CN104351240B - A kind of composition containing cyfloxylate and application - Google Patents
A kind of composition containing cyfloxylate and application Download PDFInfo
- Publication number
- CN104351240B CN104351240B CN201410643741.1A CN201410643741A CN104351240B CN 104351240 B CN104351240 B CN 104351240B CN 201410643741 A CN201410643741 A CN 201410643741A CN 104351240 B CN104351240 B CN 104351240B
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- CN
- China
- Prior art keywords
- cyfloxylate
- composition containing
- macro tetrolide
- neopelex
- attapulgite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims abstract description 45
- 239000003120 macrolide antibiotic agent Substances 0.000 claims abstract description 38
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 9
- 239000004480 active ingredient Substances 0.000 claims abstract description 8
- 239000004563 wettable powder Substances 0.000 claims description 14
- 239000005995 Aluminium silicate Substances 0.000 claims description 13
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 13
- 235000012211 aluminium silicate Nutrition 0.000 claims description 13
- 229960000892 attapulgite Drugs 0.000 claims description 13
- 229910052791 calcium Inorganic materials 0.000 claims description 13
- 239000011575 calcium Substances 0.000 claims description 13
- 238000009472 formulation Methods 0.000 claims description 13
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 13
- 229910052625 palygorskite Inorganic materials 0.000 claims description 13
- 241000255967 Helicoverpa zea Species 0.000 claims description 9
- 241000346285 Ostrinia furnacalis Species 0.000 claims description 3
- 241000254173 Coleoptera Species 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 claims description 2
- 239000005946 Cypermethrin Substances 0.000 claims description 2
- 241000289763 Dasygaster padockina Species 0.000 claims description 2
- 241000258937 Hemiptera Species 0.000 claims description 2
- 241000255777 Lepidoptera Species 0.000 claims description 2
- 241000721451 Pectinophora gossypiella Species 0.000 claims description 2
- 241000255969 Pieris brassicae Species 0.000 claims description 2
- 235000013339 cereals Nutrition 0.000 claims description 2
- 229960005424 cypermethrin Drugs 0.000 claims description 2
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 claims description 2
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- 235000013311 vegetables Nutrition 0.000 claims description 2
- 241000254171 Curculionidae Species 0.000 claims 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- 241000238631 Hexapoda Species 0.000 claims 1
- 240000004658 Medicago sativa Species 0.000 claims 1
- 235000010624 Medicago sativa Nutrition 0.000 claims 1
- 235000013399 edible fruits Nutrition 0.000 claims 1
- 239000002917 insecticide Substances 0.000 abstract description 6
- 239000003905 agrochemical Substances 0.000 abstract description 4
- 238000013329 compounding Methods 0.000 abstract description 4
- 230000007423 decrease Effects 0.000 abstract description 3
- 239000003814 drug Substances 0.000 description 19
- 230000000694 effects Effects 0.000 description 11
- 230000002265 prevention Effects 0.000 description 10
- 238000005507 spraying Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- QQODLKZGRKWIFG-QSFXBCCZSA-N cyfluthrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-QSFXBCCZSA-N 0.000 description 5
- 229960001591 cyfluthrin Drugs 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000000375 suspending agent Substances 0.000 description 5
- 230000002195 synergetic effect Effects 0.000 description 5
- 238000007796 conventional method Methods 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 229940079593 drug Drugs 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 230000002045 lasting effect Effects 0.000 description 3
- 241000238876 Acari Species 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 206010018498 Goitre Diseases 0.000 description 1
- 241001508566 Hypera postica Species 0.000 description 1
- 241001508564 Hypera punctata Species 0.000 description 1
- 241000187392 Streptomyces griseus Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- -1 alpha-cyano-4-fluoro-3-phenoxy benzyl Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000000152 carbamate pesticide Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 201000003872 goiter Diseases 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000035772 mutation Effects 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 239000004562 water dispersible granule Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the technical field that agricultural chemical insecticide is compounding, a kind of composition containing cyfloxylate and application.Active ingredient is macro tetrolide, cyfloxylate.This compounded combination has effectively resisted the problem that pest resistance produces, the problem farthest alleviating current pest resistance to insecticide, thus decreases the consumption of agricultural chemicals, also alleviates the impact for environment.
