CN104507980B - 用于制备聚乙烯树脂的方法 - Google Patents

用于制备聚乙烯树脂的方法 Download PDF

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Publication number
CN104507980B
CN104507980B CN201380039898.7A CN201380039898A CN104507980B CN 104507980 B CN104507980 B CN 104507980B CN 201380039898 A CN201380039898 A CN 201380039898A CN 104507980 B CN104507980 B CN 104507980B
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metallocene catalyst
bis
particle size
tetrahydroindenyl
catalyst
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CN201380039898.7A
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English (en)
Chinese (zh)
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CN104507980A (zh
Inventor
C.威洛克
D.西劳克斯
A.范汤米
O.迈泽奎
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Total Petrochemicals Research Feluy SA
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Total Petrochemicals Research Feluy SA
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN201380039898.7A 2012-07-27 2013-07-24 用于制备聚乙烯树脂的方法 Active CN104507980B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12178374 2012-07-27
EP12178374.0 2012-07-27
PCT/EP2013/065562 WO2014016318A1 (en) 2012-07-27 2013-07-24 Process for preparing a polyethylene resin

Publications (2)

Publication Number Publication Date
CN104507980A CN104507980A (zh) 2015-04-08
CN104507980B true CN104507980B (zh) 2017-03-22

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ID=48832938

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CN201380039898.7A Active CN104507980B (zh) 2012-07-27 2013-07-24 用于制备聚乙烯树脂的方法

Country Status (6)

Country Link
US (1) US9340631B2 (enExample)
EP (1) EP2877502B1 (enExample)
CN (1) CN104507980B (enExample)
HU (1) HUE047672T2 (enExample)
IN (1) IN2015DN00491A (enExample)
WO (1) WO2014016318A1 (enExample)

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EP2619357B1 (en) * 2010-09-23 2019-08-28 Total Research & Technology Feluy Artificial grass
JP6517837B2 (ja) 2014-04-23 2019-05-22 トタル リサーチ アンド テクノロジー フエリユイ メタロセン触媒を用いたポリエチレン樹脂から成るパイプ
CN106574009B (zh) * 2014-06-12 2019-06-28 道达尔研究技术弗吕公司 用于在至少一个连续搅拌釜反应器中制备聚乙烯的工艺
WO2016075163A1 (en) * 2014-11-13 2016-05-19 Total Research & Technology Feluy Metallocene catalyzed polyethylene resin
CN107108993A (zh) * 2014-11-13 2017-08-29 道达尔研究技术弗吕公司 包括经茂金属催化的聚乙烯树脂的滚塑制品
US9738779B2 (en) 2015-06-05 2017-08-22 Exxonmobil Chemical Patents Inc. Heterophasic copolymers and sequential polymerization
CN107922537B (zh) 2015-06-05 2021-07-27 埃克森美孚化学专利公司 气相或淤浆相中多相聚合物的制备
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US9920176B2 (en) 2015-06-05 2018-03-20 Exxonmobil Chemical Patents Inc. Single site catalyst supportation
US10077325B2 (en) 2015-06-05 2018-09-18 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
CN107690441A (zh) 2015-06-05 2018-02-13 埃克森美孚化学专利公司 聚合物在气相或淤浆相中的单反应器制备
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US9725537B2 (en) 2015-06-05 2017-08-08 Exxonmobil Chemical Patents Inc. High activity catalyst supportation
US9725569B2 (en) 2015-06-05 2017-08-08 Exxonmobil Chemical Patents Inc. Porous propylene polymers
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
WO2016196331A1 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
WO2016197014A1 (en) * 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
TR201819970T4 (tr) * 2015-07-15 2019-01-21 Total Res & Technology Feluy Polietilen ürün hazırlamaya yönelik proses.
EP3464390A1 (en) 2016-05-27 2019-04-10 ExxonMobil Chemical Patents Inc. Metallocene catalyst compositions and polymerization process therewith
IT201600071347A1 (it) 2016-07-08 2018-01-08 Versalis Spa Composizioni espandibili contenenti polimeri vinil aromatici aventi proprietà autoestinguenti e migliorata processabilità
EP3651959B1 (en) 2017-07-11 2023-02-22 TotalEnergies OneTech Belgium Injection-molded articles comprising metallocene-catalyzed polyethylene resin
EP3710528B1 (en) * 2017-11-17 2022-04-20 TotalEnergies One Tech Belgium Polyethylene resin and caps or closures made therefrom
AR117108A1 (es) 2018-11-20 2021-07-14 Dow Global Technologies Llc Fibras multicomponentes onduladas
US11124586B1 (en) 2020-11-09 2021-09-21 Chevron Phillips Chemical Company Lp Particle size control of metallocene catalyst systems in loop slurry polymerization reactors
CA3204719A1 (en) 2020-12-08 2022-06-16 Chevron Phillips Chemical Company Lp Particle size control of supported chromium catalysts in loop slurry polymerization reactors
EP4402182A1 (en) 2021-09-13 2024-07-24 Chevron Phillips Chemical Company Lp Hydrocyclone modification of catalyst system components for use in olefin polymerizations

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CN102282182A (zh) * 2009-01-13 2011-12-14 巴塞尔聚烯烃股份有限公司 聚乙烯共聚物

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CN102282207A (zh) * 2009-01-13 2011-12-14 巴塞尔聚烯烃意大利有限责任公司 聚合物组合物
CN102282182A (zh) * 2009-01-13 2011-12-14 巴塞尔聚烯烃股份有限公司 聚乙烯共聚物
WO2011073364A1 (en) * 2009-12-18 2011-06-23 Total Petrochemicals Research Feluy Process for the preparation of a particulate bimodal polyethylene product

Also Published As

Publication number Publication date
EP2877502A1 (en) 2015-06-03
HUE047672T2 (hu) 2020-05-28
US20150239999A1 (en) 2015-08-27
WO2014016318A1 (en) 2014-01-30
EP2877502B1 (en) 2019-11-13
US9340631B2 (en) 2016-05-17
CN104507980A (zh) 2015-04-08
IN2015DN00491A (enExample) 2015-06-26

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