mineral varnish granule 10 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 10 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, shallow
Yellow true mineral varnish granule 80 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 10 weight portion, brownish red true mineral varnish granule 6 weight portion,
Pale red true mineral varnish granule 80 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 50 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, shallow
Yellow true mineral varnish granule 40 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 50 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, shallow
Red true mineral varnish granule 40 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 10 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, shallow
True mineral varnish granule 80 weight portion of palm fibre；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 50 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, shallow
True mineral varnish granule 40 weight portion of palm fibre；
Milky white true mineral varnish granule 50 weight portion, reddish brown true mineral varnish granule 6 weight portion, pale red true mineral varnish granule 40 weight portion,
Grayish green true mineral varnish granule 4 weight portion；
Milky white true mineral varnish granule 50 weight portion, reddish brown true mineral varnish granule 6 weight portion, pale yellow true mineral varnish granule 40 weight portion,
Blue true mineral varnish granule 4 weight portion of ash；
Milky white true mineral varnish granule 50 weight portion, reddish brown true mineral varnish granule 6 weight portion, grayish green true mineral varnish granule 4 weight portion, shallow
True mineral varnish granule 40 weight portion of palm fibre；
Milky white true mineral varnish granule 50 weight portion, grayish green true mineral varnish granule 10 weight portion, shallow brown true mineral varnish granule 40 weight portion；
Black true mineral varnish granule 4 weight portion, reddish brown true mineral varnish granule 6 weight portion, pale red true mineral varnish granule 60 weight portion, ash
Blue true mineral varnish granule 10 weight portion, shallow brown true mineral varnish granule 20 weight portion；
Black true mineral varnish granule 4 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, yellow grey true mineral varnish granule 30 weight portion, shallow
Yellow true mineral varnish granule 60 weight portion；
Black true mineral varnish granule 4 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, reddish brown true mineral varnish granule 10 weight portion, ash
Green true mineral varnish granule 20 weight portion, shallow brown true mineral varnish granule 60 weight portion；
Milky white true mineral varnish granule 20 weight portion, reddish brown true mineral varnish granule 20 weight portion, grayish green true mineral varnish granule 60 weight portion；
Milky white true mineral varnish granule 20 weight portion, reddish brown true mineral varnish granule 20 weight portion, blue true mineral varnish granule 60 weight portion of ash；
Black true mineral varnish granule 10 weight portion, milky white true mineral varnish granule 30 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 40 weight portion,
Reddish brown true mineral varnish granule 6 weight portion, shallow brown true mineral varnish granule 24 weight portion；
Black true mineral varnish granule 6 weight portion, milky white true mineral varnish granule 10 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 60 weight portion,
Pale yellow true mineral varnish granule 24 weight portion.
A second aspect of the present invention, provides a kind of coating, and the coating coating described in first aspect forms.
A third aspect of the present invention, provides a kind of product, comprises the coating described in first aspect.
In another preference, described product also comprises substrate, and described coating covers in described substrate.
In another preference, described product is colour atla.The stone material emulation coating colour atla that the present invention provides, by black, breast
In vain, multiple true mineral varnish modulation such as Lycoperdon polymorphum Vitt, reddish brown, yellow grey, pale red, pale yellow, grayish green, grey blue, shallow palm fibre forms, and user can be according to color
Card effect selection uses the coating of different colours.
The present invention combines the advantage of true mineral varnish and water-soluble colorful coating, provides a kind of aqueouss stone-like coating, imitative Stone technique reaches
New height: the decorative pattern not only with stone material also has the quality of stone material, perception, texture, touch sense, rough sense have all reached stone
Material effect, can meet the demand that indoor and outdoor wall substitutes stone decoration.
It should be understood that within the scope of the present invention, above-mentioned each technical characteristic of the present invention and having in below (eg embodiment)
Can be combined with each other between each technical characteristic of body description, thus constituting new or preferred technical scheme.As space is limited, exist
This no longer tires out one by one states.
Brief description
The outside drawing of the film that Fig. 1 is prepared for coating np-dc02.
The outside drawing of the film that Fig. 2 is prepared for coating np-dc05.
Specific embodiment
Present inventor, through extensively and in depth studying, has been surprisingly found that colored true mineral varnish in the liquid of point of contact first
Stirring, be chopped into granule, be filtered to remove point of contact liquid after the aqueouss stone-like coating of colour true mineral varnish particle formulation made, existing
Imitative stone material visual effect, has imitative stone texture effect again.On this basis, complete the present invention.
True mineral varnish base material
In the present invention, described true mineral varnish base material comprises: acrylic acid (ester) emulsion 4-10 weight portion, ph regulator 0.1-0.2
Weight portion, coalescents 0.1-0.2 weight portion, thickening agent 0.1-0.2 weight portion, cosolvent 0.2-0.4 weight portion, anticorrosive mildewproof
Agent 0.1-0.2 weight portion, defoamer 0.2-0.4 weight portion, 3.5% sodium alginate aqueous solution 10-20 weight portion, hollow glass bead
1-2 weight portion, water 5-15 weight portion.Wherein, described ph regulator is organic amine (as the amp95 of dow)；Described coalescents
For 12 lipidols；Described thickening agent is hydroxyethyl cellulose；Described cosolvent is propylene glycol, ethylene glycol, ethylene glycol diether, 200#
Solvent naphtha or its mixture；Described Antisepticize and mildew preventive is isothiazolinone derivatives, benzimidazole esters preservative (as pcts
The aa091lf of specialty chemicals pte ltd), or its mixture；Described defoamer be mineral oil type antifoaming agent,
Organosilicon or its mixture (as the foamaster nxz of Sheng Nuopuke).
In another preference, described hollow glass micropearl is the 3m(tm that 3m company of the U.S. produces) glass bubbles.
Colored sand
In the present invention, colored sand can for natural white sand, natural colorful sand, the colored sand of artificial sintering or
Combinations thereof.In another preference, described colour sand includes the component of following weight portion: natural white sand 0-100 part,
Natural colorful sand or artificial sintering colorful sand 0-100 part.Described artificial sintering colorful sand is by natural white sand surface
After coloring, high temperature sintering forms.In another preference, described natural white sand is natural recovery the 50- after classification
120 whitish eye smalt, described natural colorful sand is natural recovery the colour sand of the 50-120 mesh after classification, described artificial
The colored sand of sintering is formed by high temperature sintering after the coloring of 50-120 mesh natural white sand surface.
