CN104311233A - Special slow-release fertilizer taking attapulgite as matrix for paddy rice and preparation method of special slow-release fertilizer - Google Patents

Special slow-release fertilizer taking attapulgite as matrix for paddy rice and preparation method of special slow-release fertilizer Download PDF

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Publication number
CN104311233A
CN104311233A CN201410503841.4A CN201410503841A CN104311233A CN 104311233 A CN104311233 A CN 104311233A CN 201410503841 A CN201410503841 A CN 201410503841A CN 104311233 A CN104311233 A CN 104311233A
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China
Prior art keywords
parts
fertilizer
attapulgite
solution
paddy rice
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CN201410503841.4A
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Chinese (zh)
Inventor
吴全玉
杨汉民
苏松田
周军
沈林
高立成
毕宁宁
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ANHUI HEQUAN SEED INDUSTRY Co Ltd
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ANHUI HEQUAN SEED INDUSTRY Co Ltd
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Priority to CN201410503841.4A priority Critical patent/CN104311233A/en
Publication of CN104311233A publication Critical patent/CN104311233A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/90Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil

Abstract

The invention provides a special slow-release fertilizer taking attapulgite as a matrix for paddy rice. The special slow-release fertilizer comprises the following raw material components in parts by weight: 60-80 parts of attapulgite, 10-20 parts of bamboo charcoal powder, 10-15 parts of melamine, 4-6 parts of polyvinyl alcohol, 10-12 parts of urea, 50-60 parts of diammonium phosphate, 80-90 parts of potassium sulfate, 6-8 parts of sodium lignin sulfonate, 1-2 parts of turpentine oil, 3-4 parts of a herbicide, 2-4 parts of disodium cocoyl monoethanolamide sulfosuccinate, 3-4 parts of super absorbent resin and 10-15 parts of fertilizer additives. The fertilizer provided by the invention can slowly release nutrients by fertilizing once, improves the utilization rate of the fertilizer and reduces the loss of fertilizer efficiency; and by adding the super absorbent resin, the effects of fighting against drought and retaining water are realized, the yield of the paddy rice is improved, and the cost is saved.

Description

A kind of is that the paddy rice of matrix is slow-release fertilizer dedicated and preparation method thereof with attapulgite
Technical field
The present invention relates to agricultural fertilizer field, being specifically related to a kind of is that the paddy rice of matrix is slow-release fertilizer dedicated and preparation method thereof with attapulgite.
Background technology
Paddy rice is the staple food of the world 2/3 population, especially the main source of China, South East Asia and South Asia people's nutrition and energy.Nitrogen, phosphorus, potassium are the required nutritive elements of rice growth.Nitrogen is the nucleus forming organic compounds containing nitrogen important in paddy rice body.Phosphorus is one of tenuigenin and nuclear important component, and the metabolism of direct or indirect involved in sugar, protein and fat, and phosphorus participates in the metabolism of energy, and some energy-rich phosphates are again the main place of energy storage.Therefore, phosphorus cell fission and merismatic be developmentally indispensable, Seedling Stage and tillering phase even more important.Deficiency Xn Rice Plants phosphorus plant is often in sap green, and blade is narrow and upright, and lower blade is withered, minimizings of tillering, and root system development is bad, and fertility is stagnated, and often causes the phenomenon generations such as rice contracting seedling, red seedling, postponement breeding time, has a strong impact on output.Potassium can promote synthesis, the decomposition and transfer etc. of carbohydrate.Potassium also contributes to the synthesis of nitrogen metabolism and protein, so, execute nitrogen more, to the requirement also just corresponding increase of potassium.Potassium has activation to important enzyme multiple in paddy rice body.Appropriate potassium can improve photosynthesis and increase rice body carbohydrate content, and cell walls can be made thickening, thus strengthens the disease-resistant ability resistant to lodging of plant.Potassium deficiency, root system development is stagnated, and easily produces root rot.When potassium is not enough, starch, Mierocrystalline cellulose, carbohydrate reduce, and affect yield and quality.Current, Rice Production Peasants is accustomed to fertilizer mainly urea, carbon ammonium, diammonium phosphate and the universal three elements complex fertilizer used, it is very serious that the unbalanced phenomenon of the nutrient caused executed partially by fertilizer, this not only affects raising and quality improving, the reduction nutrients resource utilising efficiency of rice yield, more cannot coordinate soil nutrient balance situation, be unfavorable for improvement of soil fertility, realize paddy rice Sustainable high yield.The invention provides a kind of is that the paddy rice of matrix is slow-release fertilizer dedicated with attapulgite, and nutrition-allocated proportion is reasonable, and single-dose application energy nutrition slow releasing, fertilizer efficiency keep slow releasing.
