CN104371464A - Sand-in-water paint and manufacturing method thereof - Google Patents

Sand-in-water paint and manufacturing method thereof Download PDF

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Publication number
CN104371464A
CN104371464A CN201410558429.2A CN201410558429A CN104371464A CN 104371464 A CN104371464 A CN 104371464A CN 201410558429 A CN201410558429 A CN 201410558429A CN 104371464 A CN104371464 A CN 104371464A
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China
Prior art keywords
water
sand
deionized water
burnt
complex thickener
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Granted
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CN201410558429.2A
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Chinese (zh)
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CN104371464B (en
Inventor
司朗诵
郑树军
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Zhejiang Huade New Material Co. Ltd.
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HUATE CHEMICAL Co Ltd HUATE INDUSTRY GROUP ZHEJIANG
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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention relates to a sand-in-water paint and a manufacturing method thereof. The invention aims to provide a paint with uneven use effect like a fire board and also provide a manufacturing method with the characteristics of simple technique and lower cost. The technical scheme is as follows: the sand-in-water paint comprises the following components: 1) material A: water-based resin, deionized water, assistant, pigment, kaolin, composite thickener and quartz sand; 2) material B: deionized water and protective adhesive; and 3) material C: water-based resin and composite thickener. The manufacturing method of the sand-in-water paint comprises the following steps: 1) uniformly mixing the deionized water, pigment, kaolin and composite thickener in the material A, adding the quartz sand and emulsion, and carrying out color matching; 2) uniformly mixing the material B; 3) mixing the material A and material B prepared in the steps 1) and 2), and granulating; 4) uniformly mixing the material C; and 5) carrying out shear mixing on the materials prepared in the steps 3) and 4).

