CN104450307A - Multipurpose surfactant-free cleaning agent for fruits, vegetables and dishes and method for producing multipurpose surfactant-free cleaning agent for fruits, vegetables and dishes - Google Patents
Multipurpose surfactant-free cleaning agent for fruits, vegetables and dishes and method for producing multipurpose surfactant-free cleaning agent for fruits, vegetables and dishes Download PDFInfo
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Abstract
The invention discloses a multipurpose surfactant-free cleaning agent for fruits, vegetables and dishes. The cleaning agent comprises purified water, a composite chelating agent, an anti-deposition agent, a composite enzyme preparation, a composite builder and a composite plant extraction liquid, wherein the composite chelating agent comprises EDTA-2Na and sodium tartrate, the composite enzyme preparation comprises alkaline proteinase, lipase, amylase and cellulose, the composite builder comprises citric acid, sodium hydroxide and sodium bicarbonate, and the composite plant extraction liquid comprises an onion extraction liquid, a garlic extraction liquid, a ginger extraction liquid, a dark tea extraction liquid, a Chinese honeylocust fruit extraction liquid and a soapberry pericarp extraction liquid. The multipurpose surfactant-free cleaning agent for fruits, vegetables and dishes can avoid secondary environment pollution generated by surfactant residues, damage to human health caused by residues of organic pesticides and the like, not only can be used for cleaning and degerming vegetables and fruits and removing the residues of pesticides, but also can be used for cleaning and sterilizing dishes; and the multipurpose surfactant-free cleaning agent for fruits, vegetables and dishes and the method for producing the multipurpose surfactant-free cleaning agent for fruits, vegetables and dishes have the advantages of less investment, easy availability of the raw materials, simple and convenient production, high cleaning rate, wide application range, and are beneficial for environment protection and human health.
Description
Technical field
The invention belongs to filed of daily-use chemical industry, be specifically related to a kind of multi-usage fruits and vegetables cleaning agent for dinnerware of surfactant-free.
Background technology
Existing gourd, fruit and vegetable and cleaning agent for dinnerware main component are all that the surfactant compound foamed by decontamination forms, and are added with the sanitas and synthetic perfume that affect health of human body, mainly there is following defect:
One, existence is polluted again
Due to the perviousness of tensio-active agent, while the cleaning dirty dirt of fruits and vegetables and tydrophilization pesticide residue, not only tensio-active agent is residual can penetrate into fruits and vegetables inside, also can be easily inner to fruit and vegetable food by remains of pesticide composition in the lump percdation because of its perviousness, bring second time to pollute and the infringement new to human body;
Two, HUMAN HEALTH is affected
Because tensio-active agent has the strong characteristic of emulsifying power; synthetic surfactant can produce emulsifying effect when cleaning fruits and vegetables and tableware; the lubricant component in tableware can be made to depart from from tableware surface; but also make the grease emulsifying of wash dishes personnel skin surface simultaneously; make the sebum film of protection skin impaired, cause polluting toxic substance and invade skin inside thus affect healthy.
Although market there is a kind of fruit vegetables apparatus for sterilization remain for removing fruits and vegetables, but fruit vegetables apparatus for sterilization destroys fruit-vegetable fibre element while sterilization, found through experiments, what use various fruit-vegetable cleaner truly has a kind of effect, that is exactly that ozone concn is higher, except toxic effect fruit is better.The experiment display of similarity condition, pesticide residue are removed can reach 60%-83%.But, in the face of immersing the deep layer residue problem in fruit and vegetable, fruit vegetables apparatus for sterilization just can not get instant result as its remained on surface agricultural chemicals of removal.The more important thing is, in the process of the fruit vegetables apparatus for sterilization based on air source for vegetables " removing toxic substances ", also can have side effects.As civilian in " inferior quality concentration of ozone water is on the impact of Plantula Brassicae chinensis nutrition " of Zhongshan University's journal (natural science edition) in published originally, be the Experiment Result of the scientific research personnel such as engine hygiene Xi Wuji state of Nanfang Medical Univ and biological control National Key Laboratory of the Zhongshan University goldenrain tree Big Dipper.This report shows: the ozone water process Plantula Brassicae chinensis 30 minutes taking concentration as 1.4 mg/litre, and the dehydrogenation vitamins C of 67% is destroyed, and total vitamins C also loses nearly 30%.Result of study illustrates, during with leafy vegetables such as ozone water process Plantula Brassicae chinensiss, needs to consider that ozone is to destruction ascorbic in vegetables.In fact, compared with the harm of ozone itself, if technology does not pass a test, the by product oxynitride of Household ozone generator in making ozone process (strong carcinogen that the World Health Organization is assert, international standard is for being no more than 0.25%) is larger for user's threat.Oxynitride as fruit product exceeds standard, and probably making originally to be used for the Household ozone generator of disinfection becomes the nightmare that user can't get rid of.Therefore, invent a kind of can clean and can sterilize and without secondary harm fruits and vegetables and cleaning agent for dinnerware, be health of people life in the urgent need to.