Summary of the invention
The invention provides a kind of is that the paddy rice of matrix is slow-release fertilizer dedicated with attapulgite, fertilizer of the present invention, single-dose application, nutrients help slow releasing, improve the utilization ratio of fertilizer, reduce the loss of fertilizer efficiency, High hydrophilous resin add the effect playing drought-resistant water-preserving, improve the output of paddy rice, saved cost.
The technical solution used in the present invention is:
A kind of is that the paddy rice of matrix is slow-release fertilizer dedicated with attapulgite, it is characterized in that, make with the raw material of following weight part: attapulgite 60-80, bamboo charcoal powder 10-20, trimeric cyanamide 10-15, polyvinyl alcohol 4-6, urea 10-12, diammonium phosphate 50-60, potassium sulfate 80-90, sodium lignosulfonate 6-8, turps 1-2, weedicide 3-4, Coconut Fatty Acid Monoethanolamide sulfosuccinic acid monoesters two 2-4, High hydrophilous resin 3-4, fertilizer additive 10-15
Described fertilizer additive is made up of following parts by weight of component raw material: zeolite powder 10-20, corn cob meal 30-40, the fertilizer 10-15 become thoroughly decomposed, polyvinyl alcohol 10-15, bamboo fibers 6-8, diammonium phosphate 6-8, Repone K 4-6, zinc sulfate 0.3-0.5, manganous sulfate 0.1-0.3, polyglutamic acid 1-2, nitrification inhibitor 4-6, Flower of Royal Paulownia 4-5, radix aconiti agrestis 6-7, mentha leave 4-6, betel nut 4-6, Fructus Cnidii 4-6, Rangooncreeper Fruit 4-6, wormwood 4-6, Cortex erythrinae 4-6, Herba Siegesbeckiae 4-6, Fructus Solani melongenae root 4-6, Leaf of Camphortree 4-6, insect protected chrysanthemum 4-6, Chinese prickly ash 4-6, Vegetable Sponge of Luffa 4-6, gamma-polyglutamic acid-0.02-0.04, 80% mancozeb wettable powder 0.1-0.3, concentration is 0.01-0.02% paclobutrazol solution 2-4, concentration is 0.01-0.02% amine DA-6 DA-6 solution 1-2, concentration is 0.01-0.02% sodium nitrophenolate solution 2-3, Vitamin C preparation 0.1-0.2, Sodium dodecylbenzene sulfonate 8-10, water is appropriate, rare-earth mineral material 0.2-0.6,
The preparation method of fertilizer additive:
(1) by formula rate, Sodium dodecylbenzene sulfonate is dissolved in water, then diammonium phosphate, Repone K, the fertilizer become thoroughly decomposed, zinc sulfate, manganous sulfate, polyglutamic acid, nitrification inhibitor is added wherein, fully stir;
(2), after all the other medicinal herb componentses such as Flower of Royal Paulownia, radix aconiti agrestis, mentha leave, betel nut, Fructus Cnidii being pulverized, with the alcohol-pickled 10-12 hour of 70%, then soak solution and the dregs of a decoction are joined in the material of step (1) together and mix;
(3) gamma-polyglutamic acid-, mancozeb wettable powder and zeolite powder are mixed, sodium nitrophenolate solution, amine DA-6 DA-6 solution, naphthalene acid solution are joined in corn cob meal and fully mix thoroughly, even with the mixing of materials of step (2) together, finally add polyvinyl alcohol, bamboo fibers, Deng all the other compositions, granulation after abundant mixing.
