CN104430377A - Suspoemulsion for chrysanthemum - Google Patents
Suspoemulsion for chrysanthemum Download PDFInfo
- Publication number
- CN104430377A CN104430377A CN201410630363.3A CN201410630363A CN104430377A CN 104430377 A CN104430377 A CN 104430377A CN 201410630363 A CN201410630363 A CN 201410630363A CN 104430377 A CN104430377 A CN 104430377A
- Authority
- CN
- China
- Prior art keywords
- suspension emulsion
- allicin
- difenoconazole
- chrysanthemum
- suspoemulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000007516 Chrysanthemum Nutrition 0.000 title claims abstract description 28
- 239000004548 suspo-emulsion Substances 0.000 title abstract 7
- 244000189548 Chrysanthemum x morifolium Species 0.000 title description 21
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 35
- JDLKFOPOAOFWQN-VIFPVBQESA-N Allicin Natural products C=CCS[S@](=O)CC=C JDLKFOPOAOFWQN-VIFPVBQESA-N 0.000 claims abstract description 29
- JDLKFOPOAOFWQN-UHFFFAOYSA-N allicin Chemical compound C=CCSS(=O)CC=C JDLKFOPOAOFWQN-UHFFFAOYSA-N 0.000 claims abstract description 29
- 235000010081 allicin Nutrition 0.000 claims abstract description 29
- 239000005760 Difenoconazole Substances 0.000 claims abstract description 28
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 claims abstract description 28
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims abstract description 23
- 240000003377 Shepherdia canadensis Species 0.000 claims abstract description 12
- 235000018324 Shepherdia canadensis Nutrition 0.000 claims abstract description 12
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 12
- 239000005011 phenolic resin Substances 0.000 claims abstract description 12
- 239000000843 powder Substances 0.000 claims abstract description 12
- 239000004480 active ingredient Substances 0.000 claims abstract description 11
- 241000723353 Chrysanthemum Species 0.000 claims abstract 8
- 239000000839 emulsion Substances 0.000 claims description 33
- 239000000725 suspension Substances 0.000 claims description 33
- 239000002253 acid Substances 0.000 claims description 12
- 150000007513 acids Chemical class 0.000 claims description 11
- 238000004821 distillation Methods 0.000 claims description 11
- 239000002994 raw material Substances 0.000 claims description 11
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000008367 deionised water Substances 0.000 claims description 9
- 229910021641 deionized water Inorganic materials 0.000 claims description 9
- 238000005507 spraying Methods 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 10
- 230000002195 synergetic effect Effects 0.000 abstract description 6
- 230000002045 lasting effect Effects 0.000 abstract description 3
- -1 alkyl naphthalene sulfonate Chemical compound 0.000 abstract 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 235000003441 saturated fatty acids Nutrition 0.000 abstract 1
- 150000004671 saturated fatty acids Chemical class 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 17
- 239000000575 pesticide Substances 0.000 description 10
- 239000007921 spray Substances 0.000 description 9
- 240000002234 Allium sativum Species 0.000 description 6
- 239000002131 composite material Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 235000004611 garlic Nutrition 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 241000234282 Allium Species 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 201000010099 disease Diseases 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000008686 ergosterol biosynthesis Effects 0.000 description 2
- FRXSZNDVFUDTIR-UHFFFAOYSA-N 6-methoxy-1,2,3,4-tetrahydroquinoline Chemical compound N1CCCC2=CC(OC)=CC=C21 FRXSZNDVFUDTIR-UHFFFAOYSA-N 0.000 description 1
- 241000235349 Ascomycota Species 0.000 description 1
- 241000221198 Basidiomycota Species 0.000 description 1
- 235000009604 Chrysanthemum X morifolium Nutrition 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 206010020772 Hypertension Diseases 0.000 description 1
- 241000234280 Liliaceae Species 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 208000029078 coronary artery disease Diseases 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000004438 eyesight Effects 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 235000013402 health food Nutrition 0.000 description 1
- 235000008216 herbs Nutrition 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000000447 pesticide residue Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000002560 therapeutic procedure Methods 0.000 description 1
Abstract
The invention relates to a suspoemulsion for chrysanthemum. The suspoemulsion is used for preventing and treating chrysanthemum anthracnose, the active ingredients of the suspoemulsion refer to difenoconazole and allicin, and the aids refer to alkyl naphthalene sulfonate, soapberry powder, methylbenzene, phosphate polyoxyethylene nonyl phenol, C10-20 saturated fatty acids, phenolic resins and diethylene glycol. The suspoemulsion disclosed by the invention has an excellent effect of preventing and treating the chrysanthemum anthracnose. The suspoemulsion has a good synergistic effect on the chrysanthemum anthracnose by utilizing difenoconazole and allicin, the effect of preventing and treating the chrysanthemum anthracnose is effectively enhanced, and the suspoemulsion is fast in effectiveness and long in lasting period and does not influence non-target crops.