In another preference, described colour sand is selected from the group:
Black sand 4 weight portion, milky white sand 80 weight portion, pale red sand 16 weight portion；
Black sand 4 weight portion, milky white sand 80 weight portion, Lycoperdon polymorphum Vitt sand 16 weight portion；
Black sand 4 weight portion, milky white sand 80 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, reddish brown sand 10 weight portion；
Black sand 4 weight portion, milky white sand 10 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, pale yellow sand 80 weight portion；
Black sand 4 weight portion, milky white sand 10 weight portion, brownish red sand 6 weight portion, pale red sand 80 weight portion；
Black sand 4 weight portion, milky white sand 50 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, pale yellow sand 40 weight portion；
Black sand 4 weight portion, milky white sand 50 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, pale red sand 40 weight portion；
Black sand 4 weight portion, milky white sand 10 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, shallow palm fibre sand 80 weight portion；
Black sand 4 weight portion, milky white sand 50 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, shallow palm fibre sand 40 weight portion；
Milky white sand 50 weight portion, reddish brown sand 6 weight portion, pale red sand 40 weight portion, grayish green sand 4 weight portion；
Milky white sand 50 weight portion, reddish brown sand 6 weight portion, pale yellow sand 40 weight portion, ash indigo plant sand 4 weight portion；
Milky white sand 50 weight portion, reddish brown sand 6 weight portion, grayish green sand 4 weight portion, shallow palm fibre sand 40 weight portion；
Milky white sand 50 weight portion, grayish green sand 10 weight portion, shallow palm fibre sand 40 weight portion；
Black sand 4 weight portion, reddish brown sand 6 weight portion, pale red sand 60 weight portion, ash indigo plant sand 10 weight portion, shallow
Brown sand 20 weight portion；
Black sand 4 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, yellow ash sand 30 weight portion, pale yellow sand 60 weight portion；
Black sand 4 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, reddish brown sand 10 weight portion, grayish green sand 20 weight portion, shallow
Brown sand 60 weight portion；
Milky white sand 20 weight portion, reddish brown sand 20 weight portion, grayish green sand 60 weight portion；
Milky white sand 20 weight portion, reddish brown sand 20 weight portion, ash indigo plant sand 60 weight portion；
Black sand 10 weight portion, milky white sand 30 weight portion, Lycoperdon polymorphum Vitt sand 40 weight portion, reddish brown sand 6 weight portion, shallow
Brown sand 24 weight portion；
Black sand 6 weight portion, milky white sand 10 weight portion, Lycoperdon polymorphum Vitt sand 60 weight portion, pale yellow sand 24 weight portion.
Colored true mineral varnish
The true mineral varnish of colour of the present invention comprises true mineral varnish base material and colored sand.
In a preference, described colored true mineral varnish comprises 25-35 weight portion true mineral varnish base material and 65-75 weight portion is colored
Sand.In another preference, described colored true mineral varnish is by 25-35 weight portion true mineral varnish base material and 65-75 weight portion colour sand
Son mixes.
In a preference, described colored true mineral varnish is the mixture of the true mineral varnish of colour of several different colours, is selected from down
Group:
The true mineral varnish of black 4 weight portion, milky white true mineral varnish 80 weight portion, pale red true mineral varnish 16 weight portion；
The true mineral varnish of black 4 weight portion, milky white true mineral varnish 80 weight portion, the true mineral varnish of Lycoperdon polymorphum Vitt 16 weight portion；
The true mineral varnish of black 4 weight portion, milky white true mineral varnish 80 weight portion, the true mineral varnish of Lycoperdon polymorphum Vitt 6 weight portion, reddish brown true mineral varnish 10 weight
Amount part；
The true mineral varnish of black 4 weight portion, milky white true mineral varnish 10 weight portion, the true mineral varnish of Lycoperdon polymorphum Vitt 6 weight portion, pale yellow true mineral varnish 80 weight
Amount part；
The true mineral varnish of black 4 weight portion, milky white true mineral varnish 10 weight portion, the true mineral varnish of brownish red 6 weight portion, pale red true mineral varnish 80
Weight portion；
The true mineral varnish of black 4 weight portion, milky white true mineral varnish 50 weight portion, the true mineral varnish of Lycoperdon polymorphum Vitt 6 weight portion, pale yellow true mineral varnish 40 weight
Amount part；
The true mineral varnish of black 4 weight portion, milky white true mineral varnish 50 weight portion, the true mineral varnish of Lycoperdon polymorphum Vitt 6 weight portion, pale red true mineral varnish 40 weight
Amount part；
The true mineral varnish of black 4 weight portion, milky white true mineral varnish 10 weight portion, the true mineral varnish of Lycoperdon polymorphum Vitt 6 weight portion, shallow brown true mineral varnish 80 weight
Amount part；
The true mineral varnish of black 4 weight portion, milky white true mineral varnish 50 weight portion, the true mineral varnish of Lycoperdon polymorphum Vitt 6 weight portion, shallow brown true mineral varnish 40 weight
Amount part；
Milky white true mineral varnish 50 weight portion, reddish brown true mineral varnish 6 weight portion, pale red true mineral varnish 40 weight portion, grayish green true mineral varnish 4 weight
Amount part；
Milky white true mineral varnish 50 weight portion, reddish brown true mineral varnish 6 weight portion, pale yellow true mineral varnish 40 weight portion, blue true mineral varnish 4 weight of ash
Amount part；
Milky white true mineral varnish 50 weight portion, reddish brown true mineral varnish 6 weight portion, grayish green true mineral varnish 4 weight portion, shallow brown true mineral varnish 40 weight
Amount part；
Milky white true mineral varnish 50 weight portion, grayish green true mineral varnish 10 weight portion, shallow brown true mineral varnish 40 weight portion；
The true mineral varnish of black 4 weight portion, reddish brown true mineral varnish 6 weight portion, pale red true mineral varnish 60 weight portion, blue true mineral varnish 10 weight of ash
Amount part, shallow brown true mineral varnish 20 weight portion；
The true mineral varnish of black 4 weight portion, the true mineral varnish of Lycoperdon polymorphum Vitt 6 weight portion, yellow grey true mineral varnish 30 weight portion, pale yellow true mineral varnish 60 weight
Amount part；
The true mineral varnish of black 4 weight portion, the true mineral varnish of Lycoperdon polymorphum Vitt 6 weight portion, reddish brown true mineral varnish 10 weight portion, grayish green true mineral varnish 20 weight
Amount part, shallow brown true mineral varnish 60 weight portion；
Milky white true mineral varnish 20 weight portion, reddish brown true mineral varnish 20 weight portion, grayish green true mineral varnish 60 weight portion；
Milky white true mineral varnish 20 weight portion, reddish brown true mineral varnish 20 weight portion, blue true mineral varnish 60 weight portion of ash；
The true mineral varnish of black 10 weight portion, milky white true mineral varnish 30 weight portion, the true mineral varnish of Lycoperdon polymorphum Vitt 40 weight portion, reddish brown true mineral varnish 6
Weight portion, shallow brown true mineral varnish 24 weight portion；
The true mineral varnish of black 6 weight portion, milky white true mineral varnish 10 weight portion, the true mineral varnish of Lycoperdon polymorphum Vitt 60 weight portion, pale yellow true mineral varnish 24
Weight portion.
