CN103374818B - Biological source insect-preventing fabric and preparation method thereof - Google Patents
Biological source insect-preventing fabric and preparation method thereof Download PDFInfo
- Publication number
- CN103374818B CN103374818B CN201210111287.6A CN201210111287A CN103374818B CN 103374818 B CN103374818 B CN 103374818B CN 201210111287 A CN201210111287 A CN 201210111287A CN 103374818 B CN103374818 B CN 103374818B
- Authority
- CN
- China
- Prior art keywords
- biogenic
- fabric
- preparation
- ether
- mothproof
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 59
- 238000002360 preparation method Methods 0.000 title claims abstract description 27
- 238000004519 manufacturing process Methods 0.000 title description 4
- 238000004043 dyeing Methods 0.000 claims abstract description 27
- 239000007788 liquid Substances 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000002728 pyrethroid Substances 0.000 claims abstract description 14
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 12
- 239000003960 organic solvent Substances 0.000 claims abstract description 12
- 238000005406 washing Methods 0.000 claims abstract description 3
- 230000000035 biogenic effect Effects 0.000 claims description 48
- 239000002917 insecticide Substances 0.000 claims description 31
- SWOVVKGLGOOUKI-ZHGGVEMFSA-N triptonide Chemical compound O=C1OCC([C@@H]2C3)=C1CC[C@]2(C)[C@]12O[C@H]1[C@@H]1O[C@]1(C(C)C)C(=O)[C@]21[C@H]3O1 SWOVVKGLGOOUKI-ZHGGVEMFSA-N 0.000 claims description 14
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 10
- 238000004513 sizing Methods 0.000 claims description 8
- 210000000481 breast Anatomy 0.000 claims description 7
- -1 ethylene glycol monoalkyl ether carboxylic acid ester Chemical class 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 claims description 4
- 239000004210 ether based solvent Substances 0.000 claims description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims description 4
- 229930182490 saponin Natural products 0.000 claims description 4
- 150000007949 saponins Chemical class 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 claims description 2
- JOLQKTGDSGKSKJ-UHFFFAOYSA-N 1-ethoxypropan-2-ol Chemical compound CCOCC(C)O JOLQKTGDSGKSKJ-UHFFFAOYSA-N 0.000 claims description 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 2
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 claims description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 claims description 2
- 241000255925 Diptera Species 0.000 abstract description 26
- 241000238631 Hexapoda Species 0.000 abstract description 9
- 238000007865 diluting Methods 0.000 abstract description 2
- 230000002045 lasting effect Effects 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract 2
- 230000009545 invasion Effects 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 description 13
- 238000003809 water extraction Methods 0.000 description 12
- 210000004209 hair Anatomy 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 239000000575 pesticide Substances 0.000 description 5
- 239000008280 blood Substances 0.000 description 4
- 210000004369 blood Anatomy 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000004567 concrete Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 2
- 235000017491 Bambusa tulda Nutrition 0.000 description 2
- 241001330002 Bambuseae Species 0.000 description 2
- 241000282836 Camelus dromedarius Species 0.000 description 2
- 241000283707 Capra Species 0.000 description 2
- 241000144210 Culex pipiens pallens Species 0.000 description 2
- 241000256113 Culicidae Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 235000008708 Morus alba Nutrition 0.000 description 2
- 240000000249 Morus alba Species 0.000 description 2
- 241000283973 Oryctolagus cuniculus Species 0.000 description 2
- 241001494479 Pecora Species 0.000 description 2
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 210000001015 abdomen Anatomy 0.000 description 2
- 239000011425 bamboo Substances 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229920002239 polyacrylonitrile Polymers 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920006306 polyurethane fiber Polymers 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- 206010002091 Anaesthesia Diseases 0.000 description 1
- 241000256057 Culex quinquefasciatus Species 0.000 description 1
- 206010061217 Infestation Diseases 0.000 description 1
- 241000257159 Musca domestica Species 0.000 description 1
- AOILXFWEUKCKQQ-UHFFFAOYSA-N Saponin 8 Natural products COC(=O)C1(C)CCC2(CCC3(C)C(=CCC4C5(C)CCC(OC6OC(CO)C(O)C(O)C6OC7OC(CO)C(O)C(O)C7O)C(C)(C)C5CCC34C)C2C1)C(=O)OC8OC(CO)C(O)C(O)C8O AOILXFWEUKCKQQ-UHFFFAOYSA-N 0.000 description 1
- 241000190070 Sarracenia purpurea Species 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 230000037005 anaesthesia Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000035617 depilation Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 229930000044 secondary metabolite Natural products 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
Abstract
The invention discloses a biological source insect-preventing fabric and a preparation method thereof. The preparation method is characterized by comprising the following steps of: (1) diluting biological source insect-preventing missible oil for 50-100 times by water to form dip dyeing liquid; and (2) dip-dyeing a fabric in the dip dyeing liquid, spin-drying, washing by water, spin-drying for the second time, and setting, thus obtaining the insect-preventing fabric. The biological source insect-preventing missible oil comprises the following components in percentage by weight: 5%-15% of pyrethroid, 2%-4% of LeiTeng ketone, 8%-15% of an emulsifying agent, and the balance of an organic solvent. The biological source insect-preventing fabric prepared by the preparation method provided by the invention has strong capacity for resisting invasion of insects such as mosquitoes, and has a lasting effect for preventing mosquitoes.