Description
Technical field
The present invention relates to a kind of suspension emulsion for chrysanthemum, be specifically related to a kind of suspension emulsion for preventing and treating chrysanthemum anthracnose, its active ingredient is Difenoconazole and allicin, belongs to technical field of pesticide.
Background technology
The functions such as chrysanthemum has diseases prevention, cures the disease, keeps healthy, appreciation, chrysanthemum is used as medicine with a long history in China, there is dispelling wind, heat-clearing, improving eyesight, detoxicating functions, chrysanthemum and preparation thereof can treat headache, dizzy, the disease such as hot eyes, treatment sore, pyogenic infections, virus flu, hypertension, high fat of blood, coronary heart disease, are the health food liked of people and desirable medicine.Meanwhile, chrysanthemum is again one of China's bulk medicinal materials, is also one of important outlet medicinal material kind.Chrysanthemum morifolium artificial cultivation is the trend of the times of Producing medicinal herbs, and the raw-material high-quality of traditional Chinese medicine, safety in production are the prerequisites of the modernization of Chinese medicine.Only have some traditional Chinese medicinal materials assortments of a few countries artificial cultivation such as Japan, the U.S., Korea S and Southeast Asia abroad, but the current artificial cultivation traditional Chinese medicinal materials assortment of China reaches kind more than 300, accounts for about 2/3 of more than the 500 kind of parts of generic medicinal plants circulated in China's medicinal material market.China has more than 600 traditional Chinese medicine planting base, and cultivated area has reached more than 600 ten thousand mu.But in recent years, China mainland traditional Chinese medicine export volume only accounts for about 10% of global trade amount, main cause is that the understable and medicinal material Pesticide Residues of raw material active ingredient or content of beary metal exceed standard.
Difenoconazole is a kind of pathogen ergosterol biosynthesis inhibitor, acts on the interruption of ergosterol synthesis in phytopathogen thalline, and then shows as strong bacteriostasis.This medicament disinfecting spectrum is wide, the lasting period long, have excellent bacteriostatic activity to the fungi of sac fungi, imperfect fungus and Basidiomycetes, goes out excellent prevention, treatment and eradicant action at variable rate technology; To crop and Environmental security.
Allicin (Allicin) is a kind of organosulfur compound extracted from the bulb (garlic) of Liliaceae allium garlic (Allium Sativum), is also present in onion and other alliums.Formal name used at school GIUCOSinoate.Pale yellow oily liquid body.Boiling point 80-85 DEG C (0.2kPa), relative density 1.112(20/4 DEG C), index of refraction 1.561.Be dissolved in ethanol, chloroform or ether.Solvability 2.5% (quality) (10 DEG C) in water, its pH value of water solution is 6.5, has grease sediment to be formed time standing.With ethanol, ether and benzene can dissolve each other.Unstable to thermokalite, acid is stablized.By being present in the bulb of liliaceous plant garlic, under large allinase effect, transform generation by the garlic aminoacid existed.Also be present in the bulb of green onion.Have strong large garlic odour, taste is peppery.
In the real process of agricultural production, the problem that pest control the most easily produces is the generation of pest resistance to insecticide.Different cultivars composition carries out composite, is to prevent and treat the very common method of resistant insect.Heterogeneity is carried out composite, according to practical application effect judge certain composite be synergy, add and or antagonism.
Summary of the invention
For the problems referred to above, the invention provides a kind of suspension emulsion for chrysanthemum, the present invention is a kind of suspension emulsion for preventing and treating chrysanthemum anthracnose, and its active ingredient is Difenoconazole and allicin, and instant effect of the present invention, holding effect are long, to non-target crop safety.
