CN104498551A - Preparation method of macromolecule gamma-polyglutamic acid and shaving foam - Google Patents
Preparation method of macromolecule gamma-polyglutamic acid and shaving foam Download PDFInfo
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Abstract
The invention discloses a preparation method of macromolecule gamma-polyglutamic acid. The molecular weight of the prepared gamma-polyglutamic acid is 200,000-2,000,000 Dalton; and the macromolecule gamma-polyglutamic acid has the functions of holding water, moisturizing and repairing skin injuries. Meanwhile, the invention provides shaving foam to which a gamma-polyglutamic acid macromolecular compound is added, so that the after-shave skin can be effectively protected; and the effects of moistening the skin and efficiently holding water are achieved. The invention further provides a preparation method of the shaving foam. The macromolecule gamma-polyglutamic acid is prepared from bacillus licheniformis CGMCC NO.3336 in a fermentation manner.
Description
Technical field:
The present invention relates to a kind of preparation method of polymer gamma-polyglutamic acid-, and relate to this polymer gamma-polyglutamic acid-of interpolation, moisturizing, the shaving foam of moisturizing, belongs to cosmetic technical field.
Background technology:
Shaving foam a kind of increases the comfort level that shaves, and the chemical agent of effect of strengthening shaving, before shaving, just shaving foam is coated on beard, can make beard swelling, softness, be easy to shaving.And have prevent from shaving after local skin coarse, pore expands, the function that relaxes mechanical stimulus when shaving, make skinfeel comfortable.
Shaving foam is as the important Shaving Products of a class, and have deeply softening beard, make to shave more thoroughly effect, more comfortable when can make to scrape recklessly, but easy scratch skin when using razor to shave, generally also need to nurse one's health separately skin after therefore shaving.In order to simplify, in shaving foam, combine moisturizing, calmness, moisturizing ingredient has become a kind of trend.
The international application " Shave composition " of application number 200810155597.1, relates to Shave composition, and described Shave composition comprises water-insoluble lubricating polymer particles and/or one or more water-soluble polymerss.Some preferred compositions comprise lubricant, and described lubricant comprises water-insoluble lubricating polymer particles and two or more have the blend of the water-soluble polymers of different molecular weight.The invention still further relates to the method for shaving, wherein Shave composition of the present invention is coated to skin area, then region described in shaving, preferably by wetting razor shaving.And to disclose described Shave composition be shaving liquid, shaving cream, shaving foam or shaving gel form.
The international application " attapulgite gas-dissoluble shaving foam " of application number 200580027167.6 discloses a kind of attapulgite gas-dissoluble shaving foam, is made up of modified paste attapulgite clay, stearic acid, lanolin, tetradecanoic acid, white oil, propylene glycol, trolamine, SP, Trimethylmethane, mentha camphor, Tegosept E four ester, propylben and deionized water.The production method of attapulgite gas-dissoluble shaving foam is: pulping, sodium, batching, making beating, grinding, high-speed stirring, emulsification, the canned finished product for attapulgite gas-dissoluble shaving foam.Attapulgite gas-dissoluble shaving foam emulsify well, foaming abundancy, stickiness are moderate, performance is gentle; Well can be attached to the surface of skin, increase the contact area with beard, improve the result of use of shaving foam, attapulgite gas-dissoluble shaving foam is applicable to shave except beard and fine hair.
The international application " self-heating shave foam product " of application number 200580027167.6 discloses a kind of self-heating shave foam product and shaving foam product.Described shaving foam comprises nonionic emulsifying agent system, such as, comprise one or more fatty alcohol ethoxylates.
The PCT application " liquid shaving preparation " of application number 201080045935.1, discloses the preparation used for local, forms by allowing the cosmetic solution being used as Shaving Products.Comprise the deodorizing alcohol that working concentration is equal to or less than 60wt.-%.The use of deodorizing alcohol allows the essence using lower concentration or zero-dose, user need not be regulated with regard to perfume uses, but the spices of shaving preparation with the selection provided by other products can be combined.The determining alcohol lower than 60wt.-% is used to alleviate when using the hotness of skin and stimulation.In addition, in conjunction with thickening material, preparation is clamminess, promotes thus to adhere on the face and improve its use.