Description
Technical field
The present invention relates to a kind of fabric and preparation method thereof, particularly relate to biogenic Mothproof fabric and preparation method thereof.
Background technology
Mosquito sucks human blood, spreads disease, serious harm human health.For a long time, people use multiple method to control mosquito, and all kinds of chemical insecticide is effective and efficiency time is long to mosquito control, play the important and pivotal role in the sick control of the mosquito matchmaker in certain areas.In people's daily life, also play irreplaceable effect at present, but organic synthesis pesticide is while efficient insecticide, has also left over many problems.Facts have proved, along with pesticide uses in a large number and chronically, particularly pesticide is in a large number for preventing and treating agricultural pests, and the resistance to the action of a drug degree of mosquito is more and more serious, and diffusion rapidly, and pesticide pollution environment and the impact on balance of nature thereof, be also growing on and on.They all become the outstanding problem in modern mosquito control.These factors impel people seek environmentally safe, be easy to degrade and have and select the pesticide of toxicity.In recent years, domestic and international researcher drops into a large amount of human and material resources and attempts from natural products, from plant, particularly find bioactivator with alternative chemical insecticide, have now found that the secondary metabolites of some plant has positive effect in mosquito control, and have person poultry safety, not easily develop immunity to drugs, be easy in natural environment degrade feature.
Summary of the invention
For above shortcomings in prior art, one of technical problem to be solved by this invention provides a kind of preparation method of biogenic Mothproof fabric.
Two of technical problem to be solved by this invention provides a kind of biogenic Mothproof fabric.
The present invention seeks to be achieved through the following technical solutions:
A preparation method for biogenic Mothproof fabric, comprises the steps:
(1) after biogenic emulsifiable insecticide dilute with water 50-100 times, dip dyeing liquid for shell is formed,
(2) contaminated in described dip dyeing liquid for shell by fabric, dry, washing, then dry, sizing, can obtain Mothproof fabric of the present invention.
Described biogenic emulsifiable insecticide, is made up of following compositions in weight percentage: pyrethroid 5-15%, triptonide 2-4%, emulsifying agent 8-15%, and surplus is organic solvent.
Described pyrethroid is decis or Cyhalothrin.
Described emulsifying agent is Tea Saponin or agriculture breast 2201.Optimum, described emulsifying agent is mixed by 20-40wt% Tea Saponin and 60-80wt% agriculture breast 2201.
Described organic solvent is dimethylbenzene or alcohol ether solvents.
Described alcohol ether solvents is one in butyl glycol ether, EGME, ethylene glycol ethyl ether, ethylene glycol phenyl ether, butyl, propylene glycol monomethyl ether, propylene-glycol ethyl ether, propandiol butyl ether, ethylene glycol monoethyl ether acetate and ethylene glycol monoalkyl ether carboxylic acid ester or its mixture.
Triptonide, English name: Triptonide, CAS accession number: 38647-11-9.Its molecular structural formula, as follows:
The missible oil preparation method that above-mentioned biogenic emulsifiable insecticide can adopt the industry general is prepared, concrete, following step can be adopted: add in organic solvent by pyrethroid, triptonide and emulsifying agent, be heated to 50-60 DEG C, be uniformly mixed, biogenic emulsifiable insecticide of the present invention can be obtained.Biogenic emulsifiable insecticide of the present invention, after dilution, can also be directly used in spraying desinsection, can reduce rapidly mosquito, fly adult density.
