CN104480706B - Biogenic Mothproof fabric - Google Patents

Biogenic Mothproof fabric Download PDF

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Publication number
CN104480706B
CN104480706B CN201410838017.4A CN201410838017A CN104480706B CN 104480706 B CN104480706 B CN 104480706B CN 201410838017 A CN201410838017 A CN 201410838017A CN 104480706 B CN104480706 B CN 104480706B
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biogenic
kilograms
shell
fabric
dyeing liquid
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CN104480706A (en
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宋国新
黄毅
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Foshan Chuangfu Yonghong Textile Co. Ltd.
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Shanghai Taohong Chemical Technology Co Ltd
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Abstract

The invention discloses a kind of biogenic Mothproof fabric, adopt following method to be prepared from: (1) forms dip dyeing liquid for shell by after biogenic emulsifiable insecticide dilute with water 100 times; (2) contaminated in described dip dyeing liquid for shell by pure-cotton fabric, the quality of described dip dyeing liquid for shell is 15 times of pure-cotton fabric, and contaminating temperature is 80 DEG C, immerged time 50min; (3) dry with conventional Water Extraction Machinery, conventional water wash, then dry with conventional Water Extraction Machinery, sizing; Described biogenic emulsifiable insecticide, is made up of following component: 10 kilograms of decises, 3 kilograms of triptonides, 3 kilograms of Tea Saponins, 7 kilograms of agriculture breasts, 2201,77 kilograms of dimethylbenzene.Biogenic Mothproof fabric prepared by the present invention, resist the insect infestations abilities such as mosquito strong, mosquito proof effect is lasting.

