CN104311262A - High-efficiency chemical fertilizer synergist and production method thereof - Google Patents
High-efficiency chemical fertilizer synergist and production method thereof Download PDFInfo
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- CN104311262A CN104311262A CN201410518242.XA CN201410518242A CN104311262A CN 104311262 A CN104311262 A CN 104311262A CN 201410518242 A CN201410518242 A CN 201410518242A CN 104311262 A CN104311262 A CN 104311262A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
- C05F11/02—Other organic fertilisers from peat, brown coal, and similar vegetable deposits
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Soil Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a high-efficiency chemical fertilizer synergist and a production method thereof. The high-efficiency chemical fertilizer synergist comprises the following components: 13 parts of compound sodium nitrophenolate, 13 parts of A-pimacol, 18 parts of chlormequat chloride, 15 parts of boric acid, 15 parts of humic acid, 22 parts of 2,4-dinitrophenol or sodium salt of 2,4-dinitrophenol, 18 parts of o-hydroxynitrobenzene or sodium salt of o-hydroxynitrobenzene, 23 parts of p-nitrophenol or sodium salt of p-nitrophenol, 14 parts of dodecylbenzene sulfonic acid or sodium salt of dodecylbenzene sulfonic acid, 18 parts of polyaspartic acid, 17 parts of triiodobenzoicacid, 18 parts of a biological azotobacter and 11 parts of a synergism additive. The high-efficiency chemical fertilizer synergist disclosed by the invention can overcome the defects of a conventional chemical fertilizer, improve the efficiency of the chemical fertilizer and increase the chemical fertilizer utilization rate. Cell division and tissue differentiation of plants, fruits, vegetables and fruit trees are promoted, root system formation is promoted, and the fruit rate is increased. Due to appreciate raw materials and appreciate proportions, the process is simple, the operation is convenient, and the effects of energy conservation and cost reduction are achieved.
Description
Technical field
The present invention relates to a kind of high-effective chemical fertilizer synergistic agent, the invention still further relates to a kind of high-effective chemical fertilizer synergistic agent, belong to field of fertilizer production.
Background technology
General, be based on the necessary medium trace element of farm crop, coordinate urease inhibitor, ammonia stablizer, be aided with bacteria agent again, sterilant, plant production promotor are formulated.This product is by trace element, and urease inhibitor, the synergy of bacteria agent etc. can improve nitrogen, phosphorus, potassium utilization rate about 20% comprehensively, extends fertilizer effectiveness to 90 ~ 120 day.
Research finds, sodium nitrophenolate is a kind of powerful cell-activating agent, with energy rapid permeability after plant contact in plant materials, promotes the protoplasma flowing of cell, improves cell viability.Can the speed of growth be accelerated, breaking dormancy, enhancing development, prevent fruit drop, improve product quality, improve output, improve disease-resistant, pest-resistant, the drought resisting of crop, waterlogging-resistant, cold-resistant, the anti-anti-adversity ability such as saline and alkaline, resistant to lodging; Secondly high purity α-naphthaleneacidsodium is a kind of broad spectrum plant-growth amendment, cell fission and expansion (swollen fruit agent, enlarging agent) can be promoted rapidly, induced synthesis adventive root (root-growing agent), there is growth regulation, hestening rooting, sprout, bloom, prevent fruit drop, form seedless fruit, promote the effect such as precocity, volume increase, also can strengthen simultaneously the drought resisting of plant, cold-resistant, disease-resistant, resist ability that is saline and alkaline, hot-dry wind tolerance.A kind of wide spectrum, efficient, low toxicity plant-growth amendment.
For improving crop quality, sodium nitrophenolate is a kind of new plant growth regulator integrating nutrition, adjustment, prevention, is applicable to the vital plant of all tools, and all can use in the whole lifetime of plant, effect is all extremely remarkable.Improve fertilizer (medicine) with fertilizer, agriculture chemical compounding later and imitate more than 20%, reduce fertile (medicine) consumption 20%, fertilizer (medicine) is made to imitate more aobvious mystery, significantly can improve crop quality, make food crop full seed, vegetable crop blade plumpness, solanberry crop pulp enrich, and mouthfeel is good, strengthen crop disease-resistant, anti-deterioration, cold-resistant, drought resisting, the anti-anti-adversity ability such as saline and alkaline, resistant to lodging.
