CN1918995A - Pesticides compounds of elliptone and cyfiuthrin and their use as pesticides - Google Patents
Pesticides compounds of elliptone and cyfiuthrin and their use as pesticides Download PDFInfo
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Abstract
The invention discloses a rotenone and alphamethrin pesticide composition and application in the pesticide domain, which comprises the following parts: 0.1-10.0% rotenone, 1.4-30.0% application and adjuvant. The invention can prepare missible oil agent, micro-emulsion agent, aqueous emulsion and wet powder agent, which displays wide prospect in the future.
Description
Technical field
The present invention relates to pesticide field, specifically, relate to the composition pesticide of a kind of rotenone and cyfloxylate and as the application of insecticide.
Background technology
In recent years, people more and more note the sustainable development of agricultural production and the coordination of human and environment, the inherent limitation that chemical pesticide exists becomes increasingly conspicuous, the research and development of environment amenable agricultural chemicals of new generation receives much attention, and the development biopesticide has become the important trend that ensures human health and agricultural sustainable development.But safety, biopesticide also exists drug effect performance slowly efficiently, and the biopesticide longevity of residure that cost has is shorter, and the insecticidal spectrum that has is narrower, and what have is subjected to shortcomings such as such environmental effects is bigger and is difficult to be accepted by most of peasant, is difficult to meet the needs of production.Cost is higher in addition also is the key factor of restriction biopesticide industry development.Therefore, the efficient chemical pesticide of biopesticide and low toxicity that should develop in harmony.The cost height, mechanism of action uniqueness, insecticidal effect biopesticide and cost slowly is lower, quick-acting, and the chemical pesticide that pesticide resistance is bigger rationally is mixed and has good research prospect.Being mixed of biopesticide finds new outlets both for old chemical pesticide kind, make new synthetic agricultural chemicals life-saving, delay or alleviate drug-fast generation and development, can enlarge biopesticide control spectrum again, improve its control efficiency, reduce the control cost, widen wide development space for the research and development of biopesticide.This has significance to the sustainable development of agricultural and the protection of environmental ecology.
Summary of the invention
The purpose of this invention is to provide and a kind ofly can effectively prevent and treat various pest, insect is difficult for developing immunity to drugs, and environment amenable is the composition pesticide of main active with rotenone and cyfloxylate.
Another object of the present invention provides above-mentioned composition pesticide as the application in the agricultural fungicides.
A kind of composition pesticide is made up of following component and percetage by weight: rotenone 0.1～10.0%, cyfloxylate 4.0～30.0%, surplus auxiliary agent.
In above-mentioned composition pesticide, composition pesticide can be prepared into cream preparation, and this moment, auxiliary agent was: solvent 25.0～93.0 weight %, emulsifier 1～25.0 weight %, cosolvent 0.1～5.0 weight %, stabilizing agent 0.1～5.0 weight %.Described solvent is one or more the mixture in dimethylbenzene, toluene, benzene, acetone, dimethyl formamide, methyl alcohol, ethanol, butanols, ethylene glycol or the acetonitrile; Described emulsifier is one or more the mixture in the multiple phenol polyethenoxy ether of benzyl, dibenzyl phenol APEO, the multiple phenol polyethenoxy base ether of α-Jia Jibianji, calcium dodecyl benzene sulfonate, styryl phenol APEO, farming breast 0201, farming breast 1602, Nongru-700, Tween-20, Tween-80, the alkylphenol polyoxyethylene phosphate; Described cosolvent is one or more the mixture in ethyl acetate, cyclohexanone, pyrrolidones, the dimethyl formamide; Described stabilizing agent is one or more the mixture in aminobenzoic acid, pyrogallic acid, paranitrobenzoic acid, castor oil, sudan black, the n-propyl gallate.
In above-mentioned composition pesticide, composition pesticide can be prepared into microemulsion, this moment, auxiliary agent was: emulsifier 0.1～60.0 weight %, solvent 0.1～40.0 weight %, cosolvent 0.1～5.0 weight %, stabilizing agent 0.1～10.0 weight %, antifreeze 0.1～5.0 weight %, water 0.1～90.0 weight %.Described emulsifier is one or more the mixture in alkyl two polyoxy vinyl sulfonic acid calcium salts, styryl phenol APEO, xenol APEO, polyoxyethylene phenylphenol ether, the triphenyl vinyl phenol oxirane nitranol salt; Described solvent is one or more the mixture in cyclohexanone, pyrrolidones, dimethyl formamide, dimethylbenzene, toluene, benzene, the cyclohexanol; Described cosolvent is one or more the mixture in pyrrolidones, ethyl acetate, dimethyl formamide, the cyclohexanone; Described stabilizing agent is aminobenzoic acid, pyrogallic acid, paranitrobenzoic acid, castor oil, sudan black, n-propyl gallate, 3-chloro-1, the mixture of one or more in 2-epoxychloropropane, butyl glycidyl ether, phenyl glycidyl ether, polyethylene glycol diglycidyl ether, the sorbitol; Described antifreeze is one or more the mixture in ethylene glycol, propane diols, glycerine, polyethylene glycol, the sorbierite.
In above-mentioned composition pesticide, composition pesticide can be prepared into aqueous emulsion, this moment, auxiliary agent was: solvent 0.1～50.0 weight %, emulsifier 0.1～60.0 weight %, dispersant 0.1～5.0 weight %, cosolvent 0.1～5.0 weight %, antifreeze 0.1～5.0 weight %, water 0.1～90.0 weight %.Described solvent is one or more the mixture in dimethylbenzene, toluene, ethylene glycol, propane diols, polyethylene glycol, the N-chain alkyl pyrrolidones; Described cosolvent is one or more the mixture in ethyl acetate, cyclohexanone, pyrrolidones, the dimethyl formamide; Described emulsifier is alkyl polyglycol ether, alkyl phenyl polyglycol ether, polyoxyethylene sorbitol acid anhydride ester, polyoxyethylene fatty acid ester, 2,4,6-three (1-phenethyl) phenol gathers one or more the mixture in (20) ethylene glycol phosphate monoester, ethoxyquin alkyl phenylate, ethoxyquin alkyl ether, alkyl benzene calcium sulfonate, the oxirane-fatty acid primary amine condensation product; Described dispersant is polyvinyl alcohol or gum Arabic or its mixture; Described antifreeze is one or more the mixture in ethylene glycol, propane diols, glycerine, polyethylene glycol, the sorbierite.
In above-mentioned composition pesticide, composition pesticide can be prepared into wetting powder, this moment, auxiliary agent was: solvent 0.1～50.0 weight %, cosolvent 0.1～5.0 weight %, emulsifier 0.1～60.0 weight %, dispersant 0.1～5.0 weight %, antifreeze 0.1～5.0 weight %, thickener 0.1～5.0 weight %, filler 10.0～80.0 weight %, water 0.1～90.0 weight %.Described solvent is one or more the mixture in toluene, dimethylbenzene, ethylene glycol, propane diols, polyethylene glycol, the N-chain alkyl pyrrolidones; Described cosolvent is one or more the mixture in ethyl acetate, cyclohexanone, pyrrolidones, the dimethyl formamide; Described emulsifier is alkyl polyglycol ether, alkyl phenyl polyglycol ether, polyoxyethylene sorbitol acid anhydride ester, polyoxyethylene fatty acid ester, 2,4,6-three (1-phenethyl) phenol gathers one or more the mixture in (20) ethylene glycol phosphate monoester, ethoxyquin alkyl phenylate, ethoxyquin alkyl ether, alkyl benzene calcium sulfonate, the oxirane-fatty acid primary amine condensation product; Described dispersant is polyvinyl alcohol or gum Arabic or its mixture; Described antifreeze is one or more the mixture in ethylene glycol, propane diols, glycerine, polyethylene glycol, the sorbierite; Described thickener is one or more the mixture in sodium carboxymethylcellulose, polyvinyl alcohol, the polyvinylpyrrolidone; Described filler is one or more the mixture in ammonium salt, kaolin, clay, talcum, diatomite, imvite, silica, quartz, atlapulgite, calcite, the marble.
One of the active ingredient rotenone that has the composition of insecticidal activity as the present invention is from fabaceous Derris, extract in the Baptisia and have insecticidal active ingredient, its mechanism of action: act on the respiration inhibitor on the electron transport chain, mainly act on a certain composition between nadh dehydrogenase and the ubiquinone, and be partial to ubiquinone this on one side, the electron transport chain of insect cell is suppressed, thereby reduce the ATP level in the organism, finally make insect can not get the energy supply, drumble, paralysis and slowly dead.Rotenone as plant insecticide does not have overt toxicity or phyto toxicity to vertebrate, degrades in the environment rapidly, and the biologically active height, insecticidal spectrum is wider, and natural enemy is not had injury.
Another active ingredient cyfloxylate that has the composition of insecticidal activity as the present invention is the chrysanthemum ester class medicament of using always, and tool is tagged and stomach poison function, and the lasting period is long.Multiple lepidopterous larvae there is good result; Also can effectively prevent and treat some soil insect, insecticidal spectrum is wide, and effect rapidly; To the mammal low toxicity,, be applicable to crops such as vegetables, fruit tree, cotton, tea tree to crop safety.
Research object phyllotreta striolata as the pest of inventing is that insect frequent and that harm is serious is taken place in the brassicaceous vegetable field.Phyllotreta striolata is the special insect of a kind of habit, and its larva moves in underground, the root of harm seedling, and the imago feeding acrial part is got the food symptom and is and incises point-like, and kind the jump, the control difficulty.This worm fertility is strong, and fulminant requires high to the control medicament.
Compared with prior art, the present invention has following beneficial effect: the present invention is mixed fish Teng ketone and pyrethroid insecticides cyfloxylate, have good tagging and stomach poison function, can effectively prevent and treat vegetable-crop pest-insects such as various pest, especially phyllotreta striolata.Selected two kinds of hosts have different mechanism of action, and insect is difficult for developing immunity to drugs, and after being mixed obvious synergistic effect is arranged, and reduce the use cost of biopesticide, prolong agricultural chemicals service life.Selected medicament is environmental friendliness class agricultural chemicals, and is low to environmental selection pressure, applies to safety in the control of vegetable-crop pest-insect, holds effect, meets the needs that pollution-free vegetable produces.
Embodiment
Embodiment 1: prepare 4.1% rotenone cyfloxylate cream preparation
Insecticidal active ingredient percentage by weight (%) is: rotenone 0.1, cyfloxylate 4.0;
Each composition percentage by weight (%) of auxiliary agent is: solvent: dimethylbenzene 77.5; Emulsifier: farming breast 0,201 5.4, styryl phenol APEO 6.0; Cosolvent: ethyl acetate 5.4; Stabilizing agent: pyrogallic acid 1.6.
With above-mentioned weight ratio raw material be mixed the back make emulsifiable formulation preparation of insecticide with the missible oil processing method.
Embodiment 2: prepare 4.1% rotenone cyfloxylate microemulsion
Each active ingredient percentage by weight (%) of desinsection is: rotenone 0.1, cyfloxylate 4.0;
Each composition percentage by weight (%) of auxiliary agent is: solvent: toluene 3.2; Cosolvent: dimethyl formamide 0.5; Emulsifier: alkyl dioxy vinyl sulfonic acid calcium salt 5.5, polyoxyethylene phenylphenol ether 4.5; Stabilizing agent: polyethylene glycol diglycidyl ether 1.2, castor oil 0.7, n-propyl gallate 0.5; Antifreeze, propane diols 2.0, water 77.8;
The insecticide microemulsion is made with the microemulsion processing method in the raw material of the above-mentioned weight ratio back that is mixed.
Embodiment 3: prepare 4.1% rotenone cyfloxylate aqueous emulsion
Each active ingredient percentage by weight (%) of desinsection is: rotenone 0.1, cyfloxylate 4.0;
Each composition percentage by weight (%) of auxiliary agent is: solvent: dimethylbenzene 4.3; Cosolvent: ethyl acetate 0.7; Emulsifier: polyoxyethylene sorbitol acid anhydride ester 8.0; Dispersant: gum Arabic 2.0; Antifreeze, polyethylene glycol 2.0; Water 78.9;
The insecticide aqueous emulsion is made with the aqueous emulsion processing method in the raw material of the above-mentioned weight ratio back that is mixed.