Point of contact solution
In the present invention, point of contact solution refers to a kind of medium for there is chemical reaction with colored stone paint, also can claim
For protecting liquid.In the present invention, preferred point of contact liquid comprises 0.3-1 weight portion calcium chloride and 99.7-99 weight portion water.Another
In preference, described point of contact liquid is made up of 0.3-1 weight portion calcium chloride and 99.7-99 weight portion water.It is preferred that being pure
Water.
Emulsion phase
In the present invention, emulsion phase is one of component of coating, and described emulsion comprises: silicone acrylic emulsion 20-30 weight portion, ph adjust
Section agent 0.1-0.2 weight portion, coalescents 1-2 weight portion, cosolvent 1-2 weight portion, defoamer 0.2-0.3 weight portion, anti-corrosion
Antifungus agent 1-2 weight portion, water 10-15 weight portion, thickening agent 0.5-1 weight portion.
Silicone acrylic emulsion described in emulsion phase is organosilicon-modified acrylate emulsion (as Shanghai sunrise Chemical Co., Ltd.
Td-636 silicone acrylic emulsion)；Described ph regulator is organic amine ph regulator (as the amp95 of dow)；Described coalescents are ten
Two lipidols；Described cosolvent is propylene glycol, ethylene glycol, ethylene glycol diether, 200# solvent naphtha or its mixture；Described anticorrosive mildewproof
Agent is isothiazolinone derivatives preservative, benzimidazole esters preservative (as pcts specialty chemicals pte
The aa091lf of ltd) or its mixture；Described defoamer be mineral oil type antifoaming agent, organic silicon defoamer or its mixture (such as
The foamaster nxz of Sheng Nuopuke)；Described thickening agent is hydroxyethyl cellulose (as sub- Silan (Chinese) Investment Co., Ltd
Natrosol250hbr) and modified alkali swellable thickening agent (association type alkali swollen thickener) (as the tt-935 of dow).
In another preference, described thickening agent comprises 0.3-0.5 weight portion hydroxyethyl cellulose (as sub- Silan (Chinese)
The natrosol250hbr of Investment Co., Ltd) and 0.2-0.5 weight portion dow tt-935.
Aqueouss anti-stone coating
In the present invention, stone material emulation coating, aqueouss stone-like coating have identical implication, each mean and comprise colored true mineral varnish
The coating of granule, described colored true mineral varnish granule is stirred in the liquid of point of contact, is cut into granule, is filtered to remove by colored true mineral varnish
Make after the liquid of point of contact, wherein said colored true mineral varnish comprises true mineral varnish base material and colored sand, described point of contact liquid comprises
0.3-1 weight portion calcium chloride and 99.7-99 weight portion water.
In the present invention, by mechanical agitation, true for the colour of different colours mineral varnish is put into and carries out in the liquid of point of contact cutting again
Obtain the colour true mineral varnish granule (also referred to as color point granule) of different size size, after unnecessary point of contact liquid is filtered, finally
Add required emulsion phase, thus obtaining final aqueouss stone-like coating.According to the difference of color point granular size, select different
Mixing speed, ordinary circumstance, the big mixing speed of color point is slow, and the little mixing speed of color point is fast.Mixing speed general control scope is:
100—300rpm.
In another preference, the gross weight of described colored true mineral varnish granule accounts for the 65-75wt% of coating weight.
The aqueouss stone-like coating of the present invention, the particle diameter of the colour being comprised true mineral varnish granule is 0.5-8mm, it is preferred that being
1-6mm, more preferably for 3-5mm.In a preference, described colored true mineral varnish granule is the true mineral varnish of colour of several different colours
The mixture of granule, is selected from the group:
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 80 weight portion, pale red true mineral varnish granule 16 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 80 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 16 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 80 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, palm fibre
Red true mineral varnish granule 10 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 10 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, shallow
Yellow true mineral varnish granule 80 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 10 weight portion, brownish red true mineral varnish granule 6 weight portion,
Pale red true mineral varnish granule 80 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 50 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, shallow
Yellow true mineral varnish granule 40 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 50 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, shallow
Red true mineral varnish granule 40 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 10 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, shallow
True mineral varnish granule 80 weight portion of palm fibre；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 50 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, shallow
True mineral varnish granule 40 weight portion of palm fibre；
Milky white true mineral varnish granule 50 weight portion, reddish brown true mineral varnish granule 6 weight portion, pale red true mineral varnish granule 40 weight portion,
Grayish green true mineral varnish granule 4 weight portion；
Milky white true mineral varnish granule 50 weight portion, reddish brown true mineral varnish granule 6 weight portion, pale yellow true mineral varnish granule 40 weight portion,
Blue true mineral varnish granule 4 weight portion of ash；
Milky white true mineral varnish granule 50 weight portion, reddish brown true mineral varnish granule 6 weight portion, grayish green true mineral varnish granule 4 weight portion, shallow
True mineral varnish granule 40 weight portion of palm fibre；
Milky white true mineral varnish granule 50 weight portion, grayish green true mineral varnish granule 10 weight portion, shallow brown true mineral varnish granule 40 weight portion；
Black true mineral varnish granule 4 weight portion, reddish brown true mineral varnish granule 6 weight portion, pale red true mineral varnish granule 60 weight portion, ash
Blue true mineral varnish granule 10 weight portion, shallow brown true mineral varnish granule 20 weight portion；
Black true mineral varnish granule 4 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, yellow grey true mineral varnish granule 30 weight portion, shallow
Yellow true mineral varnish granule 60 weight portion；
Black true mineral varnish granule 4 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, reddish brown true mineral varnish granule 10 weight portion, ash
Green true mineral varnish granule 20 weight portion, shallow brown true mineral varnish granule 60 weight portion；
Milky white true mineral varnish granule 20 weight portion, reddish brown true mineral varnish granule 20 weight portion, grayish green true mineral varnish granule 60 weight portion；
Milky white true mineral varnish granule 20 weight portion, reddish brown true mineral varnish granule 20 weight portion, blue true mineral varnish granule 60 weight portion of ash；
Black true mineral varnish granule 10 weight portion, milky white true mineral varnish granule 30 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 40 weight portion,
Reddish brown true mineral varnish granule 6 weight portion, shallow brown true mineral varnish granule 24 weight portion；
Black true mineral varnish granule 6 weight portion, milky white true mineral varnish granule 10 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 60 weight portion,
Pale yellow true mineral varnish granule 24 weight portion.
