CN104294400A - Cotton fibers with antibacterial anti-mite effects and manufacturing method thereof - Google Patents

Abstract

The invention discloses cotton fibers with antibacterial anti-mite effects. The cotton fibers are characterized by being prepared from the following raw materials in parts by weight: 17-23 parts of cotton fibers, 8-9 parts of soft silk fibers, 7-12 parts of silk fibroin, 5-7 parts of high-shrinkage polyester fiber, 6-10 parts of mulberry fibers, 4-7 parts of densefruit pittany root-bark extract, 1.1-3.1 parts of nanometer zirconia powder, 1-3 parts of diatomite, 6-8 parts of polyvinyl alcohol, 2.1-4.3 parts of fatty acid amide sodium sulfonate, 18-22 parts of alkylphenol ethoxylates, 2-3 parts of mint, 3-4 parts of sweet-scented osmanthus, 100-110 parts of 1-ethyl-3-methylimidazole diethyl phosphate, 105-110 parts of 1-butyl-3-methylimidazole acetate, 3-6 parts of aids and a proper amount of water. The densefruit pittany root-bark extract is added into the raw materials by utilizing ultrasonic technology means, the mint, sweet-scented osmanthus and other active ingredients are added, the prepared cotton fibers have the advantages of antibiosis, mite resistance, lightness, softness, flame retardant property and heat retention property, and the cotton fabrics prepared by the cotton fibers prepared by the invention have the effects of dispelling the wind and detoxifying.

Description

A kind of have cotton fiber of antibiosis anti-acarien effect and preparation method thereof

Technical field

The present invention relates to textile material technical field, be specifically related to a kind of to there is cotton fiber of antibiosis anti-acarien effect and preparation method thereof.

Background technology

Cotton fiber is fiber coating on the seed of Malvaceae cotton, and also known as cotton, being called for short cotton, is the main raw material of China's textile industry.The moisture absorption of cotton fiber goods and good permeability, wear-resisting washable, soft and warming, wear warmth retention property winter good, dress in summer is ventilative nice and cool, is widely used in garment material, drapery.

But cotton fiber makes it apply to be restricted because it exists many defects in the prior art.Such as cotton fiber goods are subject to microbial action, are easily corroded by bacterium, mould, and antibacterial and mouldproof effect is not remarkable; The anti-uv-ray of cotton fiber own is poor, makes it make summer clothes and skin chromogenesis precipitation can be caused even to cause cutaneum carcinoma; Cotton fiber flame retardant effect is poor, and the disaster hidden-trouble caused thus is in rising trend.For overcoming the deficiencies in the prior art, be necessary natural cotton fiber in addition modification, thus be obtainedly applicable to the cotton fiber with functions such as cost low, function diversification, fire-retardant, intensity high, sterilization uvioresistant, radiation proofs of modern for the different demands of cotton fiber goods.

Summary of the invention

Object of the present invention is just to provide a kind ofly has cotton fiber of antibiosis anti-acarien effect and preparation method thereof, to overcome the deficiencies in the prior art.

The object of the present invention is achieved like this:

A kind of cotton fiber with antibiosis anti-acarien effect, it is characterized in that, be made up of the raw material of following weight portion: cotton fiber 17-23, soft silk fiber 8-9, fibroin fiber 7-12, high-shrinkage polyster 5-7, mulberry fibre 6-10, Cortex Dictamni extract 4-7, nano oxidized zirconium powder 1.1-3.1, diatomite 1-3, polyvinyl alcohol 6-8, fatty acid amide sodium sulfonate 2.1-4.3, alkylphenol polyoxyethylene 18-22, peppermint 2-3, sweet osmanthus 3-4, 1-ethyl-3-methylimidazole diethyl phosphate 100-110, 1-butyl-3-N-Methylimidazoleacetic salt 105-110, auxiliary agent 3-6, suitable quantity of water.