Embodiment 4: prepare 4.1% rotenone cyfloxylate wetting powder
Each active ingredient percentage by weight (%) of desinsection is: rotenone 0.1, cyfloxylate 4.0;
Each composition percentage by weight (%) of auxiliary agent is: solvent: toluene: 5.0; Cosolvent: dimethyl formamide 0.5; Emulsifier: polyoxyethylene sorbitol acid anhydride ester 8.0; Dispersant: gum Arabic 2.0; Antifreeze: glycerine 2.0; Thickener: sodium carboxymethylcellulose 2.5; Filler: clay 15.0; Water 60.9;
The insecticide wetting powder is made with the wetting powder processing method in the raw material of the above-mentioned weight ratio back that is mixed.
Embodiment 5: prepare 9.0% rotenone cyfloxylate cream preparation
Each active ingredient percentage by weight (%) of desinsection is: rotenone 2.0, cyfloxylate 7.0;
Each composition percentage by weight (%) of auxiliary agent is: solvent: dimethylbenzene 77.5; Emulsifier: the multiple phenol polyethenoxy ether 5.6 of benzyl, farming breast 1,602 3.8, Tween-20 2.6; Cosolvent: dimethyl formamide 0.3; Stabilizing agent: aminobenzoic acid 1.2;
Emulsifiable formulation preparation of insecticide is made with traditional missible oil processing method in the raw material of the above-mentioned weight ratio back that is mixed.
Embodiment 6: prepare 9.0% rotenone cyfloxylate microemulsion
Each active ingredient percentage by weight (%) of desinsection is: rotenone 2.0, cyfloxylate 7.0;
Each composition percentage by weight of auxiliary agent is: solvent: toluene 7.0; Cosolvent: dimethyl formamide 0.7; Emulsifier: alkyl two polyoxy vinyl sulfonic acid calcium salts 2.3, styryl phenol APEO 8.6; Stabilizing agent: paranitrobenzoic acid 1.2, castor oil 2.0; Antifreeze: glycerine 1.8; Water 67.4;
The insecticide microemulsion is made with the microemulsion processing method in the raw material of the above-mentioned weight ratio back that is mixed.
Embodiment 7: prepare 9.0% rotenone cyfloxylate aqueous emulsion
Each active ingredient percentage by weight (%) of desinsection is: rotenone 2.0, cyfloxylate 7.0;
Each composition weight percentage of auxiliary agent: solvent: dimethylbenzene 6.5; Cosolvent: dimethyl formamide 1.3; Emulsifier: alkyl phenyl polyglycol ether 10.2, ethoxyquin alkyl phenylate 4.9; Antifreeze: polyethylene glycol 3.0; Dispersant: polyvinyl alcohol 3.2; Water 61.9.
The insecticide aqueous emulsion is made with the aqueous emulsion processing method in the raw material of the above-mentioned weight ratio back that is mixed.
Embodiment 8: prepare 9.0% rotenone cyfloxylate wetting powder
Each active ingredient percentage by weight (%) of desinsection is: rotenone 2.0, cyfloxylate 7.0;
Each composition percentage by weight (%) of auxiliary agent is: solvent: toluene 7.7; Cosolvent: ethyl acetate 1.0; Emulsifier: alkyl phenyl polyglycol ether 3.2, polyoxyethylene fatty acid ester 7.8; Dispersant: gum Arabic 1.6, polyvinyl alcohol 1.8; Antifreeze: ethylene glycol 3.0; Thickener: sodium carboxymethylcellulose 0.4; Filler: be stained with 7.8, diatomite 5.6; Water 51.1.
The insecticide wetting powder is made with traditional wetting powder processing method in the raw material of the above-mentioned weight ratio back that is mixed.
Embodiment 9: prepare 13.0% rotenone cyfloxylate cream preparation
Each active ingredient percentage by weight (%) of desinsection is: rotenone 3.0, cyfloxylate 10.0;
Each composition percentage by weight (%) of auxiliary agent is: solvent: dimethylbenzene 73.5; Emulsifier: dibenzyl phenol APEO 8.0, farming breast 02014.0; Cosolvent: dimethyl formamide 0.5; Stabilizing agent: pyrogallic acid 0.5, castor oil 0.5;
Emulsifiable formulation preparation of insecticide is made with traditional missible oil processing method in the raw material of the above-mentioned weight ratio back that is mixed.