The paddy rice of matrix that described with attapulgite is is slow-release fertilizer dedicated, it is characterized in that, be made up of following mass parts raw material: attapulgite 72, bamboo charcoal powder 17, trimeric cyanamide 13, polyvinyl alcohol 5, urea 11, diammonium phosphate 57, potassium sulfate 85, sodium lignosulfonate 7, turps 23, weedicide 3, Coconut Fatty Acid Monoethanolamide sulfosuccinic acid monoesters 23, High hydrophilous resin 4, fertilizer additive 14
Described fertilizer additive is made up of following parts by weight of component raw material: zeolite powder 16, corn cob meal 36, the fertilizer 13 become thoroughly decomposed, polyvinyl alcohol 14, bamboo fibers 7, diammonium phosphate 7, Repone K 5, zinc sulfate 0.4, manganous sulfate 0.2, polyglutamic acid 2, nitrification inhibitor 5, Flower of Royal Paulownia 4.5, radix aconiti agrestis 6.5, mentha leave 5, betel nut 5, Fructus Cnidii 5, Rangooncreeper Fruit 5, wormwood 5, Cortex erythrinae 5, Herba Siegesbeckiae 5, Fructus Solani melongenae root 5, Leaf of Camphortree 5, insect protected chrysanthemum 5, Chinese prickly ash 5, Vegetable Sponge of Luffa 5, gamma-polyglutamic acid-0.03, 80% mancozeb wettable powder 0.2, concentration is 0.02% paclobutrazol solution 3, concentration is 0.01% amine DA-6 DA-6 solution 1, concentration is 0.02% sodium nitrophenolate solution 2.5, Vitamin C preparation 0.15, Sodium dodecylbenzene sulfonate 9, water is appropriate, rare-earth mineral material 0.4.
The preparation method that the paddy rice of matrix that described with attapulgite is is slow-release fertilizer dedicated, is characterized in that, comprise the following steps:
Sodium lignosulfonate, Coconut Fatty Acid Monoethanolamide sulfosuccinic acid monoesters two is soluble in water, after dissolving completely, add attapulgite, stir into suspension liquid, by urea, diammonium phosphate, potassium sulfate, fertilizer additive, add and wherein fully stir 20-30 minute, then add after in bamboo charcoal powder, trimeric cyanamide, polyvinyl alcohol, High hydrophilous resin and formula remaining component fully mixes thoroughly successively, granulation.
Beneficial effect
Of the present invention is that the paddy rice of matrix is slow-release fertilizer dedicated, according to the growth needs of paddy rice, by organic composition and mineral manure, medium trace element with attapulgite, reasonable mixed preparing, meanwhile, with the addition of homemade fertilizer additive, nutrition-allocated proportion is reasonable, comprehensively, and fertilizer of the present invention, single-dose application, nutrients help slow releasing, improve the utilization ratio of fertilizer, reduce the loss of fertilizer efficiency, High hydrophilous resin add the effect playing drought-resistant water-preserving, improve the output of paddy rice, save cost.
