CN104371464B - A kind of water burnt-in sand coating and preparation method thereof - Google Patents

A kind of water burnt-in sand coating and preparation method thereof Download PDF

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Publication number
CN104371464B
CN104371464B CN201410558429.2A CN201410558429A CN104371464B CN 104371464 B CN104371464 B CN 104371464B CN 201410558429 A CN201410558429 A CN 201410558429A CN 104371464 B CN104371464 B CN 104371464B
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Prior art keywords
water
sand
burnt
base resin
deionized water
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CN201410558429.2A
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CN104371464A (en
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司朗诵
王伟东
郑树军
朱从华
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Zhejiang Huade New Material Co. Ltd.
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HUATE CHEMICAL Co Ltd HUATE INDUSTRY GROUP ZHEJIANG
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to a kind of water burnt-in sand coating and preparation method thereof.The coating that purpose is to provide should have the rough using effect of similar fired slab, and the manufacture method provided should have technique feature simple, lower-cost.Technical scheme is: a kind of water burnt-in sand coating, including composition be: 1) A material: water-base resin, deionized water, auxiliary agent, pigment, Kaolin, complex thickener, quartz sand;2) B material: deionized water, protection glue;3) C material: water-base resin, complex thickener.The manufacture method of above-mentioned water burnt-in sand coating, follows the steps below: 1) by the deionized water in A material, pigment, Kaolin, add quartz sand and emulsion after complex thickener mix homogeneously, then mix colours;2) B is expected mix homogeneously;3) by above-mentioned steps 1), 2) prepare A material, B material mixing after made into particulate form;4) C is expected mixing and stirring;5) by step 3) with step 4) prepare material shear-mixed.