Description
Technical field
The invention belongs to the technical field that agricultural chemical insecticide is compounding, a kind of composition containing cyfloxylate and
Application.
Background technology
Cyfloxylate
Hundred establish one's virtue；Cyfluthrin, hundred control chrysanthemum ester (RS) alpha-cyano-4-fluoro-3-phenoxy benzyl (1RS, 3RS;1RS,
3RS)-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid's ester.
[density] 1.27～1.28；[fusing point (DEG C)] 60(industrial goods)；[toxicity LD50 (mg/kg).
Rat acute LD50 of passing through mouth about 500, mouse 450.90 days feeding experiment action-less dose 125mg/kg feeds of rat.
Sterling is thickness, partially crystallizable amber grease.Having and tag and stomach poison function, the lasting period is long.
Macro tetrolide
By the antibiotic produced by the mutation of streptomyces griseus Liuyang with macrolide structure, for low toxicity, low-residual,
Can prevent and treat the broad spectrum acaricides of the multiple mites of various crop, prevention effect is good.The tetranychid of various crop there is good tagging
Effect, without interior absorption, medicament has lipophilicity, if to becoming mite to have efficiently, does not kill Predatory Mites, and evil mite is not likely to produce resistance, kills
Mite spectrum is relatively wide, the most effective to tetranychid, goitre mite.Compound with some organophosphors or carbamate pesticide, have significant synergistic effect.
Action of contace poison to evil mite, lasting period 7～14 days.
Physicochemical property: the mixture being made up of 5 components, four viable bacteria elements are main active component.Sterling is colourless
Prism-shaped crystallizes, fusing point 112 DEG C～113 DEG C.Be soluble in benzene, ethyl acetate, chloroform, ether, acetone, dissolve in ethanol, just oneself
Alkane etc. 50% solvent, water insoluble.To ultraviolet-sensitive, irradiating 2 days in the sun, decomposable asymmetric choice net 50% is with property percutaneous LDso > 2
000mg/kg.Proterties sterling is the crystallization of colourless prism-shaped.
Currently, with respect to the compounding of macro tetrolide and cyfloxylate it is not yet reported that.
Summary of the invention
It is an object of the invention to provide a kind of composition containing cyfloxylate and application, active ingredient is that Liuyang is mould
Element and cyfloxylate.This compounded combination has effectively resisted the problem that pest resistance produces, and farthest alleviates at present
The problem of pest resistance to insecticide, thus decrease the consumption of agricultural chemicals, also alleviate the impact for environment.
The technical scheme is that
A kind of composition containing cyfloxylate, active ingredient is macro tetrolide and cyfloxylate.
Wherein, the total weight percentage of described active ingredient is 1～90%.
As preferably, the total weight percentage of described active ingredient is 70～80%.
Wherein, the weight ratio of macro tetrolide and cyfloxylate is, cyfloxylate: macro tetrolide=1-5:3.
As preferably, the weight ratio of macro tetrolide and cyfloxylate is, cyfloxylate: macro tetrolide=3:3.
The composition containing cyfloxylate of the present invention, adds auxiliary agent and excipients, makes various preparation, including wettable
Property pulvis, suspending agent, water dispersible granules, aqueous emulsion or missible oil；It is preferably wettable powder.
The composition containing cyfloxylate of the present invention, its formulation is wettable powder, consisting of percentage by weight
Following component than meter:
Cyfloxylate: 1-50%
Macro tetrolide: 10-40%
Neopelex 2-6%,
Wooden calcium 5-10%,
White carbon 1-10%
K12 2-5%,
Attapulgite 1-2%,
Surplus is kaolin.