Description

Biogenic Mothproof fabric
Patent of the present invention is at application number 201210111287.6, applying date 2012-04-16, and denomination of invention is the divisional application that the patent of invention basis of biogenic Mothproof fabric and preparation method thereof proposes.
Technical field
The present invention relates to a kind of fabric, particularly relate to biogenic Mothproof fabric.
Background technology
Mosquito sucks human blood, spreads disease, serious harm human health.For a long time, people use multiple method to control mosquito, and all kinds of chemical insecticide is effective and efficiency time is long to mosquito control, play the important and pivotal role in the sick control of the mosquito matchmaker in certain areas.In people's daily life, also play irreplaceable effect at present, but organic synthesis pesticide is while efficient insecticide, has also left over many problems.Facts have proved, along with pesticide uses in a large number and chronically, particularly pesticide is in a large number for preventing and treating agricultural pests, and the resistance to the action of a drug degree of mosquito is more and more serious, and diffusion rapidly, and pesticide pollution environment and the impact on balance of nature thereof, be also growing on and on.They all become the outstanding problem in modern mosquito control.These factors impel people seek environmentally safe, be easy to degrade and have and select the pesticide of toxicity.In recent years, domestic and international researcher drops into a large amount of human and material resources and attempts from natural products, from plant, particularly find bioactivator with alternative chemical insecticide, existing oneself finds that the secondary metabolites of some plant has positive effect in mosquito control, and has person poultry safety, not easily develops immunity to drugs, in natural environment, be easy to the feature of degrading.
Summary of the invention
For above shortcomings in prior art, technical problem to be solved by this invention is to provide a kind of biogenic Mothproof fabric.
The present invention seeks to be achieved through the following technical solutions:
A preparation method for biogenic Mothproof fabric, comprises the steps:
(1) after biogenic emulsifiable insecticide dilute with water 50-100 times, dip dyeing liquid for shell is formed,
(2) contaminated in described dip dyeing liquid for shell by fabric, dry, washing, then dry, sizing, can obtain Mothproof fabric of the present invention.
Described biogenic emulsifiable insecticide, is made up of following compositions in weight percentage: pyrethroid 5-15%, triptonide 2-4%, emulsifying agent 8-15%, and surplus is organic solvent.
Described pyrethroid is decis or Cyhalothrin.
Described emulsifying agent is Tea Saponin or agriculture breast 2201.Optimum, described emulsifying agent is mixed by 20-40wt% Tea Saponin and 60-80wt% agriculture breast 2201.
Described organic solvent is dimethylbenzene or alcohol ether solvents.
Described alcohol ether solvents is one in butyl glycol ether, EGME, ethylene glycol ethyl ether, ethylene glycol phenyl ether, butyl, propylene glycol monomethyl ether, propylene-glycol ethyl ether, propandiol butyl ether, ethylene glycol monoethyl ether acetate and ethylene glycol monoalkyl ether carboxylic acid ester or its mixture.
Triptonide, English name: Triptonide, CAS accession number: 38647-11-9.Its molecular structural formula, as follows:
The missible oil preparation method that above-mentioned biogenic emulsifiable insecticide can adopt the industry general is prepared, concrete, following step can be adopted: add in organic solvent by pyrethroid, triptonide and emulsifying agent, be heated to 50-60 DEG C, be uniformly mixed, biogenic emulsifiable insecticide of the present invention can be obtained.Biogenic emulsifiable insecticide of the present invention, after dilution, can also be directly used in spraying desinsection, can reduce rapidly mosquito, fly adult density.
Preferably, the quality of described dip dyeing liquid for shell is 10-20 times of fabric, and contaminating temperature is 50 ~ 90 DEG C, immerged time 20 ~ 60min.
Obviously, corresponding step can also be added according to specific needs in the preparation method of above-mentioned biogenic Mothproof fabric, as bleaching etc., act on accordingly to realize it.
Obviously, described fabric can be natural fabric or synthetic fiber, concrete as real silk, cotton, fiber crops, bamboo, sheep's wool, goats hair, camel hair, the rabbit hair, yak hair, mulberry silk, tussah silk, or polyester, polyamide, polypropylene, polyethylene, polyacrylonitrile, polyvinyl chloride, polyurethane fiber etc.
Present invention also offers a kind of biogenic Mothproof fabric, adopt said method to be prepared from.
Biogenic Mothproof fabric prepared by the present invention, resist the insect infestations abilities such as mosquito strong, mosquito proof effect is lasting.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1: preparation biogenic emulsifiable insecticide
Take each component by embodiment 1 data corresponding to table 1, pyrethroid, triptonide and emulsifying agent are added in organic solvent, is heated to 50-60 DEG C, be uniformly mixed, biogenic emulsifiable insecticide of the present invention can be obtained.
Table 1: biogenic emulsifiable insecticide formula table unit: kilogram
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Decis 5 15 10 10 10
Triptonide 4 2 3 3 3
Tea Saponin 8 / 10 / 3
Agriculture breast 2201 / 15 / 10 7
Dimethylbenzene 83 68 77 77 77
Embodiment 2: preparation biogenic emulsifiable insecticide
Take each component by embodiment 2 data corresponding to table 1, pyrethroid, triptonide and emulsifying agent are added in organic solvent, is heated to 50-60 DEG C, be uniformly mixed, biogenic emulsifiable insecticide of the present invention can be obtained.
Embodiment 3: preparation biogenic emulsifiable insecticide
Take each component by embodiment 3 data corresponding to table 1, pyrethroid, triptonide and emulsifying agent are added in organic solvent, is heated to 50-60 DEG C, be uniformly mixed, biogenic emulsifiable insecticide of the present invention can be obtained.
Embodiment 4: preparation biogenic emulsifiable insecticide
Take each component by embodiment 4 data corresponding to table 1, pyrethroid, triptonide and emulsifying agent are added in organic solvent, is heated to 50-60 DEG C, be uniformly mixed, biogenic emulsifiable insecticide of the present invention can be obtained.
Embodiment 5: preparation biogenic emulsifiable insecticide
Take each component by embodiment 5 data corresponding to table 1, pyrethroid, triptonide and emulsifying agent are added in organic solvent, is heated to 50-60 DEG C, be uniformly mixed, biogenic emulsifiable insecticide of the present invention can be obtained.
Comparative example 1 prepares insect protected missible oil
13 kilograms of decises, 10 kilograms of agriculture breasts, 2201,77 kilograms of dimethylbenzene.
Decis, agriculture breast 2201 are added in organic solvent dimethylbenzene, is heated to 50-60 DEG C, is uniformly mixed, insect protected missible oil can be obtained.
Test case 1:
