CN1044913C - 乙烯均聚物或共聚物在线接枝烯类不饱和羧酸和羧酸酐的方法 - Google Patents
乙烯均聚物或共聚物在线接枝烯类不饱和羧酸和羧酸酐的方法 Download PDFInfo
- Publication number
- CN1044913C CN1044913C CN92109328A CN92109328A CN1044913C CN 1044913 C CN1044913 C CN 1044913C CN 92109328 A CN92109328 A CN 92109328A CN 92109328 A CN92109328 A CN 92109328A CN 1044913 C CN1044913 C CN 1044913C
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- Prior art keywords
- monomer
- copolymer
- zone
- ethylene
- polymer
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- Expired - Lifetime
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- 229920001577 copolymer Polymers 0.000 title claims abstract description 70
- 239000005977 Ethylene Substances 0.000 title claims abstract description 48
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 238000000034 method Methods 0.000 title claims description 40
- 229920001519 homopolymer Polymers 0.000 title claims description 9
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 title description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 title description 4
- 239000000178 monomer Substances 0.000 claims abstract description 93
- 239000003999 initiator Substances 0.000 claims abstract description 36
- 238000000926 separation method Methods 0.000 claims abstract description 22
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 16
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 5
- 229920000642 polymer Polymers 0.000 claims description 28
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical class O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 26
- 238000002347 injection Methods 0.000 claims description 20
- 239000007924 injection Substances 0.000 claims description 20
- 239000002609 medium Substances 0.000 claims description 13
- 239000002904 solvent Substances 0.000 claims description 13
- 239000004711 α-olefin Substances 0.000 claims description 13
- 239000000243 solution Substances 0.000 claims description 11
- 238000007334 copolymerization reaction Methods 0.000 claims description 10
- 229920000578 graft copolymer Polymers 0.000 claims description 9
- 150000003254 radicals Chemical class 0.000 claims description 9
- 238000011144 upstream manufacturing Methods 0.000 claims description 9
- 239000002612 dispersion medium Substances 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 8
- -1 alkyl methacrylates Chemical class 0.000 claims description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 6
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 5
- 150000001735 carboxylic acids Chemical class 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 229920001038 ethylene copolymer Polymers 0.000 claims description 5
- 238000001125 extrusion Methods 0.000 claims description 5
- 150000002978 peroxides Chemical class 0.000 claims description 5
- 229920000098 polyolefin Polymers 0.000 claims description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
- 150000008064 anhydrides Chemical class 0.000 claims description 4
- 150000002976 peresters Chemical class 0.000 claims description 4
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 4
- 239000000725 suspension Substances 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 3
- 150000003949 imides Chemical class 0.000 claims description 3
- 239000003505 polymerization initiator Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 2
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 claims description 2
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 2
- 239000004714 Polar ethylene copolymer Substances 0.000 claims description 2