Technical scheme of the present invention is as follows:
For a suspension emulsion for chrysanthemum, described suspension emulsion is for preventing and treating chrysanthemum anthracnose, and active ingredient is Difenoconazole and allicin, and auxiliary agent is alkylnaphthalene sulfonate, soapberry powder, toluene, thermally coupled distillation columns, C
10-20saturated fat acids, phenolic resins, diethylene glycol (DEG).
Further, each raw material components of the present invention is by weight percentage:
Difenoconazole 15%-40%, allicin 0.1%-1%, alkylnaphthalene sulfonate 5%-10%, soapberry powder 5%-10%, toluene 1%-5%, thermally coupled distillation columns 5%-10%, C
10-20saturated fat acids 0.1%-0.5%, phenolic resins 0.1%-0.5%, diethylene glycol (DEG) 1%-5%, deionized water add to 100%.
Further, each raw material components of the present invention is by weight percentage:
Difenoconazole 20%-35%, allicin 0.1%-1%, alkylnaphthalene sulfonate 6%-9%, soapberry powder 6%-9%, toluene 2%-4%, thermally coupled distillation columns 6%-9%, C
10-20saturated fat acids 0.2%-0.4%, phenolic resins 0.2%-0.4%, diethylene glycol (DEG) 2%-4%, deionized water add to 100%.
Further, each raw material components of the present invention is by weight percentage:
Difenoconazole 19.5%, allicin 0.5%, alkylnaphthalene sulfonate 6%, soapberry powder 6%, toluene 4%, thermally coupled distillation columns 6%, C
10-20saturated fat acids 0.4%, phenolic resins 0.3%, diethylene glycol (DEG) 2.4%, deionized water add to 100%.
Suspension emulsion of the present invention is for dispenser period of preventing and treating chrysanthemum anthracnose being morbidity early stage; Annual spraying times is 1 or 2 time; Active ingredient dosage is 10 grams/ha-50 grams/ha, and preferably, dosage is 15 grams/ha.
The present invention compared to existing technology tool has the following advantages:
(1) have synergistic effect, sterilization adds protective effect, and its effect is not the simple superposition of each composition activity, but has synergistic effect significantly;
(2) times for spraying is few, and drug cost is low;
(3) generation of resistance is slowed down, good to crop safety, meet the security requirement of pesticidal preparations;
(4) the present invention effectively enhances the effect of the prevention and therapy to chrysanthemum anthracnose, instant effect, and the lasting period is long, on non-Target crops without impact.
Embodiment
Further describe the present invention below in conjunction with specific embodiment, advantage and disadvantage of the present invention will be more clear along with description.But embodiment is only exemplary, does not form any restriction to scope of the present invention.It will be understood by those skilled in the art that and can modify to the details of technical solution of the present invention and form or replace down without departing from the spirit and scope of the present invention, but these amendments and replacement all fall within the scope of protection of the present invention.
Embodiment 1
20% Difenoconazole and allicin suspension emulsion
Each raw material components is by weight percentage:
Difenoconazole 19.5%
Allicin 0.5%
Alkylnaphthalene sulfonate 6%
Soapberry powder 6%
Toluene 4%
Thermally coupled distillation columns 6%
C
10-20saturated fat acids 0.4%
Phenolic resins 0.3%
Diethylene glycol (DEG) 2.4%
Deionized water adds to 100%.
By above-mentioned each composition application conventional pesticide process technology, the suspension emulsion goods being applicable to agriculturally using made.In the present embodiment, the co-toxicity coefficient of Difenoconazole and allicin is 265.7.
The suspension emulsion that the embodiment of the present invention 1 obtains is used for preventing and treating chrysanthemum anthracnose, the dispenser of chrysanthemum anthracnose their early stage, active ingredient dosage is 15 grams/ha, sprays 2 times, and after secondary medicine, the control efficiency of 7 days, 14 days and 30 days is respectively 87.6%, 89.1%, 92.3%.25% Difenoconazole missible oil is by 20 grams/ha of spray pesticides 2 times, and after secondary medicine, the control efficiency of 7 days, 14 days and 30 days is respectively 70.6%, 74.6%, 65.8%.0.3% allicin aqua is by 2000 times of spray pesticides 2 times, and after secondary medicine, the control efficiency of 7 days, 14 days and 30 days is respectively 34.1%, 36.5%, 32.5%.Difenoconazole and the composite rear synergistic effect of allicin are obvious, to the preventive effect of anthracnose significantly better than single dose.