In another preference, described aqueouss stone-like coating includes following components: colored true mineral varnish granule 60 weight portion, breast
Liquid 40 weight portion.Described colored true mineral varnish granule is stirred and is chopped into granule in the liquid of point of contact, excessively filtered by colored true mineral varnish
Make after removing point of contact liquid, in another preference, the true mineral varnish of described colour includes following components: true mineral varnish base material 31 weight
Part, colored sand 69 weight portion.In another preference, described true mineral varnish base material includes the component of following mass parts: acrylic acid
4 parts of emulsion, 0.15 part of ph regulator, 0.1 part of coalescents, 0.16 part of hec cellulose thickener, 0.3 part of cosolvent, anti-corrosion anti-
Mould dose 0.1 part, 0.3 part of defoamer, 3.5% 17 parts of sodium alginate aqueous solution, 1 part of hollow glass bead, 7.89 parts of water.Another excellent
Select in example, described point of contact liquid includes the component of following mass parts: 99.7 parts of water, 0.3 part of calcium chloride.In another preference,
Described emulsion includes the component of following mass parts: 25 parts of silicone acrylic emulsion, 0.15 part of ph regulator, 1.3 parts of coalescents, cosolvent
1.4 parts, 0.2 part of defoamer, 1.0 parts of Antisepticize and mildew preventive, 10.15 parts of water, hec cellulose thickener 0.4, hase thickening agent 0.4
Part.
Coating, product
The coating that the present invention provides, is formed by coating of the present invention coating.
The present invention also provides a kind of product, comprises coating of the present invention.In another preference, described product also wraps
Containing substrate, described coating covers in described substrate.
In another preference, described product is colour atla.The stone material emulation coating colour atla that the present invention provides, by black, breast
In vain, multiple true mineral varnish modulation such as Lycoperdon polymorphum Vitt, reddish brown, yellow grey, pale red, pale yellow, grayish green, grey blue, shallow palm fibre forms, and user can be according to color
Card effect selection uses the coating of different colours.
In another preference, the coating of the present invention or product are by the coating of the formula (unit: wt%) comprising shown in table 1
Make.
Table 1 coating color number and the colour true mineral varnish species and content being comprised
The features described above that the present invention mentions, or the feature that embodiment is mentioned can be in any combination.Disclosed in this case description
All features can be used in combination with any combinations thing form, each feature disclosed in description, can by any provide identical,
The alternative characteristics of impartial or similar purpose replace.Therefore removing has special instruction, and disclosed feature is only impartial or similar spy
The general example levied.
Using by black, milky white, Lycoperdon polymorphum Vitt, reddish brown, yellow grey, pale red, pale yellow, grayish green, grey in stone material emulation coating of the present invention
The colored true mineral varnish such as blue, shallow palm fibre, forms water paint, the imitative stone material vision of existing water-soluble colorful coating together with continuous phase emulsion
Effect, has true mineral varnish to imitate the texture effect of stone material again.The coating of the present invention, has more preferable decoration materials quality and concavo-convex texture, with
The water-soluble colorful coating using at present compares, and has higher fidelity, all reaches in perception, texture, touch sense, rough sense
Stone effect, its stone material simulated effect surmounts " true mineral varnish+aqueous colorful " and the classical imitative stone material application of two kinds of trichroism true mineral varnish
System, both can meet the demand of decoration of exterior wall, can meet interior decoration demand again.Additionally, coating of the present invention is one application, carry
High application work efficiency.
With reference to specific embodiment, the present invention is expanded on further.It should be understood that these embodiments are merely to illustrate the present invention
Rather than restriction the scope of the present invention.The experimental technique of unreceipted actual conditions in the following example, generally according to conventional strip
Part or according to the condition proposed by manufacturer.Unless otherwise indicated, otherwise percentage ratio and number are calculated by weight.Unless separately
Definition, all specialties used in literary composition and scientific words and same meaning familiar to one skilled in the art institute.Additionally, it is any
The method similar or impartial to described content and material all can be applicable in the inventive method.Preferable embodiment party described in literary composition
Method is only presented a demonstration with material and is used.
Raw material employed in following examples is as follows:
The amp95 of ph regulator: dow；
Coalescents: 12 lipidols；
Cosolvent: propylene glycol, ethylene glycol, the mixture of ethylene glycol diether；
Antisepticize and mildew preventive: the aa091lf of pcts specialty chemicals pte ltd；
The foamaster nxz of defoamer: Sheng Nuopuke；
Hollow glass bead: 3m glass bubbles；
Silicone acrylic emulsion: the td-636 silicone acrylic emulsion of Shanghai sunrise Chemical Co., Ltd.；
Hec cellulose thickener: the natrosol250hbr of sub- Silan (Chinese) Investment Co., Ltd；
The tt-935 of hase thickening agent: dow.