Culex quinquefasciatus and each 20 of housefly are loaded in two irony fly-traps, is hung on respectively in the closed room of 2.By insect protected missible oil and water in after the ratio mixed diluting of 1: 9, by 1.0ml/m 3formulation rate carry out ultra-low volume spray in room.After dispenser, every 3min observes a mosquitos and flies and knocks down number, continuous 30min.Then tested mosquitos and flies shifted out room and proceed in clean rearging cage, being placed in home and raising 24h, record death toll.
By the insect protected missible oil of embodiment 1-5 and comparative example 1, adopt above-mentioned method of testing to test respectively, concrete test data is in table 2 and table 3.
Table 2: the mosquito-proof effect table of laboratory ultra-low volume spray
15min rate of knockdown after dispenser, % KT50,min The 24h death rate, %
Embodiment 1 100 4.5 100
Embodiment 2 100 2.8 100
Embodiment 3 100 3.5 100
Embodiment 4 100 3.6 100
Embodiment 5 100 2.8 100
Comparative example 1 100 4.3 100
Table 3: laboratory ultra-low volume spray prevention table
15min rate of knockdown after dispenser, % KT50,min The 24h death rate, %
Embodiment 1 100 3.8 100
Embodiment 2 100 2.4 100
Embodiment 3 100 3.3 100
Embodiment 4 100 3.2 100
Embodiment 5 100 2.5 100
Comparative example 1 100 3.7 100
By comparing embodiment 4 and comparative example 1, following conclusion can be drawn: triptonide and pyrethroid built use, effectively can improve and kill mosquito, fly worm ability, there is synergistic effect.Add biogenic in insect protected missible oil---triptonide, can the addition of effective Substitute For Partial pyrethroid, environmental protection more.
By comparing embodiment 5 and embodiment 3,4, following conclusion can be drawn: the composite use of Tea Saponin and agriculture breast 2201, has fabulous synergistic effect to pyrethroid and triptonide, effectively can improve and kill mosquito, fly worm ability.
The preparation method of the biogenic Mothproof fabric of embodiment 6
(1) dip dyeing liquid for shell is formed by after biogenic emulsifiable insecticide dilute with water 80 times,
(2) contaminated in described dip dyeing liquid for shell by pure-cotton fabric, the quality of described dip dyeing liquid for shell is 15 times of pure-cotton fabric, and contaminating temperature is 70 DEG C, immerged time 40min.
(3) dry with conventional Water Extraction Machinery, conventional water wash, then dry with conventional Water Extraction Machinery, sizing, can obtain Mothproof fabric of the present invention.
The present embodiment adopts the biogenic emulsifiable insecticide prepared by embodiment 1.
Obviously, described fabric can also be real silk, fiber crops, bamboo, sheep's wool, goats hair, camel hair, the rabbit hair, yak hair, mulberry silk, tussah silk, or polyester, polyamide, polypropylene, polyethylene, polyacrylonitrile, polyvinyl chloride, polyurethane fiber etc.
The preparation method of the biogenic Mothproof fabric of embodiment 7
(1) dip dyeing liquid for shell is formed by after biogenic emulsifiable insecticide dilute with water 100 times,
(2) contaminated in described dip dyeing liquid for shell by pure-cotton fabric, the quality of described dip dyeing liquid for shell is 15 times of pure-cotton fabric, and contaminating temperature is 80 DEG C, immerged time 50min.
(3) dry with conventional Water Extraction Machinery, conventional water wash, then dry with conventional Water Extraction Machinery, sizing, can obtain Mothproof fabric of the present invention.
The present embodiment adopts the biogenic emulsifiable insecticide prepared by embodiment 2.
The preparation method of the biogenic Mothproof fabric of embodiment 8
(1) dip dyeing liquid for shell is formed by after biogenic emulsifiable insecticide dilute with water 100 times,
(2) contaminated in described dip dyeing liquid for shell by pure-cotton fabric, the quality of described dip dyeing liquid for shell is 15 times of pure-cotton fabric, and contaminating temperature is 80 DEG C, immerged time 50min.
(3) dry with conventional Water Extraction Machinery, conventional water wash, then dry with conventional Water Extraction Machinery, sizing, can obtain Mothproof fabric of the present invention.
The present embodiment adopts the biogenic emulsifiable insecticide prepared by embodiment 3.
The preparation method of the biogenic Mothproof fabric of embodiment 9
(1) dip dyeing liquid for shell is formed by after biogenic emulsifiable insecticide dilute with water 100 times,
(2) contaminated in described dip dyeing liquid for shell by pure-cotton fabric, the quality of described dip dyeing liquid for shell is 15 times of pure-cotton fabric, and contaminating temperature is 80 DEG C, immerged time 50min.
(3) dry with conventional Water Extraction Machinery, conventional water wash, then dry with conventional Water Extraction Machinery, sizing, can obtain Mothproof fabric of the present invention.
The present embodiment adopts the biogenic emulsifiable insecticide prepared by embodiment 4.
The preparation method of the biogenic Mothproof fabric of embodiment 10
(1) dip dyeing liquid for shell is formed by after biogenic emulsifiable insecticide dilute with water 100 times,
(2) contaminated in described dip dyeing liquid for shell by pure-cotton fabric, the quality of described dip dyeing liquid for shell is 15 times of pure-cotton fabric, and contaminating temperature is 80 DEG C, immerged time 50min.
(3) dry with conventional Water Extraction Machinery, conventional water wash, then dry with conventional Water Extraction Machinery, sizing, can obtain Mothproof fabric of the present invention.
The present embodiment adopts the biogenic emulsifiable insecticide prepared by embodiment 5.
The preparation method of comparative example 2 Mothproof fabric
(1) dip dyeing liquid for shell is formed by after insect protected missible oil dilute with water 100 times,
(2) contaminated in described dip dyeing liquid for shell by pure-cotton fabric, the quality of described dip dyeing liquid for shell is 15 times of pure-cotton fabric, and contaminating temperature is 80 DEG C, immerged time 50min.
(3) dry with conventional Water Extraction Machinery, conventional water wash, then dry with conventional Water Extraction Machinery, sizing, can obtain Mothproof fabric of the present invention.
The present embodiment adopts the insect protected missible oil prepared by comparative example 1.
Test case 2:
(1) treatment samples cloth: Mothproof fabric is cut into 15cm × 8cm.
(2) prepare examination worm: mosquito is put into plate with after ether light anesthesia, and is placed on ice cube, select the female mosquito of Culex pipiens pallens, every 50 are one group and put into mosquito cage.
(3) observing effect: after small white mouse being fixed belly depilation, overlay on belly with treatment samples cloth, and by plastic wraps, expose 2cm × 4cm area, be treated to contrast equally with untreated sample cloth.In temperature control laboratory, examination mouse is put into cage, observe the mosquito number that Culex pipiens pallens 15min stops to fall on sample cloth, take out examination mouse through 2h, record knocks down mosquito number and mosquito number of sucking blood, and continues to place 12h, checks dead mosquito number and mosquito number of sucking blood.
(4) data processing: calculate mosquito and stop fall frequency (on average every mosquito stops the number of times that falls), rate of sucking blood and the death rate.
Table 4: the mosquito-proof effect table of Mothproof fabric