Summary of the invention
For the problems referred to above, the object of the invention is to, be major ingredient with environmentally friendly materials such as plant extraction liquids, there is provided a kind of be not only conducive to health of human body and avoided environmental pollution, but also the fruits and vegetables cleaning agent for dinnerware that a kind of clean-out system just can meet the multi-usage surfactant-free of fruits and vegetables and wash dishes can be realized, can not only Rapid Cleaning fruits and vegetables and tableware, the microbial bacterial such as intestinal bacteria, sporeformer can also be removed, effectively can also eliminate the organophosphorus pesticide in fruit and vegetable food, fundamentally overcome the deficiency that existing rinse product exists.
The multi-usage fruits and vegetables cleaning agent for dinnerware of surfactant-free of the present invention is made as follows:
Step one, according to mass ratio successively by pure water 400-700 part, EDTA-2Na1-5 part, citric acid 8-35 part, sodium tartrate 3-8 part, carboxymethyl cellulose 0.5-2 part stirring and dissolving in stainless steel stirred vessel;
Step 2, continues to stir by Sumizyme MP 8-30 part, lipase 5-25 part, amylase 7-28 part, cellulase 5-25 in mass ratio successively in aforesaid reaction vessel;
Step 3, add the composite plant extraction liquid conventionally refined in mass ratio, wherein onions extracting liquid 30-700 part, garlic extract 25-70 part, ginger extract 20-90 part, black tea extract 50-120 part, Chinese honey locust extracting solution 60-200 part, timbol extracting solution 60-250 part, continue to stir in aforesaid reaction vessel;
Step 4, get sodium hydroxide 8-40 part in mass ratio, sodium bicarbonate 20-70 part be dissolved in water formed saturated solution, slowly add in above-mentioned stainless steel stirred vessel afterwards, the pH value of product is regulated to be neutral 7, namely generate the multi-usage fruits and vegetables cleaning agent for dinnerware of surfactant-free of the present invention, be finished product finally by after container filling.
Further, the carboxymethyl cellulose in fruits and vegetables cleaning agent for dinnerware of the present invention is food grade, and the viscosity of 2% solution is greater than 1200mPas;
The vigor of the Sumizyme MP in this product, amylase, cellulase, lipase all should be greater than 2.5 ten thousand units (Da), pH value 8-9.
The multi-usage fruits and vegetables cleaning agent for dinnerware of surfactant-free of the present invention includes pure water, association complex, compound enzymic preparation, anti-deposition agent, compound washing auxiliary agent, composite plant extraction liquid, is a kind of multi-usage fruits and vegetables cleaning agent for dinnerware be composited by above Multiple components; Wherein, EDTA-2Na, sodium tartrate is utilized to form association complex; Utilize carboxymethyl cellulose for anti redeposition agent, avoid objectionable constituent again to pollute fruits and vegetables and tableware, make the organophosphorus pesticide being insoluble in water not be adsorbed on fruits and vegetables and tableware surface; Utilize Sumizyme MP, lipase, amylase, cellulase to form compound enzymic preparation, strengthen fat hydrolysis active, the protein dirts such as wipe oil, the active catalytic effect of this prozyme is 30-90 times of traditional catalyst; Citric acid and sodium bicarbonate and sodium hydroxide is utilized to form compound washing auxiliary agent, utilize in citric acid and sodium hydroxide simultaneously and improve product washing ability with the sequestering action of rear formation, utilize the whole component in sodium hydroxide and the good sodium bicarbonate of biological degradability and in formula and remaining in acid organophosphorus pesticide further, to ensure that product plays better effect in a neutral state, organophosphorus pesticide is also made better to decompose; The onions extracting liquid utilizing conveniently extracting method to extract, garlic extract, ginger extract, black tea extract, Chinese honey locust extracting solution, Seed of Chinese Soapberry Fruit peel extract composition composite plant extract liquid; Wherein garlic extract is natural plant broad-spectrum antibiotics, the garlicin contained in garlic has very strong germicidal action, wherein, main component in black tea is theoflavin and thearubigins, theoflavin is not only a kind of effective free-radical scavengers and antioxidant, also has obvious antibacterial sterilization functions to meat poisoning bud bacillus, intestines genera bacillus, staphylococcus glucose bacterium, Bacillus cereus etc.; Wherein, ginger effectively can remove peculiar smell; Onions extracting liquid has very strong sterilizing power too; Wherein Seed of Chinese Soapberry Fruit peel extract contains the triterpenoid saponins such as saponin(e, is the washing material of natural nuisance-free.