Foregoing invention uses traditional wetting Agent for Printing Inks, such as, mainly rely on glycerine, although moisture retention is fine, more sticky.And the biodegradability of polyglutamic acid, good biocompatibility, strong water-retentivity, to characteristics such as human non-toxic's evils, the field such as industrial and plant seed protection all can widespread use at agricultural, food, medicine, environmental protection, cosmetic industry, tobacco, leather manufacture to determine polyglutamic acid.Shaving Products is almost blank to this research, how to prepare the polyglutamic acid of applicable Shaving Products, and has moisturizing, the shaving foam of moisture-keeping efficacy after obtaining a kind of interpolation polyglutamic acid, is problem to be solved by this invention.
Summary of the invention:
For solving the problem, the invention provides a kind of preparation method of polymer gamma-polyglutamic acid-, the gamma-polyglutamic acid-molecular weight prepared, 20 ten thousand to 200 ten thousand dalton, has water conservation, moisturizing, repairs skin injury function; The shaving foam that with the addition of this gamma-polyglutamic acid-macromolecular compound is provided simultaneously, effectively can protects the skin after palpus, reach moistening skin, the effect of highly effective water-keeping, and the preparation method that this shaving foam is provided.
Described polymer gamma-polyglutamic acid-is standby by bacillus licheniformis fermentation;
Described B. licheniformis strain is specially Bacillus licheniformis (Bacillus licheniformis) CGMCC NO.3336.This bacterial strain is preserved in China Committee for Culture Collection of Microorganisms's common micro-organisms center on October 14th, 2009, address is: No. 3, Yard 1, BeiChen xi Road, Chaoyang District, Beijing City. Institute of Microorganism, Academia Sinica, preserving number is CGMCC NO.3336, taxonomy called after bacillus licheniformis (Bacillus licheniformis).
(1) actication of culture: be seeded on slant medium by Bacillus licheniformis CGMCC NO.3336 original strain, cultivates 16 hours in 37 DEG C, so activation 2-3 time, the inclined-plane seed that preparation is ripe;
(2) preparation of seed liquor: the inclined-plane seed after a ring activation is inoculated in and is equipped with in the 500ml triangular flask of 50ml seed culture medium, 37 DEG C, 220rpm cultivates 16 little of logarithmic phase;
Described seed culture medium consists of: glucose 30g/L, yeast extract paste 7g/L, Tryptones 10g/L, K
2hPO
40.5g/L, MgSO
47H
2o 0.5g/L, pH7.2, insufficient section pure water is supplied;
(3) ferment tank: the seed liquor in step (2) is inoculated in fermentor tank with the inoculum size of 5-10%, 30L ferment tank substratum loading amount is 15L, Preliminary fermentation temperature 38-40 DEG C, tank pressure 0.01-0.05Mpa, ventilation 0.5-1.0vvm, rotating speed 400-600rpm; As fermented liquid OD
660when 0.550-0.600, control leavening temperature 30-35 DEG C, adjusting rotary speed is to 200-350rpm, and ventilation 1.5-2.0vvm, fermentation total time is 72h, and pH is at 7.2-7.5 in period control, until 2-6 hour before fermentation ends.
Described fermention medium component is: glucose 80g/L, sodium-chlor 10g/L, MgSO
47H
2o 1g/L, Calcium Chloride Powder Anhydrous 1g/L, FeSO
47H
2o 0.02g/L, KCl 0.5g/L, arginine 0.8g/L, Histidine 0.5g/L, Threonine 0.5g/L, methionine(Met) 0.4g/L, glutamine 0.5g/L, choline 0.31g/L, pyridoxol 0.001g/L, insufficient section pure water is supplied.