Embodiment 1
The preparation of the true mineral varnish of milky
Add water 100g, sodium alginate 3.5g stirring 15min under the speed stirring of 300r/min, obtain 3.5% alginic acid
Sodium water solution.
Add acrylic emulsion 40g, water 50g, hec cellulose thickener 1.6g under the speed stirring of 300r/min；Carry
Speed stirs 5 minutes to 800r/min, adds ph regulator 1.5g, coalescents 1g, cosolvent 3g, Antisepticize and mildew preventive 1g, froth breaking
Agent 3g, 3.5% sodium alginate aqueous solution 170g, stirs 2min；Reduce speed 300r/min, add hollow glass bead 10g, water
28.9g, stir about 10min, uniformly, obtain true mineral varnish base material 310g.
Turn speed and arrive 300r/min, add true mineral varnish base material 310g, add 50-120 whitish eye color natural sand 690g, stirring
5min, obtains milky true mineral varnish 1000g.
Embodiment 2
The preparation of the true mineral varnish of yellow-gray
Add water 100g, sodium alginate 3.5g stirring 15min under the speed stirring of 300r/min, obtain 3.5% alginic acid
Sodium water solution.
Add acrylic emulsion 80g, water 90g, hec cellulose thickener 2.0g under the speed stirring of 300r/min；Carry
Speed stirs 5 minutes to 800r/min, adds ph regulator 1.9g, coalescents 1.8g, cosolvent 3.5g, Antisepticize and mildew preventive
1.8g, defoamer 3.5g, 3.5% sodium alginate aqueous solution 200g, stirs 2min；Reduce speed 300r/min, add hollow glass
Pearl 15g, water 30.5g, stir about 10min, uniformly, obtain true mineral varnish base material 430g.
Turn speed and arrive 300r/min, add true mineral varnish base material 310g, add 50-120 icteric sclera Lycoperdon polymorphum Vitt natural sand 690g, stirring
5min, obtains black true mineral varnish 1000g.
Embodiment 3-10
The preparation of colored true mineral varnish
The method of reference implementation example 1, the natural colorful sand from different colours or artificial sintering colorful sand, can adjust
Make following assorted true mineral varnish: Lycoperdon polymorphum Vitt, reddish brown, black, pale red, pale yellow, grayish green, grey blue, shallow palm fibre.
Embodiment 11
The preparation of stone material emulation coating (np-dc01)
Rotating speed, to 300r/min, adds water 997g, calcium chloride powder 3g, stirs 2min, and speed brings up to 400r/min, plus
Enter black true mineral varnish 40g, milky white true mineral varnish 800g, pale red true mineral varnish 160g, stir 3-15min, use 100 mesh filter screens, filter off water
Point, that is, obtain the true mineral varnish granule 1000g of the coating of color np-dc01.
Rotating speed, to 300r/min, adds silicone acrylic emulsion 250g, ph regulator 1.5g, coalescents 13g, cosolvent 14g, disappears
Infusion 2g, Antisepticize and mildew preventive 10g, water 101.5g, stir 5min, add the true mineral varnish granule 600g of the coating of color np-dc01,
Add hec cellulose thickener 4g, hase thickening agent 4g.Obtaining color np-dc01 is stone material emulation coating.
Embodiment 12
The preparation of stone material emulation coating (np-dc02)
Rotating speed, to 300r/min, adds water 997g, calcium chloride powder 3g, stirs 2min, and speed brings up to 400r/min, plus
Enter black true mineral varnish 40g, milky white true mineral varnish 800g, Lycoperdon polymorphum Vitt true mineral varnish 160g, stir 3-15min, use 100 mesh filter screens, filter off water
Point, that is, obtain the true mineral varnish granule 1000g of the coating of color np-dc02.
Rotating speed, to 300r/min, adds silicone acrylic emulsion 250g, ph regulator 1.5g, coalescents 13g, cosolvent 14g, disappears
Infusion 2g, Antisepticize and mildew preventive 10g, water 101.5g, stir 5min, add the true mineral varnish granule 600g of the coating of color np-dc02,
Add hec cellulose thickener 4g, hase thickening agent 4g.Obtaining color np-dc02 is stone material emulation coating.
Embodiment 13
The preparation of stone material emulation coating (np-dc02)
Rotating speed, to 300r/min, adds water 994g, calcium chloride powder 6g, stirs 2min, and speed brings up to 400r/min, plus
Enter black true mineral varnish 40g, milky white true mineral varnish 800g, Lycoperdon polymorphum Vitt true mineral varnish 60g, brownish red true mineral varnish 100g, stir 3-15min, use
100 mesh filter screens, filter off moisture, that is, obtain the true mineral varnish granule 1000g of the coating of color np-dc02.
Rotating speed, to 300r/min, adds silicone acrylic emulsion 250g, ph regulator 1.5g, coalescents 15g, cosolvent 14g, disappears
Infusion 2.5g, Antisepticize and mildew preventive 13g, water 101.5g, stir 5min, add the true mineral varnish granule of the coating of color np-dc02
600g, adds hec cellulose thickener 4g, hase thickening agent 4g.Obtaining color np-dc02 is stone material emulation coating.
Embodiment 14-20
The preparation of stone material emulation coating (np-dc03～np-dc20)
The method of reference implementation example 11 and 12, similarly, the proportioning using table 2 below can obtain np-dc04 to np-dc20
The stone material emulation coating of assorted number.
The colored true mineral varnish consumption of table 2 embodiment 14-20
Embodiment 21
The preparation of stone material emulation coating coating (film)
Brush transparent confinement priming paint on the cement plate of 1m x1m, is dried.Patch color separation paper, color separation lateral lattice: thick 2mm, width
2cm.
Using the coating np-dc02 of embodiment 12 preparation, together, japanning amount is 3.5-4kg/m for spraying2, spray gun is common
True mineral varnish spray gun, nozzle diameter φ 10mm, spraying air pressure is 3-4kg/cm2.The plain drum libation at an ancient wedding ceremony wet 200# solvent is used after having sprayed
Oily back roller presses coating surface.Throw off color separation paper slip, by the dried coating film 4-6 hour of stone material emulation coating.
Cover one finishing varnish, be dried 7 days.
Appearance of film as shown in figure 1, extremely similar to the outward appearance of lithotome, have preferably imitate stone effect, emulation
Degree is high.