Described auxiliary agent is made up of following raw materials in part by weight: bleeding agent OE-35 1-3, lemon 2-5, butyl 10-13, diepoxy triethylene glycol glycidol ether 8-10, thymol 4-6, chitosan 1.2-2.2, nanoscale Tourmaline 3-5, Tea Saponin 0.5-0.8, dimethyl silicone polymer two quaternary amine 4.5-6.5, its preparation method is by the swelling 2-3 hour of nanoscale Tourmaline room temperature in distilled water, form suspension, then butyl, diepoxy triethylene glycol glycidol ether, thymol, dimethyl silicone polymer two quaternary amine mix and blend is also warming up to 140-160 DEG C of stirring 1-2 hour, join in above-mentioned suspension and stir 30-40 minute, add other residual componentss again strong agitation 2-3 hour and get final product.

Described a kind of preparation method with the cotton fiber of antibiosis anti-acarien effect, is characterized in that comprising the following steps:

(1) get peppermint, sweet osmanthus puts into hot water and soak filtration in 6-8 hour, cotton fiber, soft silk fiber, fibroin fiber, high-shrinkage polyster, mulberry fibre immersion 7-10 hour is added in filtrate, filtering drying, sprays into Cortex Dictamni extract, nano oxidized zirconium powder sonic oscillation grinding 1-2 hour;

(2) by diatomite high-temperature calcination 30-40 minute, add polyvinyl alcohol, fatty acid amide sodium sulfonate adds water and grind spraying dry after 30-50 minute together, add alkylphenol polyoxyethylene and stir and evenly mix;

(3) step (1) product is dipped in step (2) and adopts two leaching two roll process, then steam treatment 5-10 minute, also dewatered drying adds 1-ethyl-3-methylimidazole diethyl phosphate, 1-butyl-3-N-Methylimidazoleacetic salt stirs 20-40 minute in cleaning, be heated to 90-100 DEG C, add other residual components again and stir 40-60 minute, obtained spinning solution is through spinning, winding, boundling, stretching and get final product.

The present invention has following beneficial effect: the present invention prepares simple to operation, and cost is low; Ultrasonic technology means are utilized by Cortex Dictamni extract to add in raw material, also added peppermint, sweet osmanthus and other active ingredient, obtained cotton fiber has the advantages such as antibiosis anti-acarien, light and handy softness, fire-retardant warmth retention property be good, also has the detoxicating functions that dispels the wind with the cotton goods that the present invention obtains.

Detailed description of the invention

Described a kind of cotton fiber with antibiosis anti-acarien effect, it is characterized in that, be made up of the raw material of following weight portion: cotton fiber 18, soft silk fiber 9, fibroin fiber 7, high-shrinkage polyster 6, mulberry fibre 8, Cortex Dictamni extract 5, nano oxidized zirconium powder 2.1, diatomite 1, polyvinyl alcohol 6, fatty acid amide sodium sulfonate 3.4, alkylphenol polyoxyethylene 22, peppermint 2, sweet osmanthus 4,1-ethyl-3-methylimidazole diethyl phosphate 100,1-butyl-3-N-Methylimidazoleacetic salt 105, auxiliary agent 4, suitable quantity of water.

Described auxiliary agent is made up of following raw materials in part by weight: bleeding agent OE-35 1, lemon 3, butyl 12, diepoxy triethylene glycol glycidol ether 9, thymol 5, chitosan 1.8, nanoscale Tourmaline 4, Tea Saponin 0.6, dimethyl silicone polymer two quaternary amine 4.9, its preparation method is by the swelling 2-3 hour of nanoscale Tourmaline room temperature in distilled water, form suspension, then butyl, diepoxy triethylene glycol glycidol ether, thymol, dimethyl silicone polymer two quaternary amine mix and blend is also warming up to 140-160 DEG C of stirring 1-2 hour, join in above-mentioned suspension and stir 30-40 minute, add other residual componentss again strong agitation 2-3 hour and get final product.