(4) extraction of gamma-polyglutamic acid-: centrifugally after fermentation ends remove thalline, then the ethanol of supernatant liquor 5 times of volumes is used, alcohol precipitation separates out gamma-polyglutamic acid-, then redissolves in the distilled water of supernatant liquor same volume, utilizes spray drying process to prepare dry powder gamma-polyglutamic acid-.Content gamma-polyglutamic acid-being diluted to gamma-polyglutamic acid-, at 1-3g/L, is detected its molecular weight by high performance liquid chromatography, and molecular weight is 20 ten thousand to 200 ten thousand dalton.
The preparation method of the shaving foam of described interpolation gamma-polyglutamic acid-comprises the steps:
(1) distilled water, glycerine, vitamin-E, potassium hydroxide, sodium hydroxide are mixed and are heated to 70 DEG C, by stearic acid, paraffin oil, gamma-polyglutamic acid-Hybrid Heating to 70 DEG C, saponification reaction is carried out in the mixture mixing after heating two kinds.
(2) add lanolin anhydrous bp93 and carry out emulsifying effect, lower the temperature afterwards.
(3) can also be comprised the mixture after emulsifying effect is cooled to 45 DEG C, then add essence and pigment carries out blending and toning;
Described shaving foam is prepared by the raw material of following parts by weight: distilled water 65-70 part, glycerine 4-5 part, vitamin-E 1-3 part, potassium hydroxide 3-5 part, sodium hydroxide 1-3 part, stearic acid 5-7 part, paraffin oil 4-6 part, gamma-polyglutamic acid-3-5 part, lanolin anhydrous bp93 5 parts;
Preferably, described shaving foam also comprises 0.5 part, essence, pigment 0.5 part.
Beneficial effect
The present invention adds gamma-polyglutamic acid-bioabsorbable polymer material in the preparation process of shaving foam, utilize the effect of gamma-polyglutamic acid-highly effective water-keeping, and repair the effect of skin, after shaving foam after interpolation gamma-polyglutamic acid-is used, skin can keep moistening for a long time, improves the skin-friendliness after shaving.
Utilize Bacillus licheniformis CGMCC NO.3336 wide adaptability, the characteristic of high yield gamma-polyglutamic acid-, by Optimal Medium and culture condition, make gamma-polyglutamic acid-output increased to 31.4 ± 1.2g/L, and gamma-polyglutamic acid-molecular weight is 20 ten thousand to 200 ten thousand dalton.
Embodiment
Bacillus licheniformis CGMCC NO.3336 characteristic is as follows:
(1) thalli morphology: thalline is rod-short, forms obvious pod membrane around thalline, thalline divisional mode binary fission is bred, and forms barrier film gradually, and then split into two forms from centre, size and the identical daughter cell of structure.Gemma growth is in the centre of bacterium or side.
(2) colonial morphology: on flat board, when substratum is moist, bacterium colony is rounded substantially, and area is comparatively large, lawn neat in edge, and bacterium colony is opaque and viscosity large, has touched wire drawing shape with transfering loop; When substratum is dry, the coarse gauffer of bacterium colony, comparatively cave in centre, edge is irregular.
(3) cultural characteristic: 37 DEG C, shaking culture 60-72h under 180-220r/m, fermented liquid color is more shallow, stabilizes to stalk yellow.
(4) utilizable carbon source: glucose, fructose, maltose, sucrose, citric acid, glycerine, L-glutamic acid, above-mentioned carbon source is generally used in combination, and be of little use single carbon source.
(5) can grow for sole carbon source with L-glutamic acid, citric acid, glycerine respectively, and well-grown.
