CN104304299B - A kind of macro tetrolide and the water dispersible granules of Hexythiazox and application - Google Patents
A kind of macro tetrolide and the water dispersible granules of Hexythiazox and application Download PDFInfo
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- CN104304299B CN104304299B CN201410543910.4A CN201410543910A CN104304299B CN 104304299 B CN104304299 B CN 104304299B CN 201410543910 A CN201410543910 A CN 201410543910A CN 104304299 B CN104304299 B CN 104304299B
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- Prior art keywords
- hexythiazox
- macro tetrolide
- water dispersible
- dispersible granules
- tetrolide
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- XGWIJUOSCAQSSV-XHDPSFHLSA-N (S,S)-hexythiazox Chemical compound S([C@H]([C@@H]1C)C=2C=CC(Cl)=CC=2)C(=O)N1C(=O)NC1CCCCC1 XGWIJUOSCAQSSV-XHDPSFHLSA-N 0.000 title claims abstract description 52
- 239000005661 Hexythiazox Substances 0.000 title claims abstract description 52
- 239000003120 macrolide antibiotic agent Substances 0.000 title claims abstract description 50
- 239000004562 water dispersible granule Substances 0.000 title claims abstract description 14
- 239000004615 ingredient Substances 0.000 claims abstract description 5
- 241001161749 Stenchaetothrips biformis Species 0.000 claims description 5
- 208000000260 Warts Diseases 0.000 claims description 5
- 201000010153 skin papilloma Diseases 0.000 claims description 5
- 241000238631 Hexapoda Species 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000002270 dispersing agent Substances 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 235000013312 flour Nutrition 0.000 claims description 3
- 239000008233 hard water Substances 0.000 claims description 3
- 239000000080 wetting agent Substances 0.000 claims description 3
- 241000500437 Plutella xylostella Species 0.000 claims description 2
- 241001414989 Thysanoptera Species 0.000 claims description 2
- 239000003242 anti bacterial agent Substances 0.000 claims description 2
- 229940088710 antibiotic agent Drugs 0.000 claims description 2
- 235000013339 cereals Nutrition 0.000 claims description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims 2
- 150000002576 ketones Chemical class 0.000 claims 1
- 229930192474 thiophene Natural products 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 12
- 238000013329 compounding Methods 0.000 abstract description 7
- 230000002195 synergetic effect Effects 0.000 abstract description 5
- 239000002917 insecticide Substances 0.000 abstract description 4
- 239000003905 agrochemical Substances 0.000 abstract description 2
- 239000003814 drug Substances 0.000 description 15
- 230000000694 effects Effects 0.000 description 12
- 230000002265 prevention Effects 0.000 description 7
- 238000005507 spraying Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 235000015424 sodium Nutrition 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- -1 alkyl naphthalene sulfonic acid sodium salt Chemical compound 0.000 description 4
- 239000006071 cream Substances 0.000 description 4
- 241000238876 Acari Species 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 3
- 229920001400 block copolymer Polymers 0.000 description 3
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 231100000053 low toxicity Toxicity 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 239000000375 suspending agent Substances 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920000388 Polyphosphate Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 229960000892 attapulgite Drugs 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 2
- PMYUVOOOQDGQNW-UHFFFAOYSA-N hexasodium;trioxido(trioxidosilyloxy)silane Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] PMYUVOOOQDGQNW-UHFFFAOYSA-N 0.000 description 2
- 231100000194 ovacidal Toxicity 0.000 description 2
- 230000003151 ovacidal effect Effects 0.000 description 2
- 229910052625 palygorskite Inorganic materials 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 239000001205 polyphosphate Substances 0.000 description 2
- 235000011176 polyphosphates Nutrition 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 239000005739 Bordeaux mixture Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000488583 Panonychus ulmi Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- 241000187392 Streptomyces griseus Species 0.000 description 1
- JNVCSEDACVAATK-UHFFFAOYSA-L [Ca+2].[S-]SSS[S-] Chemical compound [Ca+2].[S-]SSS[S-] JNVCSEDACVAATK-UHFFFAOYSA-L 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000000152 carbamate pesticide Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- HAFJKKYURCIBBG-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid;sodium Chemical compound [Na].O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 HAFJKKYURCIBBG-UHFFFAOYSA-N 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000035772 mutation Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the technical field that agricultural chemical insecticide is compounding, a kind of macro tetrolide and the water dispersible granules of Hexythiazox and application.Said composition effective ingredient is macro tetrolide and Hexythiazox; wherein the weight ratio of macro tetrolide and Hexythiazox is, macro tetrolide: Hexythiazox=1:1 1:20, serves good synergistic function by compounding; reach the purpose of cover crop, and yield and quality can be improved.