Embodiment 22
The preparation of stone material emulation coating coating (film)
Brush transparent confinement priming paint on the cement plate of 1m x1m, is dried.Patch color separation paper, color separation lateral lattice: thick 2mm, width
2cm.
Using the coating np-dc05 of embodiment 15 preparation, criticize and scrape together, japanning amount 3.0-3.5kg/m2.Criticize to scrape and constructed
The plain drum libation at an ancient wedding ceremony wet 200# solvent naphtha back roller is used to press coating surface afterwards.
Throw off color separation paper slip, by the dried coating film 4-6 hour of stone material emulation coating.
Cover one finishing varnish, be dried 7 days.
Appearance of film as shown in Fig. 2 extremely similar to the outward appearance of lithotome, have preferably imitate stone effect, emulation
Degree is high.
Embodiment 23-30
The preparation of stone material emulation coating coating (film)
The method of reference implementation example 21 and 22, the color number using the preparation of embodiment 13-20 is np-dc01, np-dc03, np-
Dc04, the stone material emulation coating of np-dc06 to np-dc20, it is possible to obtain the film of different-effect.
Comparative example 1
Copy the effect of decorative patterns of granites stone using existing conventional coating, the first coating is that have color true mineral varnish face
Color is milky, for bottoming, provides background color and stone texture for stone；Second coating is water-soluble colorful coating, its
The coloured silk comprising puts the stain that granule is 20% and 80% pale red point.It is sprayed on coloured true mineral varnish surface, be that stone carries
For stone patterns.
Comparative example 2
Copy the effect of decorative patterns of granites stone using existing conventional coating, the first coating is that have color true mineral varnish face
Color is milky, for bottoming, provides background color and stone texture for stone；Second coating is water-soluble colorful coating, its
The color pale yellow color point putting the black color point that granule is 10%, 10% grey color point and 80% comprising.It is sprayed on coloured true
Mineral varnish surface, provides stone patterns for stone.
Randomly select volunteer 20 people, using range estimation, the film to embodiment and comparative example preparation for the mode being touched with handss
It is compared, result is as shown in Table 3 and Table 4.
The film of table 3np-dc01 and the film comparative result of comparative example 1
The film that film prepared by np-dc01 is prepared with comparative example 1 compares, and in 5 meters of distant surveillances, 19 people all recognize
Similar to lithotome effect for two film effect, but in 1 meter of close-ups, 18 people all think np-dc01 film effect with
Natural flowers ridge rock stone effect is similar, and has 4 people to think that comparative example 1 film effect is dissimilar with natural flowers ridge rock stone effect.
20 people all think that np-dc01 film decorative pattern has stereovision, and only 2 people think that ratio 1 film decorative pattern has stereovision, but many
Number people (18 people) thinks that comparative example 1 film decorative pattern lacks stereovision.Touch sense in terms of, 20 people all think np-dc01 film with
Natural flowers ridge rock material sense of touch is similar, and has 4 people to think that comparative example 1 film is dissimilar with natural flowers ridge rock material sense of touch.
The film of table 4np-dc06 and the film comparative result of comparative example 2
The film that film prepared by np-dc06 is prepared with comparative example 2 compares, and in 5 meters of distant surveillances, 19 people all recognize
Similar to lithotome effect for two film effect, but in 1 meter of close-ups, 18 people all think np-dc06 film effect with
Natural flowers ridge rock stone effect is similar, and has 4 people to think that comparative example 2 film effect is dissimilar with natural flowers ridge rock stone effect.
20 people all think that np-dc06 film decorative pattern has stereovision, and only 2 people think that ratio 1 film decorative pattern has stereovision, but many
Number people (18 people) thinks that comparative example 2 film decorative pattern lacks stereovision.Touch sense in terms of, 20 people all think np-dc06 film with
Natural flowers ridge rock material sense of touch is similar, and has 4 people to think that comparative example 1 film is dissimilar with natural flowers ridge rock material sense of touch.
It can be seen that, compared with existing true mineral varnish and multicolor finish, the coating of the present invention has higher fidelity, is seeing
Sense, texture, touch sense, rough sense have all reached stone effect, and efficiency of construction is higher.
The all documents referring in the present invention are all incorporated as reference in this application, independent just as each document
It is incorporated as with reference to like that.In addition, it is to be understood that after the above-mentioned teachings having read the present invention, those skilled in the art can
To make various changes or modifications to the present invention, these equivalent form of values equally fall within the model that the application appended claims are limited
Enclose.
Claims (10)
1. a kind of aqueouss stone-like coating is it is characterised in that described coating comprises colored true mineral varnish granule, described colored true mineral varnish
Grain stirred in the liquid of point of contact by colored true mineral varnish, be chopped into granule, be filtered to remove point of contact liquid after make, wherein said colour
True mineral varnish comprises true mineral varnish base material and colored sand, and described point of contact liquid comprises 0.3-1 weight portion calcium chloride and 99.7-99 weight
Part water；
And described true mineral varnish base material comprises: acrylic emulsion 4-10 weight portion, ph regulator 0.1-0.2 weight portion, coalescents
0.1-0.2 weight portion, thickening agent 0.1-0.2 weight portion, cosolvent 0.2-0.4 weight portion, Antisepticize and mildew preventive 0.1-0.2 weight
Part, defoamer 0.2-0.4 weight portion, 3.5% sodium alginate aqueous solution 10-20 weight portion, hollow glass bead 1-2 weight portion, water
5-15 weight portion.
2. coating as claimed in claim 1 is it is characterised in that the particle diameter of described colored true mineral varnish granule is 0.5-8mm.
3. coating as claimed in claim 1 is it is characterised in that described colored true mineral varnish comprises 25-35 weight portion true mineral varnish base
Material and 65-75 weight portion colour sand.
4. coating as claimed in claim 3 is it is characterised in that described ph regulator is organic amine ph regulator；Described one-tenth
Film auxiliary agent is 12 lipidols；Described thickening agent is hydroxyethyl cellulose；Described cosolvent is propylene glycol, ethylene glycol, ethylene glycol bisthioglycolate
Ether, 200# solvent naphtha or its mixture；Described Antisepticize and mildew preventive is isothiazolinone derivatives preservative, benzimidazole esters are prevented
Rotten agent or its mixture；Described defoamer is mineral oil type antifoaming agent, organic silicon defoamer or its mixture.