As preferably,
The composition containing cyfloxylate of the present invention, its formulation is wettable powder, consisting of percentage by weight
Following component than meter:
Cyfloxylate: 40%
Macro tetrolide: 40%
Neopelex 2%,
Wooden calcium 5%,
White carbon 1%
K12 2%,
Attapulgite 1%,
Surplus is kaolin.
As preferably,
The composition containing cyfloxylate of the present invention, its formulation is wettable powder, consisting of percentage by weight
Following component than meter:
Cyfloxylate: 50%
Macro tetrolide: 30%
Neopelex 6%,
Wooden calcium 5%,
White carbon 2%
K12 2%,
Attapulgite 2%,
Surplus is kaolin.
As preferably,
The composition containing cyfloxylate of the present invention, its formulation is wettable powder, consisting of percentage by weight
Following component than meter:
Cyfloxylate: 4%
Macro tetrolide: 12%
Neopelex 5%,
Wooden calcium 10%,
White carbon 10%
K12 5%,
Attapulgite 2%,
Surplus is kaolin.
As preferably,
The composition containing cyfloxylate of the present invention, its formulation is wettable powder, consisting of percentage by weight
Following component than meter:
Cyfloxylate: 40%
Macro tetrolide: 30%
Neopelex 4%,
Wooden calcium 8%,
White carbon 4%
K12 5%,
Attapulgite 1%,
Surplus is kaolin.
The composition containing cyfloxylate of the present invention, can prevent and treat cereal crop, cotton, really effectively for preventing and treating
Coleoptera, Semiptera, Homoptera and lepidoptera pest on tree and vegetables, specially prevents and treats bollworm, pink bollworm, cloverleaf
Weevil, Lay white butterfly, looper, little apple moth, cutworm, corn borer；It is particularly suited for preventing and treating bollworm.
The invention have the benefit that
Said composition is complex insecticidal composition, significantly enhances insecticidal effect, delays the generation of pest resistance to insecticide, should
Compounded combination effectively resisted pest resistance produce problem, the problem farthest alleviating current pest resistance to insecticide,
And expand effective active preventing and treating spectrum, and there is speed fast, the lasting period is long, and consumption is low, eco-friendly feature, thus decreases agriculture
The consumption of medicine, also alleviates the impact for environment.The prevention effect of the composition of the present invention is the best to preventing and treating bollworm, main
If by the result of the synergistic function between each component, meeting the trend of future society environmental protection.
Compound synergic research to the composition of the present invention, test uses bollworm to be used for testing.
The toxicity index of medicament and mixed co-toxicity coefficient (CTC value) is calculated according to the abundant method of Sun Yun.
The table 1 different ratio relation toxicity test result to bollworm
| Process | Co-toxicity coefficient |
| Cyfloxylate 1: macro tetrolide 3 | 200.1 |
| Cyfloxylate 3: macro tetrolide 3 | 427.2 |
| Cyfloxylate 4: macro tetrolide 3 | 416.5 |
| Cyfloxylate 5: macro tetrolide 3 | 407.3 |
| Cyfloxylate | |
| Macro tetrolide |
From table 1 it follows that cyfloxylate and macro tetrolide is compounding, there are the highest synergistic effect, especially fluorine
Cypermethrin: during macro tetrolide=3:3, synergistic effect becomes apparent from, and the good results are evident to bollworm.
Detailed description of the invention
Below by specific embodiment, technical scheme is described in detail.
Embodiment 1
The composition of 80% wettable powder
Cyfloxylate: 40%
Macro tetrolide: 40%
Neopelex 2%,
Wooden calcium 5%,
White carbon 1%
K12 2%,
Attapulgite 1%,
Surplus is kaolin.
Preparation method is the conventional method of this area.
It is watered 60 kilograms by every mu of medication amount of formulation and carries out even spraying.
This embodiment medicament be applied to prevent and treat bollworm:
Co-toxicity coefficient is: 427.2；
Being diluted with water spraying by 6000 times, after medicine, 7 days prevention effects are 99.8%, 40% macro tetrolide suspending agent dilution 2000
Times and 40% cyfluthrin dilute 2000 times, use with same method respectively, after medicine 7 days, prevention effect is respectively
71.2%, 70.2%, significant difference.
