CN104387408A - 六甲基六羟基六元瓜环-稀土加合物及合成方法和应用 - Google Patents
六甲基六羟基六元瓜环-稀土加合物及合成方法和应用 Download PDFInfo
- Publication number
- CN104387408A CN104387408A CN201410511917.8A CN201410511917A CN104387408A CN 104387408 A CN104387408 A CN 104387408A CN 201410511917 A CN201410511917 A CN 201410511917A CN 104387408 A CN104387408 A CN 104387408A
- Authority
- CN
- China
- Prior art keywords
- rare earth
- hexahydroxy
- hexamethyl
- hhq
- hexa
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052761 rare earth metal Inorganic materials 0.000 title claims abstract description 67
- 238000010189 synthetic method Methods 0.000 title claims description 13
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 31
- YKYOUMDCQGMQQO-UHFFFAOYSA-L cadmium dichloride Chemical compound Cl[Cd]Cl YKYOUMDCQGMQQO-UHFFFAOYSA-L 0.000 claims abstract description 21
- 239000007787 solid Substances 0.000 claims abstract description 20
- 238000000926 separation method Methods 0.000 claims abstract description 15
- -1 rare earth ions Chemical class 0.000 claims abstract description 14
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 9
- 229910052693 Europium Inorganic materials 0.000 claims abstract description 9
- 229910052779 Neodymium Inorganic materials 0.000 claims abstract description 9
- 229910052777 Praseodymium Inorganic materials 0.000 claims abstract description 9
- 229910052772 Samarium Inorganic materials 0.000 claims abstract description 9
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract description 9
- 230000007935 neutral effect Effects 0.000 claims abstract description 5
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical group N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 claims description 49
- 241000219112 Cucumis Species 0.000 claims description 19
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 claims description 19
- 239000013078 crystal Substances 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 8
- 229910052691 Erbium Inorganic materials 0.000 claims description 8
- 229910052689 Holmium Inorganic materials 0.000 claims description 8
- 229910052765 Lutetium Inorganic materials 0.000 claims description 8
- 229910052771 Terbium Inorganic materials 0.000 claims description 8
- 229910052775 Thulium Inorganic materials 0.000 claims description 8
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 7
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 6
- 239000012153 distilled water Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 11
- 239000007864 aqueous solution Substances 0.000 abstract description 3
- MSBXTPRURXJCPF-DQWIULQBSA-N cucurbit[6]uril Chemical compound N1([C@@H]2[C@@H]3N(C1=O)CN1[C@@H]4[C@@H]5N(C1=O)CN1[C@@H]6[C@@H]7N(C1=O)CN1[C@@H]8[C@@H]9N(C1=O)CN([C@H]1N(C%10=O)CN9C(=O)N8CN7C(=O)N6CN5C(=O)N4CN3C(=O)N2C2)C3=O)CN4C(=O)N5[C@@H]6[C@H]4N2C(=O)N6CN%10[C@H]1N3C5 MSBXTPRURXJCPF-DQWIULQBSA-N 0.000 abstract 7
- UYRHHBXYXSYGHA-UHFFFAOYSA-N 2-heptyl-4-quinolone Chemical compound C1=CC=C2NC(CCCCCCC)=CC(=O)C2=C1 UYRHHBXYXSYGHA-UHFFFAOYSA-N 0.000 description 11
- 230000000694 effects Effects 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 238000000605 extraction Methods 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 229910021645 metal ion Inorganic materials 0.000 description 4
- 229910002651 NO3 Inorganic materials 0.000 description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000001338 self-assembly Methods 0.000 description 3
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- XIEPJMXMMWZAAV-UHFFFAOYSA-N cadmium nitrate Inorganic materials [Cd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XIEPJMXMMWZAAV-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000004255 ion exchange chromatography Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- NMHMNPHRMNGLLB-UHFFFAOYSA-N phloretic acid Chemical compound OC(=O)CCC1=CC=C(O)C=C1 NMHMNPHRMNGLLB-UHFFFAOYSA-N 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001941 electron spectroscopy Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001640 fractional crystallisation Methods 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000001455 metallic ions Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000013110 organic ligand Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/003—Compounds containing elements of Groups 3 or 13 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B59/00—Obtaining rare earth metals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410511917.8A CN104387408B (zh) | 2014-09-29 | 2014-09-29 | 六甲基六羟基六元瓜环-稀土加合物及合成方法和应用 |
Applications Claiming Priority (1)
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---|---|---|---|
CN201410511917.8A CN104387408B (zh) | 2014-09-29 | 2014-09-29 | 六甲基六羟基六元瓜环-稀土加合物及合成方法和应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104387408A true CN104387408A (zh) | 2015-03-04 |
CN104387408B CN104387408B (zh) | 2016-04-13 |
Family
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CN201410511917.8A Active CN104387408B (zh) | 2014-09-29 | 2014-09-29 | 六甲基六羟基六元瓜环-稀土加合物及合成方法和应用 |
Country Status (1)
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CN (1) | CN104387408B (zh) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103951687A (zh) * | 2014-05-14 | 2014-07-30 | 贵州大学 | 邻位四甲基六元瓜环-稀土加合物及合成方法和应用 |
CN103965229A (zh) * | 2014-04-17 | 2014-08-06 | 贵州大学 | 邻位四甲基六元瓜环-稀土超分子聚合物及合成方法和应用 |
CN103992340A (zh) * | 2014-05-28 | 2014-08-20 | 贵州大学 | 单取代六甲基六元瓜环-稀土加合物及合成方法和应用 |
-
2014
- 2014-09-29 CN CN201410511917.8A patent/CN104387408B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103965229A (zh) * | 2014-04-17 | 2014-08-06 | 贵州大学 | 邻位四甲基六元瓜环-稀土超分子聚合物及合成方法和应用 |
CN103951687A (zh) * | 2014-05-14 | 2014-07-30 | 贵州大学 | 邻位四甲基六元瓜环-稀土加合物及合成方法和应用 |
CN103992340A (zh) * | 2014-05-28 | 2014-08-20 | 贵州大学 | 单取代六甲基六元瓜环-稀土加合物及合成方法和应用 |
Non-Patent Citations (1)
Title |
---|
倪新龙等: "功能性单甲基取代六元瓜环的合成及其晶体结构", 《全国第十四届大环化学里第六届超分子化学学术研讨会论文专辑》 * |
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Publication number | Publication date |
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CN104387408B (zh) | 2016-04-13 |
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Effective date of registration: 20201203 Address after: No. 13, Youcheng Road, Pingma Town, Tiandong County, Baise City, Guangxi Zhuang Autonomous Region Patentee after: GUANGXI TIANDONG INDUSTRIAL INVESTMENT DEVELOPMENT Co.,Ltd. Address before: 550025 Huaxi, Guiyang, Guizhou University (North) Technology Department Patentee before: Guizhou University |
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Application publication date: 20150304 Assignee: GUANGXI JINHUA NEW MATERIAL TECHNOLOGY Co.,Ltd. Assignor: GUANGXI TIANDONG INDUSTRIAL INVESTMENT DEVELOPMENT Co.,Ltd. Contract record no.: X2023980048151 Denomination of invention: Hexamethylhexahydroxyhexamembered melon ring rare earth adduct and its synthesis method and application Granted publication date: 20160413 License type: Common License Record date: 20231123 |