CN104327426A - 可与硅橡胶粘接的氟橡胶配方 - Google Patents

可与硅橡胶粘接的氟橡胶配方 Download PDF

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CN104327426A
CN104327426A CN201410574673.8A CN201410574673A CN104327426A CN 104327426 A CN104327426 A CN 104327426A CN 201410574673 A CN201410574673 A CN 201410574673A CN 104327426 A CN104327426 A CN 104327426A
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李群峰
李海华
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HAINING JIACHENG RUBBER Co Ltd
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HAINING JIACHENG RUBBER Co Ltd
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
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    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/222—Magnesia, i.e. magnesium oxide

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Abstract

本发明公开了一种可与硅橡胶热硫化粘接的氟橡胶配方，该配方中各原料组份的重量份数为：三元氟橡胶100份，双酚AF1.2-1.8份，苄基三苯基氯化磷BPP0.2-0.4份，氢氧化钙3-6份，活性氧化镁3-8份，三烯丙基异氰脲酸酯TAIC0.2-0.8份，2,5-二甲基-2,5-双过氧化叔丁基己烷0.2-0.8份，炭黑15-30份。本配方制作的氟橡胶与硅橡胶热硫化粘接后，粘接力可达1.5KN/m，工艺简单，成本低廉。

Description

可与硅橡胶粘接的氟橡胶配方
技术领域
本发明属于橡胶制造技术领域，涉及一种成本低廉、性能优异的氟橡胶配方。
背景技术
涡轮增压，是一种利用内燃机运作所产生的废气驱动空气压缩机的技术，可增加进入内燃机的空气流量，从而使机器效率提升。发动机在采用了增压技术后，还能提高燃油经济性和降低尾气排。而随着涡轮增压技术的进步以及涡轮柴油机市场的发展，提高了对这些系统部件所采用材料性能的要求。涡轮增压胶管用于输送空气和废气，通常要承受200 摄氏度以上的高温，为此材料需要具备耐高温、耐油、耐燃油，而且要求各层之间的粘接力好。涡轮增压器软管一般使用VMQ 有机硅胶，并配以含氟弹性体衬里（FVMQ 含氟有机硅或FKM 碳氟化合物），涡轮增压器软管是汽车发动机中要求最苛刻、成本最高的软管之一。
目前通常采用价格昂贵的过氧化物氟胶或氟硅胶做为内层，普通氟胶因无法与硅胶粘合而无法使用。
 
发明内容
针对上述不足，本发明所要解决的技术问题是，提供一种可与硅橡胶直接硫化粘接的，且粘接力优良的氟橡胶。
本发明所述的可与硅橡胶粘接的氟橡胶配方，该配方中各原料的重量份数为 ：可与硅橡胶热硫化粘接的氟橡胶配方，其特征在于该配方中各原料的重量份数为 ：三元氟橡胶 100份，双酚AF1.2-1.8份，苄基三苯基氯化磷BPP 0.2-0.4份，氢氧化钙3-6份 ，活性氧化镁3-8 份，三烯丙基异氰脲酸酯TAIC      0.2-0.8份，2,5-二甲基-2,5-双过氧化叔丁基己烷0.2-0.8份，炭黑15-30份。
本发明的有益效果：本发明提供的橡胶，采用普通三元氟胶，成本低，可与硅胶直接粘接，工艺简单。
具体实施方式
为了加深对本发明的理解，下面将结合实施例对本发明作进一步详述，该实施例仅用于解释本发明，并不构成对本发明保护范围的限定。
本发明所述的可与硅橡胶热硫化粘接的氟橡胶配方中各原料的重量份数为 ：三元氟橡胶 100份，双酚AF  1.2-1.8份，苄基三苯基氯化磷BPP 0.2-0.4份，氢氧化钙3-6份 ，活性氧化镁3-8 份，三烯丙基异氰脲酸酯TAIC   0.2-0.8份，2,5-二甲基-2,5-双过氧化叔丁基己烷0.2-0.8份， 炭黑15-30份。
现具体说明如下：
实施例一
本实施例提供了一种可与硅橡胶粘接的氟橡胶配方，该配方中各原料的重量份数为 ：三元氟橡胶 100 份，双酚AF 1.5份，苄基三苯基氯化磷（BPP） 0.3份  氢氧化钙4 份， 活性氧化镁6份 ，三烯丙基异氰脲酸酯（ TAIC） 0.6 份， 2,5-二甲基-2,5-双（过氧化叔丁基）己烷0.3份， N990炭黑20份。
实施例二
本实施例提供了一种可与硅橡胶粘接的氟橡胶配方，该配方中各原料的重量份数为 ：三元氟橡胶 100 份，双酚AF 1.4份，苄基三苯基氯化磷（BPP） 0.3份  氢氧化钙4 份， 活性氧化镁6份 ，三烯丙基异氰脲酸酯（ TAIC） 0.6 份， 2,5-二甲基-2,5-双（过氧化叔丁基）己烷0.3份， N990炭黑25份。
实施例三
本实施例提供了一种可与硅橡胶粘接的氟橡胶配方，该配方中各原料的重量份数为 ：三元氟橡胶 100 份，双酚AF 1.5份，苄基三苯基氯化磷（BPP） 0.3份  氢氧化钙3 份， 活性氧化镁7份 ，三烯丙基异氰脲酸酯（ TAIC） 0.5 份， 2,5-二甲基-2,5-双（过氧化叔丁基）己烷0.3份， N990炭黑25份。
    上述2,5-二甲基-2,5-双（过氧化叔丁基）己烷也称为硫化剂双25 ， 双25。