Embodiment
A kind of is that the paddy rice of matrix is slow-release fertilizer dedicated with attapulgite, its feed composition by weight (kg) is as follows: attapulgite 72, bamboo charcoal powder 17, trimeric cyanamide 13, polyvinyl alcohol 5, urea 11, diammonium phosphate 57, potassium sulfate 85, sodium lignosulfonate 7, turps 23, weedicide 3, Coconut Fatty Acid Monoethanolamide sulfosuccinic acid monoesters 23, High hydrophilous resin 4, fertilizer additive 14
Wherein, fertilizer additive is made up of following weight (kg) component raw material: zeolite powder 16, corn cob meal 36, the fertilizer 13 become thoroughly decomposed, polyvinyl alcohol 14, bamboo fibers 7, diammonium phosphate 7, Repone K 5, zinc sulfate 0.4, manganous sulfate 0.2, polyglutamic acid 2, nitrification inhibitor 5, Flower of Royal Paulownia 4.5, radix aconiti agrestis 6.5, mentha leave 5, betel nut 5, Fructus Cnidii 5, Rangooncreeper Fruit 5, wormwood 5, Cortex erythrinae 5, Herba Siegesbeckiae 5, Fructus Solani melongenae root 5, Leaf of Camphortree 5, insect protected chrysanthemum 5, Chinese prickly ash 5, Vegetable Sponge of Luffa 5, gamma-polyglutamic acid-0.03, 80% mancozeb wettable powder 0.2, concentration is 0.02% paclobutrazol solution 3, concentration is 0.01% amine DA-6 DA-6 solution 1, concentration is 0.02% sodium nitrophenolate solution 2.5, Vitamin C preparation 0.15, Sodium dodecylbenzene sulfonate 9, water is appropriate, rare-earth mineral material 0.4.
Take attapulgite as the slow-release fertilizer dedicated preparation method of the paddy rice of matrix, comprise the following steps:
Sodium lignosulfonate, Coconut Fatty Acid Monoethanolamide sulfosuccinic acid monoesters two is soluble in water, after dissolving completely, add attapulgite, stir into suspension liquid, by urea, diammonium phosphate, potassium sulfate, fertilizer additive, add and wherein fully stir 20-30 minute, then add after in bamboo charcoal powder, trimeric cyanamide, polyvinyl alcohol, High hydrophilous resin and formula remaining component fully mixes thoroughly successively, granulation.
Comparative example
The common urea of nutrient content 46%, total nutrient content is the Repone K composite fertilizer of 45%.
The present embodiment and comparative example effect as follows:
For examination rice varieties: rich two excellent No. 6, Soil-rice soil, paddy rice of the present invention is slow-release fertilizer dedicated disposablely before rice transplanting to be applied, in comparative example, application process is divided base manure by peasant's ordinary method and topdresses, by the fertilizer amount of per hectare 500kg Repone K composite fertilizer and 550kg urea, composite fertilizer spreads fertilizer over the fields after rice terrace is turned over, and mixing with soil, urea spreads fertilizer over the fields at twice, spreads fertilizer over the fields in soil surface respectively after turning green and when young fringe is formed.The dedicated fertilizer amount ratio comparative example total amount of embodiment reduces 20%.Effect is as shown in the following chart:

Claims (3)

1. one kind is that the paddy rice of matrix is slow-release fertilizer dedicated with attapulgite, it is characterized in that, make with the raw material of following weight part: attapulgite 60-80, bamboo charcoal powder 10-20, trimeric cyanamide 10-15, polyvinyl alcohol 4-6, urea 10-12, diammonium phosphate 50-60, potassium sulfate 80-90, sodium lignosulfonate 6-8, turps 1-2, weedicide 3-4, Coconut Fatty Acid Monoethanolamide sulfosuccinic acid monoesters two 2-4, High hydrophilous resin 3-4, fertilizer additive 10-15