Embodiment 1
The preparation method of described polymer gamma-polyglutamic acid-is as follows:
(1) actication of culture: be seeded on slant medium by Bacillus licheniformis CGMCC NO.3336 original strain, cultivates 16 hours in 37 DEG C, so activation 2-3 time, the inclined-plane seed that preparation is ripe;
(2) preparation of seed liquor: the inclined-plane seed after a ring activation is inoculated in and is equipped with in the 500ml triangular flask of 50ml seed culture medium, 37 DEG C, 220rpm cultivates 16 little of logarithmic phase;
Described seed culture medium consists of: glucose 30g/L, yeast extract paste 7g/L, Tryptones 10g/L, K
2hPO
40.5g/L, MgSO
47H
2o 0.5g/L, pH7.2, insufficient section pure water is supplied;
(3) ferment tank: by the seed liquor in step (2) with 10% inoculum size be inoculated in fermentor tank, 30L ferment tank substratum liquid amount is 15L, Preliminary fermentation temperature 38 DEG C, tank pressure 0.03Mpa, ventilation 0.8vvm, rotating speed 500rpm; As fermented liquid OD
660when 0.550-0.600, control leavening temperature 32 DEG C, adjusting rotary speed is to 250rpm, and ventilation 2.0vvm, fermentation total time is 72h, and pH is 7.3 in period control, until first 2 hours of fermentation ends.
Described fermention medium consists of: glucose 80g/L, sodium-chlor 10g/L, MgSO
47H
2o 1g/L, Calcium Chloride Powder Anhydrous 1g/L, FeSO
47H
2o 0.02g/L, KCl 0.5g/L, arginine 0.8g/L, Histidine 0.5g/L, Threonine 0.5g/L, methionine(Met) 0.4g/L, glutamine 0.5g/L, choline 0.31g/L, pyridoxol 0.001g/L, insufficient section pure water is supplied.
(4) extraction of gamma-polyglutamic acid-: centrifugally after fermentation ends remove thalline, then the ethanol of supernatant liquor 5 times of volumes is used, alcohol precipitation separates out gamma-polyglutamic acid-, then redissolves in the distilled water of supernatant liquor same volume, utilizes spray drying process to prepare dry powder gamma-polyglutamic acid-.Gamma-polyglutamic acid-is diluted to content at 1-3g/L, is detected by high performance liquid chromatography to its molecular weight, molecular weight is 20 ten thousand to 200 ten thousand dalton.
The preparation method of described shaving foam comprises the steps:
(1) distilled water, glycerine, vitamin-E, potassium hydroxide, sodium hydroxide are mixed and are heated to 70 DEG C, by stearic acid, paraffin oil, gamma-polyglutamic acid-Hybrid Heating to 70 DEG C, saponification reaction is carried out in the mixture mixing after heating two kinds.
(2) add lanolin anhydrous bp93 and carry out emulsifying effect, lower the temperature afterwards.
(3) mixture after emulsifying effect is cooled to 45 DEG C, then adds essence and pigment carries out blending and toning;
Described shaving foam is prepared by the raw material of following parts by weight: distilled water 70 parts, glycerine 4 parts, vitamin E2 part, 3 parts, potassium hydroxide, 1 part, sodium hydroxide, stearic acid 7 parts, paraffin oil 4 parts, gamma-polyglutamic acid-3 parts, lanolin anhydrous bp93 5 parts, 0.5 part, essence, pigment 0.5 part.
Embodiment 2
The preparation method of described polymer gamma-polyglutamic acid-is as follows:
(1) ferment tank: by seed liquor with 5% inoculum size be inoculated in fermentor tank, 30L ferment tank substratum liquid amount is 15L, Preliminary fermentation temperature 40 DEG C, tank pressure 0.01Mpa, ventilation 0.5vvm, rotating speed 400rpm; As fermented liquid OD
660when 0.550-0.600, control leavening temperature 30 DEG C, adjusting rotary speed to 200rpm, ventilation 1.5vvm, fermentation total time is 72h, and pH is 7.2 in period control, until first 6 hours of fermentation ends;
Described fermention medium component is: glucose 80g/L, sodium-chlor 10g/L, MgSO
47H
2o 1g/L, Calcium Chloride Powder Anhydrous 1g/L, FeSO
47H
2o 0.02g/L, KCl 0.5g/L, arginine 0.8g/L, Histidine 0.5g/L, Threonine 0.5g/L, methionine(Met) 0.4g/L, glutamine 0.5g/L, choline 0.31g/L, pyridoxol 0.001g/L, insufficient section pure water is supplied.(2) extraction of gamma-polyglutamic acid-: centrifugally after fermentation ends remove thalline, then the ethanol of supernatant liquor 5 times of volumes is used, alcohol precipitation separates out gamma-polyglutamic acid-, then redissolves in the distilled water of supernatant liquor same volume, utilizes spray drying process to prepare dry powder gamma-polyglutamic acid-.Gamma-polyglutamic acid-is diluted to content at 1-3g/L, is detected by high performance liquid chromatography to its molecular weight, molecular weight is 20 ten thousand to 200 ten thousand dalton;
Actication of culture and seed liquor preparation are with embodiment 1.