Embodiment 2
The composition of 80% wettable powder
Cyfloxylate: 50%,
Macro tetrolide: 30%,
Neopelex 6%,
Wooden calcium 5%,
White carbon 2%,
K12 2%,
Attapulgite 2%,
Surplus is kaolin.
Preparation method is the conventional method of this area.
It is watered 60 kilograms by every mu of medication amount of formulation and carries out even spraying.
This embodiment medicament be applied to prevent and treat corn borer:
Co-toxicity coefficient is: 407.3；
Being diluted with water spraying by 6000 times, after medicine, 7 days prevention effects are 97.8%, 30% macro tetrolide suspending agent dilution 2000
Times, 50% cyfluthrin water emulsion dilutes 4000 times, uses with same method respectively, after medicine 7 days, and prevention effect is respectively
70.1%, 73.2%, significant difference.
Embodiment 3
The composition of 16% wettable powder
Cyfloxylate: 4%
Macro tetrolide: 12%
Neopelex 5%,
Wooden calcium 10%,
White carbon 10%
K12 5%,
Attapulgite 2%,
Surplus is kaolin.
Preparation method is the conventional method of this area.
It is watered 60 kilograms by every mu of medication amount of formulation and carries out even spraying.
This embodiment medicament be applied to prevent and treat looper:
Co-toxicity coefficient is: 200.1；
Being diluted with water spraying by 4000 times, after medicine, 7 days prevention effects are 89.9%, 12% macro tetrolide suspending agent dilution 1000
Times and 4% cyfluthrin dilute 800 times, use with same method respectively, after medicine 7 days, prevention effect is respectively 62.5%,
70.6%, significant difference.
Embodiment 4
The composition of 70% wettable powder
Cyfloxylate: 40%
Macro tetrolide: 30%
Neopelex 4%,
Wooden calcium 8%,
White carbon 4%
K12 5%,
Attapulgite 1%,
Surplus is kaolin.
Preparation method is the conventional method of this area.
It is watered 60 kilograms by every mu of medication amount of formulation and carries out even spraying.
This embodiment medicament be applied to prevent and treat alfalfa weevil:
Co-toxicity coefficient is: 416.5；
Being diluted with water spraying by 6000 times, after medicine, 7 days prevention effects are 97.9%, 30% macro tetrolide suspending agent dilution 2000
Times and 40% cyfluthrin dilute 3000 times, use with same method respectively, after medicine 7 days, prevention effect is respectively
70.1%, 68.7%, significant difference.
Claims (10)
1. the composition containing cyfloxylate, active ingredient is macro tetrolide and cyfloxylate, macro tetrolide and fluorine
The weight ratio of cypermethrin is, cyfloxylate: macro tetrolide=1-5:3.
Composition containing cyfloxylate the most according to claim 1, the weight percent that described active ingredient is total contains
Amount is 1～90%.
Composition containing cyfloxylate the most according to claim 1, the weight percent that described active ingredient is total contains
Amount is 70～80%.
Composition containing cyfloxylate the most according to claim 1, macro tetrolide and the weight ratio of cyfloxylate
For, cyfloxylate: macro tetrolide=3:3.
Composition containing cyfloxylate the most according to claim 1, its formulation is wettable powder, consisting of press
The following component of percentage by weight meter:
Cyfloxylate: 40%
Macro tetrolide: 40%
Neopelex 2%,
Wooden calcium 5%,
White carbon 1%
K12 2%,
Attapulgite 1%,
Surplus is kaolin.
Composition containing cyfloxylate the most according to claim 1, its formulation is wettable powder, consisting of press
The following component of percentage by weight meter:
Cyfloxylate: 50%
Macro tetrolide: 30%
Neopelex 6%,
Wooden calcium 5%,
White carbon 2%
K12 2%,
Attapulgite 2%,
Surplus is kaolin.