Description
Technical field
The invention belongs to the water-dispersible of the technical field that agricultural chemical insecticide is compounding, a kind of macro tetrolide and Hexythiazox
Granule and application.
Background technology
Macro tetrolide
By the antibiotic produced by the mutation of streptomyces griseus Liuyang with macrolide structure, for low toxicity, low-residual,
Can prevent and treat the broad spectrum acaricides of the multiple mites of various crop, prevention effect is good.The tetranychid of various crop there is good tagging
Effect, without interior absorption, medicament has lipotropy, if to becoming demodicid mite to have efficiently, does not kill Predatory Mites, and evil demodicid mite is not likely to produce resistance, kills
Demodicid mite spectrum is relatively wide, the most effective to tetranychid, wart demodicid mite.Compound with some organophosphors or carbamate pesticide, have significant potentiation.
Action of contace poison to evil demodicid mite, lasting period 7～14 days.
Physicochemical property: the mixture being made up of 5 components, four viable bacteria elements are main active component.Sterling is colourless
Prism-shaped crystallizes, fusing point 112 DEG C～113 DEG C.Be soluble in benzene, ethyl acetate, chloroform, ether, acetone, dissolve in ethanol, just oneself
Alkane etc. 50% solvent, water insoluble.To ultraviolet-sensitive, irradiating 2 days in the sun, decomposable asymmetric choice net 50% is with property percutaneous LDso > 2
000mg/kg.Character sterling is the crystallization of colourless prism-shaped.
Hexythiazox
Former medicine is light yellow or white crystals, and fusing point 108～108.5 ° of C, during 20 ° of C, vapour pressure is 338.6 × 10-8Pa, water
Middle dissolubility is 0.5 mg/litre, and the dissolubility in the methanol of every 100 milligrams, hexane, acetone and other organic solvent is respectively
2.06 grams, 0.39 gram, 16.0 grams, preserve under 50 ° of C and do not decompose for 3 months.
If various plants evil demodicid mite is had strong ovicidal, kills the characteristic of children demodicid mite.Good to tetranychid preventive effect, to rust mite, wart demodicid mite
Preventive effect is poor.Can be mixed with the Multiple Pesticides such as Bordeaux mixture, lime sulfur.Based on action of contace poison, plant tissue is had well
Permeability, without interior absorption effect.Preventing and treating European red mite, if containing the phase of sending out children demodicid mite, when average every leaf has 3～4 demodicid mites, with 5%
Cream or 5% wettable powder 1500～2000 times of liquid are sprayed.Before results, 7d stops using.
To people, animal low toxicity, eye is had minimal irritation effect, to birds low toxicity, to Apis non-toxic reaction under constant, right
Natural enemy impact is the least, poisonous to Fish.If evil demodicid mite is had ovicidal, kills demodicid mite effect.
Currently, with respect to the compounding of macro tetrolide and Hexythiazox it is not yet reported that.
Summary of the invention
It is an object of the invention to provide a kind of has macro tetrolide and the water dispersible granules of Hexythiazox and application thereof, this combination
Thing effective ingredient is macro tetrolide and Hexythiazox, and wherein the weight ratio of macro tetrolide and Hexythiazox is, macro tetrolide: Hexythiazox=
1:1-1:20, serves good synergistic function by compounding, reaches the purpose of cover crop, and can improve yield
And quality.
The technical scheme is that
A kind of macro tetrolide and the water dispersible granules of Hexythiazox, effective ingredient is macro tetrolide and Hexythiazox, wherein Liuyang
The weight ratio of mycin and Hexythiazox is, macro tetrolide: Hexythiazox=1:1-1:20.
As preferably, the weight ratio of macro tetrolide and Hexythiazox is, macro tetrolide: Hexythiazox=1:5-1:10.
The total weight percentage of described effective ingredient is 16～40%.
The macro tetrolide of the present invention and the water dispersible granules of Hexythiazox, consisting of by weight percentage following group
Point:
Macro tetrolide 1-10%,
Hexythiazox 15-30%,
Hard water resistance dose of 3-4%；
Wetting agent 5-6%；
Dispersant 3-11%；
Disintegrating agent 9-14%；
Filler surplus.