The preparation method of described shaving foam comprises the steps:
(1) distilled water, glycerine, vitamin-E, potassium hydroxide, sodium hydroxide are mixed and are heated to 70 DEG C, by stearic acid, paraffin oil, gamma-polyglutamic acid-Hybrid Heating to 70 DEG C, saponification reaction is carried out in the mixture mixing after heating two kinds.
(2) add lanolin anhydrous bp93 and carry out emulsifying effect, lower the temperature afterwards.
(3) mixture after emulsifying effect is cooled to 45 DEG C, then adds plants essential oil 0.3;
Described shaving foam is prepared by the raw material of following parts by weight: distilled water 68 parts, glycerine 3 parts, vitamin-E 2 parts, 4 parts, potassium hydroxide, 2 parts, sodium hydroxide, stearic acid 6 parts, paraffin oil 5 parts, gamma-polyglutamic acid-4 parts, lanolin anhydrous bp93 5 parts, plants essential oil 0.3 part;
Embodiment 3
The preparation method of described polymer gamma-polyglutamic acid-is as follows:
(1) ferment tank: by seed liquor with 7% inoculum size be inoculated in fermentor tank, 30L ferment tank substratum liquid amount is 15L, Preliminary fermentation temperature 40 DEG C, tank pressure 0.05Mpa, ventilation 1.0vvm, rotating speed 600rpm; As fermented liquid OD
660when 0.550-0.600, control leavening temperature 35 DEG C, adjusting rotary speed is to 350rpm, and ventilation 2.0vvm, fermentation total time is 72h, and pH is 7.5 in period control, until first 4 hours of fermentation ends.
Described fermention medium component is: glucose 80g/L, sodium-chlor 10g/L, MgSO
47H
2o 1g/L, Calcium Chloride Powder Anhydrous 1g/L, FeSO
47H
2o 0.02g/L, KCl 0.5g/L, arginine 0.8g/L, Histidine 0.5g/L, Threonine 0.5g/L, methionine(Met) 0.4g/L, glutamine 0.5g/L, choline 0.31g/L, pyridoxol 0.001g/L, insufficient section pure water is supplied.
(2) extraction of gamma-polyglutamic acid-: centrifugally after fermentation ends remove thalline, then the ethanol of supernatant liquor 5 times of volumes is used, alcohol precipitation separates out gamma-polyglutamic acid-, then redissolves in the distilled water of supernatant liquor same volume, utilizes spray drying process to prepare dry powder gamma-polyglutamic acid-.Gamma-polyglutamic acid-is diluted to content at 1-3g/L, is detected by high performance liquid chromatography to its molecular weight, molecular weight is 20 ten thousand to 200 ten thousand dalton.
The preparation method of described shaving foam comprises the steps:
(1) distilled water, glycerine, vitamin-E, potassium hydroxide, sodium hydroxide are mixed and are heated to 70 DEG C, by stearic acid, paraffin oil, gamma-polyglutamic acid-Hybrid Heating to 70 DEG C, saponification reaction is carried out in the mixture mixing after heating two kinds.