Description

A kind of water burnt-in sand coating and preparation method thereof
Technical field
The present invention relates to the manufacture method of a kind of exterior coating and this coating.
Background technology
Granite is the dalle that people like;The especially granite through high temperature process (is referred to as burnt Plate), owing to surface differential expansion of being heated is different, and produce texture and the vision of a little concavo-convex similar bush-hammered face Effect, has decoration and anti-skidding effect, is favored by many consumers, but price is the most expensive.To this end, Attempt to study imitation products, use tradition water-water coating to produce the visual effect of similar fired slab; But it is because being a granulated into of water-water coating and is divided into water and superfine paint filler, thus the color produced and matter Sense effect is the strongest.
Summary of the invention
It is an object of the invention to overcome the deficiency in above-mentioned background technology, it is provided that a kind of water burnt-in sand coating and system thereof Making method, the coating provided should have the rough using effect of similar fired slab, the system provided Make method and should have technique feature simple, lower-cost.
Present invention provide the technical scheme that
A kind of water burnt-in sand coating, including composition and weight portion be:
1) A material:
Water-base resin 30-40, deionized water 10~30, auxiliary agent 3~5, pigment 5~10, Kaolin 10~20, Complex thickener 3~5, quartz sand 30~40;
2) B material:
Deionized water 94~98, protection glue 2~6;
3) C material
Water-base resin 95-100, complex thickener 3~5;
Described complex thickener is mixed in 1:1 ratio by hydroxyethyl cellulose and special gelatin;Described special gelatin For the one in hydroxypropyl guar gum, gelatin, sodium alginate and carrageenan;
Described protection glue is mixed in 8:2 ratio by lithium bentonite and aluminium-magnesium silicate;
Described water-base resin is pure-acrylic emulsion or fluorocarbon resin emulsion or organosilicon acrylic resin emulsion or fluorine silicon resin breast Liquid.
Described pigment is titanium dioxide, preferably rutile titanium white lead R975.
Kaolin fineness is not more than 1250 mesh, and the fineness of quartz sand is not more than 120 mesh;
Composition and the weight portion of described water burnt-in sand coating be:
1) A material:
Water-base resin 30-40, deionized water 10~25, auxiliary agent 3~4, pigment 6~8, Kaolin 10~15, multiple Close thickening agent 3~4, quartz sand 30~40;
2) B material:
Deionized water 95~97, protection glue 3~5;
3) C material
Water-base resin 95-97, complex thickener 3~5.
Composition and the weight portion of described water burnt-in sand coating be:
1) A material:
Water-base resin 30.0, deionized water 10.0, auxiliary agent 3.0, pigment 7.0, Kaolin 10.0, composite thickening Agent 3.0, quartz sand 37.0;
2) B material:
Deionized water 95.0, protection glue 5.0;
3) C material
Water-base resin 97.0, complex thickener 3.0.
Described auxiliary agent includes cation dispersing agent, cationic wetting agents, coalescents, antibacterial, defoamer And antifreezing agent.
The manufacture method of above-mentioned water burnt-in sand coating, follows the steps below:
1) deionized water in A being expected, pigment, Kaolin, add stone after complex thickener mix homogeneously Sand and emulsion, further according to requiring toning;
2) B is expected mix homogeneously;
3) by above-mentioned steps 1), 2) prepare A material, B material mixing after made into particulate form;
4) C is expected mixing and stirring;
5) by step 3) with step 4) prepare material shear-mixed, i.e. formed different colours granule uniformly divide The water burnt-in sand coating of cloth.
Described step 3) in grain diameter be 1-5mm.
The invention has the beneficial effects as follows: owing to water burnt-in sand spray painting is dried, present be not of uniform size, Height does not waits and the small sand heap of irregular distribution, embodies natural rock (especially fired slab) completely Texture and color, have extremely strong relief emulation visual effect, after solving conventional water-water coating use Third dimension is not strong, lacks the defect of texture.And processing technique is simple, employing is again have a large capacity and a wide range normal Rule raw material, therefore cost of manufacture is the highest, is suitable for promoting the use of in the industry.
Detailed description of the invention
The thinking of the present invention is;If changing the pelletize composition in coating into quartz sand, needs just can be obtained Natural rock texture effect;The present invention is formed with regard to this.
Embodiment 1
A kind of water burnt-in sand coating, including composition and weight portion be:
1) A material:
Pure-acrylic emulsion 30.0, deionized water 10.0, auxiliary agent 3.0, titanium dioxide 7.0, Kaolin 10.0, ethoxy Complex thickener 3.0 that cellulose and hydroxypropyl guar gum are mixed in 1:1 ratio, quartz sand 37.0;
2) B material:
The protection glue 6 that deionized water 94, lithium bentonite and aluminium-magnesium silicate are mixed in 8:2 ratio;
3) C material
The composite thickening that pure-acrylic emulsion 95, hydroxyethyl cellulose and hydroxypropyl guar gum are mixed in 1:1 ratio Agent 5.0;
The manufacture method of this water burnt-in sand coating, follows the steps below:
1) deionized water in being expected by A, titanium dioxide, Kaolin, auxiliary agent, complex thickener mixes, high Speed adds quartz sand and pure-acrylic emulsion after being uniformly dispersed, further according to requiring that toning (recommends shading process: A material A material is divided into several parts, the no color of furnishing as requested during toning);
2) B is expected mix homogeneously
3) by above-mentioned steps 1), 2) prepare A, B material mixing, be stirred for making grain shape one by one; Grain diameter controls as 3mm;
4) C is expected mixing and stirring;
5) by step 3) material and the step 4 that prepare) material for preparing mixes, i.e. and formation different colours granule is equal The water burnt-in sand coating of even distribution.
Embodiment 2
A kind of water burnt-in sand coating, including composition and weight portion be:
1) A material:
Fluorine carbon emulsion 30.0, deionized water 10.0, titanium dioxide 6.0, Kaolin 12.0, auxiliary agent 3.0, hydroxyl second The complex thickener 4.0 that base cellulose and gelatin are mixed in 1:1 ratio, quartz sand 35;
2) B material:
The protection glue 4 that deionized water 96, lithium bentonite and aluminium-magnesium silicate are mixed in 8:2 ratio;
3) C material
The complex thickener that fluorocarbon resin emulsion 96, hydroxyethyl cellulose and gelatin are mixed in 1:1 ratio 4.0;
The manufacture method of this water burnt-in sand coating, follows the steps below:
1) deionized water in being expected by A, titanium dioxide, Kaolin, auxiliary agent, complex thickener mixes, high Speed adds quartz sand and fluorine carbon emulsion after being uniformly dispersed, further according to requiring toning;
2) B is expected mix homogeneously
3) by above-mentioned steps 1), 2) prepare A, B material mixing, be stirred for making grain shape one by one; Grain diameter controls as 1mm;
4) C is expected mixing and stirring;
5) by step 3) material and the step 4 that prepare) material for preparing mixes, i.e. and formation different colours granule is equal The water burnt-in sand coating of even distribution.
Embodiment 3
A kind of water burnt-in sand coating, including composition and weight portion be:
1) A material:
Organosilicon acrylic resin emulsion 35.0, deionized water 10.0, titanium dioxide 6.0, auxiliary agent 3.5, Kaolin 15.0, Complex thickener 3.0 that hydroxyethyl cellulose and carrageenan are mixed in 1:1 ratio, quartz sand 31.0;
2) B material:
The protection glue 4 that deionized water 96.0, lithium bentonite and aluminium-magnesium silicate are mixed in 8:2 ratio;
3) C material
The complex thickener that organosilicon acrylic resin emulsion 95, hydroxyethyl cellulose and carrageenan are mixed in 1:1 ratio 5.0;
The manufacture method of this water burnt-in sand coating, follows the steps below:
1) deionized water in being expected by A, titanium dioxide, Kaolin, auxiliary agent, complex thickener mixes, high Speed adds quartz sand and organosilicon acrylic resin emulsion after being uniformly dispersed, further according to requiring toning;
2) B is expected mix homogeneously
3) by above-mentioned steps 1), 2) prepare A, B material mixing, be stirred for making grain shape one by one; Grain diameter controls as 5mm;
4) C is expected mixing and stirring;
5) by step 3) material and the step 4 that prepare) material for preparing mixes, i.e. and formation different colours granule is equal The water burnt-in sand coating of even distribution.
Above-described embodiment use auxiliary agent include successively cation dispersing agent, cationic wetting agents, coalescents, Antibacterial, defoamer and antifreezing agent;Recommendation ratio between each composition is 3: 2: 6: 1: 10.Described Each composition of auxiliary agent is the conventional variety for coating.
In embodiment 3, cation dispersing agent is SUA-110;Cationic wetting agents is SUA-030;Coalescents For W825;Antibacterial is QK20;Defoamer is NXZ;Antifreezing agent is propylene glycol.