Preferably, the quality of described dip dyeing liquid for shell is 10-20 times of fabric, and contaminating temperature is 50 ~ 90 DEG C, immerged time 20 ~ 60min.
Obviously, corresponding step can also be added according to specific needs in the preparation method of above-mentioned biogenic Mothproof fabric, as bleaching etc., act on accordingly to realize it.
Obviously, described fabric can be natural fabric or synthetic fiber, concrete as real silk, cotton, fiber crops, bamboo, sheep's wool, goats hair, camel hair, the rabbit hair, yak hair, mulberry silk, tussah silk, or polyester, polyamide, polypropylene, polyethylene, polyacrylonitrile, polyvinyl chloride, polyurethane fiber etc.
Present invention also offers a kind of biogenic Mothproof fabric, adopt said method to be prepared from.
Biogenic Mothproof fabric prepared by the present invention, resist the insect infestations abilities such as mosquito strong, mosquito proof effect is lasting.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1: preparation biogenic emulsifiable insecticide
Take each component by embodiment 1 data corresponding to table 1, pyrethroid, triptonide and emulsifying agent are added in organic solvent, is heated to 50-60 DEG C, be uniformly mixed, biogenic emulsifiable insecticide of the present invention can be obtained.
Table 1: biogenic emulsifiable insecticide formula table unit: kilogram
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Decis | 5 | 15 | 10 | 10 | 10 |
| Triptonide | 4 | 2 | 3 | 3 | 3 |
| Tea Saponin | 8 | / | 10 | / | 3 |
| Agriculture breast 2201 | / | 15 | / | 10 | 7 |
| Dimethylbenzene | 83 | 68 | 77 | 77 | 77 |
Embodiment 2: preparation biogenic emulsifiable insecticide
Take each component by embodiment 2 data corresponding to table 1, pyrethroid, triptonide and emulsifying agent are added in organic solvent, is heated to 50-60 DEG C, be uniformly mixed, biogenic emulsifiable insecticide of the present invention can be obtained.
Embodiment 3: preparation biogenic emulsifiable insecticide
Take each component by embodiment 3 data corresponding to table 1, pyrethroid, triptonide and emulsifying agent are added in organic solvent, is heated to 50-60 DEG C, be uniformly mixed, biogenic emulsifiable insecticide of the present invention can be obtained.
Embodiment 4: preparation biogenic emulsifiable insecticide
Take each component by embodiment 4 data corresponding to table 1, pyrethroid, triptonide and emulsifying agent are added in organic solvent, is heated to 50-60 DEG C, be uniformly mixed, biogenic emulsifiable insecticide of the present invention can be obtained.
Embodiment 5: preparation biogenic emulsifiable insecticide
Take each component by embodiment 5 data corresponding to table 1, pyrethroid, triptonide and emulsifying agent are added in organic solvent, is heated to 50-60 DEG C, be uniformly mixed, biogenic emulsifiable insecticide of the present invention can be obtained.
Comparative example 1 prepares insect protected missible oil
13 kilograms of decises, 10 kilograms of agriculture breasts, 2201,77 kilograms of dimethylbenzene.
Decis, agriculture breast 2201 are added in organic solvent dimethylbenzene, is heated to 50-60 DEG C, is uniformly mixed, insect protected missible oil can be obtained.
Test case 1:
Culex quinquefasciatus and each 20 of housefly are loaded in two irony fly-traps, is hung on respectively in the closed room of 2.By insect protected missible oil and water in after the ratio mixed diluting of 1: 9, by 1.0ml/m
3formulation rate carry out ultra-low volume spray in room.After dispenser, every 3min observes a mosquitos and flies and knocks down number, continuous 30min.Then tested mosquitos and flies shifted out room and proceed in clean rearging cage, being placed in home and raising 24h, record death toll.
By the insect protected missible oil of embodiment 1-5 and comparative example 1, adopt above-mentioned method of testing to test respectively, concrete test data is in table 2 and table 3.