Composition containing cyfloxylate the most according to claim 1, its formulation is wettable powder, consisting of press
The following component of percentage by weight meter:
Cyfloxylate: 4%
Macro tetrolide: 12%
Neopelex 5%,
Wooden calcium 10%,
White carbon 10%
K12 5%,
Attapulgite 2%,
Surplus is kaolin.
Composition containing cyfloxylate the most according to claim 1, its formulation is wettable powder, consisting of press
The following component of percentage by weight meter:
Cyfloxylate: 40%
Macro tetrolide: 30%
Neopelex 4%,
Wooden calcium 8%,
White carbon 4%
K12 5%,
Attapulgite 1%,
Surplus is kaolin.
Composition containing cyfloxylate the most according to claim 1 be used for preventing and treating cereal crop, cotton, fruit tree and
The application of coleoptera, Semiptera, Homoptera and lepidoptera pest on vegetables, described insect is bollworm, pink bollworm, lucerne
Mu leaf weevil, Lay white butterfly, looper, little apple moth, cutworm, corn borer.
Composition containing cyfloxylate the most according to claim 1 is for preventing and treating the application of bollworm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410643741.1A CN104351240B (en) | 2014-11-14 | 2014-11-14 | A kind of composition containing cyfloxylate and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410643741.1A CN104351240B (en) | 2014-11-14 | 2014-11-14 | A kind of composition containing cyfloxylate and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104351240A CN104351240A (en) | 2015-02-18 |
| CN104351240B true CN104351240B (en) | 2016-08-24 |
Family
ID=52518633
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410643741.1A Active CN104351240B (en) | 2014-11-14 | 2014-11-14 | A kind of composition containing cyfloxylate and application |
Country Status (1)
| Country | Link |
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| CN (1) | CN104351240B (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1038919A (en) * | 1988-07-02 | 1990-01-24 | 上海市农药研究所 | A kind of new liuyangmycin class complex preparation |
| CN1475115A (en) * | 2002-08-16 | 2004-02-18 | 张业生 | Pesticide for killing insect and acarid |
| CN1918995A (en) * | 2006-09-19 | 2007-02-28 | 华南农业大学 | Pesticides compounds of elliptone and cyfiuthrin and their use as pesticides |
| CN101406196A (en) * | 2008-11-28 | 2009-04-15 | 深圳诺普信农化股份有限公司 | Mite-killing composition containing active substance of tetronic acid |
| CN102084868A (en) * | 2011-03-15 | 2011-06-08 | 浙江农林大学 | Azadirachtin and cyfluthrin composite for preventive treatment on potato beetles |
| CN102696662A (en) * | 2012-06-18 | 2012-10-03 | 江苏春江农化有限公司 | Compound pesticidal composition containing cyfluthrin and thiamethoxam and application thereof |
-
2014
- 2014-11-14 CN CN201410643741.1A patent/CN104351240B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1038919A (en) * | 1988-07-02 | 1990-01-24 | 上海市农药研究所 | A kind of new liuyangmycin class complex preparation |
| CN1475115A (en) * | 2002-08-16 | 2004-02-18 | 张业生 | Pesticide for killing insect and acarid |
| CN1918995A (en) * | 2006-09-19 | 2007-02-28 | 华南农业大学 | Pesticides compounds of elliptone and cyfiuthrin and their use as pesticides |
| CN101406196A (en) * | 2008-11-28 | 2009-04-15 | 深圳诺普信农化股份有限公司 | Mite-killing composition containing active substance of tetronic acid |
| CN102084868A (en) * | 2011-03-15 | 2011-06-08 | 浙江农林大学 | Azadirachtin and cyfluthrin composite for preventive treatment on potato beetles |
| CN102696662A (en) * | 2012-06-18 | 2012-10-03 | 江苏春江农化有限公司 | Compound pesticidal composition containing cyfluthrin and thiamethoxam and application thereof |
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| Publication number | Publication date |
|---|---|
| CN104351240A (en) | 2015-02-18 |
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