Description

A kind of water burnt-in sand coating and preparation method thereof
Technical field
The present invention relates to the making method of a kind of exterior coating and this coating.
Background technology
Grouan is the dalle that people like; Especially through the grouan (being called fired slab) of high temperature process, because surface is heated differential expansion difference, and produce texture and the visual effect of a little concavo-convex similar bush-hammered face, there is decoration and anti-skidding effect, be subject to the favor of many human consumers, but price is also more expensive.For this reason, someone attempts to study imitation products, adopts traditional water-water coating to produce the visual effect of similar fired slab; But because being a granulated into of water-water coating be divided into water and superfine paint filler, the color thus produced and texture effect not strong.
Summary of the invention
The object of the invention is to overcome the deficiency in above-mentioned background technology, a kind of water burnt-in sand coating and preparation method thereof is provided, the coating provided should have the rough result of use of similar fired slab, and the making method provided should have simple, the lower-cost feature of technique.
Technical scheme provided by the invention is:
A kind of water burnt-in sand coating, the composition comprised and weight part are:
1) A material:
Water-base resin 30-40, deionized water 10 ~ 30, auxiliary agent 3 ~ 5, pigment 5 ~ 10, kaolin 10 ~ 20, complex thickener 3 ~ 5, quartz sand 30 ~ 40;
2) B material:
Deionized water 94 ~ 98, protecting glue 2 ~ 6;
3) C material
Water-base resin 95-100, complex thickener 3 ~ 5;
Described complex thickener is mixed in 1:1 ratio by Natvosol and special gelatin; Described special gelatin is the one in hydroxypropylguar gum, gelatin, sodium alginate and carrageenin;
Described protecting glue is mixed in 8:2 ratio by lithium bentonite and neusilin;
Described water-base resin is pure-acrylic emulsion or fluorocarbon resin emulsion or organosilicon acrylic resin emulsion or fluorine silicon resin emulsion.
Described pigment is titanium dioxide, preferred rutile titanium white powder R975.
Kaolin fineness is not more than 1250 orders, and the fineness of quartz sand is not more than 120 orders;
Composition and the weight part of described water burnt-in sand coating are:
1) A material:
Water-base resin 30-40, deionized water 10 ~ 25, auxiliary agent 3 ~ 4, pigment 6 ~ 8, kaolin 10 ~ 15, complex thickener 3 ~ 4, quartz sand 30 ~ 40;
2) B material:
Deionized water 95 ~ 97, protecting glue 3 ~ 5;
3) C material
Water-base resin 95-97, complex thickener 3 ~ 5.
Composition and the weight part of described water burnt-in sand coating are:
1) A material:
Water-base resin 30.0, deionized water 10.0, auxiliary agent 3.0, pigment 7.0, kaolin 10.0, complex thickener 3.0, quartz sand 37.0;
2) B material:
Deionized water 95.0, protecting glue 5.0;
3) C material
Water-base resin 97.0, complex thickener 3.0.
Described auxiliary agent comprises cation dispersing agent, cationic wetting agents, film coalescence aid, sterilant, defoamer and frostproofer.
The making method of above-mentioned water burnt-in sand coating, carry out according to following steps:
1) deionized water in A being expected, pigment, kaolin, adds quartz sand and emulsion, then mixes colours as requested after complex thickener mixes;
2) B material is mixed;
3) by above-mentioned steps 1), 2) obtained A material, made into particulate form after the mixing of B material;
4) C is expected mixing and stirring;
5) by step 3) with step 4) obtained material shear-mixed, namely form the water burnt-in sand coating of different colours uniform particles distribution.
Described step 3) in grain diameter be 1-5mm.
The invention has the beneficial effects as follows: after the drying of water burnt-in sand paint spay-coating, present be not of uniform size, height not etc. and the small sand heap of irregular distribution, embody texture and the color of natural rock (especially fired slab) completely, there is extremely strong relief emulation visual effect, solving conventional water-water coating uses rear stereoscopic sensation strong, lacks the defect of texture.And complete processing is simple, employing be again the conventional raw materials had a large capacity and a wide range, therefore cost of manufacture is not high, is applicable to promoting the use of in the industry.
Embodiment
Thinking of the present invention is; If change the granulation composition in coating into quartz sand, the natural rock texture effect needed just can be obtained; Form the present invention at this point.
Embodiment 1
A kind of water burnt-in sand coating, the composition comprised and weight part are:
1) A material:
The complex thickener 3.0 that pure-acrylic emulsion 30.0, deionized water 10.0, auxiliary agent 3.0, titanium dioxide 7.0, kaolin 10.0, Natvosol and hydroxypropylguar gum mix in 1:1 ratio, quartz sand 37.0;
2) B material:
Deionized water 94, the protecting glue 6 that lithium bentonite and neusilin mix in 8:2 ratio;
3) C material
Pure-acrylic emulsion 95, the complex thickener 5.0 that Natvosol and hydroxypropylguar gum mix in 1:1 ratio;
The making method of this water burnt-in sand coating, carry out according to following steps:
1) deionized water in A being expected, titanium dioxide, kaolin, auxiliary agent, complex thickener mixes, and adds quartz sand and pure-acrylic emulsion after high speed dispersion is even, then toning as requested (will be as requested during recommendation shading process: A material toning, A material is divided into several parts, the no color of furnishing);
2) B material is mixed
3) by above-mentioned steps 1), 2) obtained A, B material mixing, then stir and make particle shape one by one; Grain diameter controls as 3mm;
4) C is expected mixing and stirring;
5) by step 3) obtained material and step 4) obtained material mix, i.e. the water burnt-in sand coating that distributes of formation different colours uniform particles.
Embodiment 2
A kind of water burnt-in sand coating, the composition comprised and weight part are:
1) A material:
Fluorine carbon emulsion 30.0, deionized water 10.0, titanium dioxide 6.0, kaolin 12.0, the complex thickener 4.0 that auxiliary agent 3.0, Natvosol and gelatin mix in 1:1 ratio, quartz sand 35;
2) B material:
Deionized water 96, the protecting glue 4 that lithium bentonite and neusilin mix in 8:2 ratio;
3) C material
Fluorocarbon resin emulsion 96, the complex thickener 4.0 that Natvosol and gelatin mix in 1:1 ratio;
The making method of this water burnt-in sand coating, carry out according to following steps:
1) deionized water in A being expected, titanium dioxide, kaolin, auxiliary agent, complex thickener mixes, and adds quartz sand and fluorine carbon emulsion, then mix colours as requested after high speed dispersion is even;
2) B material is mixed
3) by above-mentioned steps 1), 2) obtained A, B material mixing, then stir and make particle shape one by one; Grain diameter controls as 1mm;
4) C is expected mixing and stirring;
5) by step 3) obtained material and step 4) obtained material mix, i.e. the water burnt-in sand coating that distributes of formation different colours uniform particles.
Embodiment 3
A kind of water burnt-in sand coating, the composition comprised and weight part are:
1) A material:
Organosilicon acrylic resin emulsion 35.0, deionized water 10.0, titanium dioxide 6.0, auxiliary agent 3.5, kaolin 15.0, complex thickener 3.0, quartz sand 31.0 that Natvosol and carrageenin mix in 1:1 ratio;
2) B material:
Deionized water 96.0, the protecting glue 4 that lithium bentonite and neusilin mix in 8:2 ratio;
3) C material
Organosilicon acrylic resin emulsion 95, the complex thickener 5.0 that Natvosol and carrageenin mix in 1:1 ratio;
The making method of this water burnt-in sand coating, carry out according to following steps:
1) deionized water in A being expected, titanium dioxide, kaolin, auxiliary agent, complex thickener mixes, and adds quartz sand and organosilicon acrylic resin emulsion, then mix colours as requested after high speed dispersion is even;
2) B material is mixed
3) by above-mentioned steps 1), 2) obtained A, B material mixing, then stir and make particle shape one by one; Grain diameter controls as 5mm;
4) C is expected mixing and stirring;
5) by step 3) obtained material and step 4) obtained material mix, i.e. the water burnt-in sand coating that distributes of formation different colours uniform particles.
The auxiliary agent that above-described embodiment adopts comprises cation dispersing agent, cationic wetting agents, film coalescence aid, sterilant, defoamer and frostproofer successively; Recommendation ratio between each composition is 3: 2: 6: 1: 10.Each composition of described auxiliary agent is the conventional variety for coating.
In embodiment 3, cation dispersing agent is SUA-110; Cationic wetting agents is SUA-030; Film coalescence aid is W825; Sterilant is QK20; Defoamer is NXZ; Frostproofer is propylene glycol.