Table 2: the mosquito-proof effect table of laboratory ultra-low volume spray
| 15min rate of knockdown after dispenser, % | KT50，min | The 24h death rate, % | |
| Embodiment 1 | 100 | 4.5 | 100 |
| Embodiment 2 | 100 | 2.8 | 100 |
| Embodiment 3 | 100 | 3.5 | 100 |
| Embodiment 4 | 100 | 3.6 | 100 |
| Embodiment 5 | 100 | 2.8 | 100 |
| Comparative example 1 | 100 | 4.3 | 100 |
Table 3: laboratory ultra-low volume spray prevention table
| 15min rate of knockdown after dispenser, % | KT50，min | The 24h death rate, % | |
| Embodiment 1 | 100 | 3.8 | 100 |
| Embodiment 2 | 100 | 2.4 | 100 |
| Embodiment 3 | 100 | 3.3 | 100 |
| Embodiment 4 | 100 | 3.2 | 100 |
| Embodiment 5 | 100 | 2.5 | 100 |
| Comparative example 1 | 100 | 3.7 | 100 |
By comparing embodiment 4 and comparative example 1, following conclusion can be drawn: triptonide and pyrethroid built use, effectively can improve and kill mosquito, fly worm ability, there is synergistic effect.Add biogenic in insect protected missible oil---triptonide, can the addition of effective Substitute For Partial pyrethroid, environmental protection more.
By comparing embodiment 5 and embodiment 3,4, following conclusion can be drawn: the composite use of Tea Saponin and agriculture breast 2201, has fabulous synergistic effect to pyrethroid and triptonide, effectively can improve and kill mosquito, fly worm ability.
The preparation method of the biogenic Mothproof fabric of embodiment 6
(1) dip dyeing liquid for shell is formed by after biogenic emulsifiable insecticide dilute with water 80 times,
(2) contaminated in described dip dyeing liquid for shell by pure-cotton fabric, the quality of described dip dyeing liquid for shell is 15 times of pure-cotton fabric, and contaminating temperature is 70 DEG C, immerged time 40min.
(3) dry with conventional Water Extraction Machinery, conventional water wash, then dry with conventional Water Extraction Machinery, sizing, can obtain Mothproof fabric of the present invention.
The present embodiment adopts the biogenic emulsifiable insecticide prepared by embodiment 1.
Obviously, described fabric can also be real silk, fiber crops, bamboo, sheep's wool, goats hair, camel hair, the rabbit hair, yak hair, mulberry silk, tussah silk, or polyester, polyamide, polypropylene, polyethylene, polyacrylonitrile, polyvinyl chloride, polyurethane fiber etc.
The preparation method of the biogenic Mothproof fabric of embodiment 7
(1) dip dyeing liquid for shell is formed by after biogenic emulsifiable insecticide dilute with water 100 times,
(2) contaminated in described dip dyeing liquid for shell by pure-cotton fabric, the quality of described dip dyeing liquid for shell is 15 times of pure-cotton fabric, and contaminating temperature is 80 DEG C, immerged time 50min.
(3) dry with conventional Water Extraction Machinery, conventional water wash, then dry with conventional Water Extraction Machinery, sizing, can obtain Mothproof fabric of the present invention.
The present embodiment adopts the biogenic emulsifiable insecticide prepared by embodiment 2.
The preparation method of the biogenic Mothproof fabric of embodiment 8
(1) dip dyeing liquid for shell is formed by after biogenic emulsifiable insecticide dilute with water 100 times,
(2) contaminated in described dip dyeing liquid for shell by pure-cotton fabric, the quality of described dip dyeing liquid for shell is 15 times of pure-cotton fabric, and contaminating temperature is 80 DEG C, immerged time 50min.
(3) dry with conventional Water Extraction Machinery, conventional water wash, then dry with conventional Water Extraction Machinery, sizing, can obtain Mothproof fabric of the present invention.
The present embodiment adopts the biogenic emulsifiable insecticide prepared by embodiment 3.
The preparation method of the biogenic Mothproof fabric of embodiment 9
(1) dip dyeing liquid for shell is formed by after biogenic emulsifiable insecticide dilute with water 100 times,
(2) contaminated in described dip dyeing liquid for shell by pure-cotton fabric, the quality of described dip dyeing liquid for shell is 15 times of pure-cotton fabric, and contaminating temperature is 80 DEG C, immerged time 50min.