Described fertilizer additive is made up of following parts by weight of component raw material: zeolite powder 10-20, corn cob meal 30-40, the fertilizer 10-15 become thoroughly decomposed, polyvinyl alcohol 10-15, bamboo fibers 6-8, diammonium phosphate 6-8, Repone K 4-6, zinc sulfate 0.3-0.5, manganous sulfate 0.1-0.3, polyglutamic acid 1-2, nitrification inhibitor 4-6, Flower of Royal Paulownia 4-5, radix aconiti agrestis 6-7, mentha leave 4-6, betel nut 4-6, Fructus Cnidii 4-6, Rangooncreeper Fruit 4-6, wormwood 4-6, Cortex erythrinae 4-6, Herba Siegesbeckiae 4-6, Fructus Solani melongenae root 4-6, Leaf of Camphortree 4-6, insect protected chrysanthemum 4-6, Chinese prickly ash 4-6, Vegetable Sponge of Luffa 4-6, gamma-polyglutamic acid-0.02-0.04, 80% mancozeb wettable powder 0.1-0.3, concentration is 0.01-0.02% paclobutrazol solution 2-4, concentration is 0.01-0.02% amine DA-6 DA-6 solution 1-2, concentration is 0.01-0.02% sodium nitrophenolate solution 2-3, Vitamin C preparation 0.1-0.2, Sodium dodecylbenzene sulfonate 8-10, water is appropriate, rare-earth mineral material 0.2-0.6,
The preparation method of fertilizer additive:
(1) by formula rate, Sodium dodecylbenzene sulfonate is dissolved in water, then diammonium phosphate, Repone K, the fertilizer become thoroughly decomposed, zinc sulfate, manganous sulfate, polyglutamic acid, nitrification inhibitor is added wherein, fully stir;
(2), after all the other medicinal herb componentses such as Flower of Royal Paulownia, radix aconiti agrestis, mentha leave, betel nut, Fructus Cnidii being pulverized, with the alcohol-pickled 10-12 hour of 70%, then soak solution and the dregs of a decoction are joined in the material of step (1) together and mix;
(3) gamma-polyglutamic acid-, mancozeb wettable powder and zeolite powder are mixed, sodium nitrophenolate solution, amine DA-6 DA-6 solution, naphthalene acid solution are joined in corn cob meal and fully mix thoroughly, even with the mixing of materials of step (2) together, finally add polyvinyl alcohol, bamboo fibers, Deng all the other compositions, granulation after abundant mixing.
2. according to claim 1 is that the paddy rice of matrix is slow-release fertilizer dedicated with attapulgite, it is characterized in that, be made up of following mass parts raw material: attapulgite 72, bamboo charcoal powder 17, trimeric cyanamide 13, polyvinyl alcohol 5, urea 11, diammonium phosphate 57, potassium sulfate 85, sodium lignosulfonate 7, turps 23, weedicide 3, Coconut Fatty Acid Monoethanolamide sulfosuccinic acid monoesters 23, High hydrophilous resin 4, fertilizer additive 14
Described fertilizer additive is made up of following parts by weight of component raw material: zeolite powder 16, corn cob meal 36, the fertilizer 13 become thoroughly decomposed, polyvinyl alcohol 14, bamboo fibers 7, diammonium phosphate 7, Repone K 5, zinc sulfate 0.4, manganous sulfate 0.2, polyglutamic acid 2, nitrification inhibitor 5, Flower of Royal Paulownia 4.5, radix aconiti agrestis 6.5, mentha leave 5, betel nut 5, Fructus Cnidii 5, Rangooncreeper Fruit 5, wormwood 5, Cortex erythrinae 5, Herba Siegesbeckiae 5, Fructus Solani melongenae root 5, Leaf of Camphortree 5, insect protected chrysanthemum 5, Chinese prickly ash 5, Vegetable Sponge of Luffa 5, gamma-polyglutamic acid-0.03, 80% mancozeb wettable powder 0.2, concentration is 0.02% paclobutrazol solution 3, concentration is 0.01% amine DA-6 DA-6 solution 1, concentration is 0.02% sodium nitrophenolate solution 2.5, Vitamin C preparation 0.15, Sodium dodecylbenzene sulfonate 9, water is appropriate, rare-earth mineral material 0.4.
3. as claimed in claim 1 take attapulgite as the slow-release fertilizer dedicated preparation method of the paddy rice of matrix, it is characterized in that, comprises the following steps:
Sodium lignosulfonate, Coconut Fatty Acid Monoethanolamide sulfosuccinic acid monoesters two is soluble in water, after dissolving completely, add attapulgite, stir into suspension liquid, by urea, diammonium phosphate, potassium sulfate, fertilizer additive, add and wherein fully stir 20-30 minute, then add after in bamboo charcoal powder, trimeric cyanamide, polyvinyl alcohol, High hydrophilous resin and formula remaining component fully mixes thoroughly successively, granulation.
CN201410503841.4A 2014-09-26 2014-09-26 Special slow-release fertilizer taking attapulgite as matrix for paddy rice and preparation method of special slow-release fertilizer Pending CN104311233A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105036880A (en) * 2015-06-18 2015-11-11 安徽徽普生物科技有限责任公司 Rice fertilizer slow-release additive
CN105272684A (en) * 2015-11-27 2016-01-27 安徽帝元生物科技有限公司 Efficient fertilizer containing biomass charcoal
CN106518354A (en) * 2016-10-27 2017-03-22 六安市振清生态农业有限公司 Nutrition organic matrix used for planting cephalotaxus sinensis
CN107201230A (en) * 2017-04-27 2017-09-26 广西棕海园林工程有限公司 Soil moisturizing agent
CN107347916A (en) * 2017-07-26 2017-11-17 安徽省圣丹生物化工有限公司 A kind of weeding composite for avoiding soil hardening
CN107372536A (en) * 2017-07-26 2017-11-24 安徽省圣丹生物化工有限公司 A kind of weeding composite with superior sustained-release performance
CN107410359A (en) * 2017-07-26 2017-12-01 安徽省圣丹生物化工有限公司 A kind of weeding composite that can adjust soil
CN107439538A (en) * 2017-07-26 2017-12-08 安徽省圣丹生物化工有限公司 A kind of efficient weeding composite of high slow release
CN109122258A (en) * 2018-08-10 2019-01-04 安徽省三分地农业发展有限公司 A kind of preparation method of Selenium-enriched radish shoot vegetable

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CN103497046A (en) * 2013-08-29 2014-01-08 合肥市潜溪山庄农业生态园有限公司 Chinese medical stone boron calcium potassium fertilizer and preparation method thereof
CN103497069A (en) * 2013-08-29 2014-01-08 合肥市潜溪山庄农业生态园有限公司 Slow-release urea compound fertilizer and its preparation method
CN103641649A (en) * 2013-11-06 2014-03-19 马鞍山科邦生态肥有限公司 A fertilizer with magnetic effects and a preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN103497046A (en) * 2013-08-29 2014-01-08 合肥市潜溪山庄农业生态园有限公司 Chinese medical stone boron calcium potassium fertilizer and preparation method thereof
CN103497069A (en) * 2013-08-29 2014-01-08 合肥市潜溪山庄农业生态园有限公司 Slow-release urea compound fertilizer and its preparation method
CN103641649A (en) * 2013-11-06 2014-03-19 马鞍山科邦生态肥有限公司 A fertilizer with magnetic effects and a preparation method thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105036880A (en) * 2015-06-18 2015-11-11 安徽徽普生物科技有限责任公司 Rice fertilizer slow-release additive
CN105272684A (en) * 2015-11-27 2016-01-27 安徽帝元生物科技有限公司 Efficient fertilizer containing biomass charcoal
CN106518354A (en) * 2016-10-27 2017-03-22 六安市振清生态农业有限公司 Nutrition organic matrix used for planting cephalotaxus sinensis
CN107201230A (en) * 2017-04-27 2017-09-26 广西棕海园林工程有限公司 Soil moisturizing agent
CN107347916A (en) * 2017-07-26 2017-11-17 安徽省圣丹生物化工有限公司 A kind of weeding composite for avoiding soil hardening
CN107372536A (en) * 2017-07-26 2017-11-24 安徽省圣丹生物化工有限公司 A kind of weeding composite with superior sustained-release performance
CN107410359A (en) * 2017-07-26 2017-12-01 安徽省圣丹生物化工有限公司 A kind of weeding composite that can adjust soil
CN107439538A (en) * 2017-07-26 2017-12-08 安徽省圣丹生物化工有限公司 A kind of efficient weeding composite of high slow release
CN109122258A (en) * 2018-08-10 2019-01-04 安徽省三分地农业发展有限公司 A kind of preparation method of Selenium-enriched radish shoot vegetable

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Application publication date: 20150128