Therefore, be necessary composition research is carried out for above-mentioned raw materials, while can improving chemical fertilizer utilization ratio, adjustment and promoter action can also be had to the production of plant, fruits and vegetables, fruit tree, a series of injuries that human body generation agricultural chemicals or fertilizer residue are caused can also be avoided.
Summary of the invention
The object of the invention is to for deficiency of the prior art, a kind of high-effective chemical fertilizer synergistic agent and production method thereof are provided, high-effective chemical fertilizer synergistic agent overcomes the deficiency of existing chemical fertilizer, strengthen the fertilizer efficiency of chemical fertilizer, improve chemical fertilizer utilization ratio, the cell fission of promotion plant, fruits and vegetables, fruit tree and tissue differentiation, promote root growth, improves fruit rate.
For solving the problems of the technologies described above, the technical solution used in the present invention is: a kind of high-effective chemical fertilizer synergistic agent, its innovative point is: comprise following composition and weight part thereof: sodium nitrophenolate 10 ~ 15 parts, A-Nafusaku 10 ~ 15 parts, choline dichloride 13 ~ 25 parts, boric acid 12 ~ 20 parts, humic acids 12 ~ 21 parts, 2, 2, 4-dinitrophenol or its sodium salt 11 ~ 32 parts, adjacent nitro tea phenol or its sodium salt 11 ~ 30 parts, p-NP or its sodium salt 11 ~ 30 parts, Witco 1298 Soft Acid or its sodium salt 11 ~ 20 parts, poly aspartic acid 15 ~ 20 parts, Triiodobenzoic acid 13 ~ 20 parts, biological nitrogen fixation bacterium 10 ~ 26 parts and Synergistic additives 10 ~ 12 parts.
Further, described Synergistic additives comprises sulfonic chloride 15 ~ 20 parts, octadecylamine 12 ~ 20 parts, 18 ~ 25 parts, Tai-Ace S 150, protein peptide 14 ~ 22 parts, polyether-tribasic alcohol 15 ~ 25 parts and polypropylene glycol 2 ~ 10 parts.
Further, comprise following composition and weight part thereof: sodium nitrophenolate 12 ~ 14 parts, A-Nafusaku 12 ~ 14 parts, choline dichloride 15 ~ 20 parts, boric acid 14 ~ 17 parts, humic acids 14 ~ 17 parts, 2,2, 4-dinitrophenol or its sodium salt 18 ~ 26 parts, adjacent nitro tea phenol or its sodium salt 16 ~ 22 parts, p-NP or its sodium salt 17 ~ 25 parts, Witco 1298 Soft Acid or its sodium salt 13 ~ 16 parts, poly aspartic acid 17 ~ 19 parts, Triiodobenzoic acid 16 ~ 18 parts, biological nitrogen fixation bacterium 14 ~ 23 parts and Synergistic additives 10 ~ 12 parts.
Further, comprise following composition and weight part thereof: sodium nitrophenolate 13 parts, A-Nafusaku 13 parts, choline dichloride 18 parts, boric acid 15 parts, humic acids 15 parts, 2,2, 4-dinitrophenol or its sodium salt 22 parts, adjacent nitro tea phenol or its sodium salt 18 parts, p-NP or its sodium salt 23 parts, Witco 1298 Soft Acid or its sodium salt 14 parts, poly aspartic acid 18 parts, Triiodobenzoic acid 17 parts, biological nitrogen fixation bacterium 18 parts and Synergistic additives 11 parts.