(3) dry with conventional Water Extraction Machinery, conventional water wash, then dry with conventional Water Extraction Machinery, sizing, can obtain Mothproof fabric of the present invention.
The present embodiment adopts the biogenic emulsifiable insecticide prepared by embodiment 4.
The preparation method of the biogenic Mothproof fabric of embodiment 10
(1) dip dyeing liquid for shell is formed by after biogenic emulsifiable insecticide dilute with water 100 times,
(2) contaminated in described dip dyeing liquid for shell by pure-cotton fabric, the quality of described dip dyeing liquid for shell is 15 times of pure-cotton fabric, and contaminating temperature is 80 DEG C, immerged time 50min.
(3) dry with conventional Water Extraction Machinery, conventional water wash, then dry with conventional Water Extraction Machinery, sizing, can obtain Mothproof fabric of the present invention.
The present embodiment adopts the biogenic emulsifiable insecticide prepared by embodiment 5.
The preparation method of comparative example 2 Mothproof fabric
(1) dip dyeing liquid for shell is formed by after insect protected missible oil dilute with water 100 times,
(2) contaminated in described dip dyeing liquid for shell by pure-cotton fabric, the quality of described dip dyeing liquid for shell is 15 times of pure-cotton fabric, and contaminating temperature is 80 DEG C, immerged time 50min.
(3) dry with conventional Water Extraction Machinery, conventional water wash, then dry with conventional Water Extraction Machinery, sizing, can obtain Mothproof fabric of the present invention.
The present embodiment adopts the insect protected missible oil prepared by comparative example 1.
Test case 2:
(1) treatment samples cloth: Mothproof fabric is cut into 15cm × 8cm.
(2) prepare examination worm: mosquito is put into plate with after ether light anesthesia, and is placed on ice cube, select the female mosquito of Culex pipiens pallens, every 50 are one group and put into mosquito cage.
(3) observing effect: after small white mouse being fixed belly depilation, overlay on belly with treatment samples cloth, and by plastic wraps, expose 2cm × 4cm area, be treated to contrast equally with untreated sample cloth.In temperature control laboratory, examination mouse is put into cage, observe the mosquito number that Culex pipiens pallens 15min stops to fall on sample cloth, take out examination mouse through 2h, record knocks down mosquito number and mosquito number of sucking blood, and continues to place 12h, checks dead mosquito number and mosquito number of sucking blood.
(4) data processing: calculate mosquito and stop fall frequency (on average every mosquito stops the number of times that falls), rate of sucking blood and the death rate.
Table 4: the mosquito-proof effect table of Mothproof fabric
Claims (6)
1. a preparation method for biogenic Mothproof fabric, is characterized in that, comprises the steps:
(1) after biogenic emulsifiable insecticide dilute with water 50-100 times, dip dyeing liquid for shell is formed,
(2) contaminated in described dip dyeing liquid for shell by fabric, dry, washing, then dry, sizing, can obtain Mothproof fabric of the present invention;
Described biogenic emulsifiable insecticide, is made up of following compositions in weight percentage: pyrethroid 5-15%, triptonide 2-4%, emulsifying agent 8-15%, and surplus is organic solvent;
Described emulsifying agent is mixed by 20-40wt% Tea Saponin and 60-80wt% agriculture breast 2201.
2. the preparation method of biogenic Mothproof fabric as claimed in claim 1, is characterized in that: described pyrethroid is decis or Cyhalothrin.
3. the preparation method of biogenic Mothproof fabric as claimed in claim 1, is characterized in that: described organic solvent is dimethylbenzene or alcohol ether solvents.
4. the preparation method of biogenic Mothproof fabric as claimed in claim 3, is characterized in that: described alcohol ether solvents is one in butyl glycol ether, EGME, ethylene glycol ethyl ether, ethylene glycol phenyl ether, butyl, propylene glycol monomethyl ether, propylene-glycol ethyl ether, propandiol butyl ether, ethylene glycol monoethyl ether acetate and ethylene glycol monoalkyl ether carboxylic acid ester or its mixture.
5. the preparation method of the biogenic Mothproof fabric according to any one of claim 1-4, is characterized in that: the quality of described dip dyeing liquid for shell is 10-20 times of fabric, and contaminating temperature is 50 ~ 90 DEG C, immerged time 20 ~ 60min.