Embodiment 2
30% Difenoconazole and allicin suspension emulsion
Each raw material components is by weight percentage:
Difenoconazole 29.9%
Allicin 0.1%
Alkylnaphthalene sulfonate 7%
Soapberry powder 8%
Toluene 2%
Thermally coupled distillation columns 9%
C
10-20saturated fat acids 0.3%
Phenolic resins 0.4%
Diethylene glycol (DEG) 2%
Deionized water adds to 100%.
By above-mentioned each composition application conventional pesticide process technology, the suspension emulsion preparation being applicable to agriculturally using made.In the present embodiment, the co-toxicity coefficient of Difenoconazole and allicin is 205.84.
The suspension emulsion that the embodiment of the present invention 2 obtains is used for preventing and treating chrysanthemum anthracnose, the dispenser of chrysanthemum anthracnose their early stage, active ingredient dosage is 20 grams/ha, sprays 2 times, and after secondary medicine, the control efficiency of 7 days, 14 days and 30 days is respectively 85.6%, 87.3%, 90.5%.25% Difenoconazole missible oil is by 20 grams/ha of spray pesticides 2 times, and after secondary medicine, the control efficiency of 7 days, 14 days and 30 days is respectively 70.6%, 74.6%, 65.8%.0.3% allicin aqua is by 2000 times of spray pesticides 2 times, and after secondary medicine, the control efficiency of 7 days, 14 days and 30 days is respectively 34.1%, 36.5%, 32.5%.Difenoconazole and the composite rear synergistic effect of allicin are obvious, to the preventive effect of anthracnose significantly better than single dose.
Embodiment 3
16% Difenoconazole and allicin suspension emulsion
Each raw material components is by weight percentage:
Difenoconazole 15%
Allicin 1%
Alkylnaphthalene sulfonate 9%
Soapberry powder 7%
Toluene 4%
Thermally coupled distillation columns 5%
C
10-20saturated fat acids 0.1%
Phenolic resins 0.3%
Diethylene glycol (DEG) 4%
Deionized water adds to 100%.
By above-mentioned each composition application conventional pesticide process technology, the suspension emulsion goods being applicable to agriculturally using made.In the present embodiment, the co-toxicity coefficient of Difenoconazole and allicin is 175.61.
The suspension emulsion that the embodiment of the present invention 3 obtains is used for preventing and treating chrysanthemum anthracnose, the dispenser of chrysanthemum anthracnose their early stage, active ingredient dosage is 10 grams/ha, sprays 2 times, and after secondary medicine, the control efficiency of 7 days, 14 days and 30 days is respectively 83.8%, 85.7%, 89.1%.25% Difenoconazole missible oil is by 20 grams/ha of spray pesticides 2 times, and after secondary medicine, the control efficiency of 7 days, 14 days and 30 days is respectively 70.6%, 74.6%, 65.8%.0.3% allicin aqua is by 2000 times of spray pesticides 2 times, and after secondary medicine, the control efficiency of 7 days, 14 days and 30 days is respectively 34.1%, 36.5%, 32.5%.Difenoconazole and the composite rear synergistic effect of allicin are obvious, to the preventive effect of anthracnose significantly better than single dose.
Claims (8)
1. for a suspension emulsion for chrysanthemum, it is characterized in that, described suspension emulsion is for preventing and treating chrysanthemum anthracnose, and active ingredient is Difenoconazole and allicin, and auxiliary agent is alkylnaphthalene sulfonate, soapberry powder, toluene, thermally coupled distillation columns, C
10-20saturated fat acids, phenolic resins, diethylene glycol (DEG).
2. suspension emulsion according to claim 1, is characterized in that, in described suspension emulsion, each raw material components is by weight percentage:
Difenoconazole 15%-40%, allicin 0.1%-1%, alkylnaphthalene sulfonate 5%-10%, soapberry powder 5%-10%, toluene 1%-5%, thermally coupled distillation columns 5%-10%, C
10-20saturated fat acids 0.1%-0.5%, phenolic resins 0.1%-0.5%, diethylene glycol (DEG) 1%-5%, deionized water add to 100%.