5. it is characterised in that described coating also comprises emulsion phase, described emulsion phase comprises coating as claimed in claim 1: silicon
Acrylic emulsion 20-30 weight portion, ph regulator 0.1-0.2 weight portion, coalescents 1-2 weight portion, cosolvent 1-2 weight portion, disappear
Infusion 0.2-0.3 weight portion, Antisepticize and mildew preventive 1-2 weight portion, water 10-15 weight portion, thickening agent 0.5-1 weight portion.
6. coating as claimed in claim 5 is it is characterised in that in described emulsion phase, described silicone acrylic emulsion changes for organosilicon
Property acrylic acid ester emulsion；Described ph regulator is organic amine ph regulator；Described coalescents are 12 lipidols；Described hydrotropy
Agent is propylene glycol, ethylene glycol, ethylene glycol diether, 200# solvent naphtha or its mixture；Described Antisepticize and mildew preventive is isothiazolone
Derivant preservative, benzimidazole esters preservative or its mixture；Described defoamer is mineral oil type antifoaming agent, organosilicon disappears
Infusion or its mixture；Described thickening agent is hydroxyethyl cellulose and association type alkali swollen thickener.
7. coating as claimed in claim 1 is it is characterised in that described colour sand is selected from the group:
Black sand 4 weight portion, milky white sand 80 weight portion, pale red sand 16 weight portion；
Black sand 4 weight portion, milky white sand 80 weight portion, Lycoperdon polymorphum Vitt sand 16 weight portion；
Black sand 4 weight portion, milky white sand 80 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, reddish brown sand 10 weight portion；
Black sand 4 weight portion, milky white sand 10 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, pale yellow sand 80 weight portion；
Black sand 4 weight portion, milky white sand 10 weight portion, brownish red sand 6 weight portion, pale red sand 80 weight portion；
Black sand 4 weight portion, milky white sand 50 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, pale yellow sand 40 weight portion；
Black sand 4 weight portion, milky white sand 50 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, pale red sand 40 weight portion；
Black sand 4 weight portion, milky white sand 10 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, shallow palm fibre sand 80 weight portion；
Black sand 4 weight portion, milky white sand 50 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, shallow palm fibre sand 40 weight portion；
Milky white sand 50 weight portion, reddish brown sand 6 weight portion, pale red sand 40 weight portion, grayish green sand 4 weight portion；
Milky white sand 50 weight portion, reddish brown sand 6 weight portion, pale yellow sand 40 weight portion, ash indigo plant sand 4 weight portion；
Milky white sand 50 weight portion, reddish brown sand 6 weight portion, grayish green sand 4 weight portion, shallow palm fibre sand 40 weight portion；
Milky white sand 50 weight portion, grayish green sand 10 weight portion, shallow palm fibre sand 40 weight portion；
Black sand 4 weight portion, reddish brown sand 6 weight portion, pale red sand 60 weight portion, ash indigo plant sand 10 weight portion, shallow palm fibre sand
Sub 20 weight portions；
Black sand 4 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, yellow ash sand 30 weight portion, pale yellow sand 60 weight portion；
Black sand 4 weight portion, Lycoperdon polymorphum Vitt sand 6 weight portion, reddish brown sand 10 weight portion, grayish green sand 20 weight portion, shallow palm fibre sand
Sub 60 weight portions；
Milky white sand 20 weight portion, reddish brown sand 20 weight portion, grayish green sand 60 weight portion；
Milky white sand 20 weight portion, reddish brown sand 20 weight portion, ash indigo plant sand 60 weight portion；
Black sand 10 weight portion, milky white sand 30 weight portion, Lycoperdon polymorphum Vitt sand 40 weight portion, reddish brown sand 6 weight portion, shallow palm fibre sand
Sub 24 weight portions；
Black sand 6 weight portion, milky white sand 10 weight portion, Lycoperdon polymorphum Vitt sand 60 weight portion, pale yellow sand 24 weight portion.
8. coating as claimed in claim 1 is it is characterised in that described colored true mineral varnish granule is the colour of several different colours
The mixture of true mineral varnish granule, is selected from the group:
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 80 weight portion, pale red true mineral varnish granule 16 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 80 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 16 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 80 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, reddish brown true
Mineral varnish granule 10 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 10 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, pale yellow true
Mineral varnish granule 80 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 10 weight portion, brownish red true mineral varnish granule 6 weight portion, pale red
True mineral varnish granule 80 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 50 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, pale yellow true
Mineral varnish granule 40 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 50 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, pale red true
Mineral varnish granule 40 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 10 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, shallow palm fibre are true
Mineral varnish granule 80 weight portion；
Black true mineral varnish granule 4 weight portion, milky white true mineral varnish granule 50 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, shallow palm fibre are true
Mineral varnish granule 40 weight portion；
Milky white true mineral varnish granule 50 weight portion, reddish brown true mineral varnish granule 6 weight portion, pale red true mineral varnish granule 40 weight portion, grayish green
True mineral varnish granule 4 weight portion；
Milky white true mineral varnish granule 50 weight portion, reddish brown true mineral varnish granule 6 weight portion, pale yellow true mineral varnish granule 40 weight portion, ash are blue
True mineral varnish granule 4 weight portion；
Milky white true mineral varnish granule 50 weight portion, reddish brown true mineral varnish granule 6 weight portion, grayish green true mineral varnish granule 4 weight portion, shallow palm fibre are true
Mineral varnish granule 40 weight portion；
Milky white true mineral varnish granule 50 weight portion, grayish green true mineral varnish granule 10 weight portion, shallow brown true mineral varnish granule 40 weight portion；
Black true mineral varnish granule 4 weight portion, reddish brown true mineral varnish granule 6 weight portion, pale red true mineral varnish granule 60 weight portion, ash are blue true
Mineral varnish granule 10 weight portion, shallow brown true mineral varnish granule 20 weight portion；
Black true mineral varnish granule 4 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, yellow grey true mineral varnish granule 30 weight portion, pale yellow true
Mineral varnish granule 60 weight portion；
Black true mineral varnish granule 4 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 6 weight portion, reddish brown true mineral varnish granule 10 weight portion, grayish green true
Mineral varnish granule 20 weight portion, shallow brown true mineral varnish granule 60 weight portion；
Milky white true mineral varnish granule 20 weight portion, reddish brown true mineral varnish granule 20 weight portion, grayish green true mineral varnish granule 60 weight portion；
Milky white true mineral varnish granule 20 weight portion, reddish brown true mineral varnish granule 20 weight portion, blue true mineral varnish granule 60 weight portion of ash；
Black true mineral varnish granule 10 weight portion, milky white true mineral varnish granule 30 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 40 weight portion, reddish brown
True mineral varnish granule 6 weight portion, shallow brown true mineral varnish granule 24 weight portion；
Black true mineral varnish granule 6 weight portion, milky white true mineral varnish granule 10 weight portion, Lycoperdon polymorphum Vitt true mineral varnish granule 60 weight portion, pale yellow
True mineral varnish granule 24 weight portion.