Claims (5)

1. a water burnt-in sand coating, the composition comprised and weight part are:
1) A material:
Water-base resin 30-40, deionized water 10 ~ 30, auxiliary agent 3 ~ 5, pigment 5 ~ 10, kaolin 10 ~ 20, complex thickener 3 ~ 5, quartz sand 30 ~ 40;
2) B material:
Deionized water 94 ~ 98, protecting glue 2 ~ 6;
3) C material
Water-base resin 95-97, complex thickener 3 ~ 5;
Described complex thickener is mixed in 1:1 ratio by Natvosol and special gelatin; Described special gelatin is the one in hydroxypropylguar gum, gelatin, sodium alginate and carrageenin;
Described protecting glue is mixed in 8:2 ratio by lithium bentonite and neusilin;
Described water-base resin is pure-acrylic emulsion or fluorocarbon resin emulsion or organosilicon acrylic resin emulsion or fluorine silicon resin emulsion;
Described auxiliary agent comprises cation dispersing agent, cationic wetting agents, film coalescence aid, sterilant, defoamer and frostproofer;
Described pigment is titanium dioxide.
2. water burnt-in sand coating according to claim 1, is characterized in that the composition of this water burnt-in sand coating and weight part are:
1) A material:
Water-base resin 30-40, deionized water 10 ~ 25, auxiliary agent 3 ~ 4, pigment 6 ~ 8, kaolin 10 ~ 15, complex thickener 3 ~ 4, quartz sand 30 ~ 40;
2) B material:
Deionized water 95 ~ 97, protecting glue 3 ~ 5;
3) C material
Water-base resin 95-97, complex thickener 3 ~ 5.
3. water burnt-in sand coating according to claim 2, is characterized in that the composition that this water burnt-in sand coating comprises and weight part are:
1) A material:
Water-base resin 30.0, deionized water 10.0, auxiliary agent 3.0, pigment 7.0, kaolin 10.0, complex thickener 3.0, quartz sand 37.0;
2) B material:
Deionized water 95.0, protecting glue 5.0;
3) C material
Water-base resin 97.0, complex thickener 3.0.
4. the making method of water burnt-in sand coating according to claim 1, carry out according to following steps:
1) deionized water in A being expected, pigment, kaolin, adds quartz sand after complex thickener mixes, then mixes colours as requested;
2) B material is uniformly dispersed
3) by above-mentioned steps 1), 2) obtained A material, B material be uniformly mixed made into particulate form according to 1:1;
4) C is expected mixing and stirring;
5) by step 3) with step 4) obtained material shear-mixed, namely form the water burnt-in sand coating of different colours uniform particles distribution.
5. the making method of water burnt-in sand coating according to claim 4, is characterized in that described step 3) in grain diameter be 1-5mm.
CN201410558429.2A 2014-10-20 2014-10-20 A kind of water burnt-in sand coating and preparation method thereof Active CN104371464B (en)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104831892A (en) * 2015-03-11 2015-08-12 瑞高(浙江)建筑系统有限公司 Flamed surface ceramic plate
CN105505224A (en) * 2016-01-12 2016-04-20 郑州大学 Stone-in-water paint and preparing method thereof
CN105604299A (en) * 2015-12-26 2016-05-25 铃鹿复合建材(上海)有限公司 Faux marble effect terrace
CN106590425A (en) * 2016-11-17 2017-04-26 济南好饰家化工有限公司 Litchi-surface-imitating sand-in-water multicolor coating and preparation method and application thereof in heat insulation board
CN106752482A (en) * 2015-11-25 2017-05-31 铂恩塞尔新材料(上海)股份有限公司 A kind of water burnt-in sand multicolor finish and preparation method thereof
CN107056146A (en) * 2017-05-24 2017-08-18 北京乾瑞科技有限公司 A kind of water burnt-in sand multicolor finish from thickening type
CN107227111A (en) * 2017-07-20 2017-10-03 中山市粤马建筑涂料有限公司 A kind of new type water burnt-in sand coating and preparation method thereof
CN107474672A (en) * 2017-08-23 2017-12-15 浙江华德新材料有限公司 A kind of Elastic anti-crack artificial granite heat reflection coatings and preparation method thereof
CN107722774A (en) * 2017-10-23 2018-02-23 河北晨阳工贸集团有限公司 A kind of flame-retardant water burnt-in sand coating and preparation method thereof
CN108485423A (en) * 2018-03-14 2018-09-04 江苏恒兆新材料科技有限公司 Quick-reaction type water burnt-in sand multicolor finish and its production technology
CN111607294A (en) * 2019-02-23 2020-09-01 湖南梨树园涂料有限公司 Sand-in-water multi-color paint toning bag and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102533039A (en) * 2011-12-19 2012-07-04 河南省德嘉丽科技开发有限公司 Paint with elastic texture
CN102558973A (en) * 2011-12-19 2012-07-11 河南省德嘉丽科技开发有限公司 Actual granite imitation coating