Preparation method comprises the following steps:

(1) get peppermint, sweet osmanthus puts into hot water and soak filtration in 6-8 hour, cotton fiber, soft silk fiber, fibroin fiber, high-shrinkage polyster, mulberry fibre immersion 7-10 hour is added in filtrate, filtering drying, sprays into Cortex Dictamni extract, nano oxidized zirconium powder sonic oscillation grinding 1-2 hour;

(2) by diatomite high-temperature calcination 30-40 minute, add polyvinyl alcohol, fatty acid amide sodium sulfonate adds water and grind spraying dry after 30-50 minute together, add alkylphenol polyoxyethylene and stir and evenly mix;

(3) step (1) product is dipped in step (2) and adopts two leaching two roll process, then steam treatment 5-10 minute, also dewatered drying adds 1-ethyl-3-methylimidazole diethyl phosphate, 1-butyl-3-N-Methylimidazoleacetic salt stirs 20-40 minute in cleaning, be heated to 90-100 DEG C, add other residual components again and stir 40-60 minute, obtained spinning solution is through spinning, winding, boundling, stretching and get final product.

The technical parameter index of the cotton fiber using the present invention to produce is as follows:

(1) pliability is fluffy smooth flexible, and intensity is high, flame retardant effect is excellent;

(2) bacteriostasis rate of finished product to Escherichia coli, staphylococcus aureus, Candida albicans is all greater than 99.5%.

Claims (2)

1. one kind has the cotton fiber of antibiosis anti-acarien effect, it is characterized in that, be made up of the raw material of following weight portion: cotton fiber 17-23, soft silk fiber 8-9, fibroin fiber 7-12, high-shrinkage polyster 5-7, mulberry fibre 6-10, Cortex Dictamni extract 4-7, nano oxidized zirconium powder 1.1-3.1, diatomite 1-3, polyvinyl alcohol 6-8, fatty acid amide sodium sulfonate 2.1-4.3, alkylphenol polyoxyethylene 18-22, peppermint 2-3, sweet osmanthus 3-4, 1-ethyl-3-methylimidazole diethyl phosphate 100-110, 1-butyl-3-N-Methylimidazoleacetic salt 105-110, auxiliary agent 3-6, suitable quantity of water, described auxiliary agent is made up of following raw materials in part by weight: bleeding agent OE-35 1-3, lemon 2-5, butyl 10-13, diepoxy triethylene glycol glycidol ether 8-10, thymol 4-6, chitosan 1.2-2.2, nanoscale Tourmaline 3-5, Tea Saponin 0.5-0.8, dimethyl silicone polymer two quaternary amine 4.5-6.5, its preparation method is by the swelling 2-3 hour of nanoscale Tourmaline room temperature in distilled water, form suspension, then butyl, diepoxy triethylene glycol glycidol ether, thymol, dimethyl silicone polymer two quaternary amine mix and blend is also warming up to 140-160 DEG C of stirring 1-2 hour, join in above-mentioned suspension and stir 30-40 minute, add other residual componentss again strong agitation 2-3 hour and get final product.

2. a kind of preparation method with the cotton fiber of antibiosis anti-acarien effect according to claim 1, is characterized in that comprising the following steps:

(1) get peppermint, sweet osmanthus puts into hot water and soak filtration in 6-8 hour, cotton fiber, soft silk fiber, fibroin fiber, high-shrinkage polyster, mulberry fibre immersion 7-10 hour is added in filtrate, filtering drying, sprays into Cortex Dictamni extract, nano oxidized zirconium powder sonic oscillation grinding 1-2 hour;

(2) by diatomite high-temperature calcination 30-40 minute, add polyvinyl alcohol, fatty acid amide sodium sulfonate adds water and grind spraying dry after 30-50 minute together, add alkylphenol polyoxyethylene and stir and evenly mix;

(3) step (1) product is dipped in step (2) and adopts two leaching two roll process, then steam treatment 5-10 minute, also dewatered drying adds 1-ethyl-3-methylimidazole diethyl phosphate, 1-butyl-3-N-Methylimidazoleacetic salt stirs 20-40 minute in cleaning, be heated to 90-100 DEG C, add other residual components again and stir 40-60 minute, obtained spinning solution is through spinning, winding, boundling, stretching and get final product.