- 238000010924 continuous production Methods 0.000 claims description 2
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 2
- 238000000354 decomposition reaction Methods 0.000 claims description 2
- 150000008049 diazo compounds Chemical class 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 238000005453 pelletization Methods 0.000 claims description 2
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 2
- 150000001298 alcohols Chemical class 0.000 claims 1
- 125000005250 alkyl acrylate group Chemical group 0.000 claims 1
- 239000006185 dispersion Substances 0.000 claims 1
- 239000003828 free initiator Substances 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- 239000000376 reactant Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 17
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 8
- 239000007789 gas Substances 0.000 description 7
- 238000009826 distribution Methods 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 3
- 229920001567 vinyl ester resin Polymers 0.000 description 3
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- AOGQPLXWSUTHQB-UHFFFAOYSA-N hexyl acetate Chemical compound CCCCCCOC(C)=O AOGQPLXWSUTHQB-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- WQJUBZMZVKITBU-UHFFFAOYSA-N (3,4-dimethyl-4-phenylhexan-3-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(CC)C(C)(CC)C1=CC=CC=C1 WQJUBZMZVKITBU-UHFFFAOYSA-N 0.000 description 1
- RYDFXSRVZBYYJV-ODZAUARKSA-N (z)-but-2-enedioic acid;sodium Chemical compound [Na].OC(=O)\C=C/C(O)=O RYDFXSRVZBYYJV-ODZAUARKSA-N 0.000 description 1
- MFGALGYVFGDXIX-UHFFFAOYSA-N 2,3-Dimethylmaleic anhydride Chemical compound CC1=C(C)C(=O)OC1=O MFGALGYVFGDXIX-UHFFFAOYSA-N 0.000 description 1
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
- LDLNNPJJJGKWFW-UHFFFAOYSA-N 2-(1-acetyloxybutan-2-yldiazenyl)butyl acetate Chemical compound CC(=O)OCC(CC)N=NC(CC)COC(C)=O LDLNNPJJJGKWFW-UHFFFAOYSA-N 0.000 description 1
- HFWCNOROFPLMHK-UHFFFAOYSA-N 2-(1-acetyloxypropan-2-yldiazenyl)propyl acetate Chemical compound CC(=O)OCC(C)N=NC(C)COC(C)=O HFWCNOROFPLMHK-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- NGDDOAPNMGYAIF-UHFFFAOYSA-N [2-[(1-acetyloxy-2-methylpropan-2-yl)diazenyl]-2-methylpropyl] acetate Chemical compound CC(=O)OCC(C)(C)N=NC(C)(C)COC(C)=O NGDDOAPNMGYAIF-UHFFFAOYSA-N 0.000 description 1
- RFGUTQZLDJBGMG-UHFFFAOYSA-N [2-[(2-acetyloxy-4-methylpentan-2-yl)diazenyl]-4-methylpentan-2-yl] acetate Chemical compound CC(C)CC(C)(OC(C)=O)N=NC(C)(CC(C)C)OC(C)=O RFGUTQZLDJBGMG-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- IEPRKVQEAMIZSS-AATRIKPKSA-N diethyl fumarate Chemical class CCOC(=O)\C=C\C(=O)OCC IEPRKVQEAMIZSS-AATRIKPKSA-N 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 229920006228 ethylene acrylate copolymer Polymers 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- QYZFTMMPKCOTAN-UHFFFAOYSA-N n-[2-(2-hydroxyethylamino)ethyl]-2-[[1-[2-(2-hydroxyethylamino)ethylamino]-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCNCCO QYZFTMMPKCOTAN-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- BWSZXUOMATYHHI-UHFFFAOYSA-N tert-butyl octaneperoxoate Chemical compound CCCCCCCC(=O)OOC(C)(C)C BWSZXUOMATYHHI-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/46—Reaction with unsaturated dicarboxylic acids or anhydrides thereof, e.g. maleinisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Polyesters Or Polycarbonates (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9110327A FR2680370B1 (fr) | 1991-08-14 | 1991-08-14 | Procede pour le greffage dans la ligne d'acides et anhydrides d'acides carboxyliques insatures sur des polymeres de l'ethylene et installation pour la mise en óoeuvre de ce procede. |