6. a biogenic Mothproof fabric, is characterized in that: adopt method according to any one of claim 1-5 to be prepared from.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410838017.4A CN104480706B (en) | 2012-04-16 | 2012-04-16 | Biogenic Mothproof fabric |
| CN201210111287.6A CN103374818B (en) | 2012-04-16 | 2012-04-16 | Biological source insect-preventing fabric and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210111287.6A CN103374818B (en) | 2012-04-16 | 2012-04-16 | Biological source insect-preventing fabric and preparation method thereof |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410838017.4A Division CN104480706B (en) | 2012-04-16 | 2012-04-16 | Biogenic Mothproof fabric |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103374818A CN103374818A (en) | 2013-10-30 |
| CN103374818B true CN103374818B (en) | 2015-03-25 |
Family
ID=49460625
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210111287.6A Expired - Fee Related CN103374818B (en) | 2012-04-16 | 2012-04-16 | Biological source insect-preventing fabric and preparation method thereof |
| CN201410838017.4A Expired - Fee Related CN104480706B (en) | 2012-04-16 | 2012-04-16 | Biogenic Mothproof fabric |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410838017.4A Expired - Fee Related CN104480706B (en) | 2012-04-16 | 2012-04-16 | Biogenic Mothproof fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN103374818B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105463839A (en) * | 2015-12-22 | 2016-04-06 | 常熟市泽众家用纺织品有限公司 | Window curtain fabric |
| CN108316013A (en) * | 2018-03-30 | 2018-07-24 | 湖州益科纺织科技有限公司 | The mosquito proof finishing technique of non-woven fabrics |
| CN111150132A (en) * | 2020-01-14 | 2020-05-15 | 北京歌聚科技有限公司 | Cool and insect-proof clothes |
| CN114016289B (en) * | 2021-10-27 | 2023-09-29 | 常熟市华瑞针纺织有限公司 | Mosquito-proof fabric and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5526285A (en) * | 1978-06-12 | 1980-02-25 | Ciba Geigy Ag | Protecting of keratinous material from harmful insect |
| CN101187158A (en) * | 2007-12-07 | 2008-05-28 | 深圳清华大学研究院 | Mosquito-proof finishing agent and preparation method and its uses in mosquito-preventing fabric |
| CN201151848Y (en) * | 2007-11-29 | 2008-11-19 | 杨晓蓉 | Insect-preventing mosquito-proof textiles |
| CN101718042A (en) * | 2009-11-24 | 2010-06-02 | 上海公泰纺织制品有限公司 | Mothproof fabric and preparation method thereof |
| CN102150681A (en) * | 2010-11-19 | 2011-08-17 | 绍兴中纺院江南分院有限公司 | Mosquito-proof assistant agent, preparation method and application thereof |
| CN102383258A (en) * | 2011-09-22 | 2012-03-21 | 杨晓蓉 | Long-lasting insect repellent fabric and method for producing same |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1019167B (en) * | 1989-08-13 | 1992-11-25 | 潘志荣 | Rotenone-pyrethroids insecticide |
| CN101156607B (en) * | 2007-11-20 | 2010-11-24 | 史建生 | A plant pesticide and its preparing method as well as application |
-
2012
- 2012-04-16 CN CN201210111287.6A patent/CN103374818B/en not_active Expired - Fee Related
- 2012-04-16 CN CN201410838017.4A patent/CN104480706B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5526285A (en) * | 1978-06-12 | 1980-02-25 | Ciba Geigy Ag | Protecting of keratinous material from harmful insect |
| CN201151848Y (en) * | 2007-11-29 | 2008-11-19 | 杨晓蓉 | Insect-preventing mosquito-proof textiles |
| CN101187158A (en) * | 2007-12-07 | 2008-05-28 | 深圳清华大学研究院 | Mosquito-proof finishing agent and preparation method and its uses in mosquito-preventing fabric |
| CN101718042A (en) * | 2009-11-24 | 2010-06-02 | 上海公泰纺织制品有限公司 | Mothproof fabric and preparation method thereof |
| CN102150681A (en) * | 2010-11-19 | 2011-08-17 | 绍兴中纺院江南分院有限公司 | Mosquito-proof assistant agent, preparation method and application thereof |
| CN102383258A (en) * | 2011-09-22 | 2012-03-21 | 杨晓蓉 | Long-lasting insect repellent fabric and method for producing same |
Non-Patent Citations (1)
| Title |
|---|
| 雷公藤的杀虫作用研究与应用;昆虫知识;《昆虫知识》;20081115;第33卷(第10期);第854页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104480706B (en) | 2016-04-13 |