Another object of the present invention is to provide a kind of production method of high-effective chemical fertilizer synergistic agent, and its innovative point is: specifically comprise the following steps:
(1) by sodium nitrophenolate, A-Nafusaku, choline dichloride, boric acid, humic acids, 2,2, 4-dinitrophenol or its sodium salt, adjacent nitro tea phenol or its sodium salt, p-NP or its sodium salt and Witco 1298 Soft Acid or its sodium salt are placed in a pressurized vessel according to proportional quantity, the pressure arranging pressurized vessel reaches-0.5 ~-0.2 MPa, and the temperature of pressurized vessel is 50 ~ 60 DEG C;
(2) poly aspartic acid, Triiodobenzoic acid, biological nitrogen fixation bacterium and polyether-tribasic alcohol are mixed into liquor, arranging mixing time is 30 ~ 40min, be dissolved in liquor by protein peptide, sulfonic chloride, octadecylamine, Tai-Ace S 150 and polypropylene glycol, arranging solvent temperature is 30 ~ 40 DEG C;
(3) dissolved rear filtration, arranging filter sizes is 2 ~ 3mm, and filtrate carries out evaporation drying, and arranging drying temperature is 180 ~ 220 DEG C, and the time is 2 ~ 3h;
(4) the dry thing in step (3) is made particle, grain diameter is 4 ~ 6mm, finally enters coating room and carries out coating;
(5) coating liquid is sprayed at particle surface, control coating liquid consumption be particle weight 20 ~ 30%, the temperature controlling coating room is 49 ~ 55 DEG C.
Further, the pressure of the pressurized vessel in described step (1) reaches-0.35 MPa, and the temperature of pressurized vessel is 55 DEG C.
Further, the mixing time in described step (2) is set to 35min, and solvent temperature is set to 35 DEG C.
Further, arranging drying temperature in described step (3) is 200 DEG C, and the time is 2.5h.
Further, the grain diameter in described step (4) is 4.5mm.
Further, the coating liquid consumption in described step (5) be particle weight 25%; In described step (5), the temperature of coating room is 52 DEG C.
Beneficial effect of the present invention is as follows:
(1) high-effective chemical fertilizer synergistic agent of the present invention overcomes the deficiency of existing chemical fertilizer, strengthens the fertilizer efficiency of chemical fertilizer, improves chemical fertilizer utilization ratio.
(2) high-effective chemical fertilizer synergistic agent of the present invention promotes plant, fruits and vegetables, the cell fission of fruit tree and tissue differentiation, promotes root growth, improves fruit rate.
(3) high-effective chemical fertilizer synergistic agent of the present invention selects suitable raw material and suitable proportioning, and technique is simple, easy to operate, reaches save energy, cost-saving effect.
(4) Synergistic additives added in high-effective chemical fertilizer synergistic agent of the present invention, effectively can improve end-use performance and the specific absorption of fertilizer, makes chemical fertilizer easily broken, and water content declines, and fertilising is convenient.
Embodiment
Below in conjunction with specific embodiment, technical scheme of the present invention is elaborated.
Embodiment 1
A kind of high-effective chemical fertilizer synergistic agent, its innovative point is: comprise following composition and weight part thereof: sodium nitrophenolate 10 ~ 15 parts, A-Nafusaku 10 ~ 15 parts, choline dichloride 13 ~ 25 parts, boric acid 12 ~ 20 parts, humic acids 12 ~ 21 parts, 2,2, 4-dinitrophenol or its sodium salt 11 ~ 32 parts, adjacent nitro tea phenol or its sodium salt 11 ~ 30 parts, p-NP or its sodium salt 11 ~ 30 parts, Witco 1298 Soft Acid or its sodium salt 11 ~ 20 parts, poly aspartic acid 15 ~ 20 parts, Triiodobenzoic acid 13 ~ 20 parts, biological nitrogen fixation bacterium 10 ~ 26 parts and Synergistic additives 10 ~ 12 parts.
Wherein, Synergistic additives comprises sulfonic chloride 15 ~ 20 parts, octadecylamine 12 ~ 20 parts, 18 ~ 25 parts, Tai-Ace S 150, protein peptide 14 ~ 22 parts, polyether-tribasic alcohol 15 ~ 25 parts and polypropylene glycol 2 ~ 10 parts.
A production method for high-effective chemical fertilizer synergistic agent, specifically comprises the following steps:
(1) by sodium nitrophenolate, A-Nafusaku, choline dichloride, boric acid, humic acids, 2,2, 4-dinitrophenol or its sodium salt, adjacent nitro tea phenol or its sodium salt, p-NP or its sodium salt and Witco 1298 Soft Acid or its sodium salt are placed in a pressurized vessel according to proportional quantity, the pressure arranging pressurized vessel reaches-0.5 ~-0.2 MPa, and the temperature of pressurized vessel is 50 ~ 60 DEG C;
(2) poly aspartic acid, Triiodobenzoic acid, biological nitrogen fixation bacterium and polyether-tribasic alcohol are mixed into liquor, arranging mixing time is 30 ~ 40min, be dissolved in liquor by protein peptide, sulfonic chloride, octadecylamine, Tai-Ace S 150 and polypropylene glycol, arranging solvent temperature is 30 ~ 40 DEG C;
(3) dissolved rear filtration, arranging filter sizes is 2 ~ 3mm, and filtrate carries out evaporation drying, and arranging drying temperature is 180 ~ 220 DEG C, and the time is 2 ~ 3h;
(4) the dry thing in step (3) is made particle, grain diameter is 4 ~ 6mm, finally enters coating room and carries out coating;
(5) coating liquid is sprayed at particle surface, control coating liquid consumption be particle weight 20 ~ 30%, the temperature controlling coating room is 49 ~ 55 DEG C.
The high-effective chemical fertilizer synergistic agent of the present embodiment promotes plant, fruits and vegetables, the cell fission of fruit tree and tissue differentiation, promote root growth, improve fruit rate, overcome the deficiency of existing chemical fertilizer simultaneously, strengthen the fertilizer efficiency of chemical fertilizer, improve chemical fertilizer utilization ratio, and select suitable raw material and suitable proportioning, technique is simple, easy to operate, reach save energy, cost-saving effect.
Embodiment 2
On the basis of embodiment 1, change the weight of composition, be specially: sodium nitrophenolate 12 ~ 14 parts, A-Nafusaku 12 ~ 14 parts, choline dichloride 15 ~ 20 parts, boric acid 14 ~ 17 parts, humic acids 14 ~ 17 parts, 2,4-DNP or its sodium salt 18 ~ 26 parts, adjacent nitro tea phenol or its sodium salt 16 ~ 22 parts, p-NP or its sodium salt 17 ~ 25 parts, Witco 1298 Soft Acid or its sodium salt 13 ~ 16 parts, poly aspartic acid 17 ~ 19 parts, Triiodobenzoic acid 16 ~ 18 parts, biological nitrogen fixation bacterium 14 ~ 23 parts and Synergistic additives 10 ~ 12 parts.
Produce according to the method for embodiment 1, optimize partial parameters, concrete optimization is as follows: the pressure of the pressurized vessel in step (1) reaches-0.35 MPa, and the temperature of pressurized vessel is 55 DEG C; Mixing time in step (2) is set to 35min, and solvent temperature is set to 35 DEG C; Arranging drying temperature in step (3) is 200 DEG C, and the time is 2.5h; Grain diameter in step (4) is 4.5mm; Coating liquid consumption in step (5) be particle weight 25%; The temperature of coating room is 52 DEG C.
The high-effective chemical fertilizer synergistic agent of the present embodiment promotes plant, fruits and vegetables, the cell fission of fruit tree and tissue differentiation, promote root growth, improve fruit rate, overcome the deficiency of existing chemical fertilizer simultaneously, strengthen the fertilizer efficiency of chemical fertilizer, improve chemical fertilizer utilization ratio, and select suitable raw material and suitable proportioning, technique is simple, easy to operate, reach save energy, cost-saving effect.
Embodiment 3
On the basis of embodiment 1 or 2, optimize the weight of composition, be specially: sodium nitrophenolate 13 parts, A-Nafusaku 13 parts, choline dichloride 18 parts, boric acid 15 parts, humic acids 15 parts, 2,4-DNP or its sodium salt 22 parts, adjacent nitro tea phenol or its sodium salt 18 parts, p-NP or its sodium salt 23 parts, Witco 1298 Soft Acid or its sodium salt 14 parts, poly aspartic acid 18 parts, Triiodobenzoic acid 17 parts, biological nitrogen fixation bacterium 18 parts and Synergistic additives 11 parts.
Produce according to the production method of embodiment 1 or 2, the high-effective chemical fertilizer synergistic agent of the present embodiment promotes plant, fruits and vegetables, the cell fission of fruit tree and tissue differentiation, promotes root growth, improves fruit rate, overcome the deficiency of existing chemical fertilizer simultaneously, strengthen the fertilizer efficiency of chemical fertilizer, improve chemical fertilizer utilization ratio, and select suitable raw material and suitable proportioning, technique is simple, easy to operate, reach save energy, cost-saving effect.
Claims (10)
1. a high-effective chemical fertilizer synergistic agent, it is characterized in that: comprise following composition and weight part thereof: sodium nitrophenolate 10 ~ 15 parts, A-Nafusaku 10 ~ 15 parts, choline dichloride 13 ~ 25 parts, boric acid 12 ~ 20 parts, humic acids 12 ~ 21 parts, 2,2, 4-dinitrophenol or its sodium salt 11 ~ 32 parts, adjacent nitro tea phenol or its sodium salt 11 ~ 30 parts, p-NP or its sodium salt 11 ~ 30 parts, Witco 1298 Soft Acid or its sodium salt 11 ~ 20 parts, poly aspartic acid 15 ~ 20 parts, Triiodobenzoic acid 13 ~ 20 parts, biological nitrogen fixation bacterium 10 ~ 26 parts and Synergistic additives 10 ~ 12 parts.
2. high-effective chemical fertilizer synergistic agent according to claim 1, it is characterized in that: described Synergistic additives comprises sulfonic chloride 15 ~ 20 parts, octadecylamine 12 ~ 20 parts, 18 ~ 25 parts, Tai-Ace S 150, protein peptide 14 ~ 22 parts, polyether-tribasic alcohol 15 ~ 25 parts and polypropylene glycol 2 ~ 10 parts.
3. high-effective chemical fertilizer synergistic agent according to claim 1, it is characterized in that: comprise following composition and weight part thereof: sodium nitrophenolate 12 ~ 14 parts, A-Nafusaku 12 ~ 14 parts, choline dichloride 15 ~ 20 parts, boric acid 14 ~ 17 parts, humic acids 14 ~ 17 parts, 2, 2, 4-dinitrophenol or its sodium salt 18 ~ 26 parts, adjacent nitro tea phenol or its sodium salt 16 ~ 22 parts, p-NP or its sodium salt 17 ~ 25 parts, Witco 1298 Soft Acid or its sodium salt 13 ~ 16 parts, poly aspartic acid 17 ~ 19 parts, Triiodobenzoic acid 16 ~ 18 parts, biological nitrogen fixation bacterium 14 ~ 23 parts and Synergistic additives 10 ~ 12 parts.
4. high-effective chemical fertilizer synergistic agent according to claim 1, is characterized in that: comprise following composition and weight part thereof: sodium nitrophenolate 13 parts, A-Nafusaku 13 parts, choline dichloride 18 parts, boric acid 15 parts, humic acids 15 parts, 2,2, 4-dinitrophenol or its sodium salt 22 parts, adjacent nitro tea phenol or its sodium salt 18 parts, p-NP or its sodium salt 23 parts, Witco 1298 Soft Acid or its sodium salt 14 parts, poly aspartic acid 18 parts, Triiodobenzoic acid 17 parts, biological nitrogen fixation bacterium 18 parts and Synergistic additives 11 parts.