The multi-usage fruits and vegetables cleaning agent for dinnerware technological principle of surfactant-free of the present invention:
------combinative enzyme hydrolysis expedites the emergence of biological activity, and------composite plant extraction liquid combination reaction polymerization sterilization scourability---regulates pH value and---leaves standstill purification---filling---finished product washing auxiliary detergent catalytic surface-active association complex Water warfare pure water.
The multi-usage fruits and vegetables cleaning agent for dinnerware of surfactant-free of the present invention utilizes the environmentally friendly materials such as plant extraction liquid to be major ingredient, can not only Rapid Cleaning fruits and vegetables and tableware, of many uses, the microbial bacterial such as intestinal bacteria, sporeformer can also be removed, effectively can also eliminate the organophosphorus pesticide in fruit and vegetable food, can avoid causing secondary pollution in cleaning process simultaneously, avoid HUMAN HEALTH to suffer damage, also can avoid environmental pollution.
Embodiment
Embodiment one
The multi-usage fruits and vegetables cleaning agent for dinnerware of surfactant-free of the present invention is made as follows:
Step one, according to mass ratio successively by pure water 600 parts, EDTA-2Na:3 part, citric acid 25 parts, sodium tartrate: 6 parts, carboxymethyl cellulose 1.2 parts stirring and dissolving in stainless steel stirred vessel;
Step 2, continues to stir by Sumizyme MP 12 parts, 9 parts, lipase, amylase 8 part, cellulase 16 in mass ratio successively in aforesaid reaction vessel;
Step 3, add the composite plant extraction liquid conventionally refined in mass ratio, onions extracting liquid 120 parts, garlic extract 50 parts, ginger extract 60 parts, black tea extract 70 parts, Chinese honey locust extracting solution 150 parts, timbol extracting solution 200 parts, continue to stir in aforesaid reaction vessel;
Step 4, get 25 parts, sodium hydroxide in mass ratio, sodium bicarbonate 45 parts be dissolved in water formed saturated solution, slowly add in above-mentioned stainless steel stirred vessel, the pH value of product is regulated to be neutral 7, namely the multi-usage fruits and vegetables cleaning agent for dinnerware of surfactant-free of the present invention is formed, by being finished product after container filling.Finished product is used for the ground such as restaurant, hotel, family and uses.
More than operate and carry out all at normal temperatures.
All raw materials all adopt food grade materials above.
More than to invention has been exemplary description; obvious realization of the present invention is not subject to the restrictions described above; as long as have employed the various improvement that technical solution of the present invention is carried out; or design of the present invention and technical scheme directly applied to other occasion, all in protection scope of the present invention without to improve.
Claims (4)
1. a making method for the multi-usage fruits and vegetables cleaning agent for dinnerware of surfactant-free, is characterized in that, comprise the following steps:
Step one, according to mass ratio successively by pure water 400-700 part, EDTA-2Na1-5 part, citric acid 8-35 part, sodium tartrate 3-8 part, carboxymethyl cellulose 0.5-2 part stirring and dissolving in a kettle.;
Step 2, continues to stir by Sumizyme MP 8-30 part, lipase 5-25 part, amylase 7-28 part, cellulase 5-25 in mass ratio successively in aforesaid reaction vessel;
Step 3, add plant extraction liquid in mass ratio, wherein onions extracting liquid 30-700 part, garlic extract 25-70 part, ginger extract 20-90 part, black tea extract 50-120 part, Chinese honey locust extracting solution 60-200 part, timbol extracting solution 60-250 part, continue to stir in aforesaid reaction vessel;
Step 4, gets sodium hydroxide 8-40 part in mass ratio, sodium bicarbonate 20-70 part is dissolved in water and forms saturated solution, slowly add afterwards in aforesaid reaction vessel, regulate the pH value of product be neutrality 7.