| CN103374818A (en) | 2013-10-30 |
| CN104480706A (en) | 2015-04-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103371171B (en) | Biogenic emulsifiable insecticide and method for preparing same | |
| CN103374818B (en) | Biological source insect-preventing fabric and preparation method thereof | |
| JP7258945B2 (en) | Compounds and compositions having knockdown activity or blood-sucking inhibitory activity against pests | |
| CN103371169B (en) | Sophoramine insect-preventing missible oil, sophoramine insect-preventing fabric and preparation method of fabric | |
| CN103651634B (en) | Citronella oil mosquito expelling liquid, mosquito expelling summer sleeping mat and preparation method thereof | |
| WO2017045268A1 (en) | Insecticide with high content of pyrethrin | |
| EP3606342A1 (en) | Compounds and compositions having knock-down or blood feed inhibition activity against insect pests | |
| CN107419526A (en) | A kind of production method of natural anophelifuge antibacterial wormwood summer cool silk wadding bag | |
| CN106221914A (en) | A kind of preparation method and applications killing Coptotermes formosanus Shtrari. preparation clove oil | |
| CN101133741B (en) | Vermins-expelling vermins-proof disinfection preparations for fabric | |
| CN103202314B (en) | Emulsion in water of pesticide composition for controlling cotton aphids and thrips | |
| CN104068062B (en) | Chlorine tetramethrin aqueous emulsion of a kind of repelling and killing bugs and preparation method thereof | |
| Xiaohu et al. | A Comparative Study on Toxicity of Pyrethrin and Three Conventional Pesticides against Coptotermes formosanus Shiraki. | |
| CN102308844A (en) | Preparation and applications of pesticidal atomizing agent | |
| CN103651600B (en) | Mentha piperita oil mosquito expelling liquid, mosquito expelling summer sleeping mat and preparation method thereof | |
| CN103397520B (en) | Fabric desinsection mosquito-repellent anti-static biologic product | |
| CN106811964A (en) | Biological source Mothproof fabric and preparation method thereof | |
| CN103651427B (en) | Mosquito-repelling emulsified oil as well as mosquito-repelling summer sleeping mat and preparation methods thereof | |
| CN102308845A (en) | Preparation and applications of atomizing agent with pesticide and deratization functions | |
| CN103858790A (en) | Insect-proofing neck ring device for dog and preparing method thereof | |
| CN108149482A (en) | Biological source Mothproof fabric and preparation method thereof | |
| CN107864974A (en) | Biological source Mothproof fabric and preparation method thereof | |
| CN105165905A (en) | Method for controlling aphid of green plants | |
| CN113519507A (en) | Plant oil for ultra-low-capacity spraying and insect killing of unmanned aerial vehicle | |
| CN106614789A (en) | Preparation of three tartary buckwheat stalk extracts, and application of insecticidal activity of extracts |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| C53 | Correction of patent of invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Wang Zhihua Inventor before: Song Guoxin Inventor before: Huang Yi |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: SONG GUOXIN HUANG YI TO: WANG ZHIHUA |
|
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20151231 Address after: 510032, No. 1, post industrial zone, Sha Chung Village, Tai Lung Street, Guangzhou, Guangdong, Panyu District Patentee after: GUANGZHOU T100 CHILDREN'PRODUCTS Co.,Ltd. Address before: 200137 room 1F79, building, No. 528, Yang Gao Bei Road, Shanghai, Pudong New Area Patentee before: SHANGHAI TAOHONG CHEMICAL TECHNOLOGY Co.,Ltd. |
|
| PP01 | Preservation of patent right |
Effective date of registration: 20200527 Granted publication date: 20150325 |
|
| PP01 | Preservation of patent right | ||
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20230527 Granted publication date: 20150325 |
|
| PD01 | Discharge of preservation of patent | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150325 |