9. a kind of coating is it is characterised in that coating coating described in any one of claim 1-8 for the described coating forms.
10. a kind of product is it is characterised in that described product comprises the coating described in claim 9.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310455697.7A CN104513039B (en) | 2013-09-29 | 2013-09-29 | Aqueous imitation stone coating, coat and product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310455697.7A CN104513039B (en) | 2013-09-29 | 2013-09-29 | Aqueous imitation stone coating, coat and product |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104513039A CN104513039A (en) | 2015-04-15 |
| CN104513039B true CN104513039B (en) | 2017-01-18 |
Family
ID=52788953
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310455697.7A Active CN104513039B (en) | 2013-09-29 | 2013-09-29 | Aqueous imitation stone coating, coat and product |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104513039B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107473638A (en) * | 2017-09-22 | 2017-12-15 | 苏州振振好新型建材科技有限公司 | A kind of Novel ring fidelity mineral varnish and preparation method thereof and coating, product |
| CN107522423A (en) * | 2017-09-22 | 2017-12-29 | 苏州振振好新型建材科技有限公司 | A kind of weather resistant stone-like coating and preparation method thereof and coating, product |
| CN109162417B (en) * | 2018-08-03 | 2021-01-15 | 吉安天晟新材料有限公司 | Method for manufacturing stone-like colorful coating |
| CN109486310A (en) * | 2018-12-13 | 2019-03-19 | 广东华兹卜新材料科技有限公司 | A kind of aqueous stone-like coating and its manufacturing method |
| CN109913027A (en) * | 2019-03-12 | 2019-06-21 | 青岛明月海藻集团有限公司 | A kind of imitation stone lacquer protective glue used additives |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101077952A (en) * | 2007-05-31 | 2007-11-28 | 代华南 | Decoration perlite particle spraying material and preparation technique thereof |
| CN102181196A (en) * | 2011-01-24 | 2011-09-14 | 张兴艺 | Water-in-water colorful stone simulated paint |
| CN102815888A (en) * | 2012-08-14 | 2012-12-12 | 中华制漆（深圳）有限公司 | Coating with characteristics of ceramic color and quartz sand texture, preparation method and application thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004143390A (en) * | 2002-10-25 | 2004-05-20 | Rivall:Kk | Thermally insulative coating material giving stone grain pattern and generating negative ion |
-
2013
- 2013-09-29 CN CN201310455697.7A patent/CN104513039B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101077952A (en) * | 2007-05-31 | 2007-11-28 | 代华南 | Decoration perlite particle spraying material and preparation technique thereof |
| CN102181196A (en) * | 2011-01-24 | 2011-09-14 | 张兴艺 | Water-in-water colorful stone simulated paint |
| CN102815888A (en) * | 2012-08-14 | 2012-12-12 | 中华制漆（深圳）有限公司 | Coating with characteristics of ceramic color and quartz sand texture, preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104513039A (en) | 2015-04-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104513039B (en) | Aqueous imitation stone coating, coat and product | |
| CN103709875B (en) | A kind of sliver paint and preparation method thereof | |
| CN101492577A (en) | Process for producing watersoluble stone design imitating color slice and use scheme | |
| CN104371464B (en) | A kind of water burnt-in sand coating and preparation method thereof | |
| CN108329781A (en) | Water-proof decorative integrative paint and preparation method thereof | |
| CN103694790B (en) | Waterborne flame retardant ink that a kind of flame-retardant wall paper is special and preparation method thereof | |
| CN104591598A (en) | Real stone paint, and preparation method and construction method thereof | |
| CN106752430A (en) | A kind of diatom ooze Environmentally-frieinner-wall inner-wall emulsion paint and preparation method thereof | |
| CN103184785B (en) | A kind of coating application technique | |
| CN107815215A (en) | A kind of water-based stone-like coating formula and water-based imitative stone terrace | |
| CN105199606B (en) | A kind of high stability is imitative to burn stone material water burnt-in sand environmental protection coating material and preparation method thereof | |
| CN104212288A (en) | Water-based colourful building coating and preparation method thereof | |
| CN103468082A (en) | Nanometer anti pollution self-cleaning stone paint | |
| CN109627878A (en) | A kind of sliver water burnt-in sand stone-like coating and preparation method thereof | |
| CN104177940A (en) | Sunlight heat-reflecting thermal-insulating water-in-water colorful environment-friendly coating and production method thereof | |
| CN110204978A (en) | A kind of aqueous plastic coating and preparation method thereof and application method | |
| CN111269597A (en) | Color-changing multifunctional polymer cement waterproof coating | |
| CN109535878A (en) | One kind is containing colorful stone-like coating of sand and preparation method thereof | |
| CN102218877B (en) | Processing method of multifunctional environment-friendly polyvinyl chloride composite decorative material | |
| CN102584114A (en) | Tile-like sand wall-textured coating for exterior walls and preparation method thereof | |
| CN109852128A (en) | A kind of flame retardant type flexible compound coloured silk piece and preparation method thereof | |
| CN112680035B (en) | Artistic paint and preparation method thereof | |
| CN107022270B (en) | Preparation method of fluorine-silicon modified stone-like paint | |
| CN106280650A (en) | Reflective insulation ancient painted pottery rock coating and preparation method thereof | |
| CN105440811A (en) | Aqueous liquid simulation wallpaper coating, coating layer and product |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |