CN104356496B - 一种抗静电和抗湿滑的橡塑发泡鞋底及其制备方法 - Google Patents

一种抗静电和抗湿滑的橡塑发泡鞋底及其制备方法 Download PDF

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CN104356496B
CN104356496B CN201410639415.3A CN201410639415A CN104356496B CN 104356496 B CN104356496 B CN 104356496B CN 201410639415 A CN201410639415 A CN 201410639415A CN 104356496 B CN104356496 B CN 104356496B
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罗显发
卢鑫
丁思博
郭彩莲
林荷香
林臭知
金校红
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Maotai Fujian New Material Technology Co ltd
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Abstract

本发明涉及有机高分子化合物技术领域，提供一种抗静电和抗湿滑的橡塑发泡鞋底及其制备方法，所述抗静电和抗湿滑的橡塑发泡鞋底，由下述组分按重量份原料制得：聚烯烃弹性体POE、丁腈橡胶、发泡剂、交联剂、氧化锌、硬脂酸锌、硬脂酸、耐磨剂、橡胶抗静电剂、纳米碳酸钙，经过密炼、开炼、造粒，再经一次射出成型，得到抗静电和抗湿滑的橡塑发泡鞋底，所述抗静电和抗湿滑的橡塑发泡鞋底的电阻率小于1兆欧，可以永久性的防静电，不受潮湿的坏境影响，并且具有比重小、高抗湿滑性能，特别适合在鞋底等方面应用。

Description

一种抗静电和抗湿滑的橡塑发泡鞋底及其制备方法
技术领域
本发明属于有机高分子化合物技术领域，特别涉及一种抗静电和抗湿滑的橡塑发泡鞋底的制备方法。
背景技术
高分子材料具有绝缘性，当其表面受到摩擦时,处于静止状态的电荷积聚而形成静电。当电荷积累到一定数量时,会造成电击。为了保障人身安全,在这种场合必须穿着能清除静电的抗静电鞋，尤其是医院手术室、高级试验室等重要工作场所。
目前国内一线品牌的成品鞋大都是采用橡胶鞋底，但近年来，随着人们生活水平的提高，人们对橡胶鞋底的一些特殊要求就凸显出来，橡胶鞋底比重大，穿着笨重，只能满足普通工作场所的要求，无法同时符合质轻、抗静电、抗湿滑性能等要求。
发明内容
本发明的目的在于提供一种制得具有电阻率小于1兆欧、永久性防静电、比重小、高抗湿滑性能等特点的抗静电和抗湿滑橡塑发泡鞋底，以及前述抗静电和抗湿滑橡塑发泡鞋底的制备方法。
为实现上述目的，本发明采取的解决方案为：一种抗静电和抗湿滑的橡塑发泡鞋底，由以下原料组成制得：聚烯烃弹性体POE、丁腈橡胶、发泡剂、交联剂、氧化锌、硬脂酸锌、硬脂酸、耐磨剂、橡胶抗静电剂、纳米碳酸钙。
进一步的是，各原料的重量份如下：
聚烯烃弹性体POE 50份
丁腈橡胶 25 - 45 份
发泡剂 3.6 - 5 份
交联剂 1.2 - 1.5份
氧化锌 1.5 - 2 份
硬脂酸锌 1.2 – 1.5 份
硬脂酸 1.3– 1.5 份
耐磨剂 1 - 3 份
橡胶抗静电剂 3 - 10 份
纳米碳酸钙 5- 12 份。
进一步优选的，各组分按下列重量份配置:
聚烯烃弹性体POE 50份
丁腈橡胶 30 - 35 份
发泡剂 4.2 - 4.5 份
交联剂 1.4 - 1.5份
氧化锌 1.7 份
硬脂酸锌 1.4 份
硬脂酸 1.5 份
耐磨剂 1.5 - 2 份
橡胶抗静电剂 4 - 6 份
纳米碳酸钙 8- 10 份。
进一步的是：所述聚烯烃弹性体POE的熔融温度不低于72度。
进一步的是：所述丁腈橡胶的丙烯腈含量高于32%。
进一步的是：所述发泡剂是发泡剂、微胶囊发泡剂的混合物。
进一步的是：所述交联剂至少包括DCP交联剂、BIBP交联剂中的一种。
进一步的是：所述橡胶抗静电剂至少包括聚醚-聚酰胺共聚物抗静电剂、离子键聚合物抗静电剂、聚氧乙烯醚类抗静电剂中的一种。
一种制备前述抗静电和抗湿滑橡塑发泡鞋底的制备方法：先将除了交联剂以及发泡剂之外的其他原料混合进行密炼，调整密炼温度控制为 98-101℃，保持 4-6min，然后加入架桥剂以及发泡剂，继续密炼升温，出料温度为117-120℃，密炼结束后进行开炼、造粒，得到抗静电和抗湿滑的橡塑发泡粒子，再经过射出机台一次射出成型，控制成型温度为180-185℃，时间为350-500秒，得到抗静电和抗湿滑的橡塑发泡鞋底。
通过采取前述技术方案，本发明具有如下有益效果：
1，本发明抗静电和抗湿滑的橡塑发泡鞋底的抗静电效果显著，可以永久性的防静电，不受潮湿的坏境影响，可以生产各种颜色的抗静电和抗湿滑的橡塑发泡鞋底，而且不使用有害表面活性剂，提高鞋底的环保性能。
2，本发明在提高材料抗静电性能的同时，保留了材料的质轻、高抗湿滑性能、尺寸稳定性好、综合力学性能好等特点，特别适合在鞋底等方面应用，有很好的市场前景。
具体实施方式
现结合具体实施例对本发明进一步说明。
实施例1：
本实施例中， 抗静电和抗湿滑的橡塑发泡鞋底由以下组分按重量份组成：
聚烯烃弹性体POE 0203 50份
丁腈橡胶NBR4975 35 份
发泡剂AC 2.1 份
微胶囊发泡剂 2.1 份
交联剂BIBP 1.5 份
氧化锌 1.7 份
硬脂酸锌 1.4 份
硬脂酸 1.5 份
耐磨剂FY-500 1.5 份
橡胶抗静电剂E-XCB 6 份
纳米碳酸钙 8 份。
步骤1：先将除了交联剂以及发泡剂之外的其他原料混合进行密炼，调整密炼温度控制为98℃，保持 6min，然后加入交联剂以及发泡剂，继续密炼升温，出料温度为119℃，密炼结束后进行开炼、造粒，得到抗静电和抗湿滑的橡塑发泡粒子；
步骤2：抗静电和抗湿滑的橡塑发泡粒子再经过射出机台一次射出成型，控制成型温度为180℃，时间为480秒，得到抗静电和抗湿滑的橡塑发泡鞋底。
上述制备得到的抗静电和抗湿滑橡塑发泡鞋底，密度0.41g/cm3，邵氏硬度61，DIN耐磨136 mm3，尺寸收缩0.9%，拉伸强度3.8MPa，撕裂强度16.7N/mm，动态止滑系数平滑干式1.11湿式0.83，静态止滑系数干式0.78湿式0.64，电阻率0.26MΩ。
实施例2：
本实施例中，一种抗静电和抗湿滑的橡塑发泡鞋底的制备方法与实施例1中的制备方法相同，所不同的是：
丁腈橡胶NBR 1401 40份、橡胶抗静电剂E-XCB 8份、纳米碳酸钙12份。
上述制备得到的抗静电和抗湿滑橡塑发泡鞋底，密度0.43g/cm3，邵氏硬度64，DIN耐磨172 mm3，尺寸收缩0.8%，拉伸强度3.7MPa，撕裂强度19.3N/mm，动态止滑系数平滑干式0.78湿式0.62，静态止滑系数干式0.60湿式0.51，电阻率1.5MΩ。
实施例3：
本实施例中，一种抗静电和抗湿滑的橡塑发泡鞋底的制备方法与实施例1中的制备方法相同，所不同的是：
POE 8450 50份、丁腈橡胶NBR DN003 25份、发泡剂AC 1.8份、微胶囊发泡剂1.8份、交联剂BIBP 1.2份、耐磨剂FY-500 3份、橡胶抗静电剂E-XCB 6份、聚醚-聚酰胺共聚物抗静电剂4份；
步骤1中的密炼温度100度、出料温度117度；步骤2中成型温度181度时间360秒。
上述制备得到的抗静电和抗湿滑橡塑发泡鞋底，密度0.43g/cm3，邵氏硬度67，DIN耐磨113 mm3，尺寸收缩1.1%，拉伸强度3.3MPa，撕裂强度13.8N/mm，动态止滑系数平滑干式0.61湿式0.50，静态止滑系数干式0.56湿式0.47，电阻率0.45MΩ。
实施例4：
本实施例中，一种抗静电和抗湿滑的橡塑发泡鞋底的制备方法与实施例1中的制备方法相同，所不同的是：
POE 8003 50份、丁腈橡胶NBR 3250 45份、发泡剂AC 2.5份、微胶囊发泡剂2.5份、耐磨剂AG-209 1份、橡胶抗静电剂E-XCB 3份、纳米碳酸钙5份；
步骤1中的密炼温度101度、出料温度120度；步骤2中的成型温度185度，时间500秒。
上述制备得到的抗静电和抗湿滑橡塑发泡鞋底，密度0.39g/cm3，邵氏硬度60，DIN耐磨147 mm3，尺寸收缩1.8%，拉伸强度4.2MPa，撕裂强度20.1N/mm，动态止滑系数平滑干式1.12湿式0.85，静态止滑系数干式0.80湿式0.68，电阻率7.9MΩ。
将上述实施例1 ～ 4 的数据整理后，得到如下表1（注：邵氏硬度A按照ISO7619：1997测试，DIN耐磨按照TM174：1994测试，尺寸收缩按照ISO 20873：2001测试，拉伸强度按照GB/T 10654-2001测试，撕裂强度按照GB/T 10808-2006测试，动态止滑系数按照TM144：2011测试，静态止滑系数按照F1677：2005测试，电阻率按照ISO 20344:2011测试）:
实施例 1 2 3 4
密度 (g/cm3) 0.41 0.43 0.43 0.39
邵氏硬度 61 64 67 60
DIN耐磨 (mm3) 136 172 113 147
尺寸收缩 (%) 0.9 0.8 1.1 1.8
拉伸强度(MPa) 3.8 3.7 3.3 4.2
撕裂强度(N/mm) 16.7 19.3 13.8 20.1
动态止滑系数(平滑干式) 1.11 0.78 0.61 1.12
动态止滑系数(平滑湿式) 0.83 0.62 0.50 0.85
静态止滑系数(干式) 0.78 0.60 0.56 0.80
静态止滑系数(湿式) 0.64 0.51 0.47 0.68
电阻率(MΩ ) 0.26 1.5 0.45 7.9
表1 ：实施例1～4制备的抗静电和抗湿滑橡塑发泡鞋底的性能参数对照表。
综上所述，按照本发明的抗静电和抗湿滑橡塑发泡鞋底的制备方法，制得的抗静电和抗湿滑的橡塑发泡鞋底获得电阻率小于1兆欧、永久性防静电、高抗湿滑性能等特点，并且具有优良尺寸稳定性好、综合力学性能好等特点，特别适合在鞋底等方面应用。
以上所记载，仅为利用本创作技术内容的实施例，任何熟悉本项技艺者运用本创作所做的修饰、变化，皆属本创作主张的专利范围，而不限于实施例所揭示者。

Claims (8)

1.一种抗静电和抗湿滑的橡塑发泡鞋底，其特征在于：由以下原料组成制得：
聚烯烃弹性体POE 50份
丁腈橡胶 25 - 45 份
发泡剂 3.6 - 5 份
交联剂 1.2 - 1.5份
氧化锌 1.5 - 2 份
硬脂酸锌 1.2 – 1.5 份
硬脂酸 1.3– 1.5 份
耐磨剂 1 - 3 份
橡胶抗静电剂 3 - 10 份
纳米碳酸钙 5- 12 份。
2.根据权利要求1所述的抗静电和抗湿滑的橡塑发泡鞋底，其特征在于：由以下组分按下列重量份原料制备而成:
聚烯烃弹性体POE 50份
丁腈橡胶 30 - 35 份
发泡剂 4.2 - 4.5 份
交联剂 1.4 - 1.5份
氧化锌 1.7 份
硬脂酸锌 1.4 份
硬脂酸 1.5 份
耐磨剂 1.5 - 2 份
橡胶抗静电剂 4 - 6 份
纳米碳酸钙 8- 10 份。
3.根据权利要求1所述抗静电和抗湿滑的橡塑发泡鞋底，其特征在于：所述聚烯烃弹性体POE的熔融温度不低于72度；所述丁腈橡胶的丙烯腈含量高于32%。
4.根据权利要求1所述抗静电和抗湿滑的橡塑发泡鞋底，其特征在于：所述发泡剂是AC发泡剂、微胶囊发泡剂的混合物；所述交联剂至少包括交联剂DCP、交联剂BIBP中的一种。
5.根据权利要求1所述抗静电和抗湿滑的橡塑发泡鞋底的制备方法，其特征在于：所述橡胶抗静电剂至少包括聚醚-聚酰胺共聚物抗静电剂、离子键聚合物抗静电剂、聚氧乙烯醚类抗静电剂中的一种。
6.一种制备权利要求1-5任一所述抗静电和抗湿滑的橡塑发泡鞋底的制备方法，其特征在于：包括如下步骤，
步骤1：制作抗静电和抗湿滑的橡塑发泡粒子，所述橡塑发泡粒子由以下原料组成制得：聚烯烃弹性体POE、丁腈橡胶、发泡剂、交联剂、氧化锌、硬脂酸锌、硬脂酸、耐磨剂、橡胶抗静电剂、纳米碳酸钙；
步骤2：将步骤1所得的抗静电和抗湿滑的橡塑发泡粒子经射出机台一次射出成型,制得所述抗静电和抗湿滑的橡塑发泡鞋底。
7.根据权利要求6所述抗静电和抗湿滑的橡塑发泡鞋底的制备方法，其特征在于：步骤1中是先将除了交联剂以及发泡剂之外的其他原料混合进行密炼，调整密炼温度控制为98-101℃，保持4-6min，然后加入架桥剂以及发泡剂，继续密炼升温，出料温度为117-120℃，密炼结束后进行开炼、造粒，得到抗静电和抗湿滑的橡塑发泡粒子。
8.根据权利要求6所述抗静电和抗湿滑的橡塑发泡鞋底的制备方法，其特征在于：步骤2中射出机台的成型温度为180-185℃，时间为350-500秒。
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