CN104312147A - 一种氧化锌晶须/石墨烯纳米片协同改性氰酸酯树脂导热复合材料及其制备方法 - Google Patents
一种氧化锌晶须/石墨烯纳米片协同改性氰酸酯树脂导热复合材料及其制备方法 Download PDFInfo
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- CN104312147A CN104312147A CN201410573143.1A CN201410573143A CN104312147A CN 104312147 A CN104312147 A CN 104312147A CN 201410573143 A CN201410573143 A CN 201410573143A CN 104312147 A CN104312147 A CN 104312147A
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- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 20
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- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
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- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/08—Oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
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CN201410573143.1A CN104312147B (zh) | 2014-10-23 | 2014-10-23 | 一种氧化锌晶须/石墨烯纳米片协同改性氰酸酯树脂导热复合材料及其制备方法 |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107188164A (zh) * | 2017-07-11 | 2017-09-22 | 济南大学 | 一种rGO/ZnO空心微球的制备方法 |
CN108793880A (zh) * | 2018-07-13 | 2018-11-13 | 北京新时代寰宇科技发展有限公司 | 氧化石墨烯改性水泥基复合保温材料及其制备方法和应用 |
CN110256757A (zh) * | 2019-05-16 | 2019-09-20 | 广州大学 | 一种季鏻盐复合抗菌eva鞋垫材料及其制备方法 |
CN110733225A (zh) * | 2018-10-19 | 2020-01-31 | 嘉兴学院 | 一种高导热高韧性覆铜板的制备方法 |
CN111303511A (zh) * | 2018-12-12 | 2020-06-19 | 新奥石墨烯技术有限公司 | 一种含微纳杂化结构填料的聚合物复合材料及其制备方法 |
CN111303586A (zh) * | 2018-12-12 | 2020-06-19 | 新奥石墨烯技术有限公司 | 一种基于石墨烯三维导热网链的热固性树脂组合物及其制备方法 |
CN111945274A (zh) * | 2020-08-13 | 2020-11-17 | 黎扬程 | 一种抗菌抗静电功能面料及其制备方法 |
CN113462109A (zh) * | 2021-07-02 | 2021-10-01 | 科迈特新材料有限公司 | 一种基于石墨烯的塑料添加剂及其制备方法 |
CN114196179A (zh) * | 2021-12-21 | 2022-03-18 | 东北林业大学 | 一种高导热、可降解形状记忆复合材料及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002338786A (ja) * | 2001-05-15 | 2002-11-27 | Samsung Electro Mech Co Ltd | シアナートエステル含有絶縁組成物、これから製造した絶縁フィルム及び絶縁フィルムを備える多層印刷回路基板 |
CN102775786A (zh) * | 2012-08-09 | 2012-11-14 | 西北工业大学 | 一种氧化石墨烯/氰酸酯树脂复合材料及其制备方法 |
-
2014
- 2014-10-23 CN CN201410573143.1A patent/CN104312147B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002338786A (ja) * | 2001-05-15 | 2002-11-27 | Samsung Electro Mech Co Ltd | シアナートエステル含有絶縁組成物、これから製造した絶縁フィルム及び絶縁フィルムを備える多層印刷回路基板 |
CN102775786A (zh) * | 2012-08-09 | 2012-11-14 | 西北工业大学 | 一种氧化石墨烯/氰酸酯树脂复合材料及其制备方法 |
Non-Patent Citations (2)
Title |
---|
赵春宝等: ""二烯丙基双酚A改性氰酸酯树脂的固化动力学及力学性能"", 《绝缘材料》, vol. 45, no. 1, 31 December 2012 (2012-12-31) * |
赵春宝等: ""氰酸酯树脂/氧化锌晶须复合材料的制备与性能研究"", 《化工新型材料》, vol. 41, no. 11, 30 November 2013 (2013-11-30), pages 62 - 64 * |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107188164A (zh) * | 2017-07-11 | 2017-09-22 | 济南大学 | 一种rGO/ZnO空心微球的制备方法 |
CN108793880A (zh) * | 2018-07-13 | 2018-11-13 | 北京新时代寰宇科技发展有限公司 | 氧化石墨烯改性水泥基复合保温材料及其制备方法和应用 |
CN108793880B (zh) * | 2018-07-13 | 2021-03-09 | 北京新时代寰宇科技发展有限公司 | 氧化石墨烯改性水泥基复合保温材料及其制备方法和应用 |
CN110733225A (zh) * | 2018-10-19 | 2020-01-31 | 嘉兴学院 | 一种高导热高韧性覆铜板的制备方法 |
CN110733225B (zh) * | 2018-10-19 | 2021-07-09 | 嘉兴学院 | 一种高导热高韧性覆铜板的制备方法 |
CN111303511A (zh) * | 2018-12-12 | 2020-06-19 | 新奥石墨烯技术有限公司 | 一种含微纳杂化结构填料的聚合物复合材料及其制备方法 |
CN111303586A (zh) * | 2018-12-12 | 2020-06-19 | 新奥石墨烯技术有限公司 | 一种基于石墨烯三维导热网链的热固性树脂组合物及其制备方法 |
CN110256757A (zh) * | 2019-05-16 | 2019-09-20 | 广州大学 | 一种季鏻盐复合抗菌eva鞋垫材料及其制备方法 |
CN111945274A (zh) * | 2020-08-13 | 2020-11-17 | 黎扬程 | 一种抗菌抗静电功能面料及其制备方法 |
CN113462109A (zh) * | 2021-07-02 | 2021-10-01 | 科迈特新材料有限公司 | 一种基于石墨烯的塑料添加剂及其制备方法 |
CN114196179A (zh) * | 2021-12-21 | 2022-03-18 | 东北林业大学 | 一种高导热、可降解形状记忆复合材料及其制备方法 |
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