2. the making method of the multi-usage fruits and vegetables cleaning agent for dinnerware of a kind of surfactant-free according to claim 1, is characterized in that, described carboxymethyl cellulose is food grade, and the viscosity of its 2% solution is greater than 1200mPas; The vigor of described Sumizyme MP, amylase, cellulase, lipase is all greater than 2.5 ten thousand units (Da), pH value is 8-9.
3. a multi-usage fruits and vegetables cleaning agent for dinnerware for surfactant-free, is characterized in that, comprises pure water, association complex, compound enzymic preparation, anti-deposition agent, compound washing auxiliary agent, composite plant extraction liquid, is composited by above Multiple components; Wherein,
EDTA-2Na, sodium tartrate is utilized to form association complex;
Utilize carboxymethyl cellulose for anti-deposition agent;
Utilize one or more composition compound enzymic preparations of Sumizyme MP, lipase, amylase, cellulase;
Utilize citric acid and sodium bicarbonate and sodium hydroxide to form compound washing auxiliary agent, utilize in citric acid and sodium hydroxide simultaneously and improve product washing ability with the sequestering action of rear formation;
Utilize the arbitrary combination composition composite plant extract liquid in onions extracting liquid, garlic extract, ginger extract, black tea extract, Chinese honey locust extracting solution, Seed of Chinese Soapberry Fruit peel extract.
4. the multi-usage fruits and vegetables cleaning agent for dinnerware of a kind of surfactant-free according to claim 3, is characterized in that, each composition comprised in it is in mass ratio:
Pure water: 400-700 part;
EDTA-2Na:1-5 part;
Citric acid: 8-35 part;
Sodium tartrate: 3-8 part;
Carboxymethyl cellulose: 0.5-2 part;
Sumizyme MP: 8-30 part;
Lipase: 5-25 part;
Amylase: 7-28 part;
Cellulase: 5-25 part;
Onions extracting liquid: 30-700 part;
Garlic extract: 25-70 part;
Ginger extract: 20-90 part;
Black tea extract: 50-120 part;
Chinese honey locust extracting solution: 60-200 part;
Timbol extracting solution: 60-250 part;
Sodium hydroxide: 8-40 part;
Sodium bicarbonate: 20-70 part.
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Cited By (14)
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CN105483730A (en) * | 2015-12-14 | 2016-04-13 | 华南理工大学 | Neutral environment-friendly metal oil removal and scale removal cleaning fluid and preparation method thereof |
CN105543022A (en) * | 2016-02-22 | 2016-05-04 | 苏州锐耐洁电子科技新材料有限公司 | Fruit and vegetable pesticide degradation cleaning agent |
CN105533399A (en) * | 2015-12-10 | 2016-05-04 | 北京弘宝源生物科技有限公司 | Method for both degrading remaining pesticides in fruits and vegetables and keeping fresh |
CN105733850A (en) * | 2016-03-21 | 2016-07-06 | 陈国丰 | Multifunctional cleaning liquid and preparation method thereof |
CN106336959A (en) * | 2016-08-26 | 2017-01-18 | 广州市加茜亚化妆品有限公司 | Natural active washing composition and preparation method thereof |
CN107216955A (en) * | 2017-06-15 | 2017-09-29 | 郴州市芝草农业科技开发有限公司 | A kind of detergent for hand-washing fruits and vegetables |
CN107236600A (en) * | 2017-05-26 | 2017-10-10 | 安徽肤彩生物科技有限公司 | A kind of sterilizing skin-protective powdery liquid detergent |
CN107299007A (en) * | 2016-04-15 | 2017-10-27 | 苏州昆蓝生物科技有限公司 | A kind of biological fruit-vegetable cleaning agent and preparation method |
CN107418762A (en) * | 2017-06-15 | 2017-12-01 | 郴州市芝草农业科技开发有限公司 | A kind of fruits and vegetables detergent |
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CN109965189A (en) * | 2019-04-23 | 2019-07-05 | 深圳前海千水生物科技有限公司 | A kind of plant complex enzyme pesticide scavenger |
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CN105483730B (en) * | 2015-12-14 | 2018-06-22 | 华南理工大学 | A kind of neutrality environment protection metal degreasing descales cleaning solution and preparation method thereof |
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