5. a production method for high-effective chemical fertilizer synergistic agent according to claim 1, is characterized in that: specifically comprise the following steps:
By sodium nitrophenolate, A-Nafusaku, choline dichloride, boric acid, humic acids, 2,2, 4-dinitrophenol or its sodium salt, adjacent nitro tea phenol or its sodium salt, p-NP or its sodium salt and Witco 1298 Soft Acid or its sodium salt are placed in a pressurized vessel according to proportional quantity, the pressure arranging pressurized vessel reaches-0.5 ~-0.2 MPa, and the temperature of pressurized vessel is 50 ~ 60 DEG C;
(2) poly aspartic acid, Triiodobenzoic acid, biological nitrogen fixation bacterium and polyether-tribasic alcohol are mixed into liquor, arranging mixing time is 30 ~ 40min, be dissolved in liquor by protein peptide, sulfonic chloride, octadecylamine, Tai-Ace S 150 and polypropylene glycol, arranging solvent temperature is 30 ~ 40 DEG C;
(3) dissolved rear filtration, arranging filter sizes is 2 ~ 3mm, and filtrate carries out evaporation drying, and arranging drying temperature is 180 ~ 220 DEG C, and the time is 2 ~ 3h;
(4) the dry thing in step (3) is made particle, grain diameter is 4 ~ 6mm, finally enters coating room and carries out coating;
(5) coating liquid is sprayed at particle surface, control coating liquid consumption be particle weight 20 ~ 30%, the temperature controlling coating room is 49 ~ 55 DEG C.
6. the production method of high-effective chemical fertilizer synergistic agent according to claim 4, is characterized in that: the pressure of the pressurized vessel in described step (1) reaches-0.35 MPa, and the temperature of pressurized vessel is 55 DEG C.
7. the production method of high-effective chemical fertilizer synergistic agent according to claim 4, is characterized in that: the mixing time in described step (2) is set to 35min, and solvent temperature is set to 35 DEG C.
8. the production method of high-effective chemical fertilizer synergistic agent according to claim 4, is characterized in that: arranging drying temperature in described step (3) is 200 DEG C, and the time is 2.5h.
9. the production method of high-effective chemical fertilizer synergistic agent according to claim 4, is characterized in that: the grain diameter in described step (4) is 4.5mm.
10. the production method of high-effective chemical fertilizer synergistic agent according to claim 4, is characterized in that: the coating liquid consumption in described step (5) be particle weight 25%; In described step (5), the temperature of coating room is 52 DEG C.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105036886A (en) * | 2015-06-18 | 2015-11-11 | 安徽徽普生物科技有限责任公司 | Peanut special fertilizer additive resistant to plant diseases and insect pests |
CN107500862A (en) * | 2017-08-24 | 2017-12-22 | 舒城县南港茶叶专业合作社 | A kind of tea tree chemical fertilizer additive |
WO2018049547A1 (en) * | 2016-09-13 | 2018-03-22 | 张勇健 | Fertilizer additive and preparation method therefor |
WO2018058540A1 (en) * | 2016-09-30 | 2018-04-05 | 张爱丽 | Chemical fertilizer enhancer and manufacturing method thereof |
CN109665898A (en) * | 2017-10-13 | 2019-04-23 | 黄宇 | A kind of fertilizer synergistic agent |
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CN105036886A (en) * | 2015-06-18 | 2015-11-11 | 安徽徽普生物科技有限责任公司 | Peanut special fertilizer additive resistant to plant diseases and insect pests |
WO2018049547A1 (en) * | 2016-09-13 | 2018-03-22 | 张勇健 | Fertilizer additive and preparation method therefor |
WO2018058540A1 (en) * | 2016-09-30 | 2018-04-05 | 张爱丽 | Chemical fertilizer enhancer and manufacturing method thereof |
CN107500862A (en) * | 2017-08-24 | 2017-12-22 | 舒城县南港茶叶专业合作社 | A kind of tea tree chemical fertilizer additive |
CN109665898A (en) * | 2017-10-13 | 2019-04-23 | 黄宇 | A kind of fertilizer synergistic agent |
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