(2) add lanolin anhydrous bp93 and carry out emulsifying effect, lower the temperature afterwards.
Described shaving foam is prepared by the raw material of following parts by weight: distilled water 65-70 part, glycerine 4-5 part, vitamin-E 1-3 part, potassium hydroxide 3-5 part, sodium hydroxide 1-3 part, stearic acid 5-7 part, paraffin oil 4-6 part, gamma-polyglutamic acid-3-5 part, lanolin anhydrous bp93 5 parts.
Claims (10)
1. a preparation method for polymer gamma-polyglutamic acid-, comprises the extraction of bacillus licheniformis ferment tank and gamma-polyglutamic acid-;
It is characterized in that, described B. licheniformis strain is specially Bacillus licheniformis (Bacillus licheniformis) CGMCC NO.3336; This bacterial strain is preserved in China Committee for Culture Collection of Microorganisms's common micro-organisms center on October 14th, 2009, and preserving number is CGMCC NO.3336;
Described ferment tank: seed liquor is inoculated in fermentor tank with the inoculum size of 5-10%, 30L ferment tank substratum loading amount is 15L, Preliminary fermentation temperature 38-40 DEG C, tank pressure 0.01-0.05Mpa, ventilation 0.5-1.0vvm, rotating speed 400-600rpm; As fermented liquid OD
660when 0.550-0.600, control leavening temperature 30-35 DEG C, adjusting rotary speed to 200-350rpm, ventilation 1.5-2.0vvm, fermentation total time is 72h, and pH is at 7.2-7.5 in period control, until 2-6 hour before fermentation ends;
Described fermention medium component is: glucose 80g/L, sodium-chlor 10g/L, MgSO
47H
2o 1g/L, Calcium Chloride Powder Anhydrous 1g/L, FeSO
47H
2o 0.02g/L, KCl 0.5g/L, arginine 0.8g/L, Histidine 0.5g/L, Threonine 0.5g/L, methionine(Met) 0.4g/L, glutamine 0.5g/L, choline 0.31g/L, pyridoxol 0.001g/L, insufficient section pure water is supplied;
The extraction of described gamma-polyglutamic acid-: centrifugally after fermentation ends remove thalline, then uses the ethanol of supernatant liquor 5 times of volumes, and alcohol precipitation separates out gamma-polyglutamic acid-, then redissolves in the distilled water of supernatant liquor same volume, utilizes spray drying process to prepare dry powder gamma-polyglutamic acid-.
2. the preparation method of polymer gamma-polyglutamic acid-according to claim 1, it is characterized in that, before described bacillus licheniformis is inoculated in fermentor tank, the preparation of actication of culture and seed liquor is specific as follows:
Actication of culture: be seeded on slant medium by Bacillus licheniformis CGMCC NO.3336 original strain, cultivates 16 hours in 37 DEG C, so activation 2-3 time, the inclined-plane seed that preparation is ripe;
The preparation of seed liquor: the inclined-plane seed after a ring activation is inoculated in and is equipped with in the 500ml triangular flask of 50ml seed culture medium, 37 DEG C, 220rpm cultivates 16 little of logarithmic phase;
Described seed culture medium consists of: glucose 30g/L, yeast extract paste 7g/L, Tryptones 10g/L, K
2hPO
40.5g/L, MgSO
47H
2o 0.5g/L, pH7.2, insufficient section pure water is supplied.
3. the preparation method of polymer gamma-polyglutamic acid-according to claim 1 or 2, described ferment tank step is as follows:
By seed liquor with 10% inoculum size be inoculated in fermentor tank, 30L ferment tank substratum liquid amount is 15L, Preliminary fermentation temperature 38 DEG C, tank pressure 0.03Mpa, ventilation 0.8vvm, rotating speed 500rpm; As fermented liquid OD
660when 0.550-0.600, control leavening temperature 32 DEG C, adjusting rotary speed is to 250rpm, and ventilation 2.0vvm, fermentation total time is 72h, and pH is 7.3 in period control, until first 2 hours of fermentation ends.