3. suspension emulsion according to claim 2, is characterized in that, in described suspension emulsion, each raw material components is by weight percentage:
Difenoconazole 20%-35%, allicin 0.1%-1%, alkylnaphthalene sulfonate 6%-9%, soapberry powder 6%-9%, toluene 2%-4%, thermally coupled distillation columns 6%-9%, C
10-20saturated fat acids 0.2%-0.4%, phenolic resins 0.2%-0.4%, diethylene glycol (DEG) 2%-4%, deionized water add to 100%.
4. suspension emulsion according to claim 3, is characterized in that, in described suspension emulsion, each raw material components is by weight percentage:
Difenoconazole 19.5%, allicin 0.5%, alkylnaphthalene sulfonate 6%, soapberry powder 6%, toluene 4%, thermally coupled distillation columns 6%, C
10-20saturated fat acids 0.4%, phenolic resins 0.3%, diethylene glycol (DEG) 2.4%, deionized water add to 100%.
5. the suspension emulsion according to any one of claim 1-4, is characterized in that, described suspension emulsion is for dispenser period of preventing and treating chrysanthemum anthracnose being morbidity early stage.
6. suspension emulsion according to claim 5, is characterized in that, the annual spraying times of described suspension emulsion is 1 or 2 time.
7. suspension emulsion according to claim 6, is characterized in that, in described suspension emulsion, active ingredient dosage is 10 grams/ha-50 grams/ha.
8. suspension emulsion according to claim 7, is characterized in that, described suspension emulsion dosage is 15 grams/ha.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410630363.3A CN104430377B (en) | 2014-11-11 | 2014-11-11 | A kind of suspension emulsion for chrysanthemum |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410630363.3A CN104430377B (en) | 2014-11-11 | 2014-11-11 | A kind of suspension emulsion for chrysanthemum |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104430377A true CN104430377A (en) | 2015-03-25 |
| CN104430377B CN104430377B (en) | 2016-08-24 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410630363.3A Active CN104430377B (en) | 2014-11-11 | 2014-11-11 | A kind of suspension emulsion for chrysanthemum |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104430377B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102388874A (en) * | 2011-09-30 | 2012-03-28 | 杨凌农科大无公害农药研究服务中心 | Eugenol and allicin compounded agent and application thereof |
| CN102726415A (en) * | 2012-06-19 | 2012-10-17 | 河南省大地农化有限责任公司 | Allicin-containing prevention and treatment pesticide for crop plant diseases |
-
2014
- 2014-11-11 CN CN201410630363.3A patent/CN104430377B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102388874A (en) * | 2011-09-30 | 2012-03-28 | 杨凌农科大无公害农药研究服务中心 | Eugenol and allicin compounded agent and application thereof |
| CN102726415A (en) * | 2012-06-19 | 2012-10-17 | 河南省大地农化有限责任公司 | Allicin-containing prevention and treatment pesticide for crop plant diseases |
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| Publication number | Publication date |
|---|---|
| CN104430377B (en) | 2016-08-24 |
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Effective date of registration: 20160622 Address after: 266109, No. 111, sunny road, Chengyang District, Shandong, Qingdao Applicant after: JINAN CAVIN BIOTECHNOLOGY CO., LTD. Address before: 250001 Shandong Province, Ji'nan City District Court building 2303 No. 288 Applicant before: JINAN XINQIDIAN MEDICINE SCIENCE & TECHNOLOGY CO., LTD. |
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Inventor after: Dong Jinpeng Inventor before: Sun Bo Inventor before: Sun Qian Inventor before: Mu Kexiao Inventor before: Hao Aihua Inventor before: Wang Mengmeng |
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Effective date of registration: 20170721 Address after: 300000, 8-2-502, Hongqiao District, Tianjin Patentee after: Dong Jinpeng Address before: 266109, No. 111, sunny road, Chengyang District, Shandong, Qingdao Patentee before: Qingdao Qingzhi Enterprise Management Consulting Co., Ltd. |
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Effective date of registration: 20181126 Address after: 409100 First Floor of Litangba Building, Nanbin Street, Shizhu Tujia Autonomous County, Chongqing Patentee after: Shizhu Tujia Autonomous County Balong Agricultural Development Co., Ltd. Address before: 300000 Fengmeili 8-2-502, Hongqiao District, Tianjin Patentee before: Dong Jinpeng |
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