Heretofore described hard water resistance dose is: in sodium tripolyphosphate, five polyphosphate sodiums, laminated crystal of sodium disilicate
Kind.
Heretofore described wetting agent is: alkyl naphthalene sulfonic acid sodium salt, sodium lauryl sulphate, alkylaryl polyoxyethylene
One or more in ether sulfate.
Heretofore described dispersant is: polyoxyethylene polyoxypropylene block copolymer, naphthalene sulfonic acid-formaldehyde condensation product sodium
One in salt.
Heretofore described disintegrating agent is: one or more in anhydrous sodium sulfate, carboxymethyl starch sodium.
Filler of the present invention is: the one in white carbon, attapulgite, Pulvis Talci, bentonite.
The macro tetrolide of the present invention and the water dispersible granules of Hexythiazox, be used for preventing and treating veterinary antibiotics, Folium Camelliae sinensis, cereal crops
Insect and evil demodicid mite, such as diamondback moth, thrips, flour mite, wart demodicid mite, be particularly suited for preventing and treating rice thrips.
The invention have the benefit that
Said composition is compound water dispersible granule compositions, has the feature of binary composition, significantly enhances effect,
Delaying the generation of pest resistance to insecticide, and expand effective active preventing and treating spectrum, wherein the weight ratio of macro tetrolide and Hexythiazox is, clear
Sun mycin: Hexythiazox=1:1-1:20, serves good synergistic function by compounding, reaches the purpose of cover crop,
And yield and quality can be improved.And then, decrease the consumption of pesticide, also alleviate the impact for environment, meet following society
The trend of meeting environmental protection, it is often more important that, this compounded combination has effectively resisted the problem that pest resistance produces, at utmost
The problem alleviating current pest resistance to insecticide.
Compound synergic research to the compositions of the present invention, test uses rice thrips.
The toxicity index of medicament and mixed co-toxicity coefficient (CTC value) is calculated according to the abundant method of Sun Yun.
The table 1 different ratio relation toxicity test result to rice thrips
| Process | Co-toxicity coefficient |
| Macro tetrolide 1: Hexythiazox 1 | 310.5 |
| Macro tetrolide 1: Hexythiazox 5 | 531.7 |
| Macro tetrolide 1: Hexythiazox 10 | 546.9 |
| Macro tetrolide 1: Hexythiazox 15 | 289.1 |
| Macro tetrolide 1: Hexythiazox 20 | 137.8 |
| Macro tetrolide | |
| Hexythiazox |
From table 1 it follows that macro tetrolide and Hexythiazox is compounding, there are the highest potentiation, especially Liuyang mould
Element: during Hexythiazox=1:5-1:10, synergistic effect becomes apparent from.
Detailed description of the invention
Below by specific embodiment, technical scheme is described in detail.
Embodiment 1
36% macro tetrolide and the compositions of Hexythiazox
Macro tetrolide 6%,
Hexythiazox 30%,
Five polyphosphate sodiums 4%；
Alkyl naphthalene sulfonic acid sodium salt 5%；
Polyoxyethylene polyoxypropylene block copolymer 5%；
Anhydrous sodium sulfate 9%；
Attapulgite surplus.
Preparation method is the conventional method of this area.
This embodiment medicament be applied to prevent and treat rice thrips:
Co-toxicity coefficient is: 532.9；
It is watered 60 kilograms by every mu of medication amount of formulation and carries out even spraying.
By 6000 times of dilute sprayings, after medicine, 7 days prevention effects are 99.6%, and 6% macro tetrolide suspending agent dilutes 500 times
Diluting 5000 times with 30% Hexythiazox cream, use with same method respectively, after medicine 7 days, prevention effect was respectively 80.2% He
74.5%, significant difference.
Embodiment 2
16.5% macro tetrolide and the compositions of Hexythiazox
Macro tetrolide 1.5%,
Hexythiazox 15%,
Sodium tripolyphosphate 4%；
Alkylaryl polyoxyethylene ether sulfate 6%；
Carboxymethyl starch sodium naphthalene sulfonic acid-formaldehyde condensation product sodium salt 11%；
Naphthalene sulfonic acid-formaldehyde condensation product sodium salt 10%；
White carbon surplus.
Preparation method is the conventional method of this area.
This embodiment medicament be applied to prevent and treat flour mite:
Co-toxicity coefficient is: 547.8；
It is watered 60 kilograms by every mu of medication amount of formulation and carries out even spraying.