Embodiment 10: prepare 13.0% rotenone cyfloxylate microemulsion
Each active ingredient percentage by weight (%) of desinsection is: rotenone 3.0, cyfloxylate 10.0;
Each composition percentage by weight of auxiliary agent is: solvent: dimethylbenzene 6.8; Cosolvent: ethyl acetate 0.7; Emulsifier: xenol APEO 11.0, polyoxyethylene phenylphenol ether 5.0; Stabilizing agent: butyl glycidyl ether 3.0; Antifreeze: polyethylene glycol 2.0; Water 58.5.
The insecticide microemulsion is made with the microemulsion processing method in the raw material of the above-mentioned weight ratio back that is mixed.
Embodiment 11: prepare 13.0% rotenone cyfloxylate aqueous emulsion
Each active ingredient percentage by weight (%) of desinsection is: rotenone 3.0, cyfloxylate 10.0;
Each composition weight percentage of auxiliary agent: solvent: toluene 7.0; Cosolvent: dimethyl formamide 0.7; Emulsifier: xenol APEO 11.0, alkyl sulfonic acid calcium 5.0; Antifreeze: propane diols 3.0; Dispersant: polyvinyl alcohol 2.0, gum Arabic 2.0; Water 56.3;
The insecticide aqueous emulsion is made with the aqueous emulsion processing method in the raw material of the above-mentioned weight ratio back that is mixed.
Embodiment 12: prepare 13.0% rotenone cyfloxylate wetting powder
Each active ingredient percentage by weight (%) of desinsection is: rotenone 3.0, cyfloxylate 10.0;
Each composition percentage by weight (%) of auxiliary agent is: solvent: dimethylbenzene 8.0; Cosolvent: dimethyl formamide 1.0; Emulsifier: dibenzyl phenol APEO 4.0, alkylphenol polyoxyethylene phosphate 8.0; Dispersant: polyvinyl alcohol 2.2; Dispersant: gum Arabic 3.5; Antifreeze: glycerine 3.0; Thickener: polyvinyl alcohol 0.5; Filler: kaolin 12.0; Water 44.8.
The insecticide wetting powder is made with traditional wetting powder processing method in the raw material of the above-mentioned weight ratio back that is mixed.
Embodiment 13: prepare 24.0% rotenone cyfloxylate cream preparation
Each active ingredient percentage by weight (%) of desinsection is: rotenone 4.0, cyfloxylate 20.0;
Each composition weight percentage in the auxiliary agent: solvent: dimethylbenzene 57.2; Cosolvent: ethyl acetate 3.6, emulsifier: calcium dodecyl benzene sulfonate 8.9, agricultural newborn 0201:4.3; Stabilizing agent: sudan black 2.0.
With above-mentioned weight ratio raw material be mixed the back make emulsifiable formulation preparation of insecticide with the missible oil processing method.
Embodiment 14: prepare 30.0% rotenone cyfloxylate cream preparation
Each active ingredient percentage by weight (%) of desinsection is: rotenone 5.0, cyfloxylate 25.0;
Each composition weight percentage in the auxiliary agent: solvent: dimethylbenzene 50.9; Cosolvent: ethyl acetate 3.2; Emulsifier: calcium dodecyl benzene sulfonate 8.6, Nongru-700 5.0; Stabilizing agent: sudan black 2.3;
With above-mentioned weight ratio raw material be mixed the back make emulsifiable formulation preparation of insecticide with the missible oil processing method.
Adopt conventional bioassay method test rotenone and the agent of cyfloxylate list and mixture virulence, and estimate its synergistic effect, instruct the phyllotreta striolata comprehensive regulation with co-toxicity coefficient to phyllotreta striolata.The concrete operations main points are described below:
Test example 1
Have the indoor virulence test of the composition of insecticidal activity to phyllotreta striolata
Soak leaf dish method: choose clean fresh cabbage leaves, make the smooth leaf dish (annotating: as far as possible avoid master pulse during punching) of diameter 2.0cm of card punch.The leaf dish floods in soup after 5 seconds and takes out, and it is In Shade, after treating that solvent volatilizees naturally, put into the dactylethrae of diameter 3cm, height 10cm and end sealing, simultaneously 10 phyllotreta striolata adults of etherization are put into dactylethrae, and tighten that gauze seals in case the phyllotreta striolata adult escapes with rubber band, wet towel is preserved moisture on the mouthpiece cover.Each dactylethrae is put two leaf dish.Every processing repeats for 4 times.Then dactylethrae is placed in the insectary (temperature: 26～28 ℃, relative moisture: 70～80%, illumination: 14h: 10h (L: D)).Record examination worm is doomed dead behind processing 24 and the 48h, and calculates its lethality and LC
50
The abundant method of employing Sun Yun is calculated co-toxicity coefficient, and the best proportioning of definite mixture, promptly calculates the method for (A+B) mixture co-toxicity with toxicity index
Co-toxicity coefficient is significantly greater than representing synergistic effect at 100 o'clock, near representing summation action at 100 o'clock, significantly less than representing antagonism at 100 o'clock.