Claims (3)

1. a water burnt-in sand coating, including composition and weight portion be:
1) A material:
Water-base resin 30-40, deionized water 10~30, auxiliary agent 3~5, pigment 5~10, Kaolin 10~20, Complex thickener 3~5, quartz sand 30~40;
2) B material:
Deionized water 94~98, protection glue 2~6;
3) C material
Water-base resin 95-97, complex thickener 3~5;
Described complex thickener is mixed in 1:1 ratio by hydroxyethyl cellulose and special gelatin;Described special gelatin For the one in hydroxypropyl guar gum, gelatin, sodium alginate and carrageenan;
Described protection glue is mixed in 8:2 ratio by lithium bentonite and aluminium-magnesium silicate;
Described water-base resin is pure-acrylic emulsion or fluorocarbon resin emulsion or organosilicon acrylic resin emulsion or fluorine silicon resin breast Liquid;
Described auxiliary agent includes cation dispersing agent, cationic wetting agents, coalescents, antibacterial, defoamer And antifreezing agent;
Described pigment is titanium dioxide.
Water burnt-in sand coating the most according to claim 1, it is characterised in that the composition of this water burnt-in sand coating and Weight portion is:
1) A material:
Water-base resin 30-40, deionized water 10~25, auxiliary agent 3~4, pigment 6~8, Kaolin 10~15, multiple Close thickening agent 3~4, quartz sand 30~40;
2) B material:
Deionized water 95~97, protection glue 3~5;
3) C material
Water-base resin 95-97, complex thickener 3~5.
Water burnt-in sand coating the most according to claim 2, it is characterised in that the one-tenth that this water burnt-in sand coating includes Divide and weight portion be:
1) A material:
Water-base resin 30.0, deionized water 10.0, auxiliary agent 3.0, pigment 7.0, Kaolin 10.0, compound Thickening agent 3.0, quartz sand 37.0;
2) B material:
Deionized water 95.0, protection glue 5.0;
3) C material
Water-base resin 97.0, complex thickener 3.0.
CN201410558429.2A 2014-10-20 2014-10-20 A kind of water burnt-in sand coating and preparation method thereof Active CN104371464B (en)

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* Cited by examiner, † Cited by third party
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CN107722774A (en) * 2017-10-23 2018-02-23 河北晨阳工贸集团有限公司 A kind of flame-retardant water burnt-in sand coating and preparation method thereof

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CN106752482A (en) * 2015-11-25 2017-05-31 铂恩塞尔新材料(上海)股份有限公司 A kind of water burnt-in sand multicolor finish and preparation method thereof
CN105604299A (en) * 2015-12-26 2016-05-25 铃鹿复合建材(上海)有限公司 Faux marble effect terrace
CN105505224A (en) * 2016-01-12 2016-04-20 郑州大学 Stone-in-water paint and preparing method thereof
CN106590425B (en) * 2016-11-17 2019-07-19 济南好饰家化工有限公司 Imitative bush-hammered face water burnt-in sand multicolor finish and preparation method and the application on insulation board
CN107056146A (en) * 2017-05-24 2017-08-18 北京乾瑞科技有限公司 A kind of water burnt-in sand multicolor finish from thickening type
CN107227111A (en) * 2017-07-20 2017-10-03 中山市粤马建筑涂料有限公司 A kind of new type water burnt-in sand coating and preparation method thereof
CN107474672A (en) * 2017-08-23 2017-12-15 浙江华德新材料有限公司 A kind of Elastic anti-crack artificial granite heat reflection coatings and preparation method thereof
CN108485423A (en) * 2018-03-14 2018-09-04 江苏恒兆新材料科技有限公司 Quick-reaction type water burnt-in sand multicolor finish and its production technology
CN111607294A (en) * 2019-02-23 2020-09-01 湖南梨树园涂料有限公司 Sand-in-water multi-color paint toning bag and preparation method thereof

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CN102533039B (en) * 2011-12-19 2013-07-03 河南省德嘉丽科技开发有限公司 Paint with elastic texture

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Inventor after: Si Langsong

Inventor after: Wang Weidong

Inventor after: Zheng Shujun

Inventor after: Zhu Conghua

Inventor before: Si Langsong

Inventor before: Zheng Shujun

COR Change of bibliographic data
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Effective date of registration: 20171106

Address after: 311305 Hangzhou, Ling'an Economic Development Zone, Castle street, Tianzhu street, No. 65, No.

Patentee after: Zhejiang Huade New Material Co. Ltd.

Address before: 311305 No. 65, Tianzhu street, Qingshan street, Ling'an Economic Development Zone, Zhejiang, Hangzhou

Patentee before: Huate Chemical Co., Ltd., Huate Industry Group, Zhejiang