| FR9110327 | 1991-08-14 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1071173A CN1071173A (zh) | 1993-04-21 |
| CN1044913C true CN1044913C (zh) | 1999-09-01 |
Family
ID=9416199
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN92109328A Expired - Lifetime CN1044913C (zh) | 1991-08-14 | 1992-08-13 | 乙烯均聚物或共聚物在线接枝烯类不饱和羧酸和羧酸酐的方法 |
Country Status (16)
| Country | Link |
|---|---|
| US (2) | US5583181A (enExample) |
| EP (1) | EP0527688B1 (enExample) |
| JP (1) | JP3207540B2 (enExample) |
| KR (1) | KR100234208B1 (enExample) |
| CN (1) | CN1044913C (enExample) |
| AT (1) | ATE144782T1 (enExample) |
| BR (1) | BR9203045A (enExample) |
| CA (1) | CA2076129C (enExample) |
| DE (1) | DE69214898T2 (enExample) |
| DK (1) | DK0527688T3 (enExample) |
| ES (1) | ES2096055T3 (enExample) |
| FI (1) | FI110264B (enExample) |
| FR (1) | FR2680370B1 (enExample) |
| GR (1) | GR3022442T3 (enExample) |
| NO (1) | NO179916C (enExample) |
| TW (1) | TW225541B (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6214941B1 (en) | 1997-11-24 | 2001-04-10 | Shell Oil Company | Water soluble polyketones |
| US7230048B1 (en) * | 2000-08-25 | 2007-06-12 | Basf Corporation | Process for continuous production of reactive polymers with in-line post-modification and products thereof |
| US20050232894A1 (en) * | 2004-04-20 | 2005-10-20 | Weiner Gregory M | Antimicrobial skin treatment composition and methods for producing and using an antimicrobial skin treatment composition |
| WO2006010233A1 (en) * | 2004-07-29 | 2006-02-02 | Universidade Estadual De Campinas - Unicamp | Photodegradable films derived from polyethylene |
| GB0609973D0 (en) * | 2006-05-19 | 2006-06-28 | Exxonmobil Chem Patents Inc | An apparatus for the production of polyethylene and ethylene copolymers |
| KR20090034636A (ko) * | 2007-10-04 | 2009-04-08 | 삼성전자주식회사 | 바이오 폴리머 합성 장치 및 방법, 바이오 폴리머 합성용시료의 회수 방법 |
| US8207277B2 (en) * | 2008-09-23 | 2012-06-26 | Equistar Chemicals, Lp | Modifying tubular LDPE with free radical initiator |
| CN101947610A (zh) * | 2010-08-03 | 2011-01-19 | 浙江广山汽车零部件有限公司 | 一种液压油散热器主板生产工艺 |
| CN105793294B (zh) * | 2013-12-04 | 2017-06-13 | 巴塞尔聚烯烃股份有限公司 | 用于分离通过烯属不饱和单体的高压聚合获得的反应混合物的组分的方法 |
| CN107922517B (zh) * | 2015-09-25 | 2022-02-08 | 陶氏环球技术有限责任公司 | 用于使低粘度聚烯烃官能化的非挤出工艺 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0016797A1 (en) * | 1978-07-17 | 1980-10-15 | Kerk Motion Prod | ANTI-GAME NUT. |
| US4762882A (en) * | 1985-07-08 | 1988-08-09 | Mitsubishi Chemical Industries Limited | Modified polyolefin resin and a composition containing the same |
| US4788264A (en) * | 1986-11-05 | 1988-11-29 | Idemitsu Petrochemical Co., Ltd. | Method of preparing modified polyethylenes |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5239636B2 (enExample) * | 1973-05-01 | 1977-10-06 | ||
| DD117077A1 (enExample) * | 1974-12-18 | 1975-12-20 | ||
| FR2460306A1 (fr) * | 1979-07-05 | 1981-01-23 | Charbonnages Ste Chimique | Procede de production de polymeres de l'ethylene et appareil pour sa mise en oeuvre |
| FR2519007B1 (fr) * | 1981-12-24 | 1985-12-27 | Charbonnages Ste Chimique | Copolymeres modifies de l'ethylene et d'au moins une a-olefine et procede pour leur preparation |
| FR2538397A1 (fr) * | 1982-12-24 | 1984-06-29 | Charbonnages Ste Chimique | Procede continu de fabrication d'homopolymeres ou de copolymeres de l'ethylene |