Claims (2)

1.一种可与硅橡胶热硫化粘接的氟橡胶配方，其特征在于该配方中各原料的重量份数为 ：
 三元氟橡胶 100份，双酚AF   1.2-1.8份，苄基三苯基氯化磷BPP 0.2-0.4份，氢氧化钙3-6份 ，活性氧化镁3-8 份，三烯丙基异氰脲酸酯TAIC       0.2-0.8份，2,5-二甲基-2,5-双过氧化叔丁基己烷0.2-0.8份， 炭黑15-30份。
2.根据权利要求1所述的可与硅橡胶热硫化粘接的氟橡胶配方，其特征在于所述的炭黑为 N990炭黑。
CN201410574673.8A 2014-10-24 2014-10-24 可与硅橡胶粘接的氟橡胶配方 Pending CN104327426A (zh)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104945650A (zh) * 2015-07-07 2015-09-30 厦门柏润氟材料科技有限公司 硅橡胶o型圈表面涂层
CN107921740A (zh) * 2015-08-27 2018-04-17 3M创新有限公司 包含一种或多种含氟聚合物的具有改善的耐热性的多层制品
CN109021301A (zh) * 2018-08-14 2018-12-18 岳西县天鹅电子科技有限公司 一种绝缘的导线外皮配方
CN111087650A (zh) * 2019-12-25 2020-05-01 浙江加诚新材料有限公司 一种氟橡胶用硫化剂体系、氟橡胶混炼胶及应用
CN111363279A (zh) * 2020-03-17 2020-07-03 戚佳轩 可与硅橡胶共硫化粘结的氟橡胶组合物、橡胶制品和制备方法
CN113337056A (zh) * 2021-05-28 2021-09-03 瑞源橡塑制品有限公司 一种满足国六排放标准的中冷器进出气用合成胶管的制备配方及制备方法及专用制备设备

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CN102850700A (zh) * 2012-08-16 2013-01-02 芜湖禾田汽车工业有限公司 一种橡胶配方及其制备方法

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CN102786701A (zh) * 2012-07-04 2012-11-21 宁波丰茂远东橡胶有限公司 氟胶硅胶热硫化粘合工艺
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104945650A (zh) * 2015-07-07 2015-09-30 厦门柏润氟材料科技有限公司 硅橡胶o型圈表面涂层
CN104945650B (zh) * 2015-07-07 2017-12-29 厦门柏润氟材料科技有限公司 硅橡胶o型圈表面涂层
CN107921740A (zh) * 2015-08-27 2018-04-17 3M创新有限公司 包含一种或多种含氟聚合物的具有改善的耐热性的多层制品
CN107921740B (zh) * 2015-08-27 2019-07-23 3M创新有限公司 包含一种或多种含氟聚合物的具有改善的耐热性的多层制品
CN109021301A (zh) * 2018-08-14 2018-12-18 岳西县天鹅电子科技有限公司 一种绝缘的导线外皮配方
CN111087650A (zh) * 2019-12-25 2020-05-01 浙江加诚新材料有限公司 一种氟橡胶用硫化剂体系、氟橡胶混炼胶及应用
CN111363279A (zh) * 2020-03-17 2020-07-03 戚佳轩 可与硅橡胶共硫化粘结的氟橡胶组合物、橡胶制品和制备方法
CN113337056A (zh) * 2021-05-28 2021-09-03 瑞源橡塑制品有限公司 一种满足国六排放标准的中冷器进出气用合成胶管的制备配方及制备方法及专用制备设备

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