Claims (1)

1. a biogenic Mothproof fabric, is characterized in that, adopts following method to be prepared from:
(1) dip dyeing liquid for shell is formed by after biogenic emulsifiable insecticide dilute with water 100 times;
(2) contaminated in described dip dyeing liquid for shell by pure-cotton fabric, the quality of described dip dyeing liquid for shell is 15 times of pure-cotton fabric, and contaminating temperature is 80 DEG C, immerged time 50min;
(3) dry with conventional Water Extraction Machinery, conventional water wash, then dry with conventional Water Extraction Machinery, sizing;
Described biogenic emulsifiable insecticide, is made up of following component: 10 kilograms of decises, 3 kilograms of triptonides, 3 kilograms of Tea Saponins, 7 kilograms of agriculture breasts, 2201,77 kilograms of dimethylbenzene.
CN201410838017.4A 2012-04-16 2012-04-16 Biogenic Mothproof fabric Expired - Fee Related CN104480706B (en)

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CN201210111287.6A CN103374818B (en) 2012-04-16 2012-04-16 Biological source insect-preventing fabric and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN105463839A (en) * 2015-12-22 2016-04-06 常熟市泽众家用纺织品有限公司 Window curtain fabric
CN108316013A (en) * 2018-03-30 2018-07-24 湖州益科纺织科技有限公司 The mosquito proof finishing technique of non-woven fabrics
CN111150132A (en) * 2020-01-14 2020-05-15 北京歌聚科技有限公司 Cool and insect-proof clothes
CN114016289B (en) * 2021-10-27 2023-09-29 常熟市华瑞针纺织有限公司 Mosquito-proof fabric and preparation method thereof

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CN1049441A (en) * 1989-08-13 1991-02-27 潘志荣 Rotenone-pyrethroids insecticide
CN101156607A (en) * 2007-11-20 2008-04-09 史建生 A plant pesticide and its preparing method as well as application
CN101718042A (en) * 2009-11-24 2010-06-02 上海公泰纺织制品有限公司 Mothproof fabric and preparation method thereof
CN102150681A (en) * 2010-11-19 2011-08-17 绍兴中纺院江南分院有限公司 Mosquito-proof assistant agent, preparation method and application thereof

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DE2923217A1 (en) * 1978-06-12 1979-12-13 Ciba Geigy Ag PROCEDURE FOR PROTECTING KERATINIC MATERIALS FROM KERATIN-EATING INSECTS
CN201151848Y (en) * 2007-11-29 2008-11-19 杨晓蓉 Insect-preventing mosquito-proof textiles
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Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
CN1049441A (en) * 1989-08-13 1991-02-27 潘志荣 Rotenone-pyrethroids insecticide
CN101156607A (en) * 2007-11-20 2008-04-09 史建生 A plant pesticide and its preparing method as well as application
CN101718042A (en) * 2009-11-24 2010-06-02 上海公泰纺织制品有限公司 Mothproof fabric and preparation method thereof
CN102150681A (en) * 2010-11-19 2011-08-17 绍兴中纺院江南分院有限公司 Mosquito-proof assistant agent, preparation method and application thereof

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Inventor after: Wang Laixiong

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Address after: 528200 Guangdong Province Nanhai District of Foshan City, Guicheng Road No. 1 Tian Ping Street Jane South digital Metro 1 building 505 room

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