Result of the test sees Table 1,2:
Table 1 rotenone, cyfloxylate is to phyllotreta striolata virulence result (24h)
| Medicament | Lethal concentration of 50 LC 50(mg.L -1) | Toxicity regression linear equation (y) | Correlation coefficient (r) | Lethal concentration of 50 LC 50(mg.L -1) |
| The rotenone cyfloxylate | 41.40 193.61 | Y＝2.7553+1.3882x Y＝1.4094+1.5701x | 0.9843 0.9965 | 21.61 134.37 |
Table 2 rotenone+cyfloxylate is mixed combination to the virulence co-toxicity coefficient measurement result (24h) of phyllotreta striolata
| Proportioning (rotenone: cyfloxylate v: v) | Toxicity regression linear equation (y) | Correlation coefficient (r) | LC 50 (mg.L -1) | Co-toxicity coefficient |
| 1∶20 9∶80 27∶140 3∶10 9∶20 27∶20 21∶20 9∶5 81∶20 | Y＝2.1959+1.3488x Y＝2.5025+1.2550x Y＝2.3737+1.4024x Y＝2.5279+1.3647x Y＝2.3105+1.4730x Y＝2.3545+1.4602x Y＝2.5780+1.3790x Y＝2.3232+1.5460x Y＝2.3590+1.6084x | 0.9932 0.9986 0.9951 0.9836 0.9966 0.9870 0.9820 0.9902 0.9856 | 119.95 97.73 74.60 64.78 66.96 64.82 57.06 53.87 43.85 | 148.72 166.96 198.32 204.89 175.50 157.80 152.58 133.35 129.12 |
As can be seen from Table 2, said composition under each proportioning to the co-toxicity coefficient (CTC) of phyllotreta striolata all obviously greater than 100, show to have significant synergies.When rotenone: to co-toxicity coefficient (CTC) maximum of phyllotreta striolata, its value is 204.89 during cyfloxylate=3: 10.
Test example 2
Mixture is to the field control effectiveness test of phyllotreta striolata
With four kinds of mixtures: 9.0% rotenone cyfloxylate missible oil (embodiment 5), 9.0% rotenone cyfloxylate microemulsion (embodiment 6), 9.0% rotenone cyfloxylate aqueous emulsion (embodiment 7), 9.0% rotenone cyfloxylate wetting powder (embodiment 8) carries out field control effectiveness test, prepare 9.0% rotenone emulsifiable solution and 9.0% cyfloxylate missible oil for the contrast medicament, establish the clear water blank.
Trial crops: leaf mustard (4～6 leaf phase), experimental plot randomized arrangement, every processing are established 4 repetitions, the reagent agent dilution is carried out routine with workers and peasants-16 type knapsack hand sprayer for 1000 times spray, evenly be sprayed on leave dual sides, the clear water of control plot spray equivalent.Should spray the medicine band all around in the test region earlier before the dispenser, in case adult escapes.Duration of test is fine day, and mean temperature of air is 28 ℃.Respectively at before the medicine and medicine one day after, the residual borer population alive of insect population cardinal sum of three days, seven days investigation phyllotreta striolatas, method is: 10 strain leaf mustard are randomly drawed in every sub-district, the investigation phyllotreta striolata borer population of living, preventive effect is calculated in the tabulation record.Result of the test sees Table 3.