| JPS60247557A (ja) * | 1984-05-09 | 1985-12-07 | 株式会社クラレ | 積層体およびその製造方法 |
| CA1236613A (en) * | 1985-06-27 | 1988-05-10 | Chun S. Wong | Process for the grafting of monomers onto polyolefins |
| FR2592051B1 (fr) * | 1985-12-24 | 1988-10-14 | Charbonnages Ste Chimique | Compositions de polymeres de l'ethylene, un procede pour leur preparation et leur application a l'obtention d'articles industriels |
| GB8626353D0 (en) * | 1986-11-04 | 1986-12-03 | Du Pont Canada | Grafting of monomers onto polymers |
| DE3641513A1 (de) * | 1986-12-04 | 1988-06-09 | Basf Ag | Verfahren zur reduktion der emission von kohlenwasserstoffen bei entspannungsvorgaengen an hochdruckpolymerisationsreaktoren |
-
1991
- 1991-08-14 FR FR9110327A patent/FR2680370B1/fr not_active Expired - Fee Related
-
1992
- 1992-07-23 TW TW081105816A patent/TW225541B/zh not_active IP Right Cessation
- 1992-08-06 BR BR929203045A patent/BR9203045A/pt not_active IP Right Cessation
- 1992-08-12 KR KR1019920014474A patent/KR100234208B1/ko not_active Expired - Lifetime
- 1992-08-13 JP JP21608292A patent/JP3207540B2/ja not_active Expired - Lifetime
- 1992-08-13 CN CN92109328A patent/CN1044913C/zh not_active Expired - Lifetime
- 1992-08-13 ES ES92402280T patent/ES2096055T3/es not_active Expired - Lifetime
- 1992-08-13 DE DE69214898T patent/DE69214898T2/de not_active Expired - Lifetime
- 1992-08-13 EP EP92402280A patent/EP0527688B1/fr not_active Expired - Lifetime
- 1992-08-13 CA CA002076129A patent/CA2076129C/fr not_active Expired - Lifetime
- 1992-08-13 AT AT92402280T patent/ATE144782T1/de active
- 1992-08-13 DK DK92402280.9T patent/DK0527688T3/da active
- 1992-08-13 NO NO923170A patent/NO179916C/no not_active IP Right Cessation
- 1992-08-13 FI FI923630A patent/FI110264B/fi not_active IP Right Cessation
-
1995
- 1995-01-12 US US08/371,575 patent/US5583181A/en not_active Expired - Lifetime
- 1995-06-07 US US08/478,849 patent/US5591410A/en not_active Expired - Lifetime
-
1997
- 1997-01-30 GR GR970400157T patent/GR3022442T3/el unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0016797A1 (en) * | 1978-07-17 | 1980-10-15 | Kerk Motion Prod | ANTI-GAME NUT. |
| US4762882A (en) * | 1985-07-08 | 1988-08-09 | Mitsubishi Chemical Industries Limited | Modified polyolefin resin and a composition containing the same |
| US4788264A (en) * | 1986-11-05 | 1988-11-29 | Idemitsu Petrochemical Co., Ltd. | Method of preparing modified polyethylenes |
Non-Patent Citations (1)
| Title |
|---|
| 机械产品目录第一版 1991.6.1 机械工业出版社 * |
Also Published As
| Publication number | Publication date |
|---|---|
| KR930004344A (ko) | 1993-03-22 |
| JP3207540B2 (ja) | 2001-09-10 |
| EP0527688B1 (fr) | 1996-10-30 |
| FI923630A7 (fi) | 1993-02-15 |
| KR100234208B1 (ko) | 1999-12-15 |
| NO179916B (no) | 1996-09-30 |
| JPH05202149A (ja) | 1993-08-10 |
| ATE144782T1 (de) | 1996-11-15 |
| CA2076129A1 (fr) | 1993-02-15 |
| ES2096055T3 (es) | 1997-03-01 |
| NO179916C (no) | 1997-01-08 |
| FR2680370A1 (fr) | 1993-02-19 |
| TW225541B (enExample) | 1994-06-21 |
| DE69214898T2 (de) | 1997-05-07 |
| DK0527688T3 (da) | 1997-04-21 |
| FI923630A0 (fi) | 1992-08-13 |
| US5591410A (en) | 1997-01-07 |
| US5583181A (en) | 1996-12-10 |
| CN1071173A (zh) | 1993-04-21 |
| NO923170D0 (no) | 1992-08-13 |
| EP0527688A1 (fr) | 1993-02-17 |
| FI110264B (fi) | 2002-12-31 |
| NO923170L (no) | 1993-02-15 |
| DE69214898D1 (de) | 1996-12-05 |
| BR9203045A (pt) | 1993-03-30 |
| CA2076129C (fr) | 2003-10-21 |
| FR2680370B1 (fr) | 1993-11-05 |
| GR3022442T3 (en) | 1997-04-30 |
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