4. the preparation method of polymer gamma-polyglutamic acid-according to claim 1 or 2, described ferment tank step is as follows:
By seed liquor with 5% inoculum size be inoculated in fermentor tank, 30L ferment tank substratum liquid amount is 15L, Preliminary fermentation temperature 40 DEG C, tank pressure 0.01Mpa, ventilation 0.5vvm, rotating speed 400rpm; As fermented liquid OD
660when 0.550-0.600, control leavening temperature 30 DEG C, adjusting rotary speed is to 200rpm, and ventilation 1.5vvm, fermentation total time is 72h, and pH is 7.2 in period control, until first 6 hours of fermentation ends.
5. the preparation method of polymer gamma-polyglutamic acid-according to claim 1 or 2, described ferment tank step is as follows:
By seed liquor with 7% inoculum size be inoculated in fermentor tank, 30L ferment tank substratum liquid amount is 15L, Preliminary fermentation temperature 40 DEG C, tank pressure 0.05Mpa, ventilation 1.0vvm, rotating speed 600rpm; As fermented liquid OD
660when 0.550-0.600, control leavening temperature 35 DEG C, adjusting rotary speed is to 350rpm, and ventilation 2.0vvm, fermentation total time is 72h, and pH is 7.5 in period control, until first 4 hours of fermentation ends.
6. add the preparation method of the shaving foam of the arbitrary described gamma-polyglutamic acid-of claim 1-5, comprise the steps:
(1) distilled water 65-70 part, glycerine 4-5 part, vitamin-E 1-3 part, potassium hydroxide 3-5 part, sodium hydroxide 1-3 part are mixed and is heated to 70 DEG C, by stearic acid 5-7 part, paraffin oil 4-6 part, gamma-polyglutamic acid-3-5 part Hybrid Heating to 70 DEG C, saponification reaction is carried out in the mixture mixing after heating two kinds;
(2) add lanolin anhydrous bp93 5 parts and carry out emulsifying effect, lower the temperature afterwards.
7. the preparation method of shaving foam according to claim 6, the mixture after comprising the steps: step (2) emulsifying effect is cooled to 45 DEG C, then add 0.5 part of essence, 0.5 part of pigment carries out blending and toning.
8. the preparation method of shaving foam according to claim 7, comprises the steps:
(1) distilled water 70 parts, glycerine 4 parts, vitamin E2 part, 3 parts, potassium hydroxide, 1 part, sodium hydroxide are mixed and is heated to 70 DEG C, by stearic acid 7 parts, paraffin oil 4 parts, gamma-polyglutamic acid-3 parts of Hybrid Heating to 70 DEG C, saponification reaction is carried out in the mixture mixing after heating two kinds;
(2) add lanolin anhydrous bp93 5 parts and carry out emulsifying effect, lower the temperature afterwards;
(3) mixture after step (2) emulsifying effect is cooled to 45 DEG C, then add 0.5 part of essence, 0.5 part of pigment carries out blending and toning.
9. the preparation method of shaving foam according to claim 6, comprises the steps:
(1) distilled water 68 parts, glycerine 3 parts, vitamin-E 2 parts, 4 parts, potassium hydroxide, 2 parts, sodium hydroxide are mixed and is heated to 70 DEG C, by stearic acid 6 parts, paraffin oil 5 parts, gamma-polyglutamic acid-4 parts of Hybrid Heating to 70 DEG C, saponification reaction is carried out in the mixture mixing after heating two kinds;
(2) add lanolin anhydrous bp93 5 parts and carry out emulsifying effect, lower the temperature afterwards;
(3) mixture after step (2) emulsifying effect is cooled to 45 DEG C, then adds plants essential oil 0.3 part and carry out blending.