Table 3 mixture is to phyllotreta striolata field efficacy result
| Handle | 1 day preventive effect behind the medicine | 3 days preventive effects behind the medicine | 7 days preventive effects behind the medicine |
| Rotenone cyfloxylate embodiment 5 embodiment 6 embodiment 7 embodiment 8 | 62.81％ 70.58％ 80.06％ 78.52％ 77.96％ 81.29％ | 50.93％ 59.64％ 91.25％ 90.03％ 87.79％ 92.67％ | 26.72％ 32.86％ 58.41％ 55.28％ 56.58％ 60.30％ |
Claims (10)
1, the composition pesticide of a kind of rotenone and cyfloxylate is characterized in that being made up of following component and percetage by weight: rotenone 0.1～10.0%, cyfloxylate 4.0～30.0%, surplus auxiliary agent.
2, composition pesticide according to claim 1 is characterized in that described auxiliary agent is: solvent 25.0～93.0 weight %, emulsifier 1～25.0 weight %, cosolvent 0.1～5.0 weight %, stabilizing agent 0.1～5.0 weight %.
3, composition pesticide according to claim 2 is characterized in that described solvent is one or more the mixture in dimethylbenzene, toluene, benzene, acetone, dimethyl formamide, methyl alcohol, ethanol, butanols, ethylene glycol or the acetonitrile; Described emulsifier is one or more the mixture in the multiple phenol polyethenoxy ether of benzyl, dibenzyl phenol APEO, the multiple phenol polyethenoxy base ether of α-Jia Jibianji, calcium dodecyl benzene sulfonate, styryl phenol APEO, farming breast 0201, farming breast 1602, Nongru-700, Tween-20, Tween-80, the alkylphenol polyoxyethylene phosphate; Described cosolvent is one or more the mixture in ethyl acetate, cyclohexanone, pyrrolidones, the dimethyl formamide; Described stabilizing agent is one or more the mixture in aminobenzoic acid, pyrogallic acid, paranitrobenzoic acid, castor oil, sudan black, the n-propyl gallate.
4, composition pesticide according to claim 1, it is characterized in that described auxiliary agent is: emulsifier 0.1～60.0 weight %, solvent 0.1～40.0 weight %, cosolvent 0.1～5.0 weight %, stabilizing agent 0.1～10.0 weight %, antifreeze 0.1～5.0 weight %, water 0.1～90.0 weight %.
5, composition pesticide according to claim 4 is characterized in that: described emulsifier is one or more the mixture in alkyl two polyoxy vinyl sulfonic acid calcium salts, styryl phenol APEO, xenol APEO, polyoxyethylene phenylphenol ether, the triphenyl vinyl phenol oxirane nitranol salt; Described solvent is one or more the mixture in cyclohexanone, pyrrolidones, dimethyl formamide, dimethylbenzene, toluene, benzene, the cyclohexanol; Described cosolvent is one or more the mixture in ethyl acetate, cyclohexanone, pyrrolidones, the dimethyl formamide; Described stabilizing agent is aminobenzoic acid, pyrogallic acid, paranitrobenzoic acid, castor oil, sudan black, n-propyl gallate, 3-chloro-1, the mixture of one or more in 2-epoxychloropropane, butyl glycidyl ether, phenyl glycidyl ether, polyethylene glycol diglycidyl ether, the sorbitol; Described antifreeze is one or more the mixture in ethylene glycol, propane diols, glycerine, polyethylene glycol, the sorbierite.
6, composition pesticide according to claim 1 is characterized in that described auxiliary agent is: solvent 0.1～50.0 weight %, cosolvent 0.1～5.0 weight %, emulsifier 0.1～60.0 weight %, dispersant 0.1～5.0 weight %, antifreeze 0.1～5.0 weight %, water 0.1～90.0 weight %.
7, composition pesticide according to claim 6 is characterized in that: described solvent is one or more the mixture in dimethylbenzene, toluene, ethylene glycol, propane diols, polyethylene glycol, the N-chain alkyl pyrrolidones; Described cosolvent is one or more the mixture in ethyl acetate, cyclohexanone, pyrrolidones, the dimethyl formamide; Described emulsifier is alkyl polyglycol ether, alkyl phenyl polyglycol ether, polyoxyethylene sorbitol acid anhydride ester, polyoxyethylene fatty acid ester, 2,4,6-three (1-phenethyl) phenol gathers one or more the mixture in (20) ethylene glycol phosphate monoester, ethoxyquin alkyl phenylate, ethoxyquin alkyl ether, alkyl benzene calcium sulfonate, the oxirane-fatty acid primary amine condensation product; Described dispersant is polyvinyl alcohol or gum Arabic or its mixture; Described antifreeze is one or more the mixture in ethylene glycol, propane diols, glycerine, polyethylene glycol, the sorbierite.