By 4000 times of dilute sprayings, after medicine, 7 days prevention effects are 99.2%, 1.5% macro tetrolide suspending agent dilution
200 times and 15% Hexythiazox cream dilute 3000 times, use with same method respectively, after medicine 7 days, and prevention effect is respectively 80.6%
With 74.4%, significant difference.
Embodiment 3
21% macro tetrolide and the compositions of Hexythiazox
Macro tetrolide 1%,
Hexythiazox 20%,
Laminated crystal of sodium disilicate 3.5%；
Alkyl naphthalene sulfonic acid sodium salt 5%；
Polyoxyethylene polyoxypropylene block copolymer 10%；
Carboxymethyl starch sodium 14%；
Bentonite surplus.
Preparation method is the conventional method of this area.
This embodiment medicament is applied to prevent and treat wart demodicid mite:
Co-toxicity coefficient is: 140.4；
It is watered 60 kilograms by every mu of medication amount of formulation and carries out even spraying.
By 5000 times of dilute sprayings, after medicine, 7 days prevention effects are 96.0%, and 1% macro tetrolide suspending agent dilutes 100 times
Diluting 4000 times with 20% Hexythiazox cream, use with same method respectively, after medicine 7 days, prevention effect was respectively 82.2% He
79.8%, significant difference.
Claims (6)
1. macro tetrolide and a water dispersible granules for Hexythiazox, effective ingredient is macro tetrolide and Hexythiazox, and wherein Liuyang is mould
The weight ratio of element and Hexythiazox is, macro tetrolide: Hexythiazox=1:1-1:20.
Macro tetrolide the most according to claim 1 and the water dispersible granules of Hexythiazox, it is characterised in that macro tetrolide and thiophene
The weight ratio of demodicid mite ketone is, macro tetrolide: Hexythiazox=1:5-1:10.
Macro tetrolide the most according to claim 2 and the water dispersible granules of Hexythiazox, it is characterised in that described effective one-tenth
Dividing total weight percentage is 16～40%.
Macro tetrolide the most according to claim 3 and the water dispersible granules of Hexythiazox, it is characterised in that consisting of by weight
The following component of amount percentages:
Macro tetrolide 1-10%,
Hexythiazox 15-30%,
Hard water resistance dose of 3-4%；
Wetting agent 5-6%；
Dispersant 3-11%；
Disintegrating agent 9-14%；
Filler surplus.
The water dispersible granules of macro tetrolide the most according to claim 4 and Hexythiazox be used for preventing and treating veterinary antibiotics, Folium Camelliae sinensis,
The insect of cereal crops and evil demodicid mite, described insect and evil demodicid mite are diamondback moth, thrips, flour mite, wart demodicid mite.
The water dispersible granules of macro tetrolide the most according to claim 4 and Hexythiazox is used for preventing and treating rice thrips.
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| CN201410543910.4A CN104304299B (en) | 2014-10-15 | 2014-10-15 | A kind of macro tetrolide and the water dispersible granules of Hexythiazox and application |
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| CN104304299B true CN104304299B (en) | 2016-08-24 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1788569A (en) * | 2005-12-18 | 2006-06-21 | 刘起麟 | Preparation and uses of false proof highly-effective insecticide and bactericide |
| CN101743966A (en) * | 2009-12-29 | 2010-06-23 | 华南农业大学 | Mixed insecticide of tea saponin and acaricide |
| CN101984809A (en) * | 2010-07-22 | 2011-03-16 | 福建诺德生物科技有限责任公司 | Oil suspension preparation using resin-based vegetable oil as carrier and preparation method thereof |
-
2014
- 2014-10-15 CN CN201410543910.4A patent/CN104304299B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1788569A (en) * | 2005-12-18 | 2006-06-21 | 刘起麟 | Preparation and uses of false proof highly-effective insecticide and bactericide |
| CN101743966A (en) * | 2009-12-29 | 2010-06-23 | 华南农业大学 | Mixed insecticide of tea saponin and acaricide |
| CN101984809A (en) * | 2010-07-22 | 2011-03-16 | 福建诺德生物科技有限责任公司 | Oil suspension preparation using resin-based vegetable oil as carrier and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 2000倍噻螨酮与1000倍浏阳霉素搭配喷药3次对板栗红蜘蛛的防治效果最佳;郑庆伟;《农药应用科技》;20131116;第47页 * |
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| CN104304299A (en) | 2015-01-28 |
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