10. the shaving foam that method prepares according to claim 6-9.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105380816A (en) * | 2015-12-14 | 2016-03-09 | 北京肽康生物科技有限公司 | Use of bioactive peptide in preparation of cosmetics |
| CN105603012A (en) * | 2015-12-11 | 2016-05-25 | 天津北洋百川生物技术有限公司 | Preparation method for gamma-polyglutamic acid, and moisturizing face cream and preparation method thereof |
| CN105603013A (en) * | 2015-12-11 | 2016-05-25 | 天津北洋百川生物技术有限公司 | Preparation method for gamma-polyglutamic acid, and hand cream and preparation method thereof |
| CN106389249A (en) * | 2016-09-18 | 2017-02-15 | 天津北洋百川生物技术有限公司 | Gamma-polyglutamic acid containing hydrating toner and preparation method thereof |
| CN112870151A (en) * | 2021-02-08 | 2021-06-01 | 武汉骏安生物科技有限公司 | Skin barrier repair composition containing sodium polyglutamate and application thereof |
| US11872711B2 (en) | 2019-05-10 | 2024-01-16 | The Gillette Company Llc | Lubricating member for razor cartridges |
| WO2024059429A1 (en) * | 2022-09-14 | 2024-03-21 | The Gillette Company Llc | Lubricating member comprising polyglutamic acid |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102154395A (en) * | 2010-12-30 | 2011-08-17 | 天津北洋百川生物技术有限公司 | Method for extracting gamma-polyglutamic acid by inorganic salt/organic solvent coprecipitation effect |
| US20120164096A1 (en) * | 2009-08-12 | 2012-06-28 | Jose Andres Prieto Alonso | Liquid shaving preparation |
| CN103690396A (en) * | 2013-12-25 | 2014-04-02 | 天津北洋百川生物技术有限公司 | Mask containing high-molecular polyglutamic acid and preparation method of mask |
-
2014
- 2014-12-23 CN CN201410816849.6A patent/CN104498551A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120164096A1 (en) * | 2009-08-12 | 2012-06-28 | Jose Andres Prieto Alonso | Liquid shaving preparation |
| CN102154395A (en) * | 2010-12-30 | 2011-08-17 | 天津北洋百川生物技术有限公司 | Method for extracting gamma-polyglutamic acid by inorganic salt/organic solvent coprecipitation effect |
| CN103690396A (en) * | 2013-12-25 | 2014-04-02 | 天津北洋百川生物技术有限公司 | Mask containing high-molecular polyglutamic acid and preparation method of mask |
Non-Patent Citations (1)
| Title |
|---|
| 唐冻雁等: "《化妆品配方设计与制备工艺》", 30 June 2003, 化学工业出版社 * |
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| CN105603012A (en) * | 2015-12-11 | 2016-05-25 | 天津北洋百川生物技术有限公司 | Preparation method for gamma-polyglutamic acid, and moisturizing face cream and preparation method thereof |
| CN105603013A (en) * | 2015-12-11 | 2016-05-25 | 天津北洋百川生物技术有限公司 | Preparation method for gamma-polyglutamic acid, and hand cream and preparation method thereof |
| CN105380816A (en) * | 2015-12-14 | 2016-03-09 | 北京肽康生物科技有限公司 | Use of bioactive peptide in preparation of cosmetics |
| CN105380816B (en) * | 2015-12-14 | 2019-04-30 | 北京肽康生物科技有限公司 | Purposes of the biologically active peptide in cosmetics preparation |
| CN106389249A (en) * | 2016-09-18 | 2017-02-15 | 天津北洋百川生物技术有限公司 | Gamma-polyglutamic acid containing hydrating toner and preparation method thereof |
| US11872711B2 (en) | 2019-05-10 | 2024-01-16 | The Gillette Company Llc | Lubricating member for razor cartridges |
| CN112870151A (en) * | 2021-02-08 | 2021-06-01 | 武汉骏安生物科技有限公司 | Skin barrier repair composition containing sodium polyglutamate and application thereof |
| WO2024059429A1 (en) * | 2022-09-14 | 2024-03-21 | The Gillette Company Llc | Lubricating member comprising polyglutamic acid |
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