8, composition pesticide according to claim 1, it is characterized in that described auxiliary agent is: solvent 0.1～50.0 weight %, cosolvent 0.1～5.0 weight %, emulsifier 0.1～60.0 weight %, dispersant 0.1～5.0 weight %, antifreeze 0.1～5.0 weight %, thickener 0.1～5.0 weight %, filler 10.0～80.0 weight %, water 0.1～90.0 weight %.
9, composition pesticide according to claim 8 is characterized in that: described solvent is one or more the mixture in toluene, dimethylbenzene, ethylene glycol, propane diols, polyethylene glycol, the N-chain alkyl pyrrolidones; Described emulsifier is alkyl polyglycol ether, alkyl phenyl polyglycol ether, polyoxyethylene sorbitol acid anhydride ester, polyoxyethylene fatty acid ester, 2,4,6-three (1-phenethyl) phenol gathers one or more the mixture in (20) ethylene glycol phosphate monoester, ethoxyquin alkyl phenylate, ethoxyquin alkyl ether, alkyl benzene calcium sulfonate, the oxirane-fatty acid primary amine condensation product; Described dispersant is polyvinyl alcohol or gum Arabic or its mixture; Described antifreeze is one or more the mixture in ethylene glycol, propane diols, glycerine, polyethylene glycol, the sorbierite; Described thickener is one or more the mixture in sodium carboxymethylcellulose, polyvinyl alcohol, the polyvinylpyrrolidone; Described filler is one or more the mixture in ammonium salt, kaolin, clay, talcum, diatomite, imvite, silica, quartz, atlapulgite, calcite, the marble; Described cosolvent is one or more the mixture in ethyl acetate, cyclohexanone, pyrrolidones, the dimethyl formamide.
10, the described composition pesticide of claim 1 is as the application in the agricultural fungicides.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101222423A CN100399902C (en) | 2006-09-19 | 2006-09-19 | Pesticides compounds of elliptone and cyfiuthrin and their use as pesticides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101222423A CN100399902C (en) | 2006-09-19 | 2006-09-19 | Pesticides compounds of elliptone and cyfiuthrin and their use as pesticides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1918995A true CN1918995A (en) | 2007-02-28 |
| CN100399902C CN100399902C (en) | 2008-07-09 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006101222423A Expired - Fee Related CN100399902C (en) | 2006-09-19 | 2006-09-19 | Pesticides compounds of elliptone and cyfiuthrin and their use as pesticides |
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| CN (1) | CN100399902C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101341877B (en) * | 2007-07-11 | 2013-03-27 | 红塔烟草(集团)有限责任公司 | Pesticide preparation mixed with tubatoxin, pyrethroid and phoxim |
| CN104351240A (en) * | 2014-11-14 | 2015-02-18 | 济南新起点医药科技有限公司 | Cyfluthrin-containing composition and application thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2677223B1 (en) * | 1991-06-05 | 1997-06-06 | Jean Gueyne | INSECTICIDE COMPOSITION BASED ON ROTENONE, PARTICULARLY FOR THE TREATMENT OF HUMAN AND ANIMAL PESTS. |
| CN1107293A (en) * | 1994-02-23 | 1995-08-30 | 郑树勤 | Multifunctional emulsified insecticide |
-
2006
- 2006-09-19 CN CNB2006101222423A patent/CN100399902C/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101341877B (en) * | 2007-07-11 | 2013-03-27 | 红塔烟草(集团)有限责任公司 | Pesticide preparation mixed with tubatoxin, pyrethroid and phoxim |
| CN104351240A (en) * | 2014-11-14 | 2015-02-18 | 济南新起点医药科技有限公司 | Cyfluthrin-containing composition and application thereof |
| CN104351240B (en) * | 2014-11-14 | 2016-08-24 | 青岛青知企业管理咨询有限公司 | A kind of composition containing cyfloxylate and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100399902C (en) | 2008-07-09 |
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