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102533039A (en) * 2011-12-19 2012-07-04 河南省德嘉丽科技开发有限公司 Paint with elastic texture
CN102558973A (en) * 2011-12-19 2012-07-11 河南省德嘉丽科技开发有限公司 Actual granite imitation coating

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104831892A (en) * 2015-03-11 2015-08-12 瑞高(浙江)建筑系统有限公司 Flamed surface ceramic plate
CN106752482A (en) * 2015-11-25 2017-05-31 铂恩塞尔新材料(上海)股份有限公司 A kind of water burnt-in sand multicolor finish and preparation method thereof
CN105604299A (en) * 2015-12-26 2016-05-25 铃鹿复合建材(上海)有限公司 Faux marble effect terrace
CN105505224A (en) * 2016-01-12 2016-04-20 郑州大学 Stone-in-water paint and preparing method thereof
CN106590425B (en) * 2016-11-17 2019-07-19 济南好饰家化工有限公司 Imitative bush-hammered face water burnt-in sand multicolor finish and preparation method and the application on insulation board
CN106590425A (en) * 2016-11-17 2017-04-26 济南好饰家化工有限公司 Litchi-surface-imitating sand-in-water multicolor coating and preparation method and application thereof in heat insulation board
CN107056146A (en) * 2017-05-24 2017-08-18 北京乾瑞科技有限公司 A kind of water burnt-in sand multicolor finish from thickening type
CN107227111A (en) * 2017-07-20 2017-10-03 中山市粤马建筑涂料有限公司 A kind of new type water burnt-in sand coating and preparation method thereof
WO2019037427A1 (en) * 2017-08-23 2019-02-28 浙江华德新材料有限公司 Elastic anti-cracking imitation granite heat reflective coating and preparation method therefor
CN107474672A (en) * 2017-08-23 2017-12-15 浙江华德新材料有限公司 A kind of Elastic anti-crack artificial granite heat reflection coatings and preparation method thereof
CN107722774A (en) * 2017-10-23 2018-02-23 河北晨阳工贸集团有限公司 A kind of flame-retardant water burnt-in sand coating and preparation method thereof
CN108485423A (en) * 2018-03-14 2018-09-04 江苏恒兆新材料科技有限公司 Quick-reaction type water burnt-in sand multicolor finish and its production technology
CN111607294A (en) * 2019-02-23 2020-09-01 湖南梨树园涂料有限公司 Sand-in-water multi-color paint toning bag and preparation method thereof

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Inventor after: Si Langsong

Inventor after: Wang Weidong

Inventor after: Zheng Shujun

Inventor after: Zhu Conghua

Inventor before: Si Langsong

Inventor before: Zheng Shujun

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Effective date of registration: 20171106

Address after: 311305 Hangzhou, Ling'an Economic Development Zone, Castle street, Tianzhu street, No. 65, No.

Patentee after: Zhejiang Huade New Material Co. Ltd.

Address before: 311305 No. 65, Tianzhu street, Qingshan street, Ling'an Economic Development Zone, Zhejiang, Hangzhou

Patentee before: Huate Chemical Co., Ltd., Huate Industry Group, Zhejiang